Ionic Bonding
CA Standards
Students know atoms combine
to form molecules by sharing
electrons to form covalent or
metallic bonds or by exchanging
electrons to form ionic bonds.
Students know salt crystals,
such as NaCl, are repeating
patterns of positive and
negative ions held together by
electrostatic attraction.
Bonds
Forces that hold groups of
atoms
together and make them
function
Ionic bonds – transfer of
as a unit.
electrons
Covalent bonds – sharing
of electrons
The Octet Rule – Ionic
Compounds
Ionic compounds form so that each atom,
by gaining or losing electrons, has an
octet of electrons in its highest occupied
energy level.
Metals lose electrons to form positively-
charged cations
Nonmetals gains electrons to form
negatively-charged anions
Ionic Bonding:
The Formation of Sodium
Chloride
Sodium has 1 valence electron
Chlorine has 7 valence electrons
An electron transferred gives
each an octet
Na: 1s22s22p63s1
Cl: 1s22s22p63s23p5
Ionic Bonding:
The Formation of Sodium
Chloride
This transfer forms ions, each
with an octet:
Na+ 1s22s22p6
Cl- 1s22s22p63s23p6
Ionic Bonding:
The Formation of Sodium
Chloride
The resulting ions come
together due to electrostatic
attraction
(opposites attract):
Cl-
Na+
The net charge on the
compound must equal zero
Examples of Ionic
compounds
Mg2+Cl-2 Magnesium chloride:
Magnesium loses two electrons
and each chlorine gains one
electron
Na+2O2- Sodium oxide: Each sodium
loses one electron and the
oxygen gains two electrons
Al3+2S2-3 Aluminum sulfide: Each
aluminum loses two electrons
(six total) and each sulfur
gains two electrons (six total)
Metal Monatomi Ion name
c
Cations
Lithium Li+ Lithium
Sodium Na+ Sodium
Potassium K+ Potassium
Magnesium Mg2+ Magnesiu
m
Calcium Ca2+ Calcium
Barium Ba2+ Barium
Aluminum Al3+ Aluminum
Nonmetal Monatomic Ion Name
Anions
Fluorine F- Fluoride
Chlorine Cl- Chloride
Bromine Br- Bromide
Iodine I- Iodide
Oxygen O2- Oxide
Sulfur S2- Sulfide
Nitrogen N3- Nitride
Phosphorus P3- Phosphide
Sodium Chloride Crystal Lattice
Ionic compounds form
solid crystals at
ordinary
temperatures.
Ionic compounds
organize in a
characteristic crystal
lattice of alternating
positive and negative
ions.
All salts are ionic compounds and form
crystals.
Properties of Ionic
Compounds
Structure: Crystalline solids
Melting Generally high
point:
Boiling Generally high
Point:
Electrical Excellent conductors,
Conductivi molten and aqueous
ty:
Solubility in Generally soluble
water: