Diamond Coatings Customer Presentation
Diamond Coatings Customer Presentation
Hydraulic Pressure
Impeller
The Hole
Shaft
Hard Face Materials Timeline
Flowserve’s first recorded use of
Stellite as a face coating Pursuit of
Flowserve releases
API 682 1st Edition diamond coated
Durchrome coating
Mass production standardizes on RB SiC seal faces
Tungsten Carbide
of silicon carbide formula is refined Flowserve’s first use of Tungsten Flowserve’s first use of
powder and becomes Carbide DS SiC
suitable as a seal
Reaction bonded face material DS SiC pricing drops to
Silicon Carbide around RB SiC price
Flowserve’s first use of
produced Flowserve tests solid
Graphite Loaded SiC
Reaction Bonded SiC faces
Flowserve begins working with ANL ADT spins off ANL to Flowserve begins field trialing
on diamond coatings commercialize UNCD UNCD coated seal faces
Flowserve signs development Flowserve begins testing UNCD Flowserve signs agreement with
agreement with ANL coatings on seal faces ADT
What else does ADT do?
UNCD coatings provide benefits in a number of industries
• Electrochemical water treatment
• Journal bearings
• NaDiaProbes
– Solid UNCD ultra-fine probe tips
1
Our Agreement with Advanced Diamond Technologies
Positions Flowserve as the exclusive provider of UNCD seal faces
• Provides Flowserve unique access to UNCD for use on mechanical seal
faces
– UNCD’s ability to run opposite a seal face of any material is unique in the
marketplace
• Establishes an R&D collaboration effort with ADT to continue to advance
seal face technology
1
How Diamond Coatings are Applied
Coating type varies by manufacturing process. Process control is significant
• Flowserve uses HF-CVD (Hot Filament Chemical Vapor Deposition)
– 2000-2100°C (3600-3800°F) hot filaments positioned over substrate parts at
600-800°C (1100-1500°F) in a carbon-rich gas chamber grow diamond
grains on the substrate
– Diamond is grown from the seal face; chemistry bonds the diamond to the
substrate
1
Inside the Reactor
Reaction with methane gas liberates carbon atoms providing the building blocks of diamond
H H H
H H
H C H H H C H
H C H H
H H
H H
H
1
Flowserve Diamond Coating
Flowserve recommends Ultrananocrystalline diamond (UNCD®)
• UNCD formulation improves coating adhesion
– Flowserve setout to provide a coating with adhesion strength that would
exceeded the strength of the SiC substrate and to be able to prove it
During scratch testing, adhesion strength exceeded the limits of the testing equipment.
Tested to 6400 MPa (928 ksi); 2x the compressive strength of the SiC substrate
Competitor adhesion has not been tested to this extent
– Competitor testing with the pin-pull method proved adhesive strength up to 76-90 MPa
(11-13 ksi) for their product.
1
All scales shown represent 10 μm on that image
How Diamond Coatings Compare
Diamond coatings offer exceptional hardness
• Hardness is an indicator for resistance to three-body abrasion
• Hardness is an important property in applications containing abrasive
solids
1
How Diamond Coatings Compare
Diamond coatings offer extremely low friction
• Lower friction can equal lower wear
• Diamond exhibits low frictions when operating on either liquids or
gases
Average Coefficient of Friction in Deionized Water
0.12
0.1
0.08
0.06
Coefficient of Friction
0.04
0.02
0
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1
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How Diamond Coatings Compare
Diamond coatings offer extremely high thermal conductivity
• High thermal conductivity translates into consistent temperatures
across the seal faces
• Seal face temperatures are closer to the bulk fluid temperature
1
Wet-Dry-Wet Running Performance
UNCD coatings show significant increase in dry running life compared with SiC
vs. SiC faces
• UNCD vs. uncoated SiC provides short term dry running performance
similar to uncoated SiC vs. Carbon
30
Face Tempearture (Minutes)
25
20
15
10
0
SiC/SiC SiC/Carbon K30/SiC K10/Carbon K30/K30 Competitor
Diamond*
Face Material Combination
Temperature (°C)
Thermocouple failed at 182
373°F (33 seconds)
300
132
200
82
100 32
0 -18
23 23 0: 0: 0: 0: 0: 0: 0: 0: 0: 0: 0: 0: 0: 0: 0: 0: 0:
:5 :5 00 00 01 01 02 02 02 03 03 04 04 05 05 05 06 06 07
9 :2 9 :5 :1 :4 :0 :3 :0 :2 :5 :1 :4 :1 :3 :0 :2 :5 :2 :4 :1
