CH 13
CH 13
1. Properties of Polymer Melts 2. Extrusion 3. Production of Sheet, Film, and Filaments 4. Coating Processes 5. Injection Molding 6. Other Molding Processes 7. Thermoforming 8. Casting 9. Polymer Foam Processing and Forming 10. Product Design Considerations
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Plastic Products
Plastics can be shaped into a wide variety of products: Molded parts Extruded sections Films Sheets Insulation coatings on electrical wires Fibers for textiles
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Polymer Melts
To shape a thermoplastic polymer it must be heated so that it softens to the consistency of a liquid In this form, it is called a polymer melt Important properties of polymer melts: Viscosity Viscoelasticity
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Figure 13.1 Viscosity relationships for Newtonian fluid and typical polymer melt.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Figure 13.2 Viscosity as a function of temperature for selected polymers at a shear rate of 103 s-1.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Viscoelasticity
Combination of viscosity and elasticity Possessed by both polymer solids and polymer melts Example: die swell in extrusion, in which the hot plastic expands when exiting the die opening
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Die Swell
Extruded polymer "remembers" its previous shape when in the larger cross section of the extruder, tries to return to it after leaving the die orifice
Figure 13.3 Die swell, a manifestation of viscoelasticity in polymer melts, as depicted here on exiting an extrusion die.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Extrusion
Compression process in which material is forced to flow through a die orifice to provide long continuous product whose cross-sectional shape is determined by the shape of the orifice Widely used for thermoplastics and elastomers to mass produce items such as tubing, pipes, hose, structural shapes, sheet and film, continuous filaments, and coated electrical wire Carried out as a continuous process; extrudate is then cut into desired lengths
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Extruder
Figure 13.4 Components and features of a (single-screw) extruder for plastics and elastomers
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Extruder Barrel
Internal diameter typically ranges from 25 to 150 mm (1.0 to 6.0 in.) L/D ratios usually between 10 and 30: higher ratios for thermoplastics, lower ratios for elastomers Feedstock fed by gravity onto screw whose rotation moves material through barrel Electric heaters melt feedstock; subsequent mixing and mechanical working adds heat which maintains the melt
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Extruder Screw
Divided into sections to serve several functions: Feed section - feedstock is moved from hopper and preheated Compression section - polymer is transformed into fluid, air mixed with pellets is extracted from melt, and material is compressed Metering section - melt is homogenized and sufficient pressure developed to pump it through die opening
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Extruder Screw
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Hollow Profiles
Examples: tubes, pipes, hoses, and other cross-sections containing holes Hollow profiles require mandrel to form the shape Mandrel held in place using a spider Polymer melt flows around legs supporting the mandrel to reunite into a monolithic tube wall Mandrel often includes an air channel through which air is blown to maintain hollow form of extrudate during hardening
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Figure 13.11 Side view cross-section of die for coating of electrical wire by extrusion.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Figure 13.14 Wiley & Sons, Inc. M P Groover, Fundamentals ofsheet & film. 2007 John A die configurations for extruding Modern Manufacturing 3/e
Figure 13.16 Blown-film process for high production of thin tubular film.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Calendering
Feedstock is passed through a series of rolls to reduce thickness to desired gage Expensive equipment, high production rates Process is noted for good surface finish and high gage accuracy Typical materials: rubber or rubbery thermoplastics such as plasticized PVC Products: PVC floor covering, shower curtains, vinyl table cloths, pool liners, and inflatable boats and toys
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Melt Spinning
Starting polymer is heated to molten state and pumped through spinneret Typical spinneret is 6 mm (0.25 in) thick and contains approximately 50 holes of diameter 0.25 mm (0.010 in) Filaments are drawn and air cooled before being spooled onto bobbin Significant extension and thinning of filaments occur while polymer is still molten, so final diameter wound onto bobbin may be only 1/10 of extruded size Used for polyester and nylon filaments
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Melt Spinning
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Dry Spinning
