16-11-2025

9610ZJA802263250013 JA

PART 1 : PHYSICS

SECTION-I

1) 100 g of ice at 0°C is mixed with 100 g of water at 100°C. What will be the final temperature of
the mixture

(A) 10°C
(B) 20°C
(C) 30°C
(D) 40°C

2) A block of ice at –12°C is slowly heated and converted into steam at 100°C. Which of the following
curves best represents the event ?

(A)

(B)

(C)

(D)

3) A solid material is supplied with heat at a constant rate. The temp. of material is changing with

heat input as shown in the figure. What does slope DE represents?

(A) Latent heat of liquid
(B) Latent heat of vapour
(C) Heat capacity of vapour
(D) Inverse of heat capacity of vapour

4) A sphere and a cube of same material and same volume are heated upto same temperature and
allowed to cool in the same surroundings. The ratio of the amounts of radiations emitted will be:-

(A) 1 : 1

(B)

(C)

(D)

5) A composite rod made of 3 rods of equal length and cross-section as shown in figure. The end A
and B are at constant temperature. The effective thermal conductivity of the bar is :-

(A) 15K/16
(B) 6K/13
(C) 5K/16
(D) 2K/13

6) A sealed hollow cylinder of plastic is pivoted at the top and partially submerged in liquid as
shown. Now if we start rising container slowly then find out the ratio of total length of rod to the
submerged length of rod, till its equilibrium will not disturbed. Given density of liquid is 9/5 times
the density of plastic

(A) 2
(B) 3
(C) 4
(D) 6

7) At Sukhadia Circle, Udaipur (Rajasthan) there is a small circular pond in which let ,water flows at
a speed u along a circular path. A Swan shaped boat is steered radially with speed v relative to
water from inner statue circle (ro is radius of central circle.) to reach a diametrically opposite point ,
as shown in figure, on the other bank in half round (180°). The time to cross the river and reach that
point is.

(A)

(B)

(C)

(D) None of these

8) As shown in figure a particle of mass ‘m’ is moving on the circular path under the influence of a
force whose magnitude always remains ‘F’ & direction towards a fixed point ‘p’ on circumference.

Find the ratio of &

(A) 2 tan θ
(B) tan θ

(C)

(D)

9) In the figure shown a particle ฀ strikes the inclined smooth plane horizontally and rebounds
vertically. If the angle ฀ is 60∘ , then the co-efficient of restitution is:

(A)

(B)

(C)

(D) 1

10) Shown in the figure is rigid and uniform one meter long rod AB held in horizontal position by two
strings tied to its ends and attached to the ceiling. The rod is of mass 'm' and has another weight of
mass 2 m hung at a distance of 75 cm from A. the tension in the string at A is :

(A) 0.5 mg
(B) 2 mg
(C) 0.75 mg
(D) 1 mg

11) The velocity of water in a river is 5 m/s near the surface. If the river is 5 m deep, find the
shearing stress between the horizontal layers of water. The co-efficient of viscosity of water
= poise.

(A)
(B)
(C)
(D)

12) The primary of a 1 : 3 step-up transformer is connected to a source and the secondary is
connected to a resistor R. The power dissipated by R in this situation is P. If R is connected directly
to the source will dissipate a power of :

(A) P/9
(B) P/3
(C) P
(D) 3P

13) In the given figure all identical conductive plates are placed infront of each other all have plate
area S and equally separated by d. Plate A and B have been given charges 2Q and 3Q, then find the
potential difference (VA – VB) in volts between plate B and A. [given that (in SI unit)]

(A) 1 V
(B) 2V
(C) V
(D) –1V

14) A fixed sphere of radius R and uniform mass density 'd' has a cavity of radius as shown in

figure. The centre of the solid sphere is at 'C' while that of the cavity is at 'O'. A liquid of density is
filled in the cavity. The gravitational force exerted by the liquid on the solid sphere is :-

(A)

(B)

(C)

(D)

15) The angular speed of rotation of earth about its axis when the weight of a man standing on
equator will become half of its weight at the north pole (assume earth to be a perfect sphere) R –
6400 km.

(A) 275 × 10–4 rad sec–1

(B) 9.75 × 10–4 rad sec–1
(C) 8.75 × 10–4 rad sec–1
(D) 8.0 × 10–4 rad sec–1

16) In the given circuit diagram, find the heat generated on closing the switch S. (Initially the

capacitor of capacitance C is uncharged) :-

(A)

(B) CV2

(C)

(D) 2CV2

17) Two identical uncharged capacitors A and B are connected in series with an ideal battery. When
separation between plates of capacitor A is doubled then choose INCORRECT options(s).

(A) Battery will act as load in this process

(B) Potential difference between plates of capacitor A increases.
(C) Potential difference between plates of capacitor B decreases
(D) Energy of capacitor ‘A’ increases

18) Two equal positive point charges are kept at points A and B. The electric potential, while moving
from A to B along straight line :

(A) continuously increases

(B) remains constant
(C) decreases then increases
(D) increases then decreases

19) Three vectors and are shown in the figure. Let S be any point on the vector . The
distance between the points P and S is . The general relation among vector and is.
(A)
(B)
(C)
(D)

20) The diagram shown the energy levels for an electron in a certain atom. Which transition shown

represents the emission of a photon with the most energy ?

