1.

The standard Gibbs energy charge at 300 K for the reaction

JI
2A ⇌ B + C is 2494.2J. At a gives time, the composition of the
1 1
reaction mixture is [A] = , [B] = 2 and [C] = . The reaction
2 2
proceeds in the [ R = 8.314J/K/mole = 2.718]

LA
1) Forward direction because Q > Kc

2) Reverse direction because Q > Kc

A
3) Forward direction because Q < Kc

4) Reverse direction because Q < Kc

B
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Solution : ∵△ 𝑮𝒐𝒓 = -300× 𝟖. 𝟑𝟏𝟒 𝑰𝒏 𝑲𝒄

JI
−𝟐𝟒𝟗𝟒. 𝟐
= 𝑰𝒏 𝑲𝒄
𝟑𝟎𝟎 × 𝟖. 𝟑𝟏𝟒

LA
𝑰𝒏 𝑲𝒄 = −𝟏
𝟏 𝟏
⇒ 𝑲𝒄 = 𝒆−𝟏⇒ ⇒
𝒆 𝟐. 𝟕𝟏𝟖
A 𝟏
𝑩 [𝑪] 𝟐 × 𝟐
𝑸𝒄 = = =𝟒
[𝑨]𝟐 𝟏𝟐
B
𝟐
𝑸 > 𝑲𝒄
CLASSES BY ANKUR SIR 7983744732
 JI
2. Which one of the following is not state function ?

LA
1) Internal energy

2) Work

3) Entropy
A
4) Free energy
B
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3. An organic compound having C, H and O has 13.13% H, 52.14%C,

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its molar mass is 46.068 g. What are its empirical and molecular
formula

1) 𝑪𝟐 𝑯𝟔 𝑶, 𝑪𝟒 𝑯𝟏𝟐 𝑶𝟐 2) 𝐂𝑯𝟑 𝑶, 𝑪𝟐 𝑯𝟔 𝑶𝟐

LA
3) 𝑪𝟐 𝑯𝟔 𝑶, 𝑪𝟐 𝑯𝟔 𝑶 4) 𝑪𝟐 𝑯𝟔 𝑶𝟐 , 𝑪𝟑 𝑯𝟗 𝑶𝟒

Solution : 𝟓𝟐.𝟏𝟒
AC= 𝟏𝟐
= 4.34
𝟒.𝟑𝟒
= 2
𝟐.𝟏𝟔
B
𝟏𝟑.𝟏𝟑
H= 𝟏
= 13.13

CLASSES BY ANKUR SIR 7983744732

 JI
𝟏𝟑.𝟏𝟑
=6
𝟐.𝟏𝟔
𝟏𝟑.𝟏𝟑
O= = 2.16
𝟏𝟔

LA
𝟐.𝟏𝟔
=1
𝟐.𝟏𝟔
∴ E.F = 𝑪𝟐 𝑯𝟔O
∴ Mol.wt given = 46.068
E.F wt = 46
∴n =
A
𝑴𝒐𝒍.𝒘𝒕
𝑬.𝑭 𝒘𝒕
=
𝟒𝟔.𝟎𝟔𝟖
𝟒𝟔
=1
∴ M.F = E.F ×n = 𝑪𝟐 𝑯𝟔 𝑶 × 𝟏 = 𝑪𝟐 𝑯𝟔 𝑶
B
CLASSES BY ANKUR SIR 7983744732
4. According to significant figure convention the result obtained by

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adding 12.11, 18.0 and 1.012 is

1) 31.12 2) 31.1 3) 31 4) 31.122

LA
A
B
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5. The temperature in K at which ∆G = 0, for a given reaction with

JI
∆H = -20.5 kJ 𝒎𝒐𝒍−𝟏 and
∆S = -50.0 JK 𝒎𝒐𝒍−𝟏 is 𝑬 − 𝟐𝟎𝟏𝟒

LA
1) 410 2) 2.44 3) -2.44 4) 410

Solution :
∆G = ∆H - T∆S
A∆H = T∆S
∆𝑯 𝟐𝟎.𝟓 𝐱 𝟏𝟎𝟑
T= =
∆𝑺 𝟓𝟎
∴ T = 410 K
B
CLASSES BY ANKUR SIR 7983744732
6. A carbon compound contains 12.8% of carbon, 2.1% of hydrogen

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and 85.1% of bromine. The molecular weight of the compound is
187.9. Calculate the molecular formula of the compound. (Atomic
wts: H = 1.008, C = 12.0, Br = 79.9)

LA
1) 𝑪𝑯𝟑 𝑩𝒓 2) 𝑪𝑯𝟐 𝑩𝒓𝟐 3) 𝑪𝟐 𝑯𝟒 𝑩𝒓𝟐 4) 𝑪𝟐 𝑯𝟑 𝑩𝒓𝟑
Solution :
𝟏𝟐.𝟖 𝟐.𝟏 𝟖𝟓.𝟏
; ;
𝟏𝟐 𝟎.𝟎𝟎𝟖 𝟕𝟗.𝟗
𝟏.𝟎𝟔 𝟐.𝟎𝟖 𝟏.𝟎𝟔

1
A ; ;
𝟏.𝟎𝟔 𝟏.𝟎𝟔 𝟏.𝟎𝟔
2 1
B
𝟏𝟖𝟕.𝟗
 𝑪𝑯𝟐 𝑩𝒓 = 12+ 2 + 80 = 𝟗𝟒 = 2 𝑪𝟐 𝑯𝟒 𝑩𝒓𝟐
CLASSES BY ANKUR SIR 7983744732
 JI
7 . Which one of the following is applicable for an adiabatic
expansion of an ideal gas

1) ∆𝑬 = 𝟎

LA
2) ∆W = ∆E

3) ∆W = -∆E

4) ∆W = 0 A
B
CLASSES BY ANKUR SIR 7983744732
8. On increasing temperature, the equilibrium constant of

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exothermic and endothermic reactions, respectively

LA
1) Increases and decreases

2) Decreases and increases

3) Increases and increases

A
4) Decreases and decreases
B
CLASSES BY ANKUR SIR 7983744732
9. The molar heat capacity (Cp) of CD2O is 10 cals at 1000 K. The

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change in entropy associated with cooling of 32 g of CD2O vapour
from 1000 K to 100 K at constant pressure will be :
(D = deuterium, at. mass = 2u)

LA
1) 23.03 cal deg–1 2) –23.03 cal deg–1
3) 2.303 cal deg–1 4) –2.303 cal deg–1
Solution :
100
2.303 (1)(10)log 1000
A
2.303 ×10×log (0.1)
2.303 ×10 × (-1) 2.303 cal deg-1
B
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10. The standard enthalpy of formation of NH3 of is – 46.0 kJ/mol. If

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the enthalpy of formation of H2 from its atoms is – 436 kJ/mol and
that of N2 is –712 kJ/mol, the average bond enthalpy of N – H bond
in NH3 is :
1) –1102 kJ/mol 2) –964 kJ/mol

LA
3) +352 kJ/mol 4) +1056 kJ/mol
Solution :
N2+3H2 2NH3
A
H of products – H of reactants = –2 × 46
6x –[–712+3(–436)] = 2× –46
B
6x + 2020 = 92 6x = 2112 x = 352 kJ/mole
CLASSES BY ANKUR SIR 7983744732
11. For complete combustion of ethanol,

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C2H5OH(l) + 3O2(g)  2CO2(g) + 3H2O(l), the amount of heat produced
as measured in bomb calorimeter, is 1364.47 kJ mol-1 at 250C .
Assuming ideality the Enthalpy of combustion, CH, for the

LA
reaction will be: (R = 8.314 kJ mol-1)
[JEEMAINS-2014]-1
1) –1366.95 kJ mol 2) –1361.95 kJ mol-1
3) –1460.50 kJ mol-1 4) –1350.50 kJ mol-1

Solution : A HC = U + (n)gRT

 – 1364.47kJ + (–1)8.314×298J
B
= – (1364.47+2.48)kJ = –1366.95kJ

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12. The entropy (S0) of the following substances are

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CH4(g) 186.2 JK-1mol-1 O2(g) 205.0 JK-1mol-1
CO2(g) 213.6 JK-1mol-1 H2O(l) 69.9 JK-1mol-1

LA
The entropy change (S0) for the reaction
CH4(g) +2O2(g) CO2(g) + 2H2O(l) is [J.M.O.L-2014]

1) –312.5JK-1mol-1
A 2) –242.8JK-1mol-1

3) –108.1JK-1mol-1 4) –37.6JK-1mol-1
B
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13. The standard enthalpy of formation (fH0298) for methane, CH4 is

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–74.9kJ 𝒎𝒐𝒍−𝟏 . In order to calculate the average energy given out
in the formation of a C-H bond from this it is necessary to know
which one of the following?

LA
1) The dissociation energy of the hydrogen molecule, H2.

2) The first four ionisation energies of carbon.

3) The dissociation energy of H2 and enthalpy of sublimation of
A
carbon (graphite).
4) The first four ionisation energies of carbon and electron
B
affinity of hydrogen.

CLASSES BY ANKUR SIR 7983744732

14. For which one of the following reactions, the entropy change is

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positive?
(E-2013)1
1) H2 + O2 H2O 2) Na+ + Cl− NaCl
2
(g) (g) (g) (g)

LA
(l) (s)
3) NaCl  NaCl 4) H2O  H2O
(l) (s) (l) (g)

Solution :

H2O(l) H2O(g), S > 0

A
B
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15. A piston filled with 0.04 mol of an ideal gas expands reversibly from

JI
50.0mL to 375mL at a constant temperature 𝟑𝟕. 𝟎𝟎 𝐂. As it does so, it
absorb 208J of heat. The values of q and w for the process will be :
(R = 8.314 J / mol K) (ln 7.5 = 2.01) 𝐉𝐄𝐄 𝐌𝐀𝐈𝐍𝐒 − 𝟐𝟎𝟏𝟑

LA
1) q = -208 J, w = -208 J 2) q = -208 J, w = +208 J
3) q = +208 J, w = +208 J 4) q = +208 J, w = -208 J

Solution : A
In this process temperature remains constant, so change internal
energy dE=0
B
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 JI
According to thermodynamics first law dQ = dE + w
In a reversible expensition work done by the system is
negative

LA
So,
dQ = dE - w
208 = 0 - W
∴ W = -208J
A
Heat absorbed by the system Q = +208J
B
CLASSES BY ANKUR SIR 7983744732
16. Given :

JI
1
a) H2(g) + 2O2(g)H2O(l); 𝑯𝟎 𝟐𝟗𝟖𝑲 = –285.91 kJ mol-1
1
b) H2(g) + O2(g)H2O(g);  𝑯𝟎 𝟐𝟗𝟖𝑲 = –241.8 kJ mol-1
2

LA
The molar enthalpy of vapourisation of water will be :

[J.M.O.L-2013]
1) 22.0 kJ mol-1 2) 241.8 kJ mol-1

A
3) 527.7 kJ mol-1 4) 44.1 kJ mol-1
B
CLASSES BY ANKUR SIR 7983744732
17. Given

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Reaction Energy Change (H in kJ)
Li(s)  Li(g) 161
Li(g)  Li+(g) 520

LA
1
F (g)  F(g) 77
2 2
F2(g) +e–  F –(g) (Electron gain enthalpy)
Li+(g) +𝑭− (g)  LiF (s) –1047
1 A
Li+(s) + 2 F2 (g)  LiF (s) –617
Based on data provided, the value of electron gain enthalpy of
B
fluorine would be :

CLASSES BY ANKUR SIR 7983744732

 JI
1) – 328 kJ mol–1 2) – 300 kJ mol–1

3) – 350 kJ mol–1 4) – 228 kJ mol–1

LA
Solution :

Hf = S + D/2 + I.E + (–E.A) + (–U)

– 617 = 161 + 77 + 520 + E.A –1047
A
E.A = –617 + 289 = –328KJ
B
CLASSES BY ANKUR SIR 7983744732
18. Which of the following statements/ relationship is not correct in

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thermodynamic changes?
[J.M.O.L-2013]
V 2) PV𝜸 = constant
1) W = –2.303nRT log 𝟐

LA
V𝟏
H+G 4) G = H – TS
3) S =
T

A
B
CLASSES BY ANKUR SIR 7983744732
19. Given that

JI
(i) fH0 of N2O is KJ mol-1
(ii) Bond energies of N≡N, N=N, O=O and N=O are 946, 418, 498
and 607 KJ mol-1 respectively.

