HAZARDOUS MATERIALS HANDLING
TRAINING OF TRAINERS
CONTENT
Objective
Hazardous Material
Classification of hazardous material
Type of labels
Hazmat kit contents
Spillage management
Examples for spillage magangment
OBJECTIVE
Allow response personnel to prepare for and safely
respond to spill incidents.
Ensure an effective and efficient response despite
geographical challenges.
To reduce the quantity of ...spills/releases is required and
must be recorded through the appropriate procedures and
reported to relevant authorities.
WHAT ARE HAZARDOUS MATERIALS?
Hazardous material can be defined as any material that,
because of its quantity, concentration, or physical or
chemical characteristics, may pose a real hazard to
human health or the environment.
HAZARDOUS MATERIALS & WASTES
Knowledge of the proper
procedures in the special
handling, use, storage, and
disposal of hazardous
materials (hazmats) and
wastes.
TYPES OF HAZARDOUS MATERIALS
CLASSIFICATION OF HAZARDOUS
MATERIALS
Class 1- Explosives e.g. Nitroglycerine
Class 2- Gases e.g. Compressed gases
Class 3- Flammable Liquids e.g. Isopropyl alcohol
Class 4- Flammable Solids [Link]
Class 5- Oxidizers and Organic Peroxide e.g.
Hydrogen peroxide
Class 6- Toxic and Infectious Substances
[Link] drugs & body fluids
Class 7- Radioactive Materials
Class 8- Corrosives e.g. Acids
Class 9- Miscellaneous Dangerous Goods.
INCIDENT
HAZMAT is a term used to describe incidents
involving hazardous materials or specialized teams
who deal with these incidents.
LABELS ARE REQUIRED TO HAVE:
Pictograms
Signal Words
Hazard Statement
Precautionary Statements
Product Identifier
Supplier Identification
Supplemental Information (as required)
GHS PICTOGRAMS
LABELS – SIGNAL WORDS DESCRIBE
THE SEVERITY OF A HAZARD
Danger
This is reserved for the more severe hazards
Warning
This is used on less severe hazards
If there is no significant hazard, a signal word won’t be used
LABELS – HAZARD STATEMENTS
Phrases that describe the
nature of the hazard:
Examples:
Highly flammable liquid
and vapor
May cause liver and
kidney damage
Fatal if swallowed
KNOW THE POTENTIAL HAZARDS
Ineach area of the
facility where you work:
Observe signs
Take precautions when
entering an area identified
as hazardous
Know what’s inside a
container before you
handle it!
PERSONAL PROTECTIVE
EQUIPMENT (PPE)
Gloves
Goggles
Masks
Respirator
Gowns
Aprons
Footwear
Good hygiene
WHAT IS HAZMAT KIT/SPILL KIT
Spill kits with instructions, absorbents, neutralizing agents if
applicable, protective equipment, and sealable waste bags
should be present in the workplace.
Refer to the chemical Material Safety Data Sheet (MSDS) for
specific guidance on the chemical hazards and spill clean up.
CONTENTS OF SPILL KIT
1. Gloves
2. Disposable gowns
3. Goggles
4. Disposable shoe cover
5. Disinfectant(10% hypo solution)
6. Absorbent papers
7. Disposable forceps
8. Biohazard Disposable bags
9. Glass bottle(for mercury spill)
[Link] board or x-ray film
IN CASE OF SMALL SPILLS
• Isolate the spill and evacuate the
surrounding area
• Assign responsibility for dealing
with the spill – this must be someone
who has had appropriate training in
the use of spill kits and dealing with
chemical spills
• Put on PPE
• If possible, stop the source of the
spill
• Contain and clean up the spill,
thoroughly disinfect, rinse and dry the
area.
• Report the spill
IN CASE OF LARGE SPILLS
•Isolate the spill and evacuate the area
• Assign responsibility for dealing with the
spill - again, this must be someone who has
had appropriate training in the use of spill kits
and dealing with chemical spills
• Consult the Materials Safety Data Sheet
(MSDS) for advice on dealing with the type of
spill that has occurred.
• Put on PPE
• If possible and safe to do so, stop the source
of the spill
• Contain and cover the spill, using the
appropriate absorbent materials or granules.
• Dispose of the granules in the correct
container and manner for the product in
question
• Report the spill
BE SURE TO WASH YOUR HANDS
Before entering or leaving the work area
Before and after contact with a patient
After handling items such as bedpans, dressings, etc.
After removing gloves
After using the toilet, blowing your nose or covering a
sneeze
Before eating, drinking or handling food or smoking
PREVENT INJURIES FROM
SHARPS
Let falling objects fall
Practice safe handling
techniques
Don’t reach into containers
Dispose of sharps carefully
HAZMAT FUNCTIONING
HAZMAT to be available round the clock for cleaning
up large spills of hazardous materials.