5 1 7 3 9 5 0 6 2 8 4 0 6 2 8 4 0 6 2
250.0 482.0
432.0
200.0 382.0
332.0
Temperature (°C)
Temperature (°F)
150.0
282.0
232.0
100.0
182.0
50.0 132.0
82.0
0.0 32.0
23 0:0 0:0 0:0 0:0 0:0 0:0 0:0 0:0 0:0 0:0 0:0 0:1 0:1 0:1
:59 0:0 0:5 1:5 2:5 3:5 4:5 5:5 6:5 7:5 8:5 9:5 0:5 1:5 2:5
:00 0 9 9 9 9 9 9 9 9 9 9 9 9 9
2
Test Result – Partial Dry Running with Water
ISC2 1.875 dry run testing @ 4,800 rpm
• Enlarged bore seal chamber with residual water
• Maximum temperature reached after 90 minutes was just 85°C
(185°F)
– 108 times longer than SiC vs SiC under the same conditions @ 3,600 rpm
212 100
192 90
172 80
70
Temperature (°C)
Temperature (°F)
152
60
132
50
112
40
92
30
72 20
52 10
32 0
0:00 0:15 0:30 0:45 1:00 1:15 1:30
Time (hh:mm)
Flowserve UNCD vs Tunsten Carbide 2
Test Result – Partial Dry Running with Oil
ISC2 1.875 dry run testing @ 3,600 rpm
• Enlarged bore seal chamber with residual oil
• Average temperature reached after 90 minutes was just 103°C (217°F)
• Average temperature reached over 5 hours was 121°C (251°F)
500
245
450
225
400 205
Temperature (°C)
Temperature (°F)
185
350
165
300 145
250 125
105
200
85
150 65
0:00 0:15 0:30 0:45 1:00 1:15 1:30 1:45 2:00 2:15 2:30 2:45 3:00 3:15 3:30 3:45 4:00 4:15 4:30 4:45 5:00 5:15
Time (hh:mm)
2
Comparison of Wear Post Test
OD
Slight Buildup
ID
Severe Wear
Uncoated SiC
Uncoated SiC
2
Analysis of Face Condition Post Test
Radial surface taper & surface roughness
• Even wear on tungsten carbide vs UNCD
– The increase in measured radial taper on UNCD face was buildup not wear
– The increase in surface roughness on UNCD was from buildup and not wear
• Uneven wear on SiC faces evident by high radial taper changes
2
Test Results – Warm Water
This K30 diamond coated
ThisDiamond shows
SiC face was run clear benefits over traditional face materialsface ran in the same service
opposite another SiC face in for 4,000 hours with barely a
68°C (155°F) water for witness mark
200 hours
Severe
flashing
damage
2
Test Results – Hot Water
Eliminating Plan 21 or 23
• Test conditions
– 100 hours per material combination
– 150°C (300°F) Hot water, uncooled (Plan 11)
– 6.9 bar (100 psi )
– 3,600 rpm
– 35 mm (1.375 inch ) shaft
– QB series seal
• Test Combinations:
– UNCD vs UNCD
– UNCD vs SiC
– UNCD vs Carbon
– Carbon vs SiC
– QBU
2
Test Results – Hot Water
Control tests
• Carbon vs RB SiC with Plan 23
• QBU Carbon vs RB SiC with Plan 11
Results table
Carbon Carbon QBU UNCD vs UNCD vs UNCD vs
vs SiC vs SiC UNCD SiC Carbon
Plan 23 Plan 11 Plan 11 Plan 11 Plan 11 Plan 11
Overall Wear Low High Low Zero Medium Medium
Radial Taper High High Low Low Low Medium
Initial Leakage Zero Zero Zero 1 dpm 1 dph Zero
Steady State Leakage Zero Zero Zero Zero Zero Zero
3
Guidance on Using UNCD in Hot Water
Approved range without cooling
• Up to 355°F (180°C)
• Up to 3,600 rpm
• UNCD vs UNCD or UNCD vs SiC
• QB Series or ISC2 Series
Notes
• Either grade of SiC may be run against
UNCD
• Carbon may be used with UNCD with Enhanced images of seal face surfaces
from UNCD vs UNCD test – no wear
ATS approval
• UNCD may be used in hot water service with Plan 23 beyond the
stated ranges or seal types
3
Test Result - Entrained Gas
Material Combinations Tested:
• SiC vs SiC
• SiC vs Diamond
• WC vs Diamond
• Diamond vs
Diamond
15% air by volume
85% water by
volume
100 hour test
25.4 mm (1.000 inch) unbalanced seal @ 1,750 rpm
3
Entrained Gas
Simulates poorly vented vertical pump
3
Test Result - Entrained Gas
Diamond combinations ran an average of 37ºC (67ºF) cooler than SiC vs SiC
• Statically insignificant running temperature between the diamond
combinations
3
Field Result
Flashing hydrocarbon application at major US refinery
Uncoated SiC after running against UNCD diamond after running against
carbon carbon
Severe
flashing
damage
3
Target Applications
Providing solutions for challenging applications
• Low wear
– Intermittent dry running
loading and unloading applications
• High hardness
– Three-body abrasion on seal face running surface
Slurries
Silicon carbide scoring and binder pullout can be eliminated
• Reduced friction
– Low lubricity fluids
Hot water
Multiphase fluids
Gas entrainment
• USP Class VI tested and approved
– Food and pharmaceutical applications
3
Are Diamond Coatings Right for Your Application?