LA
The resonance energy of N2O is:
1) – 88KJ 2) – 66KJ 3) – 62KJ 4) – 44KJ

Solution :
A
Resonance energy =expt. H– calculated H from the bond
B
energy
data given.
CLASSES BY ANKUR SIR 7983744732
H = Bond energy data used for the formation of bond ( taken negative

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(-Ve) ) + bond energy data used for the dissociation ( to be taken as
positive)

LA
H = –[418 +607] + [946+1/2×498] =
– 1025 + 1195 = +170 KJ
N=N N=O Na≡N O=O bond energies.
Resonance energy = 82 – 170 = – 88KJ.
A
B
CLASSES BY ANKUR SIR 7983744732
20. The Gibbs energy for the decomposition of Al2O3 at 5000C is as

JI
follows:
𝟐 4
Al2O3 Al + O2
𝟑 3
rG = +940 kJ mol-1 The potential difference needed for the

LA
electrolytic reduction of aluminium oxide at C should be at least:

1) 4.5 V 2) 3.0 V 3) 5.0 V 4) 2.435 V

Solution :
A
–G = –nFE 2Al = 6e 4/3Al =? 4/3×6=4
B
(this from the stoichiometric equation)
CLASSES BY ANKUR SIR 7983744732
 JI
E=G/nF n=4 F=96500 G=940KJ = 940000J

LA
E = 940000/4 × 96500=2.4352V

A
B
CLASSES BY ANKUR SIR 7983744732
21. The enthalpy of neutralisation of NH4OH with HCl is –51.46 kj mol-1

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and the neutralization of NaOH with HCl is -55.90 kj mol-1. The
enthalpy of ionization of NH4OH is

2) –107.36 kj mol-1

LA
1) +4.44 kj mol-1

3) – 4.44 kj mol-1 4) +107.36 kj mol-1

Solution :
A
∆𝑯(𝑵𝑯𝟒𝑶𝑯+𝑯𝑪𝑰)= ∆𝑯(𝑵𝒂𝑶𝑯+𝑯𝑪𝑰) + 𝒅𝒊𝒔𝒔𝒐𝒄𝒊𝒂𝒕𝒊𝒐𝒏
enthalpy of 𝑵𝑯𝟒 𝑶𝑯
B
CLASSES BY ANKUR SIR 7983744732
22. The entropy of a sample of a certain substance increases by

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0.836 JK-1 on adding reversibly 0.3344J of heat at constant
temperature. The temperature of the sample is
1) 0.016 K 2) 0.3 K 3) 0.4 K 4) 2.5 K

LA
Solution :
S = 0.836JK-1
H = 0.334J

S =
H
T
A
 T = 0.4K
B
CLASSES BY ANKUR SIR 7983744732
23. The difference b/w the reaction enthalpy change (r,H) and reaction

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internal energy change (r,U) for the reaction
2 C6H6(l) + 15 O2(g) 12 CO2(g) + 6 H2O(l) at 300 K
is (R=8.314 J mol-1 K-1)

LA
1) 0 J mol-1 2) 2490 J mol-1
3) -7482 J mol-1 4) -2490 J mol-1

Solution :
A
n = n(g)(Prod) – n(g)(Rea) = 12 – 15 = –3
B
H – E = nRT = – 3×8.314×300 = – 7482J

CLASSES BY ANKUR SIR 7983744732

24. One mole an ideal gas is expanded isothermally and reversibly to

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half its initial pressure s for the process in JK-1 mol-1 is
(log2=0.3010 and R=8.314jmol-1 K-1)

LA
1) 6.76 2) 5.76 3) 8.03 4) 10.76

Solution :

A p𝟏
s = 2.303 n.R.log
p𝟐
1
B
= 2.303×1×8.314 log = 5.76
1/2
CLASSES BY ANKUR SIR 7983744732
25. The molar heat capacity (CP) of water at constant pressure is

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75 J.K-1.mol-1 The increase in temperature (in K) of of water when 1
k.J. of heat is supplied to it is. (E-
2012)

LA
1) 2.4 2) 0.24 3) 1.3 4) 0.13

Solution :
Q = ncpt
100 A
1000 = 18 × 75 × t
B
CLASSES BY ANKUR SIR 7983744732
26. The incorrect expression among the following is (AIEEE 2012)

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H −TS
𝟎 𝟎

2) K = e−𝐆
1) In K = 𝟎 /𝐑𝐓
RT
Gsystem

LA
Vf
3)
Stotal
= −T 4) In isothermal process Wreversible= –nRT In
Vi

Solution :
G𝟎 = H𝟎 − 𝐓S𝟎
A G𝟎 = –RT ln Keq
B
CLASSES BY ANKUR SIR 7983744732
27. In the Born-Haber cycle of the given reaction the number of

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endothermic and exothermic steps. (E-
2011)
Na + ½ Cl  NaCl
(s) 2(g) (s)

LA
1) 2, 3 2) 3, 1 3) 3, 2 4) 2, 2

Solution :
A
Three endothermic, two exothermic.
B
CLASSES BY ANKUR SIR 7983744732
28. The entropy change involved in the isothermal reversible expansion

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of 2 moles of an ideal gas from a volume of 10 dm3 to a volume of
100 dm3 at 2700C is
1) 42.3 J mol-1 K-1 2) 38.3 J mol-1 K-1

LA
3) 35.8 J mol-1 K-1 4) 32.3 J mol-1 K-1

Solution :

A V2
S = 2.303 nR log
V1
100
B
= 2.303×2×8.314×log 10 = 38.29 J mol-1 K-1

CLASSES BY ANKUR SIR 7983744732

29. Which one of the following pairs represents the intensive properties?

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(E 2011)
1) Specific heat and temperature

LA
2) Entropy and density
3) Enthalpy and mole fraction
4) Heat and temperature

A
B
CLASSES BY ANKUR SIR 7983744732
30. The standard enthalpy of formation of NH3 is -46.0 kJ mol-1.If the

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enthalpy of formation of H2 from its atoms is -436 kJ mol-1 , and that
of N2 is -712 kJ mol-1, the average bond enthlpy of N - H bond in
NH3 is

LA
(A-2010)
1) -964 kJ mol-1 2) + 352 kJ mol-1
3) + 1056 kJ mol-1 4) - 1102 kJ mol-1

Solution :
1 3 A
2 N 2(g)+ 2H2(g)NH3(g)
H = BE of reactants -BE products
B
1 3
− 46 = × −𝟕𝟏𝟐 + × −𝟒𝟑𝟔 − 𝟑𝐱
2 2
CLASSES BY ANKUR SIR 7983744732
 JI
Where x is bond dissociation energy of N–H
3x = 1056

x = +352 kJmol-1

LA
A
B
CLASSES BY ANKUR SIR 7983744732
31. The Gibbs energy for the decomposition of Al2O3 at 5000C is as

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follows : 2 4
Al2O3 Al + O2, rG = +966kJ mol-1
3 3
The potential difference needed for electrolytic reduction of Al2O3 at

LA
is at 5000C least
(A-2010)
1) 4.5 V 2) 3.0 V 3) 2.5 V 4) 5.0 V

Solution : 2 4
AAl2O3 Al + O2 ,
3 3
G = –nFEcellEcell
B
n = 4e- 966×103J = – 4×96500×Ecell =2.5V
CLASSES BY ANKUR SIR 7983744732
32. For a particular reversible reaction at temperature T, H and S

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were found to be both +ve.If Te is the temperature at equilibrium,
the reaction would be spontaneous when (A-2010)
1) Te>T 2) T>Te 3) Te is 5 times T 4) T=Te

LA
Solution :
G = H –TS
If TS > H; G = –ve

T>
H
S
A
But at equilibrium G = 0

H
B
H –TeS = 0 =Te  T >Te
S
CLASSES BY ANKUR SIR 7983744732
33. Given that , Hf (H) = 218 KJ/mol, express the H–H bond energy in

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kcal/mol.
1) 52.15 2) 911 3) 104 4) 52153

LA
Solution :

H of H2 = 2×Hf (H)

A
1 kcal = 4.18 kJ
B
CLASSES BY ANKUR SIR 7983744732
34. Calculate H in kJ for the following reaction C(g) + O2(g)CO2(g)

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Given that,
H2O(g)+C (g)CO (g)+H2(g); H = +131KJ
1
CO (g)+ 2 O2(g)CO2(g); H = –282KJ

LA
1
H2(g)+ O2(g)H2O(g); H = –242KJ
2

1) –393 2) +393 3) +655 4) –655

Solution :
A
B
eg 1+eg 2+eg 3
CLASSES BY ANKUR SIR 7983744732
35. Oxidising power of chlorine in aqueous solution can be determined

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by the parameters indicated below:
1
𝚫𝐝𝐢𝐬𝐬𝐇 𝚫𝐄𝐚𝐇 𝚫𝐡𝐲𝐝𝐇 
1 2 −
Cl Cl (g) Cl (g) Cl− (aq)
2 2(g)

LA
The energy involved in the conversion of
1
Cl2(g) Cl− (aq) by using the following data
2

𝑪𝒍𝟐
A
𝚫𝐝𝐢𝐬𝐬𝐇 = 240kJmol-1; 𝚫𝐞𝐠𝐇  = –349kJmol-1
𝑪𝒍

𝚫𝐡𝐲𝐝𝐇 − = –381kJmol-1 will be

B
(A-
𝑪𝒍
2008)
CLASSES BY ANKUR SIR 7983744732
 JI
1) + 152 kJ mol-1 2) - 850 kJ mol-1

4) + 120 kJ mol-1

LA
3) - 610 kJ mol-1

Solution :

1
H = 2 disH𝑪𝒍𝟐 +egCl + hydHCl-

240
A
2 – 349 –381 kJ
B
= – 610 kJ
CLASSES BY ANKUR SIR 7983744732
36. Standard entropy of X2,Y2 ,and XY3are 60, 40 and 50JK-1mol-1,

JI
respectively. For the reaction,
1 3
X𝟐 + Y𝟐 XY𝟑 𝐇 = −𝟑𝟎K.J to be at equilibrium the
2 2
temperature will be (A-

LA
2008)
1) 1250K 2) 500K 3) 1000K 4) 750K

Solution :

𝟏
A
rS0 = ∑S𝟎𝐩𝐫𝐨𝐝𝐮𝐜𝐭𝐬 –∑S𝟎𝐫𝐞𝐚𝐜𝐭𝐚𝐧𝐭𝐬
𝟑
S𝟎𝑿𝒀𝟑 – 𝟐 S𝟎𝑿𝟐 + 𝟐 S𝟎𝒀𝟐
B
CLASSES BY ANKUR SIR 7983744732
 1 3
= 𝟓𝟎– × 𝟔𝟎 + × 𝟒𝟎

JI
2 2
= – 40 JK-1mol-1

rG0 = rH0 –T rS0

LA
at eqn rG0 = 0
rH0 –30×1000
T =  S0 = = 750K
r – 40
A
B
CLASSES BY ANKUR SIR 7983744732
37. Calculate the enthalpy of formation of ethylene from the following

JI
data
A) C(gr)+O2(g)CO2(g); H = –393.5KJ
(E-2007)
1
B) H2(g)+ O2(g)H2O(l); H = –286.25KJ

LA
2
5
C) C2H4(g)+ O2(g)2CO2(g)+2H2O(l); H = –1410.8KJ
2
1) – 54.1 KJ 2) – 44.8 KJ

A
3) + 51.4 KJ 4) – 48.4 KJ

Solution :
B
Ax2+Bx2- C
CLASSES BY ANKUR SIR 7983744732
38. Calculate the difference between E and H for the following

JI
equilibrium at 27°C in K.Cal
(E-2007)
C +2H CH
(graphite) 2(g) 4(g)

LA
1) – 0.6 2) – 1.2 3) 0.6 4) 1.2

Solution :

H = E+ nRT
A
n = -1
E – H = RT
B
CLASSES BY ANKUR SIR 7983744732
39. In conversion of lime stone to lime,

JI
CaCO3(s)CaO(s)+CO2(g)
the values of H0 and S0 are + 179.1 kJmol-1 and 160.2J/K
respectively at 298K and 1 bar. Assuming that H0 and S0 do not

LA
change with temperature, temperature above which conversion of
limestone to lime will be spontaneous is

1) 1118 K 2) 1008 K 3) 1200 K 4) 845 K

Solution : A
G0 = H0 – TS0
for a spontaneous reaction G0 < 0
B
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 JI
(or)

H0
H0 – 0  T > S0
TS0 <

LA
179.3×103
T >  1117.9K = T > 1118K
160.2

A
B
CLASSES BY ANKUR SIR 7983744732
40. Assuming that water vapour is an ideal gas, the internal energy

JI
change (U) when 1 mol of water is vapourised at 1 bar pressure
and 1000C, (given: molar enthalpy of vapourisation of water at 1bar
and 373 K=41 kJ mol-1 and R=8.3 Jmol-1 K-1) will be (A-2007)

LA
1) 41kJ mol-1 2) 4.1kJ mol-1
3) 3.7904kJ mol-1 4) 37.904kJ mol-1
Solution :
U = H –nRT
n = + 1
A H2O(l) H2O(g)
U = H – RT
B
U = 41 – 8.314 ×10-3×373 =37.904 kJ/mol
CLASSES BY ANKUR SIR 7983744732
41. Identify the correct statement regarding a spontaneous process:

JI
𝑨 − 𝟐𝟎𝟎𝟕

1) Lowering of energy in the process is the only certion

for spontaneity.

LA
2) For a spontaneous process in an isolated system, the
change in entropy is positive.
3) Endothermic process are never spontaneous.
A
4) Exothermic process are always spontaneous.
B
CLASSES BY ANKUR SIR 7983744732
42. Identify the reaction in which the heat liberated corresponds to the

JI
heat liberated corresponds to the heat of formation (∆H)
𝑬 − 𝟐𝟎𝟎𝟔
1) 𝑪(𝒅𝒊𝒂𝒎𝒐𝒏𝒅)+𝑶𝟐(𝒈) C𝑶𝟐(𝒈) + Heat

LA
2) 𝟐𝑯𝟐(𝒈) 𝑶𝟐(𝒈) 𝟐𝑯𝟐 𝑶(𝒈) +
3) 𝑪(𝒅𝒊𝒂𝒎𝒐𝒏𝒅) + 2𝑯𝟐(𝒈)Heat C𝑯
𝟒(𝒈) + Heat
4) 𝑺(𝒓𝒉𝒐𝒎𝒃𝒊𝒄) + 𝑶𝟐(𝒈) 𝑺𝑶𝟐(𝒈) + Heat
Solution :
A
𝑺(𝒓𝒉𝒐𝒎𝒃𝒊𝒄) is standard form
B
then ∆H = -400 = 𝑬𝒙𝟐 + 𝑬𝒚𝟐 - 2𝑬𝒙𝒚

CLASSES BY ANKUR SIR 7983744732

 JI
-400 = a + 0.5a – 2a

-400 = -0.5a

LA
𝟒𝟎𝟎
a= = 800 kJ 𝒎𝒐𝒍−𝟏
𝟎.𝟓

A
B
CLASSES BY ANKUR SIR 7983744732
 JI
43. Identify the reaction for which ∆H ≠ ∆E 𝑬 − 𝟐𝟎𝟎𝟔

1) 𝑺(𝒓𝒉𝒐𝒎𝒃𝒊𝒄) + 𝑶𝟐(𝒈) 𝑆𝑂2(𝑔)

LA
2) 𝑵𝟐(𝒈) + 𝑶𝟐(𝒈) 2𝑁𝑂(𝑔)
3) 𝑯𝟐(𝒈) + 𝑪𝒍𝟐(𝒈) 2𝐻𝐶𝑙(𝑔)
𝟏
4) 𝑪𝑶(𝒈) + 𝑶𝟐(𝒈)
𝟐
𝐶𝑂2(𝑔)
A
B
CLASSES BY ANKUR SIR 7983744732
44. An ideal gas is allowed to expand both reversibly and irreversibly in

JI
an isolated system. If Ti is the initial temperature and Tf is the final
temperature, which of the following statements is correct?
(A- 2006)
1) T𝐟 𝐫𝐞𝐯 = T𝐟 𝐢𝐫𝐫𝐞𝐯

LA
2) T𝒇 = T𝒊 for both reversible and irreversible processes

3) T𝐟 𝐢𝐫𝐫𝐞𝐯 > T𝐟 𝐫𝐞𝐯

A
4) T𝒇 > T𝒊 for reversible process but T𝒇 > T𝒊 for irreversible
B
process.