Similar to melt spinning, but starting polymer is in solution and solvent can be separated by evaporation First step is extrusion through spinneret Extrudate is pulled through a heated chamber which removes the solvent, leaving the polymer Used for filaments of cellulose acetate and acrylics
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Wet Spinning
Similar to melt spinning, but polymer is again in solution, only solvent is non-volatile To separate polymer, extrudate is passed through a liquid chemical that coagulates or precipitates the polymer into coherent strands which are then collected onto bobbins Used to produce filaments of rayon (regenerated cellulose)
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Injection Molding
Polymer is heated to a highly plastic state and forced to flow under high pressure into a mold cavity where it solidifies and the molding is then removed from cavity Produces discrete components almost always to net shape Typical cycle time 10 to 30 sec, but cycles of one minute or more are not uncommon Mold may contain multiple cavities, so multiple moldings are produced each cycle
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Figure 13.22 Typical molding cycle: (2) melt is injected into cavity.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Figure 13.22 Typical molding cycle: (4) mold opens and part is ejected.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
The Mold
The special tool in injection molding Custom-designed and fabricated for the part to be produced When production run is finished, the mold is replaced with a new mold for the next part Various types of mold for injection molding: Two-plate mold Three-plate mold Hot-runner mold
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Two-Plate Mold
Figure 13.23 Details of a two-plate mold for thermoplastic injection molding: (a) closed. Mold has two cavities to produce two cup-shaped parts with each injection shot.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Two-Plate Mold
Figure 13.23 Details of a two-plate mold for thermoplastic injection molding: (b) open
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Three-Plate Mold
Uses three plates to separate parts from sprue and runner when mold opens Advantages over two-plate mold: As mold opens, runner and parts disconnect and drop into two containers under mold Allows automatic operation of molding machine
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Hot-Runner Mold
Eliminates solidification of sprue and runner by locating heaters around the corresponding runner channels While plastic in mold cavity solidifies, material in sprue and runner channels remains molten, ready to be injected into cavity in next cycle Advantage: Saves material that otherwise would be scrap in the unit operation
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Shrinkage
Reduction in linear size during cooling from molding to room temperature Polymers have high thermal expansion coefficients, so significant shrinkage occurs during solidification and cooling in mold Typical shrinkage values:
Plastic Nylon-6,6 Polyethylene Polystyrene PVC Shrinkage, mm/mm (in/in) 0.020 0.025 0.004 0.005
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Shrinkage Factors
Fillers in the plastic tend to reduce shrinkage Injection pressure higher pressures force more material into mold cavity to reduce shrinkage Compaction time - similar effect longer time forces more material into cavity to reduce shrinkage Molding temperature - higher temperatures lower polymer melt viscosity, allowing more material to be packed into mold to reduce shrinkage
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
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2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Compression Molding
A widely used molding process for thermosetting plastics Also used for rubber tires and polymer matrix composite parts Molding compound available in several forms: powders or pellets, liquid, or preform Amount of charge must be precisely controlled to obtain repeatable consistency in the molded product
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Compression Molding
Figure 13.28 Compression molding for thermosetting plastics: (1) charge is loaded, (2) and (3) charge is compressed and cured, and (4) part is ejected and removed.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Compression Molding
Molding materials: Phenolics, melamine, urea-formaldehyde, epoxies, urethanes, and elastomers Typical compression-molded products: Electric plugs, sockets, and housings; pot handles, and dinnerware plates
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2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Transfer Molding
TS charge is loaded into a chamber immediately ahead of mold cavity, where it is heated; pressure is then applied to force soft polymer to flow into heated mold where it cures Two variants: Pot transfer molding - charge is injected from a "pot" through a vertical sprue channel into cavity Plunger transfer molding plunger injects charge from a heated well through channels into cavity