Consider diamond coated seal faces when you see seal face damage!
Is the Seal Face Running
Surface Damaged?
3
Target Applications
Seals available with diamond coated faces
• ISC2 / ISC2-682
• QB / QBQ / QBS / QBU
• UC / D
• UHTW / DHTW
• HSH
• BX Series
• SLC
• SLM
• RIS
4
General Application Range
Operating Parameters
Pressure: 0 to 140 BarG (0 to 2000 PSI)
Temperature: -40° to 204°C (0 to 400°F)
Speed: up to 46 m/s (150 fps)
Viscosity: 0.2 to 5,000 cP
Specific Gravity: 0.4 to 2.0
Sizes: 25.4 to 280 mm (1.000 to 11.000 inches)
These are not firm limits, the range of diamond coating experience continues to
increase
4
Application References
Over 250 unique Bills of Material already exist
Customers in every industry
• Dow
• DuPont
• Exxon
• Citgo
Chevron
• BP
4
Application List
Service Faces Seal Type Seal Size Pressure Temperature
Liquid Propane/Isobutane K30 Stator QBQW 2.375 209/301 95-105
Condensate (Water) K30 Stator Europac 50 mm 6.8-9 bar 30-160 C
Condensate (Water) K30 Rotor Europac 50 mm 6.8-9 bar 30-160 C
Liquid Propane/Isobutane K10 vs. Carbon QBQ 2.375 231 95-105
Propane Diamond Stator QBQW 3 215/245 110-125
Deionized Water K30 vs. SiC ISC2-PXW 1.75 40-150 75-90
LPG/Diesel/Gasoline Diamond Rotor HSHW 4 25-86 kg/cm^2 ?
LPG/Diesel/Gasoline Diamond Rotor HSHW 4 25-86 kg/cm^2 ?
Hydrocarbons K10 vs Carbon QBQW 2.125 278/315 100
Ground Bauxite & Caustic Liquor K30 vs. K30 SLC 5 2100 kPaG 87.9 C
Stripper Reflux K10 vs Carbon QBW 2.125 103 70
Caustic (NaOH) Liquor K30 vs K30 SLCW 1 <100kPa 59.1 C
Diluted Bitumen (Sales Oil) K30 vs SiC BX 2.125 0 - 136 174-650 (439 Norm)
Off Spec Vacuum Tower Bottoms K30 vs. SiC BRCSH 2.375 129.00 275-400
Sour Hydrocarbon/Water K30 vs. SiC PTO-EN 2.125 30-185 130
River water K30 vs. SiC ISC2-PXW 2.125 80 80
Caustic Soda K30 vs. K30 SlC 4 4.2-12.7 barG 85 C
6th Washer O/F, Solids K30 vs K30 SLCW 1 ? 59.1 C
Spent Liquor/Solids K30 vs K30 ISC 2 ? 90-100
Liquor Filtrate/Solids SLCW 1 486 kPaG 69 C
Caustic Concentration K30 vs K30 SLC 4 530 kPaG 85 C
Polyol K30 vs LV ISC2-PXW 1.75 45 266
Dowtherm A K30 vs SiC BXHW/BXHHW 5 12.5/36.6 304/401
Dowtherm A K30 vs SiC BXHW/BXHHW 5 12.5/36.7 304/402 4
Application List
Service Faces Seal Type Seal Size Pressure Temperature
Acetic Acid K30 vs Tungsten RO 1.375 15 220
Boiler Feed Water K10 vs Carbon DW 3.25 160 240
Caustic (NaOH) Liquor K30 vs K30 SLCW 1 <100kPa 59.1 C
CELLULOSIC SLURRY K30 vs Tungsten BXLSW 95mm 33 100
Clarifier Sludge Recirc K30 vs SiC ISC2-PXW 45mm 25 110
Clear Green Liquor Filtrate K30 vs K30 SLCW 4 105
CRUDE OIL K30 vs K30 HSHW 4.75 896.5 80
Digested Bauxite Residue K30 vs K30 SLC 4 76.9 85
Diluted Bitumen (Sales Oil) K30 vs SiC BX 2.125 19.7
DIMETHYLACETAMIDE (DMAC) K30 vs SiC ISC2-PP 1.875 15.5 360
AMMONIUM SULPHATE, AQUEOUS K30 vs SiC ISC2-BXW 1.875 54 240
Dowtherm A K30 vs SiC BXRH 3.125 20 550