CLASSES BY ANKUR SIR 7983744732

45. The standard enthalpy of formation (fH0) at 298K for methane,

JI
CH4(g) is –74.8 kJ mol-1. The additional information required to
determine the average energy for C-H bond formation would be
(A-2006)

LA
1) The first four ionization energies of carbon and electron gain
enthalpy of hydrogen

2) The dissociation energy of hydrogen molecule, H2

A
3) The dissociation energy of H2 and enthalpy of sublimation of
carbon.
B
4) Latent heat of vapourization of methane.

CLASSES BY ANKUR SIR 7983744732

46. The enthalpy changes for the following processes are listed below:

JI
Cl2(g)2Cl(g), 242.3kJ mol-1
I2(g)2I(g) 151.0kJ mol-1
2ICl (g)I(g)+Cl(g) 211.3kJ mol-1

LA
I2(S)I2(g) 62.76kJ mol-1
Given that the standard states for iodine and chlorine are I2(S)
and Cl2(g), the standard enthalpy of formation for ICl(g) is:
(A-
2006) A
1) +16.8 kJ mol-1

3) –14.6kJ mol-1
2) +244.8kJ mol-1
4) – 16.8kJ mol-1
B
CLASSES BY ANKUR SIR 7983744732
 JI
47. (H–U) for the formation of carbon monoxide from its elements at
298K is
(A-2006)
1) –2477.57 J mol-1 2) 2477.57 J mol-1

LA
3) –1238.78 J mol-1 4) 1238.78 J mol-1

A
B
CLASSES BY ANKUR SIR 7983744732
48. Which of the following is not correct?

JI
1) Dissolution of NH4Cl in excess of water is an endothermic process.

2) Neutralisation process is always exothermic.

LA
3) The absolute value of enthalpy (H) can be determined
experimentally

4) The heat of reaction at constant volume is denoted by E

A
B
CLASSES BY ANKUR SIR 7983744732
49. The heat of formation of CO(g) and CO2 (g) are H = –110 and

JI
H = –393 KJ mol–1 respectively. What is the heat of reaction (H)
1
(in KJ mol–1) for the following reaction CO(g)+ 2O2(g)CO2(g) (E-2005)

LA
1) – 504 2) –142.5 3) – 283 4) 504

A
B
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50. For a spontaneous reaction the G, equilibrium constant (K) and

JI
𝟎
E𝐜𝐞𝐥𝐥 will be respectively (A-2005)

1) –ve, > 1, –ve 2) –ve, <1, –ve

LA
3) +ve, >1, –ve 4) –ve, >1, +ve

A
B
CLASSES BY ANKUR SIR 7983744732
51. Consider the reaction: N2+3H22NH3 carried out at constant

JI
temperature and pressure. If H and U are the enthalpy and
internal energy changes for the reaction, which of the following
expressions is true?

LA
(A-2005)
1) H > U 2) H < U

3) H = U 4) H = 0

A
B
CLASSES BY ANKUR SIR 7983744732
 JI
52. If the bond dissociation energies of XY, X2 and Y2 (all diatomic
molecules) are in the ratio of 1:1:0.5 and Hf for the formation of XY
is –200 kJmol-1. The bond dissociation energy of x2 will be (in KJ/mol)
(A- 2005)

LA
1) 400 2) 300 3) 200 4) 800

A
B
CLASSES BY ANKUR SIR 7983744732
 JI
53. Which of the following is an endothermic reaction ? (E-
2004)
1) N2(g) + 3H2(g)–92KJ2NH3(g)

LA
2) N2(g) + O2(g)+180.8KJ2NO(g)
3) H2(g) + Cl2(g)2HCl(g)+184.6KJ
4) C(graphite) + 2H2(g)CH4(g)+74.8KJ
A
B
CLASSES BY ANKUR SIR 7983744732
 JI
54. Which of the following is an exothermic reaction? (E-
2004)
1) N2(g) + O2(g) + 180.8KJ2NO(g)
2) N2(g) + 3H2(g) –92KJ2NH3(g)

LA
3) C(graphite) + H2O(g)CO(g)+H2(g) – 131.4KJ

4) C(graphite) + 2S(s) CS2(l) – 91.9KJ

A
B
CLASSES BY ANKUR SIR 7983744732
55. The formation of the oxide O𝟐−
(𝐠) ion requires first an exothermic and

JI
then an endothermic step as shown below
O(𝐠) + 𝐞 → O− 𝟎
(𝐠) , H = −142kJmol
−1

O− 𝟐− 𝟎
(𝐠) + 𝐞 → O(𝐠) , H = 844kJmol

LA
−1

This is because (A-

2004)
1) O− ion will tend to resist the addition of another electron.
A
2) Oxygen has high electron affinity
3) Oxygen is more electronegative
B
4) O− ion has comparatively larger size than oxygen atom.

CLASSES BY ANKUR SIR 7983744732

 JI
Solution :

LA
O− ion exerts a force of repulsion on the in coming electron the energy
is required to over come it

A
B
CLASSES BY ANKUR SIR 7983744732
56. An ideal gas expands in volume from 1×10-3 to 1×10-2m3 at 300K

JI
against a constant pressure of 1×105Nm-2 . The work done is (A-2004)

1) 270 kJ 2) -900 kJ 3) -900 J 4) 900 kJ

LA
Solution :

w = –PV A
= –1×105×(1×10-2 –1×10-3) = –900 J
B
CLASSES BY ANKUR SIR 7983744732
57. The enthalpies of combustion of carbon and carbon monoxide are

JI
–393.5 and –283 kJ mol-1 respectively. The enthalpy of formation of
carbon monoxide per mole is
(A-2004)
1) -676.5 kJ 2) 676.5 kJ 3) 110.5 kJ 4) -110.5 kJ

LA
Solution :
C + O2CO2; H1 = –393.5 kJ …(1)
1
CO + 2 O2CO2; H2 = –283 kJ …(2)

we have
1
A
after eq 1 – eq 2

C + 2 O2CO; H = - 110.5 kJ
B
CLASSES BY ANKUR SIR 7983744732
58. The internal energy change when a system goes from state A to B is

