Air Sampling
Presentation by,
A.Mohan Raj
Air Sampling
• A means of collecting contaminates from air to
identify and quantify the concentration of the
contaminates.
• Concentration are calculated in either
dimensionless terms: ppm or ppb
Personal Sampling
• Sampled taken in the breathing zone.
Area Sampling
• Fence line monitoring
• Evaluating engineering controls
• Smoke Stacks
Need for Air Sampling
• To identify & measure air pollutants.
• To monitor personal exposures to chemicals.
• To assess the environmental impact of
manufacturing processes.
• To comply with government regulations.
• To identify the source of the pollutants.
• To evaluate the effectiveness of engineering
controls (i.e., ventilation)
Grab vs. Integrated Sampling
GRAB SAMPLING
• This technique involves the direct collection of an
air-contaminant mixture into a device (i.e. sampling
bag, syringe, or evacuated flask) over a short
interval of a few seconds or minutes. Represents
the atmospheric concentrations at the sampling site
at a given point in time.
• INTEGRATED SAMPLING
• For gases and vapors, involves passage of a known
volume of air through an absorbing or adsorbing
medium to remove the desired contaminants from
the air during a specified period of time.
• Contaminants of interest are collected and
concentrated over a period of time to obtain the
average exposure levels during the entire sampling
period.
• INTEGRATED SAMPLING
• This type of sampling to cover the entire period of
exposure is required because airborne contaminant
concentrations during a typical work shift vary with
time and activity.
• Most integrated sampling is done to determine the
8-hour TWA and/or STELs to compare with OSHA
PELs, ACGIH TLVs and NIOSH RELs.
Sampling Time
Grab Sampling
• • ~1-minute
STEL Sampling (Short-term exposure limit)
• • 15-minute exposure
TWA Sampling (Time weighted average)
• • 8-hour exposure (typical personal sampling time)
Risk Assessment
• • 24-hour
Air Sampling - The 3 Factors
• When taking air samples - there are three factors in determining the
concentration:
1. Sampling Rate
• – Active Samplers – Requires a pump to control the flow rate
• – Passive Sampler – Design of the sampler dictates the flow rate “it’s
fixed” by diffusion
2. Sampling Time
• – How long of a sample do we need?
3. Sample Volume
• The sample volume is calculated by multiplying the flow rate x
sampling time:
Flow Rate x Sampling Time = Sample Volume
Air sampling techniques for particulate pollutants
• SEDIMENTATION
• FILTRATION
• IMPINGEMENT
• PERCIPITATION
• THERMAL PRECIPITAION
• ELECTROSTATIC PRECIPITATION
AIR SAMPLING OF THE GASEOUS POLLUTANTS
• ABSORPTION SAMPLING
• ADSORPTION SAMPLING
• CONDENSATION SAMPLING