DPP No.
G3
GENERAL ORGANIC
CHEMISTRY
Instructions
Total Qn.: 14 Total Marks: 56 Time: 28 Min
SCQ: Correct +4 Incorrect -1 Not Attempt 0
INTEGER: Correct +4 Incorrect -1 Not Attempt 0
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CHAPTER: GOC DPP No. G3 CLASS: JEE 2027
1. Mesomeric effect involves the delocalisation of:
(A) Protons (B) Sigma electrons (C) π electrons (D) None of these
2. Which of the following group show +M effect?
(A) —CN (B) —O—NO (C) —CCl3 (D) —CHO
3. Which of the following group show –M effect?
(A) —CMe3 (B) (C) (D)
4. Which of the following group show +M and –I effect?
–
(A) (B) (C) —O (D) —OH
5. Which of the following group show +M > –I effect?
(A) —F (B) (C) (D) —COOH
6. Which of the following group show –M and –I effect?
(A) —NO2 (B) —NH2 (C) —OH (D) —F
7. How many groups (attached with benzene ring) show +M effect?
, , , ,
(A) five (B) six (C) eight (D) four
8. The weakest + M group of the given species is:
(A) —OCH3 (B) —F (C) —I (D) —N(CH3)2
9. Arrange the following groups in order of decreasing –M effect.
(i) NO2 (ii) COOH (iii) CN (iv) CHO
(A) i > iii > ii > iv (B) i > ii > iii > iv (C) i > iii > iv > ii (D) iv > iii > ii > i
10. Arrange the following groups in order of decreasing +M effect.
–
(i) —O (ii) —NH2 (iii) —OH (iv) —NHCOCH3
(A) i > ii > iii > iv (B) iv > iii > ii > i (C) i > iii > ii > iv (D) i > iv > iii > ii
11. In which of the following molecule, the mesomeric effect is present?
(A) (B) (C) (D)
12. In which of the following molecule, the mesomeric effect is not with the benzene nucleus?
(A) (B) (C) (D)
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CHAPTER: GOC DPP No. G3 CLASS: JEE 2027
13. Electron density order in the benzene nucleus is:
(I) (II) (III) (IV)
(A) I > II > III > IV (B) I > III > II > IV (C) IV > II > III > I (D) I > IV > II > III
14. Rank the following compounds in order of decreasing electron density in the benzene nucleus.
(I) Chlorobenzene (II) 4-nitrochlorobenzene
(III) 2, 4-dinitrochlorobenzene (IV) 2, 4, 6-trinitrochlorobenzene
(A) I > II > III > IV (B) I > III > II > IV (C) III > I > IV > II (D) IV > III > II > I
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CHAPTER: GOC DPP No. G3 CLASS: JEE 2027
ANSWER KEY
01 (C) 02 (B) 03 (D) 04 (D) 05 (B) 06 (A) 07 (B) 08 (C)
09 (C) 10 (A) 11 (A) 12 (D) 13 (B) 14 (A)
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