(A) III
(B) IV
(C) I
(D) II

SECTION-II

1) A satellite of the sun is in a circular orbit around the sun, midway between the sun and the earth.
Then the acceleration of the satellite is x times the acceleration of the earth. find x (neglect the
attraction of earth over satellite).

2) Three dielectric of relative primitivities , and are introduced in a parallel

plate capacitor of plate area A and separation d. The effective capacitance between P and Q is .

Then will be.

3) The drag coefficient CD of an automobile is determined from the expression CD = Where D
is the drag force experimentally determined in a wind tunnel, ρ is the air density, v is the speed of
the air in the wind tunnel, and S is the cross-sectional area of the car presented to the air flow.
Determine the dimension of CD in length.

4) A potentiometer is used for the comparison of e.m.f. of two cells E1 and E2. For cell E1 the no
deflection point is obtained at 20 cm and for E2 the no deflection point is obtained at 30 cm. The

ratio of their e.m.f.’s is , then N is:

5) The centres of the spheres 1, 2 and 3 lie on a single straight line. Sphere 1 is moving with an
(initial) velocity v1 directed along this line and hits sphere 2. Sphere 2, acquiring after collision a
velocity v2, hits sphere 3. Both collisions are absolutely elastic . What must be the mass of sphere 2
(in kg) for the sphere 3 to acquire maximum velocity (The masses m1 and m3 of spheres 1 and 3 are

9kg & 1kg respectively)?

PART 2 : CHEMISTRY

SECTION-I

1) Ratio of solubilities of gases N2 & O2 in water from air at 25º & 1 atm will be if air is 20 % by
volume of O2 & 80% by volume of N2
Given : KH (N2) = 2 × 104 atm
KH (O2) = 104 atm

(A) 8 : 1
(B) 1 : 8
(C) 2 : 1
(D) 1 : 2

2) The resistance of 0.05 M solution of oxalic acid is 200 ohm and cell constant is 2.0 cm–1, the
equivalent conductance (in S cm2 eq–1) of 0.05 M oxalic acid is :-

(A) 100
(B) 0.2
(C) 200
(D) 400

3) The decomposition of a gaseous substance (A) to yield gaseous products (B) and (C) follows first
order kinetics. If initially only (A) is present and 10 minutes after the start of the reaction, the
pressure of (A) is 200 mm Hg and the total pressure is 300mm Hg, then the rate constant for
reaction A → B + C is

(A) (1/600) ln 1.25 sec–1

(B) (2.303/10) log 1.5 min–1
(C) (1/10) ln 1.25 sec–1

(D)

4) Which of the following reaction is INCORRECT?

(A) Stability order of dihalides SiX2 < GeX2 < SnX2 < PbX2
(B) 2NH3 + H2O + CO2 → (NH4)2CO3
(C) Na2CO3 .10H2O Na2O + CO2 + 10H2O
(D) Boric acid is polymeric due to the presence of hydrogen bonds

5) When H2S gas is passed in acidic medium which set of cations get precipitated?

(A) Mn2+, Co2+, Zn2+

(B) Pb2+, Cu2+, Bi3+
(C) Ba2+, Sr2+, Ca2+
(D) Fe3+, Cr3+, Al3+

6) On heating compound X a gas Y is obtained, which is also manufactured by reaction of Ba(NO3)2 +

Zn + KOH(aq.).

(A) Compound X is (NH4)2Cr2O7

(B) Gas Y is used in Ostwald process
(C) Gas Y is colourless and odourless
(D) Gas Y produce blue solution in AgNO3 (aq.)

7) The ΔH° for the mutarotation of glucose in aqueous solution,

α – D – glucose (aq) → β – D – glucose (aq) has been measured in a microcalorimeter and found to be
–1.16 [Link]–1. The enthalpies of solution of the two forms of glucose have been determined to be
α – D – glucose (s) → α – D – glucose (aq) ΔH° = 10.72 kJ mol–1
β – D – glucose (s) → β – D – glucose (aq) ΔH° = 4.68 [Link]–1
Calculate ΔH° (in kJ/mol) for the mutarotation of solid α – D – glucose to solid β - D – glucose.

(A) +4.88 kJ/mol

(B) –4.88 kJ/mol
(C) –2.44 kJ/mol
(D) +2.44 kJ/mol

8) Select INCORRECT statement regarding KMnO4 & K2Cr2O7.

(A) Both act as oxidising agent in acidic medium

(B) Both are paramagnetic and coloured
(C) O2 is used in the preparation of both
(D) The central atom of the anion in both has d3s hybridisation

9) Select CORRECT option regarding formation of molecular orbital from the combination of 1s-1s
orbitals.

(A) Curve-(1) represents formation of BMO

(B) Curve-(2) represents formation of ABMO
(C) ψ(g) = ψA + ψB
(D) ψ(u) = ψA + ψB

10) For a d6 metal ion in an octahedral field, the correct electronic configuration is :-

(A)

(B)

(C)

(D)

11) Which one of the following order is not in accordance with the property stated against it ?

