25-10-2025

6201CJM12NSELITE01 JM

PHYSICS

SECTION-I

1) A metallic plate of surface charge density +2∈0 (in SI units) is irradiated with photons of
wavelength 620 nm. The work function of metal is 1.5 eV. What maximum distance from the metal
plate can the ejected photoelectrons go before turning back? (Assume photoelectrons to be emitted
perpendicular to the plate)

(A) No photoelectrons will be emitted

(B) Photoelectrons will not turn back at all

(C)

(D)

2) The stopping potential V for photoelectric emission from a metal surface is plotted along Y-axis
and frequency of incident light along X–axis. A straight line is obtained as shown. Planck’s constant

is given by

(A) slope of the line.

(B) product of slope of the line and charge on the electron.
(C) intercept along Y-axis divided by charge on the electron.
(D) product of intercept along X-axis and mass of the electron

3) A neutron having kinetic energy 13.6 eV collides with a hydrogen atom in ground state at rest.
Assume that the mass of neutron and hydrogen atoms are same and the neutron does not leave its
line of motion. Then which of the following is the possible KE of the neutron after the collision?

(A) Zero
(B) 3.4 eV
(C) 1.5 eV
(D) 6.8 eV

4) An electron in the ground state of the hydrogen atom has the orbital radius of 5.3 × 10–11 m while
that for the electron in third excited state is 8.48 × 10–10 m. The ratio of the de Broglie wavelengths
of electron in the ground state to that in excited state is
(A) 4
(B) 9
(C) 3
(D) 16

5)

Which of the following wavelength will be absent from the X-ray spectrum if the X-ray tube is
operated at 40,000 V?

(A) 0.2 Å
(B) 0.5 Å
(C) 1.0 Å
(D) 2.0 Å

6) The ratio of wavelength of Lβ and Lα X-rays for an atom with atomic no. 74 will be :-

(A)

(B)

(C)

(D) None of these

7) A uranium nucleus 235U liberates 200 MeV per fission 1.5 kg of uranium reacts during explosion of
a uranium bomb. What is the mass of an equivalent TNT bomb if the heating capacity of TNT is 4.1 ×
106 J/kg?

(A) 3 × 106 kg
(B) 3 × 107 kg
(C) 9 × 107 kg
(D) 9 × 106 kg

8) The mass of proton, neutron and helium nucleus are respectively 1.0073 u, 1.0087 u and 4.0015
u. The binding energy of helium nucleus is:

(A) 1.42 MeV

(B) 7.1 MeV
(C) 56.8 MeV
(D) 28.4 MeV

9) A projectile is fired with a speed u at an angle θ with the horizontal. Its speed when its direction
of motion makes an angle ‘α’ with the horizontal is :

(A) u secθ cosα

(B) u secθ sinα
(C) u cosθ secα
(D) u sinθ secα

10) A juggler projects a ball upward in a room of height H = 20m. Ball's projection speed was such
that it can just reach the ceiling. Now the ball is projected with two times of the previous velocity.
After what time interval in second does this ball return to hand of juggler. Assume collision with roof
results in reversal in direction of velocity with no change in magnitude.

(A)
(B)
(C)
(D)

11) A particle is moving along x-axis as x = t2 –6t + 8.

Find distance travelled by particle in t = 4 second

(A) 8m
(B) 9m
(C) 11m
(D) 10m

12) To cross the river in shortest distance, a swimmer should swim making angle θ with the
upstream. What is the ratio of the time taken to swim across covering shortest distance to that in
swimming across in the shortest time [Assume speed of swimmer in still water is greater than the
speed of river flow] :-

(A) cos θ
(B) sin θ
(C) tan θ
(D) cosec θ

13) Figures I, II, III and IV depicts variation of force with time. In which situation change of
momentum will be maximum

(A) I & II
(B) III & I
(C) III & IV
(D) Only IV

14) Two wooden blocks are moving on a smooth horizontal surface such that the mass m remains
stationary with respect to the block of mass M as shown in figure. The magnitude of force P is
(A) (M + m)g tan β
(B) g tan β
(C) mg cos β
(D) (M + m)g cosec β

15) Figure shows two blocks, each of mass m. The system is released from rest. If accelerations of

block A and B are a1 and a2 respectively, then

(A) a1 = a2 cos θ
(B) a2 = a1 cos θ
(C) a1 = a2
(D) None of these

16) The position vector of a particle related to time t is given by

The direction of net force experienced by the particle is :

