HOMEWORK | 1. Dimethyl glyoxime is____ ligand, | 2 TUPAC name of [eopvesynng), Joh is | 3. Sodiumnitroprussie when reacts with solution of Na, produces the complex of the formuta___ and its colour is__ 4. [icy P and [x(en), J aifferin and { 5: Coordination number of ‘Cr is six. A complex with (;02", en and superoxide ion (65) will be inthe ratio to make complex [CH(C40) (en), (04), ) xy 285 | 6 Isomerism exhibited by the complex [co(win) (sew), Jar is__,__and A six coordinate complex of formula Crh, 6/1,0 has green colour, A 0.01M solution of the complex when treated with excess of AgNO, gave 28.7 gm of white precipitate. The formula of the compound is__ £8 The number of geometrical isomers possible for the square planar complex 5 [Pivo,)(Py)(x2,017}07] are In film devolping AgBr is soluble in hyposolution to forma complex of the formula and ! its IUPAC name of , 10. In the metal carbonyls of general formula [.1¢(CO), ] which follows EAN rule if ‘Mis Ni, Fe and Cr the value of ‘x’ is. and The sum of oxidation number and coordination number of the metal 'M’ in the complex [ 14(en), (C0,)]C7 is issolves in excess of KCN to, give the complex ion of the i. 112, Copper sulphate ‘formula, 13, The ligands in anti cancer drug Cis platin are___ 14. IUPAC name of Wilkinson’s catalyst is___ 15, In the complex [P2(?y), ] [PiCl,]the oxidation numbers of ‘Pt in former and later part | of the complex are __ and _. PAGE NO. VIJAYAWADA SRI CHAITANYA - GOSALAf12 [ewew), J, CuSO, + KCN (excess) 9 K 113. Ny, C1 Cis - platin is [P4( a7, | 14. Wilkinson’s catalyst is [ 2#¢7(?P%s), |, chloro (or) chloridotris tripheny! i i 2] phosphine Rhodium (1) 2 2 15. 42,42 [rr(ry), [Pech]CLASS WORK _ ANSWER ! OL. double salts 02. dando 08. 2,3,4 + 04, Homoleptic and heteroleptic 05. [Col NCHCHNH,),} (801), >. diamunine silver (1) dicyanoargentate (J), Mercury tetrathiocyanato col Geometrical and optical, Fac and mer and optical isomerisms 22 Linkage, Coordination and ionization sp, dsp? sp ‘baltate (II) { = e8es8 {Number of unpaired ¢°.s=5, 4,4 12, 5.96, 2.8,4.9 BM 1B, x= 6, y=5,2=4 14. geometrical 15, 2,4 16. symmetrical, unsymmetrical © 17, Iron (Ill) hexacyane ferrate (II) 18. Violet, grey ~ green, hydrate isomers 19, sp2d if not in the given options take dyp*, square planar 20. diamagnetic, paramagnetic. HOMEWORK _ ANSWER N-0H Dimethyl glyoxime is itis bidentate ligand. Pentammine (Thiocyanato - N) cobalt ({Il) chloride Na,| Fe(CW), Nos], Purple/ Violet hybridisation, shape ail Jonisation, linkage and geometrical 7. [orl O) C1 He 8. Mabed type square planar complex fozmns 9, Naf tg(s,0,), ], sodium dithiosulphate argentite (I) 0. 4,5,6 [Nor], [Fe(Cod, J [oco),] Oxidation number +3. Co ordination number 6 geometrical isomers. 234659 SII CHAITANYA - GOSALA PAGE NOS » [rer >[ amen, J =[coR]” : i VIsAYAWADA !SRI CHAITANYA - GOSALA ZONE ‘Outgoing Seniors + Long Term CHEMISTRY Day-16/Dt, Ogee x COMPOUNDS CLASS woRK OL. Carnatite, Mohr’s salt and potash akin are _ salts. (2 PaCIANH, and NiCT610 solution each gives 2 moles of gCF ppt with NO, solution then the secondary valencies of Pd and Ni are and 03. The ligancy of acetyl avetonate, diethylene triamine and triethylene ietraamine is»! and ‘al Nt), )" and [Cot NH,),Ch] are___and__ complexes 05. Tris (ethane «1, 2 - diammine) Cobalt (III) sulphate is correctly represented as U6. TUPAC names of | te( 0/1. }[aelen), J. me[Codsew), J are and __. 