(A) Al2O3 < SiO2 < P2O5 < SO3 (Acidic strength)
(B) Al3+ < Mg2+ < Na+ < F– (Ionic size)
(C) B < C < N < O (IE1)
(D) I < Br < F < Cl (EA)

12) Both geometrical and optical isomerism shown by :-

+
(A) [Co(en)2Cl2]
2+
(B) [Co(NH3)5Cl]
+
(C) [Co(NH3)4Cl2]
3–
(D) [Cr(Ox)3]

13) In which of the following amino acid 2°-amino group is present :

(A) Glycine
(B) Glutamine
(C) Phenyl alanine
(D) Proline

14) Which compound does not react with NaHCO3

(A) Squaric acid

(B) Salicylic acid
(C) Carbolic acid (phenol)
(D) Acetic acid

15) What will be the correct IUPAC name for the following compound.

(A) 7-Chloro-2-methyl bicyclo [3,2,1] octan-1-ol

(B) 7-Chloro-2-methyl bicyclo [3,2,1] octan-8-ol
(C) 2-Chloro-7-methyl bicyclo [3,2,1] octan-8-ol
(D) 2-Chloro-7-methyl bicyclo [3,2,1] octan-1-ol

16) product (P). , P is -

(A)

(B)

(C)

(D)

17)

For the following transformation, reagent(s) which can be used is/are :

(A) LiAlH4
(B) BH3, THF
(C) H2, Raney Ni
(D) NaBH4

18) An antipyretic is –

(A) Seldane
(B) Paracetamol
(C) Luminal
(D) Aspartame

19)

Identify which reaction(s) produce(s) single optically active Amine molecule as product

(i)

(ii)

(iii)

(A) i, iii
(B) iii only
(C) i, iii
(D) none of these

20) Which one of the following undergoes decarboxylation most readily?

(A)

(B)
(C)

(D)

SECTION-II

1) For the complex [Pt(H2 O)(NH3)(Cl)(Br)].

If oxidation number of Pt = x
Coordination number = y
and total possible geometrical isomers = Z
then find sum of x + y + z = ?

2) Expermentally it was found that a metal oxide has formula Fe0.98O. Metal Fe, is present as Fe2+
and Fe3+ in its oxide. Percentage of the metal which exists as Fe3+ would be (nearest integer) :-

3) 1 mole of monoatomic ideal gas subjected to irreversible adiabatic expansion against constant
external pressure of 1 atm starting from initial pressure of 5 atm and initial temperature of 300 K till
the final pressure is 2 atm. What is the final temperature (in K) in the process? (take R = 2 cal/mol
K).

4) How many of the following compounds will give immediate turbidity with Lucas reagent
[anhydrous ZnCl2/[Link]].

5) How many of the following compounds, gives positive test for nitrogen in lassaigen's test ?
(i) Hydrazine (ii) Ethanoic acid
(iii) Ethanamide (iv) Aniline
(v) Hydroxylamine

PART 3 : MATHEMATICS

SECTION-I

1) Solve the equation

(A)

(B)

(C)

(D)

2) Let P1 be a regular polygon of n sides with side length x and let Pk + 1 be the regular polygon of
n sides formed by joining the mid points of consecutive sides of Pk. Also perimeters of the Pi's form

an infinite geometric progression. If n = 6 and x = , then the sum of this infinite geometric
progression is :

(A) 8
(B) 17
(C) 14
(D) 12

3) Let f(x) be a non-negative function satisfying and f(1) = 0 then which of the
following is Not True

(A) f(x) is many one function

(B) f(x) is bounded
(C) range of the function f(x) is [0, 1)

(D)

4) Let y = y(x) be the solution of the differential

equation satisfying the condition . Then, is

(A)

(B)

(C)
(D)

5) If f(x) and g(x) are derivative and antiderivative of a function h(x) where = 3 and

cos x dx = 5. Let p(x) be a polynomial of degree 4 such that p(1) = 7 and attains its
local minimum value 3 at both x = 2 and x = 3. If the local maximum value of p(x) is equal to λ then

the value of is :

(A)

(B)

(C)

(D) None of these

6) Let f : (0, ∞)→R be continuous function such that f(x) = 6 (ln x)2 – .

Let Δ be area of triangle formed by tangent at x = to curve y = f(x) + 1 and co-ordinate axes. Then

the value of is equal to _______. [where [.] represents G.I.F.]

(A) 3
(B) 4
(C) 6
(D) 9

7) Let point 'P' be (5, 3) and a point 'R' on y = x and Q on x-axis such that PQ + QR + RP is
minimum, then co-ordinates of point Q is -

(A) (17, 0)

(B)

(C)

(D)
8) The ends A , B of a fixed straight line of length ‘a’ and ends A′and B′ of another fixed straight line
of length ‘b’ slide upon the axis of X & the axis of Y (one end of each line on axis of X & the other end
of each line on axis of Y). Find the locus of the centre of the circle passing through A, B, A′ and B′.