(A) Positive y-axis

(B) Positive x-axis
(C) Positive z-axis
(D) In x-y plane

17) A block of mass m is connected to a light spring of spring constant k. The block is released when
the extension of the spring is x0. The extension of spring when the power due to spring force on the

block is maximum is :

(A)

(B)

(C)
(D) x0

18) Acceleration of a particle moving in x-y plane varies with time t as . Here a is in
2
m/s and t in sec. At time t = 0 particle is at rest at origin. Mass of the particle is 1kg. Find the net
work done on the particle in first 2 sec.

(A) 40 J
(B) 34 J
(C) 16 J
(D) 48 J

19) Block is released from top of a smooth inclined plane. Speed of block is maximum when it :-

(A) just touches the spring

(B)
compress spring by

(C)
compress spring by
(D) is back to natural length again

20) A smooth chain of length 2m is kept on a table such that its length of 60cm hangs freely from the
edge of the table. The total mass of the chain is 4kg. The work done is pulling the entire chain on the
table is

(A) 3.6J
(B) 12.9J
(C) 2J
(D) 6.3J

SECTION-II

1) A body moves in a straight line for which graph of vx vs x is shown in the graph. Find the
magnitude of acceleration of the body at x = 3m.
2) Three blocks A, B and C of masses 4 kg, 2 kg and 1 kg respectively, are in contact on a frictionless
surface, as shown. If a force of 14 N is applied on the 4 kg block, then the contact force between A

and B is

3) In the photoelectric experiment, if we use a monochromatic light, the curve is as shown. If

work function of the metal is 2eV, estimate the power of light used (in W) (Assume efficiency of
photo emission i.e. number of photoelectrons emitted are of number of photons
incident on metal)

4) Electromagnetic waves of wavelength 1242 Å are incident on a metal of work function 2 eV. The
emitted electrons are now accelerated with potential difference of 5V. The electrons pass through
hole into a gas of hydrogen atoms in their ground state. Find the number of spectral lines emitted
when hydrogen atoms come back to their ground states after having been excited by the electrons.
Assume all excitations in H-atoms from ground state only. (hc = 12420 eVÅ)

5) A hydrogen like ion in first excited state absorbs 10.2eV photon and gets excited to higher energy
level. Now the excited ion can emit six different photons some of higher and same of lower energies
than the absorbed photon. Find the atomic number Z of the ion.

CHEMISTRY

SECTION-I

1) The time for half life period of a certain reaction A → products is 1 hour. When the initial
concentration of reactant 'A' is 2 mol/L. How much time does it take for its concentration to change
from 0.5 to 0.25 mol/L if it is a zero order reaction?
(A) 1 hour
(B) 4 hours
(C) 0.5 hour
(D) 0.25 hour

2) Rate of formation of SO3 in the following reaction is 2SO2 + O2 → 2SO3 is 100 g/min, hence rate of
dissappearance of O2 is :

(A) 50 g/min
(B) 40 g/min
(C) 200 g/min
(D) 20 g/min

3) For a first order homogeneous gaseous reaction, A → 2B + C then initial pressure was Pi while
total pressur after time 't' was Pt. The right expression for the rate constants k in terms of Pi, Pt and t
is :

(A)

(B)

(C)

(D) None of these

4) For the reaction A → Product, a plot between log t1/2 agianst log [A]0 is given as

Find the order of reaction.

(A) 0
(B) 0.5
(C) 1
(D) 1.5

5) For a complex reaction Products ,

overall rate constant K is related to individual rate constants by the equation The
activation energy fo overall reaction in kJ/mol is :

(A) 100
(B) 120
(C) 150
(D) 140

6) A reaction : A2 + B → Products, involves the following mechanism:

(A being the intermediate)

Products (slow).
The rate law consistent to this mechanism is :

(A) Rate = k[A2] [B]

2
(B) Rate = k[A2] [B]
1/2
(C) Rate = k[A2] [B]
2
(D) Rate = k[A2] [B]

7) The emf of the cell, Tl(s)|Tl+(aq)(0.0001M) || Cu2+(aq) (0.01M) | Cu(s) is 0.83V. The emf of this cell will
be increased by :

(A) increasing the concentration of Cu2+ ions.