Hydrocarbon Drain K30 vs SiC QBQW 2.5 271.7 55
Lime Slurry K30 vs SiC SLC 1 45 100
Polyol K30 vs Tungsten ISC1SX 1.75 12 266
Propane (Liquid) K10 vs Carbon QBQW 2.375 231 100
PROPANE, ETHANE K30 vs SiC QBQW 2 288 110
Propylene Glycol K30 vs Tungsten ISC2-PPW 1.75 100 266
Naphtha K30 vs SiC BX 2.125 285 110
Off Spec Vacuum Tower Bottoms K30 vs SiC BRCSH 2.375 15 275
Sour Hydrocarbon / Water K30 vs SiC PTO-EN 2.125 30 130
Waste Water K30 vs SiC QBQ 2.25 137.4 25
WET GYPSUM K30 vs SiC SLC 2
4
Diamond Coated Seal Face Inventory
Flowserve aims to make diamond coated faces easy to obtain
• The most common seals & sizes have been added to inventory in
Kalamazoo, Michigan
Seal Type ISC2 QB BX SLC SLM
Sizes 1.125-3.000 & 1.750-3.750 1.500-3.500 Groups 1-6 2.000, 2.625,
3.750 3.250, 3.937,
4.125, 5.375
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Pricing
Your solution options for poor lubricating services
• Example: Single ISC2 1.875” with SiC vs SiC faces and 11 month MTBF
Possible Solutions
Annual Costs UNCD Custom Seal Plan 32 Dual Seal No Change
First Cost $500 $2,000 $1,000 $1,000 for seal + $0
$1,000 for
auxiliary
Operating Cost Savings $0 $0.01/gallon 1 $0.005/gallon for Base
(Lower power gpm = $5,256 cooling water
Consumption)
$2,628
Maintenance $0 $0 $0 $30/gallon barrier $1,000 +
cost fluid, 12 gpy = down time
$360 + labor
Total Cost $500 $2,000 $6,256 >$5,000 $1,000
Lowest Cost
Option *Prices are relative 4
Pricing
Your solution options for poor lubricating services
• Example: Single ISC2 1.875” with SiC vs SiC faces and 11 month MTBF
Possible Solutions
Annual Costs UNCD Custom Seal Plan 32 Dual Seal No Change
First Cost €500 €2.000 €1.000 €1.000 for seal + €0
€1.000 for
auxiliary
Operating Cost Savings €0 €0.0025/L €0.001/L for Base
(Lower power 4 Lpm = €5.256 cooling water
Consumption)
€2.628
Maintenance €0 €0 €0 €10/L barrier fluid, €1.000 +
cost 48 Lpy = €480 + down time
labor
Total Cost €500 €2.000 €6.256 >€5.000 €1.000
Lowest Cost
Option *Prices are relative 4
What does Success Look Like?
Customers are embracing UNCD
• Over 5,900 Flowserve UNCD coated faces sold in 2014
• Currently producing over 800-1,000 UNCD faces a month
• UNCD users continue to expand their usage
• No unhappy customers have been reported
4
Marketing Materials
Tools to help understand UNCD coated seal faces
• Technology Brochure
– Available at [Link]
• [Link]/UNCD
4
Summary
Flowserve offers the widest range of seal face surface preparations to address
challenging applications
• Ultrananocrystalline diamond (UNCD) coatings
• Diamond-like carbon (DLC) coatings
– hard vs hard non-contacting Gaspac and Mixerpac seals
• Laser-applied precision face topography
– Wavy faces
– Advance pattern grooves
• Machined-applied face topography
– Lube grooves
– Hydropads
5
Questions?