(A) (2ax + 2by)² + (2bx - 2ay)² = (a² - b²)²

(B) (2ax - 2by)² + (2bx - 2ay)² = (a² + b²)²
(C) (2ax - 2by)² + (2bx + 2ay)² = (a² - b²)²
(D) (2ax - 2by)² + (2bx - 2ay)² = (a² - b²)²

9) If f(x) = 0 < x < 1, n ∈ N then f(x)dx is equal to

(A)

(B)

(C)

(D)

10) Let P be (5, 3) and a point R on y = x and Q on the x–axis be such that PQ + QR + RP is
minimum. Then the coordinates of Q are

(A)

(B) (17, 0)

(C)

(D) None of these

11) For , let and

also then is

(A) Discontinuous and non-derivable at and

(B)
Neither continuous nor derivative at

(C)
Continuous and derivable in

(D)
Continuous but not derivable at

12) Let f (x) = then f (x) is discontinuous at:

(A) x = 1 only
(B) x = -1 only
(C) x = -1, 1 only
(D) no point

13) For n ∈ N, let xn be defined as then equals

(A) 1

(B)

(C)

(D) 0

14) If where C is
the integration constant, then AB is equal to

(A)
(B)
(C)
(D)

15) Let f(x) be a differentiable function satisfying Then the

value of f(2) is

(A) e2

(B)

(C) e + e2
(D) 2e2

16) Consider two circles and as follows:

.
Let and intersects at point A and B. Line L passing through A meets at P and a line parallel
to AP passing through B meets at Q. Let S be the set of midpoints of line segment PQ as line L
varies. Then which is True?

(A)
(B)
(C)
(D)

17) Let f and g be twice differentiable functions on such that

Then which of the following is NOT true ?

(A) g(–2) –f(–2) = 20

(B) If –1 < x < 2, then |f(x) – g(x)| < 8
(C)

(D) There exists such that

18) If , then the sum of integral values of a for

which equation

, possess solution(s), is

(A) 6
(B) 7
(C) 9
(D) 10

19) If and then the value of

, is equal to

(A) 17
(B) 18
(C) 19
(D) 20

20) For , Let

Suppose a1, a2,a3,...be sequence satisfying a1>3 and and for n=1,2,3,....,2023
Define . Then

is

(A) 2024
(B) 4047
(C) 2025
(D) 4049

SECTION-II

1) Let y = f(x) (f : R → R) be an explicit function defined by the implicit equation x3 + y3 + 3(x2 +y2) +
3 (x + y) = 14 and g be the inverse function of f.

If [f(x +g(x)). g(x +f(x))] at x = – 1 + is equal , where , then find the value of .

2) Let be a permutation of (1, 2, 3 ......n) for which and

for n as, an even positive integer. Also and
for n as an odd positive integers. Let the total number of permutation of n
be p(n), if 200 < p(n) < 500, then last digit of sum of the values of n is

3) A cricket player played n (n > 1) matches during his career and made a total of

runs. If Tr represent the runs made by the player in rth match

such that T1 = 6 and Tr = 3Tr–1 + 6r , 2 ≤ r ≤ n then n is :

4)

Let
where and C is the

constant of integration. If can be expressed as in the lowest from, then

equals

5) If

where C is constant of integration and then value of is

 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A D C A B A A A D C A D D C C D C C A

SECTION-II

Q. 21 22 23 24 25
A. 4 3 0 2 3

PART 2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A A C B B A B C C C A D C B C D B B C

SECTION-II

Q. 46 47 48 49 50
A. 9 4 255 7 2

PART 3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A D D A B D C D A A C C B D B D B D C B

SECTION-II

Q. 71 72 73 74 75
A. 0 3 6 499 2
 SOLUTIONS

PART 1 : PHYSICS

1) Explain Question: Find final temperature of mixture of ice and water

Concept: Calorimetry (transfer of energy)
Solution:

= 10°C

Final Answer: (A)

2) Explain Question: Graph for ice converting to sheam

Concept: Transfer of energy
Solution:
Various process will be as follows :
Ice at –12°C Ice at 0°C water at 0°C
↓ T increase
water at 100°C
↓ T = constant
steam at 100°C
Final Answer: (A)

3) Explain Question: Temperature vs heat graph

Concept: Q = mCΔT
Solution:

(Slope) DE ∝

Final Answer: (D)

4) Explain Question: Cooling due to radiation

Concept: Thermal radiation
Solution:
Q = σA t (T4 - T0 ) If T, T0, σ and t are same for both bodies then
4

…..(i)
But according to problem, volume of sphere

= Volume of cube ⇒ ⇒
Substituting the value of a in equation (i) we get
Final Answer: (C)

5) Explain Question: Find effective thermal conductivity

Concept: Equivalent thermal conduction
Solution:
R = R1 + R2 + R3

Keq = K
Final Answer: (A)

6) Explain Question: Find ratio of total length of rod to submerged length till equilibrium
Concept: Bloyancey
Solution:

where
Balancing torque about hinge

[where θ is very small]