(B) decreasing the concentration of Tl+.
(C) increasing the concentration of both
(D) Both (A) and (B)

8) For the cell Zn(s) | Zn2+(aq) || Mx+(aq) | M(s), different half cells and their standard electrode potentials
are given below :

If which cathode will give a maximum value of per electron transferred?

(A) Fe3+/Fe2+
(B) Ag+/Ag
(C) Au3+/Au
(D) Fe2+/Fe

9)

The emf of cell is at 298 K , [log 2 = 0.3].

(A) 0.018 V
(B) 0.18 V
(C) 0.036 V
(D) 0.09 V

10) The values of for HCl, NaCI, CH3COONa are 421.5, 126 & 91 Scm2/mol respectively. The
resistance of conductivity cell with cell constant 2.01 cm–1 is 520Ω, when filled with 0.1 M CH3COOH.
The pH of solution in the conductivity cell will be :

(A) 0.2
(B) 4
(C) 2
(D) 0.4

11) A current of 9.65 A is placed for 3 hr between nickel cathode and Pt anode in 0.5L of a 2 M
solution of Ni(NO3)2. The molarity of Ni2+ after electrolysis would be

(A) 0.46 M
(B) 0.92 M
(C) 1.08 M
(D) 2.06 M

12) Kohlrausch's law states that at

Infinite dilution, each ion makes definite contribution to conductance of an electrolyte whatever
(A)
be the nature of the other ion of the electrolyte.
Infinite dilution, each ion makes definite contribution to equivalent conductance of an
(B)
electrolyte, whatever be the nature of the other ion of the electrolyte.
Finite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte,
(C)
whatever be the nature of the other ion of the electrolyte.
Infinite dilution each ion makes definite contribution to equivalent conductance an
(D)
electrolyte, depending on the nature of the other ion of the electrolyte.

13) In a hypothetical condition assuming 3 electrons can be accommodated in an orbital & all the
remaining rules for configuration applicable, the magnetic moment of Mn+x is 6.87 BM. What is the
value of 'x' and azimuthal quantum number of last electron? (Assuming out of 3 electrons in an
orbital 1 remains unpaired)

(A) 0, 2
(B) 3, 0
(C) 1, 1
(D) 3, 2

14) Which of the following statements is not correct?

(A) Rydberg constant and wave number have same units

(B) Lyman series of hydrogen spectrum occurs in the U.V region
(C) The angular momentum of the eletron in the ground state of hydrogen atom is equal to h/2π.
(D) The radius of the first Bohr orbit of hydrogen atom is 2.116 × 10–8 cm.

15) If the radius of first Bohr orbit is x, then de Broglie wavelength of electron in 4 orbit is nearly

(A) 8πx
(B) 6πx
(C) 4πx
(D) 2πx

16) What will be the uncertainty in electron velocity, if uncertainty in momentum is equal to 1.8 ×
10−18g cm s−1 (me = 9 × 10−28g)

(A) 2 × 109cm/s
(B) 1 × 106cm/s
(C) 1 × 105cm/s
(D) 1 × 1011cm/s

17) Which of the graphs shown below does not represent the relationship between incident light and
the electron ejected from metal surface?

(A)

(B)

(C)

(D)

18) Which hydride among the following is less stable?

(A) HF
(B) BeH2
(C) LiH
(D) NH3
19) The one that is not suitable for the removal of permanent hardness of water is :

(A) Clark's method

(B) Ion-exchange method
(C) Calgon's method
(D) Treatment with sodium carbonate

20) The correct statements about H2O2 are :

(I) Used in the treatment of effluents.
(II) Used as both oxidising and reducing agents.
(III) The two hydroxyl groups lie in the same plane.
(IV) Miscible with water.

(A) (I), (II), (III) and (IV)

(B) (I), (II) and (IV) only
(C) (II), (III) and (IV) only
(D) (I), (III) and (IV) only

SECTION-II

1)

2) In a H-like atom for an electron revolving in nth orbit, the variation of log10 KE versus log10 Z is
plotted as following

where Z is atomic number & KE is kinetic energy of electron (in eV). If OA = log10 3.4 then find the
value of principle quantum number of the electron.