JI
40kJ/mole. If the system goes from A to B by a reversible path and
returns to state A by an irreversible path what would be the net
change in internal energy? (A-2003)

LA
1) > 40 kJ 2) < 40 kJ 3) Zero 4) 40 kJ

Solution :
A
for a cyclic process : E = 0

E does not depend on the path

B
CLASSES BY ANKUR SIR 7983744732
59. If at 298K the bond energies of C-H, C-C, C=C and H-H bonds are

JI
respectively 414, 347, 615 and 435kJmol-1, the value of enthalpy
change for the reaction
H2C = CH2(g) + H2(g)H3C – CH3(g)

LA
at 298 K will be (A-
2003)
1) - 250 kJ 2) + 125 kJ 3) -125 kJ 4) + 250 kJ

Solution :
A
H2C=CH2+H2CH3–CH3; H = ?
B
CLASSES BY ANKUR SIR 7983744732
H =∑BE of reactants - ∑BE of products

JI
H = 1(C=C) + 4(C–H) + 1(H–H)
– [1(C–C) + 6(C–H)]

LA
A
B
CLASSES BY ANKUR SIR 7983744732
60. If liquids A and B form an ideal solution (A- 2003)

JI
1) the entropy of mixing is zero

2) the free energy of mixing is zero

LA
3) both free energy and the entropy of mixing are zero

4) the enthalpy of mixing is zero

Solution : A
When A and B form an ideal gas
B
Hmix= 0
CLASSES BY ANKUR SIR 7983744732
60. If liquids A and B form an ideal solution (A- 2003)

JI
1) the entropy of mixing is zero

2) the free energy of mixing is zero

LA
3) both free energy and the entropy of mixing are zero

4) the enthalpy of mixing is zero

Solution : A
When A and B form an ideal gas
B
Hmix= 0
CLASSES BY ANKUR SIR 7983744732
61. In an irreversible process taking place at constant T and P and in

JI
which only pressure-volume work is being done, the change in
Gibb’s free energy (G) and change in entropy (dS), satisfy the
criteria (A- 2003)

LA
1) (S) V,E > 0, (G) T,P < 0 2) (S) V,E = 0, (G) T,P = 0

3) (S) V,E = 0, (G) T,P > 0 4) (S) V,E < 0, (G) T,P < 0

Solution :
A
for a spontaneous process
B
S > 0, G < 0
CLASSES BY ANKUR SIR 7983744732
62. The correct relationship between free energy change in a reaction

JI
and the corresponding equilibrium constant KC is (A-2003)

1) –G = RT In KC 2) G𝟎 = RT In KC

LA
3) –G𝟎 = RT In KC 4) G = RT In KC

Solution :
A
–G𝟎 = RT In KC
B
CLASSES BY ANKUR SIR 7983744732
63. The enthalpy change for a reaction does not depend upon (A-2003)

JI
1) Use of different reactants for the same product
2) The nature of intermediate reaction steps

LA
3) The differences in initial or final temperatures of involved
substances
4) The physical states of reactants and products

Solution : A
𝐇 for a reaction does not depend on the nature of intermediate
B
reaction steps

CLASSES BY ANKUR SIR 7983744732

64. Calculate the heat of combustion (in KJ) of methane from the

JI
following data
(2002)
i) C + 2H CH H = – 74.8KJ
(graphite) 2(g) 4(g)

ii) C(graphite) + O2(g)CO2(g) ; H = – 393.5KJ

LA
1
iii) H2(g) + 2 O2(g)H2O(l) ; H = – 286.2KJ

1) – 891.1 2) – 816.3 3) – 965.9 4) – 1040.7

Solution :
A
B
eq 2 + 2 × eg 3 – eg 1
CLASSES BY ANKUR SIR 7983744732
65. Which one of the following is an example of exothermic reaction?

JI
1) H2(g) + Cl2(g) 2HCl(g); H = –184.6KJ
2) N2(g) + O2(g) 2NO(g); H = +180.8KJ

LA
3) C(graphite) + H2O(g)CO(g)+H2(g) –131.4KJ
4) C(graphite) + 2S(s) + 91.9KJ CS2(l)

A
B
CLASSES BY ANKUR SIR 7983744732
66. If an endothermic reaction is non-spontaneous at freezing point of

JI
water and becomes feasible at its boiling point, then (A-
2002)
1) H is -ve, S is +ve 2) H & S both are +ve

LA
3) H & S both are -ve 4) H is +ve, S is -ve

Solution :
G = H – TS
A
at low temperature S: –ve which makes G: +ve
but at high temperature S:+ve
which makes G: –ve
B
CLASSES BY ANKUR SIR 7983744732
67. A heat engine absorbs heat 𝑸𝟏 at temperature T1 and heat 𝑸𝟐 at

JI
temperature T2. Work done by the engine is . J(Q1+Q2). This data
(A- 2002)
1) Violates 1st law of thermodynamics

LA
2) Violates 1st law of thermodynamics if Q1 is negative
3) Violates 1st law of thermodynamics of is Q2negative
4) Does not violate 1st law of thermodynamics
A
B
CLASSES BY ANKUR SIR 7983744732
68. For the reactions

JI
C(s)+ O2(g)  CO2(g)
(A-2002) H = –393J
2Zn(s)+ O2(g)  2ZnO(s) H = –412J
1) carbon can oxidise Zn 2) oxidation of carbon is not feasible

LA
3) oxidation of Zn is not feasible 4) Zn can oxidise carbon.