Final Answer: (B)

7) Explain Question: Time to cross the river moving in circle

Concept: Circular motion
Solution:
Final Answer: (A)

8) Explain Question: Find ratio of

Concept: Circular motion
Solution:
Final Answer: (A)

9) Explain Question: Find co-efficient of restitution

Concept: Collision on wedge
Solution:

Final Answer: (A)

10) Explain Question: Find tension in the string

Concept: Complete equilibrium
Solution:

Final Answer: (D)

11) Explain Question: Find shear stress of water

Concept: Newton's law of viscosity
Solution:
Velocity of water (du) = 5 m/s
Depth of river (dy) = 5m
Coefficient of viscosity = poise

1 poise =

poise =

According to Newton's law of viscosity :-

Final Answer: (C)

12) Explain Question: Power dissipation in step up transformer

Concept: Transformer
Solution:

Power across 'R'

Final Answer: (A)

13) Explain Question: Find potential difference between plate B and A

Concept: Parallel plate capacitor
Solution:

Final Answer: (D)

14) Explain Question: The gravitational force exerted by the liquid on the solid sphere
Concept: Gravitational field inside solid sphere
Solution:

E=

F = ME =
Final Answer: (D)

15) Explain Question: Change in weight of person due to rotation of earth

Concept: Variation of g due to rotation
Solution:

Final Answer: (C)

16)

Explain Question: Heat generated on closing the switch

Concept: Current flow generates heat
Solution:
Only charge is that capacitor 'C' will get charged.

Hence heat =
Final Answer: (C)

17) Explain Question: Choose incorrect statement based on capacitors

Concept: Energy of capacitor
Solution:
when separation becomes doubles capacitance of A and also equivalent capacitance decreases
there for charge on both A and B decreases.
Final Answer: (D)

18) Explain Question: Electric potential while moving from A to B

Concept:
Solution:

Final Answer: (C)

19) Explain Question: Find general relation between and

Concept: Vector addition
Solution:

Final Answer: (C)

20) Explain Question: Which transition shows emission of photon with most energy
Concept: Energy of photon from transition
Solution:

When goes from n = 1 to n = 4

no emission, only absorption
Final Answer: (A)

21) Explain Question: Acceleration of satellite as compared to earth

Concept: Gravitational force
Solution:

Final Answer: (4)

22) Explain Question: Find effective capacitance between P & Q

Concept: Series & parallel combination
Solution:

Ceq =

Final Answer: (3)

23) Explain Question: Find ratio where deflection is O.

Concept: Potentiometer
Solution:

[CD] = =
0 0 0
= [M L T ]
∴ dimension in L is zero
Final Answer: (0)

24) Explain Question: Find ratio where deflection is O.

Concept: Potentiometer
Solution:

Ratio will be equal to the ratio of no deflection lengths i.e.

Final Answer: (2)

25) Explain Question: What must be mass of 2 for 3 to after vmax

Concept: Collision
Solution:

As v2 =

∴ v3 =

For maximum v3, =0 ⇒ = 3kg

Final Answer: (3)
PART 2 : CHEMISTRY

26) Explain Question: Calculate ratio of solubility of N2 & O2

Concept: Concept of henry's law
Solution:
= 0.8, = 0.2 in air
= 0.8 atm, = 0.2 atm
P = KHX (Henry's law)
0.8 = 2 × 104 .......(1)
4
0.2 = 10 .......(2)
Ratio of solubility of N2 & O2 is 2 : 1
Final Answer: (C)

27) Explain Question: Calculate equivalent conductance of oxalic acid

Concept: ∴ Equivalent conductance =

Solution:

Specific conductance ,

∴ Equivalent conductance =

= 102 S cm2 eq–1

Final Answer: (A)

28) Explain Question: Calculate rate constant fo reaction A → B + C

Concept: Apply concept of first order kinetics.
Solution:
A → B + C
P0 0 0
P0 –x x x
0 p0 p0
Given :
p0 – x = 200
p0 + x = 300
⇒ p0 = 250
x = 50

Final Answer: (A)

29) Explain Question: Identify incorrect statement
Concept: Stability of dihalides of group 14 elements.
Solution:
(A) SiX2 < GeX2 < SnX2 < PbX2
(B) 2NH3 + H2O + CO2 → (NH4)2CO3
(C) Na2CO3.10H2O Na2CO3 .H2O + 9H2O.
(D) Boric acid is polymeric due to the presence of hydrogen bonds
Final Answer: (C)

30) Explain Question: Identify which set of cations get precipitated by H2S
Concept: Sparingly soluble sulphides get precipitated.
Solution:
Sparingly soluble sulphides derived from (Pb2+, Cu2+, Bi3+) ions get precipitated.
Final Answer: (B)

31) Explain Question: Identify compound X & Y for given reaction.

Concept: Ba(NO3)2 + Zn+ KOH(aq.) → NH3 + Ba2ZnO2 + K2ZnO2 + H2O
Solution:
Ba(NO3)2 + Zn+ KOH(aq.) → NH3 + Ba2ZnO2 + K2ZnO2 + H2O
↓
(Used in ostwald process for the manufacture of nitric acid)

NH3 → Pungent smell

Final Answer: (B)

32) Explain Question: Calculate enthalpy for the Mutarotation of glucose.