3) Consider a first order reaction at 300 K

A(g) → B(g) + 2C(g)
Determine rate constant (in hr–1) for the above reaction with the help of following information
(given ln2 = 0.7 and there is an inert gas present)

4) A reaction is carried out at 600K. If the same reaction is carried out in present of a catalyst at the
same rate, the temperature required is 400K. Y is activation energy of reaction (in kJ/mol) if the
catalyst lowers the activation barrier by 15.5 kJ/mol. Find the value of 10Y.

5) The volume strength of 8.9 M H2O2 solution calculated at 273 K and 1 atm is ____. (R = 0.0821 L
atm K–1 mol–1) (Nearest Integer)

MATHEMATICS

SECTION-I

1) If is the least degree polynomial such that then

(A)

(B)

(C)

(D)

2) The largest interval lying in , for which is defined,

is

(A)

(B)

(C)

(D)

3) The range of is

(A)

(B)

(C)

(D)
4) Let denote the greatest integer x and (x) denote the least integer x. Which of the following
statements are true?
I. if and only if
II. if and only if
III. for all x,y
IV. for all x

(A) IV only
(B) I and IV only
(C) I, II and III only
(D) I, II and IV only

5) For real x, let , then

(A) f is one-one but not onto

(B) f is onto but not one-one
(C) f is one-one and onto
(D) f is neither one-one nor onto

6) Let where a > 0 and f(x) is a bijection only if

(A)
(B)
(C)
(D)

7) The range of is

(A)

(B)

(C)

(D)

8) The domain of the function is

(A)

(B)

(C)

(D)
9) Let F(x), where 'a' is a positive real number not equal to 1 and F(x) is an odd
function, Which of the following statements is true?

(A) G(x) is an odd function

(B) G(x) is an even function
(C) G(x) is neither even nor odd function
(D) Whether G(x) is an odd or even function depends on the value of ‘a’

10) If then number of solutions of is

(A) 0
(B) 2
(C) 3
(D) 4

11) For non-negative integers m, n define a function as follows

then value of f(2, 1) is

(A) 2
(B) 3
(C) 4
(D) 5

12) , where [.] denotes the greatest integer function, is equal to

(A) 0
(B) -1
(C) 2
(D) Does not exist

13) is equal to

(A)

(B)

(C)
(D)

14) If

(A)
(B)
(C)
(D)

15) The value of is

(A)

(B)

(C)

(D)

16) is equal to

(A) 7/2
(B) 7/3
(C) 7/4
(D) 7/5

17)

(A) 10
(B) 102
(C) 103
(D) 104

18) The value of is

(A) 1
(B) 6
(C) 0

(D)

19)

If be the roots of , then is equal to

(A) 0

(B)

(C)

(D)

20) The value of

(A)

(B)

(C)

(D)

SECTION-II

1) If ‘f’ is a function defined on real numbers set and takes real values only and satisfies the relation

and then the value of

2) Let and Then the number of one-one

functions from A to B is equal to ______.

3) Let and Where Then

4) The value of is (where [x] denotes the greatest integer less than or
equal to x)
5) The value of ___.
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C B A A A A B D C A D D C A A A B B C A

SECTION-II

Q. 21 22 23 24 25
A. 2 6 7 6 2

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D D A B D C D C A C B A C D A A D B A B

SECTION-II

Q. 46 47 48 49 50
A. 2 2 36 465 100

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A C C D C D A C B D D D D D A C C B C B

SECTION-II

Q. 71 72 73 74 75
A. 4 24 3 198 2
 SOLUTIONS

PHYSICS

1) K = = 0.5 eV = eEd

=e×

d=

2) eV0 = hv – W
Where, V0 is the stopping potenial.

3) Let us discuss first in perfectly inelastic collision.

Conserving linear momentum, or

Loss in KE = K – K' = K/2 and this loss is maximum in perfectly inelastic collision .

Hence, this collision is not possible. So, in inelastic collision loss will be less than .
Hence, K should more than in the case of perfectly inelastic collision. Hence, collision is 1–D
elastic collision and KE of neutron after the collision will be zero.

4)
Note : Most appropriate answer will be option (1).

5)

6) For X-rays

7) The number of atoms in 'm' kg of uranium

Energy released

Mass of TNT
8)

9) H2. velocity remains constant: u cos θ = v cos α

v = v cos θ . sec α

10)

11) The distance traveled by a particle in t = 4 second is 10m.