Solution : A
H:–ve shows that the reaction is spontaneous higher value for Zn
B
shows that the reaction is more feasible So Zn can oxidise carbon

CLASSES BY ANKUR SIR 7983744732

69. In the reaction

JI
CH3COOH(aq)+OH− −
(𝒂𝒒) CH3COO(𝒂𝒒) + H2O(l)
H = –55.2 KJ.mol-1. What is the heat of dissociation (in KJ.mol–1)
of acetic acid (E-

LA
2000)
1) + 2.1 2) – 57.3 3) – 35.1 4) – 175.1

Solution :
A
heat of dissociation = -55.2 - (-57.3) kJ
= +2.1 kJ
B
CLASSES BY ANKUR SIR 7983744732
70. Calculate the heat of formation (H) of CO (in K.Cals) from the

JI
following data (E-2000)
C(gr)+O2(g)CO2(g); H = –94KCal
1

LA
CO(g)+ 2 O2(g)CO2(g); H = –68KCal

1) –13 2) –26 3) –162 4) –81

Solution : A
eg 1 – eg 2
B
CLASSES BY ANKUR SIR 7983744732
71. Heat of combustion of carbon is -96K.Cals. When some quantity of

JI
carbon is burnt in oxygen, 48 K.Cals of heat is liberated. What is the
volume (in lits) of O2 at STP reacted with this carbon ? (E-
2000)
1) 48 2) 22.4 3) 11.2 4) 1

LA
Solution :
C + O2CO2; H = –96kcal
22.4 ltrs H = –
96kcal
?

22.4
A H = –48kcal

96 ×48 = 11.2
B
CLASSES BY ANKUR SIR 7983744732
72. The heats of combustion of carbon and carbon monoxide are – 393.5

JI
and -283.5 kJ 𝒎𝒐𝒍−𝟏 , respectively. The heat of formation (in kJ) of
carbon monoxide per mole is (JEE MAINS – 2016)

LA
1) 110.5 2) 676.5 3) -676.5 4) -110.5

Solution :
Heat of formation of (Co)
A = -393.5 – (-283.5)
B
= -110.0 kJ/mole

CLASSES BY ANKUR SIR 7983744732

73 For the reaction

JI
A(g) + B(g)  C(g) + D(g),∆𝑯𝑶 and ∆𝑺𝑶 respectively, -29.8 kJ
𝒎𝒐𝒍−𝟏and -0.100kjmol-1
at 928 K. The equilibrium constant for the reaction at 298 K is:
(J.M.O.L – 2016)

LA
1) 1.0 × 𝟏𝟎−𝟏𝟎 2) 10 3) 1 4) 1.0 × 𝟏𝟎𝟏𝟎
Solution :

∆𝑮𝑶 = ∆𝑯𝑶 - T. ∆𝑺𝑶

A
= -29.8 + 298 × (0.1)
= -29.8 + 29.8
∴ ∆𝑮𝑶 = 0
∴ ∆𝑮𝑶 = -RT ln 𝑲𝒆𝒒
B
apply relation between ∆𝑮𝑶 & 𝑲𝒆𝒒 𝑲𝒆𝒒 = 1
CLASSES BY ANKUR SIR 7983744732
74. A reaction at 1 bar is non-spontaneous at low temperature but

JI
becomes spontaneous at high temperature. Identify the correct
statement about the reaction among the following :
(J.M.O.L-2016)

LA
1) ∆H is negative while ∆S is positive.
2) Both ∆H and ∆S are negetive.
3) ∆H is positive and while ∆S are negitive.
A
4) Both ∆H and ∆S are positive.
B
CLASSES BY ANKUR SIR 7983744732
75. If 100 mole 𝑯𝟐 𝑶𝟐 decompose at 1 bar and 300 K, the work done

JI
(KJ) by one mole of 𝑶𝟐(𝒈) as it expands against 1 bar pressure is:
𝟐𝑯𝟐 𝑶𝟐 𝒍 ⇋ 𝟐𝑯𝟐 𝑶 𝒍 + 𝑶𝟐(𝒈)
(R = 8.3𝐉𝐊 −𝟏 𝐦𝐨𝐥𝐞−𝟏 )

LA
(J.M.O.L-2016)

1) 124.50 2) 249.00 3) 498.00 4) 62.25

Solution :
W = P∆v = nRT
A = 100×8.3×300
= 249000J
B
= 249KJ
CLASSES BY ANKUR SIR 7983744732
76. Identify the correct statements among the following

JI
I) At equilibrium, change in entropy for a process, ∆S = 0
II) Temperature is an extensive property

LA
III) For a cyclic process ∆U≠0
IV) During free expansion of a gas under reversible or
irrversible condition, ∆W = 0

1) I & II A 2) I & IV 3) II & III 4) I & II

B
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77. Given that

JI
𝑪(𝒔) +𝑶𝟐(𝒈) → 𝑪𝑶𝟐 𝟎
𝒈 ; ∆𝑯 = -x kJ
2𝑪𝑶(𝒈) +𝑶𝟐(𝒈) → 𝟐𝑪𝑶𝟐 𝒈 ; ∆𝑯𝟎 = -ykJ
The enthalpy of formation of CO will be (AP E – 2016)

LA
𝒀 −𝟐𝑿 𝒀 −𝟐𝑿 𝟐𝑿−𝒀 𝑿−𝒀
1) 2) 3) 4)
𝟑 𝟐 𝟐 𝟐
𝟏
Solution : 𝑪(𝑺) + 𝟐 𝑶𝟐(𝑺)  𝑪𝑶(𝒈)
C + 𝑶𝟐  𝑪𝑶𝟐 ∆𝑯 = - x
A 𝟏 𝒚
CO+ 𝑶𝟐  𝑪𝑶(𝟐) ∆𝑯 = −
𝟐 𝟐
B
𝒚 𝒚−𝟐𝒙
-x + 
𝟐 𝟐
CLASSES BY ANKUR SIR 7983744732
78. Given that

JI
𝑵𝟐(𝒈) +𝟑𝑯𝟐 (𝒈) → 𝟐𝑵𝑯𝟑 𝒈 ; ∆𝑯 = -92 kJ the standard molar enthalpy
of formation in kJ 𝒎𝒐𝒍−𝟏 of 𝑵𝑯𝟑(𝒈) is (AP E-2016)

LA
1) – 92 2) +46 3) +92 4) -46

Solution :
A
Standard molar enthalpy (for 1 mole)

= -92/2 = -46KJ/mole
B
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