Concept: By using transition reaction obtain the final change, α – D – glucose (s) → β – D –
glucose (s)
Solution:
(i) α – D – glucose (aq) → β – D – glucose (aq) ΔH° = –1.16 kJ mol–1
(ii) α – D – glucose (s) → α – D – glucose (aq) ΔH° = 10.72 kJ mol–1
(iii) β – D – glucose (s) → β – D – glucose (aq) ΔH° = 4.68 [Link]–1
To obtain reaction
(iv) α – D – glucose (s) → β – D – glucose (s)
(iv) = (ii) + (i) – (iii) \
∴ ΔH° = 10.72 – 1.16 – 4.68 = 4.88 kJ mol–1
Final Answer: (A)

33) Explain Question: Identify incorrect statement

Concept: Chemical & physical properties of KMnO4 & K2Cr2O7
Solution:
MnO4– Cr2O72–
(A) Both act as oxidising agent in acidic medium
(B) Both are diamagnetic and coloured compound
(C) O2 is used in the preparation of both
(D) The central atom of the anion in both has d3s hybridisation
Final Answer: (B)

34) Explain Question: Identify correct statement regarding formation of molecular orbitals.
Concept: ψ(g) = ψA + ψB (formation of bonding molecular orbital i.e. linear combination of
atomic orbital ψA + ψB)
Solution:
Curve-(2) represents formation of BMO
ψ(g) = ψA + ψB (formation of bonding molecular orbital i.e. linear combination of atomic orbital
ψA + ψB)
Final Answer: (C)

35) Explain Question: Find correct electronic configuration of d6

Concept: No pairing if P > Δo
Solution:

Final Answer: (C)

36) Explain Question: Identify the correct order of for given properties
Concept: Concept of acidic strength, ionic radius, IE & EA.
Solution:
(A) Acidity of the oxides of non-metals increases with the electronegativity and oxidation
number of the
element.
(Al2O3 < SiO2 < P2O3 < SO3)
(B) Al3+ < Mg2+ < Na+ < F– (Ionic size)
(C) B < C < O < N (IE1)
(D) I < Br < F < Cl (EA)
Final Answer: (C)

37) Explain Question: Which compound shows both OI & GI

Concept: Apply concept of OI & GI.
Solution:
[Co(en)2Cl2]+ → Geometrical and optical isomerism
[Co(NH3)5Cl]2+ → No geometrical isomerism
[Co(NH3)4Cl2]+ → Geometrical isomerism
[Cr(Ox)3 ]3– → Optical isomerism
Final Answer: (A)

38) Explain Question: Which amino acid having 2° amine group

Concept: –NH– is 2° amine
Solution:
 (Proline)
Final Answer: (D)

39) Explain Question: Identify compound which does not react with NaHCO3
Concept: weak acid than H2CO3 hence it will not react with NaHCO3
Solution:
Phenol is weak acid than H2CO3 hence it will not react with NaHCO3
Final Answer: (C)

40) Explain Question: Identify correct IUPAC name of given compound.

Concept: Follow IUPAC nomenclature.
Solution:

7-Chloro-2-methyl bicyclo [3,2,1] octan-8-ol

Hence, option (2) is correct.
Final Answer: (B)

41) Explain Question: Identify the product 'P'

Concept: Acid - base reaction is followed by intra moleculer SN2
Solution:

Final Answer: (C)

42) Explain Question: Which reagent produce the given product from the given reactant.
Concept: NaBH4 reduces only acyl halide, aldehyde and ketone to alcohol
Solution:
NaBH4 reduces only acyl halide, aldehyde and ketone to alcohol.
Final Answer: (D)
43) Explain Question: Which is on antipyretic drug
Concept: Paracetamol → antipyretic
Seldane → Antihistamine
Aspartame → artificial sweetening agent
Solution:
Paracetamol → antipyretic
Seldane → Antihistamine
Aspartame → artificial sweetening agent
Final Answer: (B)

44) Explain Question: Identify which reaction(s) produce(s) single optically active Amine
molecule
Concept: Preparation of aromatic & cyclic amines.
Solution:

(i)

(ii)

3 chiral centres are

generated.
(iii)
Final Answer: (B)

45) Explain Question: Identify compound which undergoes decarboxylation easily.