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Blow Molding
Molding process in which air pressure is used to inflate soft plastic into a mold cavity Important for making one-piece hollow plastic parts with thin walls, such as bottles Because these items are used for consumer beverages in mass markets, production is typically organized for very high quantities Accomplished in two steps:
1. Fabrication of a starting tube, called a parison 2. Inflation of the tube to desired final shape
Forming the parison is accomplished by either
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Figure 13.33 Stretch blow molding: (1) injection molding of parison; (2) stretching; and (3) blowing.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Thermoforming
Flat thermoplastic sheet or film is heated and deformed into desired shape using a mold Heating usually accomplished by radiant electric heaters located on one or both sides of starting plastic sheet or film Widely used in packaging of products and to fabricate large items such as bathtubs, contoured skylights, and internal door liners for refrigerators
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Vacuum Thermoforming
Figure 13.35 Vacuum thermoforming: (1) a flat plastic sheet is softened by heating Figure 13.35 Vacuum thermoforming: (2) the softened sheet is placed over&a concaveGroover, Fundamentals of Modern Manufacturing 3/e 2007 John Wiley Sons, Inc. M P mold cavity
Vacuum Thermoforming
Figure 13.35 Vacuum thermoforming: (3) a vacuum draws the sheet into the cavity Figure 13.35 (4) plastic hardens on contact with the cold mold surface, and the part is removed and subsequently trimmed from the web.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Vacuum Thermoforming
Figure 13.37 Use of a positive mold in vacuum thermoforming: (1) the heated plastic sheet is positioned above the convex mold Figure 13.37 Use of a positive mold in vacuum thermoforming: (2) the clamp is lowered into position, draping the sheet over the mold as a vacuum forces the sheet against the mold surface
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Applications of Thermoforming
Thin films: blister packs and skin packs for packaging commodity products such as cosmetics, toiletries, small tools, and fasteners (nails, screws, etc.) For best efficiency, filling process to containerize item(s) is immediately downstream from thermoforming Thicker sheet stock: boat hulls, shower stalls, advertising displays and signs, bathtubs, certain toys, contoured skylights, internal door liners for refrigerators
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Casting
Pouring liquid resin into a mold, using gravity to fill cavity, where polymer hardens Both thermoplastics and thermosets are cast Thermoplastics: acrylics, polystyrene, polyamides (nylons) and PVC Thermosetting polymers: polyurethane, unsaturated polyesters, phenolics, and epoxies Simpler mold Suited to low quantities
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Polymer Foam
A polymer-and-gas mixture that gives the material a porous or cellular structure Most common polymer foams: polystyrene (Styrofoam, a trademark), polyurethane Other polymers: natural rubber ("foamed rubber") and polyvinylchloride (PVC)
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e www.bioceramics.uni-bremen.de/research/research_scaffolds.htm
Figure 13.40 John Wiley & Sons, Inc. M P structures: (a) closed cell and (b) open cell. 2007 Two polymer foam Groover, Fundamentals of Modern Manufacturing 3/e
Figure 13.40 Two polymer foam structures: (a) closed cell and (b) open cell.
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Molding material consists of prefoamed polystyrene beads Beads are fed into mold cavity where they are further expanded and fused together to form the molded product
Products: hot beverage cups,
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2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Capacity of plastics to absorb impact is generally good; plastics compare favorably with most metals
Service temperatures
Dimensional changes due to temperature changes much more significant than for metals
Many plastics are subject to degradation from sunlight and other forms of radiation Some plastics degrade in oxygen and ozone atmospheres Plastics are soluble in many common solvents Plastics are resistant to conventional corrosion mechanisms that afflict many metals
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
Uniform wall thickness is desirable in an extruded cross section Variations in wall thickness result in non-uniform plastic flow and uneven cooling which tend to warp extrudate
Hollow sections
Hollow sections complicate die design and plastic flow Desirable to use extruded cross-sections that are not hollow yet satisfy functional requirements
Corners
Sharp corners, inside and outside, should be avoided in extruded cross sections They result in uneven flow during processing and stress concentrations in the final product
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e
2007 John Wiley & Sons, Inc. M P Groover, Fundamentals of Modern Manufacturing 3/e