Hazmat Register to be maintained in the Engineering
Control Room in which the details of the incident be
mentioned.
Hazmat to reach the site with appropriate Personal
Protective Equipment and Absorbents and Containers to
control the situation.
HANDLING HAZMAT SPILLS
Contaminated waste to be placed in a black bag with proper
labeling i.e.
Name of the Substance:
Date & Time of Incident:
Unit / Area:
Quantity of Spill:
Signature: and to be sent to Central Waste Disposal area (Backyard.)
Hazardous Chemicals will be diluted and flushed through the
drain.
Other Hazardous material will be handed over to an outside
agency for disposal.
HAZMAT register and Spill report form to be filled up and sent
to the Chairperson Safety Committee.
TYPES OF SPILL OCCUR IN THE
HOSPITAL
Blood Spill/ Body Fluid Spill
Chemical Spill
Mercury Spill
Medical gas spill
PERSONAL EXPOSURE – SKIN SPLASHES
Remove all contaminated clothing.
Rinse the affected area with water for approximately 15
minutes. Use an Emergency Shower if available.
Gently dry the area.
Seek medical attention from Emergency Department.
Complete an Incident Form and provide to the
supervisor.
PERSONAL EXPOSURE – EYE SPLASHES
Immediately flush the eye(s) with a continuous flow of
water for at least 15 minutes. Do not rub.
Seek medical attention from the Emergency Department.
Complete an Employee Incident Form and provide to the
supervisor
HAZMAT TRAINING
Mandatory for all staff
Hazmat team to ensure training of all staff
HAZMAT RESPONSIBILITIES
Obtain, review, and make available Material Safety Data Sheets
(MSDS) for the materials present at the work site.
Ensure that sufficient quantities and appropriate types of spill
control materials, as prescribed in MSDS, are available to contain
and clean up a minor spill.
Ensure that any required personal protective equipment (e.g.
eyewear or gloves) is available.
Ensure that spill control materials are located in a readily
accessible location.
Record information regarding any spills using the Spill Report
Form. Completed forms must be submitted to the Chairperson
Safety Committee.
Investigate the causes of minor spills and ensure appropriate
follow-up is conducted.
STAFF RESPONSIBILITIES
Be familiar with the properties and hazards of the
materials at work site.
Before beginning work with a chemical, be aware of its
hazards and the use of appropriate personal protective
equipment.
Ensure proper reporting procedures are followed in the
event of a spill.
MANAGING SPILLS
Mercury Spills - Minor
User is responsible for clean up of the spill.
Wear gloves. Clean up broken glass using tongs or heavy towel.
Gather all mercury and debris with a wet paper towel or sponge and place into a
bag along with wet paper towel or sponge and gloves. Label the bag as
Hazardous waste,
Name of the Substance: Mercury
Date & Time of spill
Quantity of spill:
Department / Unit:
Signature:
Contact housekeeping to promptly remove hazardous waste.
Do not dispose off mercury in general waste.
Complete a Spills Report Form and submit to the Chairperson Safety Committee.
The person responsible for spill may fill up the form and counter signed by the in-
charge of that area. However, the over all responsibility will be of in-charge’s
MANAGING SPILLS
Formalin spillage - Minor
Less than 20 –30 ml of formaldehyde spills.
Wear rubber gloves or double vinyl gloves and protective eyewear.
Clean up the spill with an absorbent material.
Wash the area with copious amounts of water.
Place all contaminated disposable material in a double bag and label as
Hazardous waste,
Name of the Substance: Formaldehyde
Date & Time of spill
Quantity of spill:
Department / Unit:
Signature:
Contact housekeeping to promptly remove hazardous waste.
Do not dispose off in general waste.
Complete a Spills Report Form and submit to the Chairperson Safety Committee.
The person responsible for spill may fill up the form and counter signed by the in-charge
of that area. However, the over all responsibility will be of in-charge’s.
MANAGING SPILLS
ETO – Primary Evacuation Procedure
Evacuate the immediate area and if possible, remove any injured
persons.
Raise an alarm. Notify the Hazmat team. Seal the area as best as
possible.
Contact the necessary companies who installed / manufactured the unit.
Persons in contact with ETO should immediately remove contaminated
clothing and wash or shower to remove any ETO from skin. Bring to
Emergency Room for proper care.
Complete a Spills Report Form and submit to the Chairperson Safety
Committee.
The person responsible for spill may fill up the form and counter signed
by the in-charge of that area. However, the over all responsibility will
be of in-charge’s
BLOOD SPILL MANAGEMENT
Isolate the area
Use personal protective equipments
Cover the spillage with absorbent materials.
Cover with 10% sodium hypochlorite solution.
Allow 20 to 30 minutes exposure time with disinfectant.
Clean spillage & dispose in yellow bag with container.
Again mob with disinfectant.