Concept: More stable carbanion → more rate of decarboxylation
Solution:

More stable carbanion → more rate of decarboxylation

β- keto acid

more stable carbanion due to resonance stabilized

Hence (C) undergo decarboxylation easily

Final Answer: (C)

46) Explain Question: Calculate the asking parameters for given complex.
Concept: Concept of co-ordination compounds.
Solution:
x = +2
y = +4
z = +3
x+y+z=2+4+3=9
Final Answer: (9)

47) Explain Question: Calculate the % of metal exist as Fe+3

Concept: Concept of stiochiometry & balancing.
Solution:
Fe0.98O
Fe+2 Fe+3
100–x% x%

200 – 2x + 3x

x = 4.08%
Final Answer: (4)

48) Explain Question: Calculate the final temperature for given process.
Concept: Apply concept of Irreversible adiabatic expansion.
Solution:

1.5 (T2 – 300) = – 1

1.5T2 – 450 = – 0.5 T2 + 60
2T2 = 510
T2 = 255 K
Final Answer: (255)

49) Explain Question: Which compounds will give immediate turbidity with Lucas reagent
Concept: Turbidity with lucas reagent.
Solution:

(B) Immediately (resonance)

(D) Immediately (Dancing Resonance)

(F) Immediately (Resonance)

(G) Immediately (3°)

(I) Immediately (Aromatic)

(J) C = C – C – OH C = C – C⊕ Immediately (Resonance)

(K) Immediately (3°)

Final Answer: (7)

50) Explain Question: Identify compounds gives positive test for nitrogen in lassaigen's test
Concept: Compounds having carbon, nitrogen, sulphur & halogens gives positive lassaignes
test.
Solution:
(iii), (iv) will give positive test.
Final Answer: (2)
PART 3 : MATHEMATICS

51) Explain Question : We have to solve for x.

Concept : Types of trigonometric equations.
Solution :

Final Answer : (A)

52) Explain Question : We have to find the value of the summation.

Concept : Sum of infinite G.P.
Solution :
The sum of the perimeters, then is
 S = nx + nx cos θ + nx cos2θ + .......... = (where θ = )

Put n = 6 , = = 12

(where x is = )

cos (π – 2θ) =

cos 2θ = – x'2

x'2 = (1 + cos 2θ) = x2 cos2θ

∴ x' = x cos θ.
Final Answer : (D)

53) Explain Question : We have to solve for f(x).

Concept : Types of functions.
Solution :

Integrate – log(1– f(x)2) = 2logx + c

f(1) = 0 c=0

log(1– f(x)2) = log

f(x) =
Final Answer : (D)

54) Explain Question : We have to find solution of the given DE.

Concept : Linear DE
Solution :
Let 2x = t

for tan x = t

Put y=2
2 = ln 1 + c ⇒ c = 2

Final Answer : (A)

55) Explain Question : We have to solve the integrant and then find maxima.
Concept : Properties of DI and maxima - minima.
Solution :

h'(x) = f (x)

h(x) = g'(x) h'(x) = g"(x) = f(x)

∴ Apply IBP

⇒ 3+g =5⇒ g =2
2 2
Let p(x) = k(x – 2) (x – 3) + 3
As, p(1) = 4k + 3 = 7
∴ k = 1 ⇒ f(x) = (x – 2)2 (x – 3)2 + 3
Now, p'(x) = 2(x – 2)(x – 3)(2x – 5)

⇒ p (x) has local maximum at x =

∴ =
Final Answer : (B)

56) Explain Question : We have to solve the integrant and find the required area.
Concept : Properties of DI and area between curves.
Solution :

f(x) = 6 (ln x)2 –

f(x) = 6 (ln x)2 – α ...(1) ​ ​

Now, α =

=
= 2 ⋅ (13 – 03) – α(1 – 0)
=2–α
⇒α=1
So, f(x) = 6 (ln x)2 – 1
Let y = g(x) = f(x) + 1 = 6 (ln x)2

g'(x) = 6 ⋅ 2 ⋅ (ln x) ⋅ = 12 ⋅

= 12e ⋅ (–1) = –12e

= = 6 ⋅ (–ln e)2 = 6

T : y – 6 = –12e
T : y – 6 = –12ex + 12
y + 12ex = 18
x = 0 ⇒ y = 18

y=0⇒x=

Δ= =

Final Answer : (D)

57) Explain Question : We have to find the required images of points.

Concept : Reflection of a point.
Solution :
Let A and B are images of (5, 3) about line y = x and x-axis
∴ A(3, 5) and B(5, –3)
Equation joining AB is y + 3 = –4(x – 5)

& is
Final Answer : (C)

58) Explain Question : We have to find the required locus.

Concept : Parametric coordinates.
Solution :
Let ∠OA′B′ = f and ∠OAB = q

⇒ θ + ϕ = and ∠OBA = ϕ
length of AB is ‘a’ and length of A′B′ is ‘b’
∴ from the figure
A′ (b cos ϕ, 0) and A(a cos θ, 0)
similarly B(0, a sin θ) and B′ (0, b sin ϕ)
Let c(h, k) be the centre of circle
∴ 2h = a cos θ + b cos ϕ

∴ 2h = a cos θ + b sin θ ........(i)

and 2k = a sin θ + b sin ϕ

∴ 2k = a sin θ + b cos θ ........(ii)

on solving (i) and (ii), we get cos θ = and sin θ =

sin2q + cos2q = 1
∴ locus of C(h, k) is (2ax - 2by)² + (2bx - 2ay)² = (a² - b²)²
Final Answer : (D)

59) Explain Question : We have to solve the given integrant.

