Stoichiometry
I. Stoichiometric
Calculations
A. Proportional Relationships
2 1/4 c. flour 3/4 c. brown sugar
1 tsp. baking soda 1 tsp vanilla extract
1 tsp. salt 2 eggs
1 c. butter 2 c. chocolate chips
3/4 c. sugar Makes 5 dozen cookies.
I have 5 eggs. How many cookies
can I make?
Ratio of eggs to cookies
5 eggs 5 doz.
= 12.5 dozen cookies
2 eggs
A. Proportional Relationships
Stoichiometry
• mass relationships between
substances in a chemical reaction
• based on the mole ratio
Mole Ratio
• indicated by coefficients in a
balanced equation
2 Mg + O2 2 MgO
B. Stoichiometry Steps
1. Write a balanced equation.
2. Identify known & unknown.
3. Line up conversion factors.
• Mole ratio - moles moles
• Molar mass - moles grams
• Molarity - moles liters soln
• Molar volume - moles liters gas
• Mole ratio - moles moles
Core step in all stoichiometry problems!!
4. Check answer.
C. Molar Volume at STP
1 mol of a gas=22.4 L
at STP
Standard Temperature& Pressure
0°C and 1 atm
C. Molar Volume at STP
LITERS
OF GAS
AT STP
Molar Volume
(22.4 L/mol)
MASS NUMBER
Molar Mass 6.02 1023
IN MOLES particles/mol OF
(g/mol)
GRAMS PARTICLES
Molarity (mol/L)
LITERS
OF
SOLUTION
D. Stoichiometry Problems
How many moles of KClO3 must
decompose in order to produce 9
moles of oxygen gas?
2KClO3 2KCl + 3O2
? mol 9 mol
9 mol O2 2 mol KClO3
= 6 mol
3 mol O2 KClO3
D. Stoichiometry Problems
How many grams of KClO3 are req’d to
produce 9.00 L of O2 at STP?
2KClO3 2KCl + 3O2
?g 9.00 L
9.00 L 1 mol 2 mol 122.55
O2 O2 KClO3 g KClO3
= 32.8 g
22.4 L 3 mol 1 mol KClO3
O2 O2 KClO3
D. Stoichiometry Problems
How many grams of silver will be
formed from 12.0 g copper?
Cu + 2AgNO3 2Ag + Cu(NO3)2
12.0 g ?g
12.0 1 mol 2 mol 107.87
g Cu Cu Ag g Ag
= 40.7 g
63.55 1 mol 1 mol Ag
g Cu Cu Ag
1. Mg(s) + HCl(aq) MgCl (aq) + H (g)
2 2
a. How many grams of HCl
are consumed by the reaction of
2.50 moles of magnesium?
b. What is the mass in grams
of H2 gas when 5.0 moles of HCl
is added to the reaction?
2. 4 NH3 + 5 O2 6 H2O + 4 NO
a. How many moles of H2O can be
made using 2.3 mol NH3?
b. What mass of NH3 is needed to
make 0.75 mol NO?
c. How many grams of NO can be
made from 47 g of NH3?