12) Shortest time

For shortest distance

So, t'/t = cosec θ

13) Area of (F – t) → change of momentum
Area will be max in case (iii) and (iv)

14) Acceleration of the system :

The FBD of mass m is shown in the figure

R sin β = ma
R cos β = mg
From Eqs. (ii) and (iii), we get
a = g tan β
Putting the value of a in (i), we get
P = (M + m)g tan β

15) Let at any time, their velocities are v1 and v2 respectively. Then v1 = v2 cos θ

16)

So Net force is along +y direction

17) When extentiaon is x

= kxV

⇒
18)

by work energy theorem

19) V is maximum at equilibrium

20)
Reference GPE = 0

= 3.6 J

21) From given graph

v = – x + 5 for 1

So,

or,
∴ magnitude of acceleration = 2m/s2

22)

14 = 7a
a = 2m/s
14 – N = 4 × 2
N = 6N

23)
 24)
–2eV = 8eV
The electrons are emitted with kinetic energy varying from zero to 8 [Link] accelerated with
5 volt potential difference their energies increases by 5eV. Hence hydrogen well get photons

of energies in the range from 5 eV to 13 eV. So max possible

transactions are upto n = 4. Hence number of spectra lines is 4C2 =6

25) Since, from the nth energy level six photons are emitted, therefore,

CHEMISTRY

26) For zero order reaction.

Initial concentration decreases 4 times from 2 mol/L to 0.25 mol/L and half life also decreases
to 4 times to intital valve.

27)
28)

29)

30)

31) From the slow step : rate = k2[A][B] ... (i)

From fast step:

... (ii)
From (i) and (ii)

32)
Ecell increases by increasing the concentration of Cu2+ and decreasing the concentration of
Tl+.

33)

34) Ecell = –0.06 log 1/2

Ecell = 0.06 × 0.3 = 0.018 V

35)

36)

37) λ∞ = λa + λc
where, λa = equivalent conductance of the anion.
λc = equivalent conductance of the cation.

38)

39)
40)

41)

42) Conceptual

43) Among the given species BeH2 is less stable as it is a hypovalent species.

44) Clark's method is used to remove temporary hardness, using lime water (or) Ca(OH)2 from
water.

45) (I) H2O2 is an important chemical used in pollution control treatment of domestic and
industrial effluents.
(II) It has both oxidising and reducing properties.
(III) It has open-book like structure and both hydroxyl groups lie in different planes.
(IV) It is miscible in water due to hydrogen bonding.

46)
 47)

48) A(g) → B(g) + 2C(g)

t=0 P0 – –
t = 70 sec P0 – x x 2x
t=∞ – P0 2P0
If N is pressure of inert gas.
P0 + N = 200 (at t = 0)
3P0 + N = 500 (at t = ∞)
P0 = 150 N = 50
at t = 70 sec Pressure at 70 sec = 350 = P0 + 2x + N
So 70 sec is t1/2

K(hr) = = 36

49) Given that rates of reaction are same,

50) Molarity of H2O2 solution

Volume strength = 8.9 × 11.2 = 99.68 V 100 V

MATHEMATICS

51) has roots 1,2,3,4,5

52) is defined for all ....................(1)

is defined for .....................(2)

In cos x is defined for ............................(3)

The desired interval is the intersection of (1), (2), (3), i.e.,

53)

The domain is given by and

Range =

54)

I. is true : if
II. is true :
III. is false: while
IV. is true:

55)

An increasing function is one-one

is onto

56)

Conceptual

57)

Conceptual.

58)

We must have and

and ----------(2)
(1) gives
(2)

(as always)

Domain is given by and x = 0

59)

G(x) is an even function.

60)
The solutions of
X= -1, 1, 0, 2

61)

f(2, 1) =f(1, f(2, 0)) = f(1, 3) = 1 + f(1, 2) = 1+ f(0, f(1, 1)) = 1 + f(0, 3) = 1 + 4 = 5

because f(1, 1) =f(0, f(1, 0)) = 1 + f(1, 0) = 1+ f(0, 1) = 1 + 2 = 3

62)

Verify L.H.L and R.H.L

63)

Apply transformation

64)

Use cos x and sin x formula

65)

66)

Use L.H Rule

67)

Divide numerator and denominator by

68)

Let

=6

69)

70)

After simplifications

71)

72)

then no. of one-one functions

73)
74)

For

75)

use L.H. Rule