Concept : Properties of DI and limits.
Solution :

Given

=–1

Let 1 – x2 = t

2xdx = dt
Multiply (–1) for
Final Answer : (A)

60) Explain Question : We have to find Q.

Concept : Image of a point with line.
Solution :

P' and P" are the images of P w.r.t. y = x and y = 0 respectively. Therefore, P' = (3, 5)
The equation of P'P" is

Final Answer : (A)

61) Explain Question : We have to solve for f3(x)

Concept : Summation of trigonometric series.
Solution :

We have

For n = 3,

Now
 , so
Final Answer : (C)

62) Explain Question : We have to solve the limit and examine the discontinuity.
Concept : Continuity at a point.
Solution :

(A)

=– sin 1

discontinuous at x = 1

(B)

f(–1 + h)=

=
= sin 1
discontinuous at x = –1, 1
Final Answer : (C)

63) Explain Question : We have to solve the given limit.

Concept : Methods of finding limits.
Solution :
Take ln on both sides

using expansion

=
Final Answer : (B)

64) Explain Question : We have to find the values of A and B.

Concept : Integration by substitution.
Solution :

I=

=
I = I 1 + I2 …… {Let}
For I1, let tan x cos θ – sin θ = t2

For I2, let

I = I 1 + I2

=
=
Comparing
AB =
Final Answer : (D)

65) Explain Question : We have to solve the integrand and find f(x).
Concept : Properties of DI
Solution :

...(1)

...(1)

in (1) put x = 0 f(0) = –1

Final Answer : (B)

66) Explain Question : We have to find the required locus.

Concept : Radical axis.
Solution :

gives

So and
Let

Hence

So
locus is circle:
Final Answer : (D)

67) Explain Question : We have to use integration and find relation between f(x) and g(x).
Concept : Properties of integration.
Solution :
…(1)
…(2)
…(3)
By integrating (1)

At x = 1,

⇒ 9=4+3+C⇒C=3
∴
Again by integrating,

At x = 2,

⇒ 12 = 4 + 8 + 6 + D ⇒ D = –6
So,
⇒
At x = –2,
⇒ (Option (A) is true)
Now, for – 1 < x , 2
h (x) =
⇒ h'(x) = 3x2 + 3
⇒ h(x)↑
So, h(–1) < h(x) < h(2)
⇒ – 10 < h(x) < 8
⇒ |h(x)| < 10 (option (B) is NOT true)
Now, h'(x) = f'(x) – g'(x) = 3x2 + 3
If |h'(x)| < 6 ⇒ |3x2 + 3| < 6
⇒ 3x2 + 3 < 6
⇒ x2 < 1
⇒ – 1 < x < 1 (option (C) is True)
If x ∈ (–1, 1) |f′(x) – g′(x)| < 6
option (C) is true and now to solve
f(x) – g(x) = 0
⇒ x3 + 3x – 6 = 0

here, and
So there exists such that
Final Answer : (B)

68) Explain Question : We have to find 'a' by finding f(x).

Concept : Properties of ITF.
Solution :

Clearly,

Now domain of equation

So,

So, and minimum and maximum is attained at x = 0 and x = -1

Also,

Hence, sum of integral values of a = 10.

Final Answer : (D)

69) Explain Question : We have to solve for x and y.

Concept : Product and sum formula.
Solution :
...

Divide and multiply by 244

Divide and multiply by 222

Final Answer : (C)

70) Explain Question : We have to solve the summation.

Concept : Special sequences.
Solution :

Hence

Final Answer : (B)

71) Explain Question : We have to solve the given expression and find λ.
Concept : Inverse of a function.
Solution :
(x + 1)3 + (y + 1)3 = 16

⇒ f(x) = g(x)

(f(x + g(x)).g(x + f(x))) = (f(x + f(x)))2

(f(x+f(x)))2 = 2f(x + f(x))

f '(x + f(x)). (1 + f '(x))

(f(x + f(x)))2 at x = –1 + =0

g = =0
Final Answer : (0)

72) Explain Question : We have to find the value of 'n'.

Concept : Problems based on nCr.
Solution :

are both 1, Note that the number of ways to choose numbers left of and

is same as that of right. We started with 9

Sum of possible values of n is (11 + 12) = 23

Final Answer : (3)

73) Explain Question : We have to find n.

Concept : Special sequences.
Solution :
We have Tr – 3Tr–1 = 6r
Dividing both sides by 3r, we get

⇒ =

(∵ T1 = 6)
n n n–1
⇒ Tn = 2 · 3 + 4 · 3 · 2 – 4 · 3n = 2n + 1 · 3n – 2 · 3n
⇒ Tn = 2(6n – 3n)

So,

Now on comparing, we get

=
2 2
⇒ n –12n + 39 = 3 ⇒ (n – 6) = 0
Hence n = 6 Ans.]
Final Answer : (6)

74) Explain Question : We have to find the values of 'm' and 'n'.
Concept : Properties of integration.
Solution :

Consider

Again

Now,

Hence,

Final Answer : (499)

75) Explain Question : We have to solve integration and find f(x).

Concept : Properties of integration.
Solution :
Final Answer : (2)