97, Isomerism eshibited by [acts fen), J’, [Caf WH) (N04), J, [Cofer), J” are and i G8, Mabed type square planar complex forms _._no of cis and __no. of trans isomers. | 09, “cat v) voayTed, [Cal sits), ][Or(C),] and [co Ht) r]sa,—exhibit__, and __ isomerism, 10. Hybridisation of metal atom ion in [SiC [renffocoy] isan 11, Correct decreasing order of paramagnetic moment uf [MuCI]”. [Fe] and [cok i 12. The spin only magnetic moment of [Mar )”, [vnc J” and [Muct,]* is —_ant___ 8M. 18. COC NTI, COCK AI, arnt COCh 2 NH, are with yellow, parple and green colours. Then, y,zare ant __ UU, Green coloured COC, ANI, and violet coloured COC ANIL, are__ isomers 15, The primary and secondary valencies of “PE in PrC1,2NMH, are___and 15, Oxalate ion is___ bidentate gard and glycinate ion bidentate ligand 7. IUPAC name of Prussian Bue coloured comple formed during detection vf nitrogen by Lassiagne’s testis. is. [ertHi0}, Je is coloured and [C>(1,0), CA)ch 70 ts __caloured and the are__ isomers. : 19, Hybridisation and shape of cuprammonium sulphate is___and ao. Free) J” and [retcx),]” are and ___ magnetic. ‘SRI CHATTANYA - GOSALA PAGE NOL vuayawapa !"SRI CHAITANYA - GOSALA ZONE Outgoing Seniors + Long Term curemisrny Day-15/Dt. oe TRACK-1: INNER TRANSITION ELEMENTS The correct order of ionic radii of Y"".La"*,Eu” and Luis {Atomic nos, Y= 39, La = $7, Eu =63, Lu = 71) 1) Y" eta! < Eu" ea" 2)" clu" < Bu! Are catoured due to Ff transiti colourless. je properties : They are strongly __— jin ator Ain i everett HAN —— "iy ise i At nore ix no regular (el ic 21, Density : All actinoids except thor 22, ____ melting and boiling points however (h number. 23. They have ionization energies. | 24, Allactinoids are . ave wsed as fuel i? 25. is used im atomic reactor and treatment of cancer. ———— ‘nuclear reactor. £26. isstecl hard. 27. bas maximom param 28. TE) of Ln are around and IEz around 29. 30. Maximum oxidation state of Np and Pu is. . 31. Actinsids + HNO, passive due to. : ANSWERS, (4) La < Eu [Link] electronic configuration of’ system is___ for octahedral complex, 16. Crystal field stabilization energy and electronic configuration of d” octahedeal compley if A

hoarerc 1. -€110.-COOH.-COC > COOR 2 ss a0" 3. Phenol ~ HO >C2HsOHT 4 +P effet |S. =F and halogen 6 1 -NH, >-Oll > -F et 8. -KMe,>-NO,>-CN >-SO\H > CHO 7 _ 9 LES HCE ME a i 1 Po Mat bear LI sie. caus aver | 4 Jrutene and Conjugating CH CCH. -C 16, Eleetromeric effect, | SRI CHAITANYA -' GOSALA PAGE NO.2 \VUAYAWADA,20. 2 2 23, 24. 28, 26. 27. 28, 29, 30. a. SRI CHAITANYA - GOSALA PAGE NO.S VIJAYAWADA difficult, small, almost same, * lanthanoid metal (- 989%) wi decrease, Reson: Due to addition of new ul Tet" By another inthe ten a Screening effect hence conten Jeetrons into fsubsell and imperfes ae, there ie greater effeet of Inerens ction in size, same h iron (- %), S, Cy Ca and Al, tracer bu ter flints, Actinoid contraction 23, 445.46 and +7, very small energy gap between Sf 6 and 7s subshells silvery white metals, oxide, nat attacked, less reactive Ach (84°), Cm (51°), Th” (5t4) paramagneti high High low strong reducing / oxidising agents. Thorium, U and Pu Sm Na 600 kavmole & 1200 kJsmole A 1A, Bu, On (ot), +H, D) Ln., Ln,¢. Ln,C B) La LnC,.Lo,[Link],C, +7 protective oxide layer formation at shietding of 00 we nuclear charge ultets, shells and