Oxidation Number: Explanation
and Practice
Chemistry Lesson - Understanding
Oxidation States
What is an Oxidation Number?
• • The oxidation number (or oxidation state)
represents the charge an atom would have if
electrons were completely transferred.
• • It is useful for tracking electron transfer in
redox reactions.
• • It follows specific rules for different
elements in compounds.
Rules for Assigning Oxidation
Numbers
• 1. Free elements (O₂, N₂, Fe) → 0
• 2. Monoatomic ions → Charge of ion (Na⁺ =
+1, Cl⁻ = -1)
• 3. Oxygen → Usually -2, except in peroxides (-
1) and with fluorine (+2)
• 4. Hydrogen → +1 (except in metal hydrides,
where it is -1)
• 5. Fluorine → Always -1
• 6. Sum in a neutral compound = 0; in a
polyatomic ion = ion charge
Examples of Oxidation Numbers
• • H₂SO₄: H = +1, O = -2, S = +6
• • KMnO₄: K = +1, Mn = +7, O = -2
• • Cr₂O₇²⁻: Cr = +6, O = -2
• • NH₄⁺: N = -3, H = +1
Oxidation and Reduction
• • Oxidation: Increase in oxidation number
(loss of electrons)
• • Reduction: Decrease in oxidation number
(gain of electrons)
• Example: Fe + Cl₂ → FeCl₃
• • Fe (0) → Fe³⁺ (+3) → Oxidation
• • Cl₂ (0) → Cl⁻ (-1) → Reduction
Practice Problems
• 1. Find the oxidation number of sulfur (S) in:
• a) H₂S b) SO₂ c) SO₄²⁻
• 2. Find the oxidation number of chromium (Cr)
in:
• a) Cr₂O₃ b) CrO₄²⁻ c) Cr₂O₇²⁻
• 3. Find the oxidation number of nitrogen (N)
in:
• a) NH₃ b) NO₂ c) NO₃⁻
• 4. Find the oxidation number of chlorine (Cl)