Class : XIth Subject : CHEMISTRY
Date : DPP No. : 2
Topic :- Equilibrium
1. A solution of FeCl3 in water acts as acidic due to:
a) Acidic impurities b) Ionisation c) Hydrolysis of Fe3+ d)Dissociation
2. The concept that an acid is a proton donor and a base is a proton acceptor was introduced by:
a) Arrhenius b) Bronsted-Lowry c) Lewis d)Faraday
3. Which is decreasing order of strength of bases?
OH,NH2,HC ≡ C― and CH3CH― 2
― ― ― ―
a) H3CCH2 > 𝑁H2 > 𝐻𝐶 ≡ C > 𝑂H b) HC ≡ C― > 𝐶H3CH― ―
2 > 𝑁H2 > 𝑂H
―
c) OH― > 𝑁H― ―
2 > 𝐶𝐻 ≡ C > H3CCH2
―
d) NH― ― ―
2 > 𝐻𝐶 ≡ C > 𝑂H > H3CCH2
―
4. The strength of an acid depends on its tendency to
a) Accept protons b) Donate protons c) Accept electrons d)Donate electrons
5. The following reactions are known to occur in the body,
CO2 + H2O⇌H2CO3⇌H+ + HCO― 3
If CO2 escapes from the system, then:
a) pH will decrease
b) Hydrogen ion concentration will diminish
c) H2CO3 concentration will be unaltered
d) The forward reaction will be promoted
6. The common ion effect is shown by which of the following sets of solutions?
a) BaCl2 + BaNO3 b) NaCl + HCl c) NH4OH + NH4Cl d)None of these
7. In the reaction, C(𝑠) + CO2(g)⇌2CO(g), the equilibrium pressure is 12 atm. If 50% of CO2
reacts, 𝐾𝑝 for the change is :
a) 12 atm b) 16 atm c) 20 atm d)6 atm
8. For a given solution pH = 6.9 at 60℃, where 𝐾𝑤 = 10 . The solution is:
―12
a) Acidic b) Basic c) Neutral d)Unpredictable
9. A quantity of PCl5 was heated in a 10 litre vessel at 250C to show PCl5(g)⇌PCl3(g) +Cl2(g). At
equilibrium the vessel contains 0.1 mole of PCl5, 0.20 mole of PCl3 and 0.20 mole of Cl2. The
equilibrium constant of the reaction is :
a) 0.02 b) 0.05 c) 0.04 d)0.025
10. One mole of ethyl alcohol was treated with one mole of acetic acid at 25C. 2/3 of the acid
changes into ester at equilibrium. The equilibrium constant for the reaction will be:
a) 1 b) 2 c) 3 d)4
11. 9.2 g of N2O4(g) is taken in a closed 1 L vessel and heated till the following equilibrium is
reached
N2O4(g)⇌2NO2(g)
At equilibrium, 50% N2O4(g) is dissociated. What is the equilibrium constant (in molL―1)?
(Molecular weight of N2O4 = 92)
a) 0.1 b) 0.2 c) 0.3 d)0.4
12. Assuming complete dissociation which of the following aqueous solutions will have the same
pH value?
(i)100 mL of 0.01 M HCl
(ii)100 mL of 0.01 MH2SO4
(iii)50 mL of 0.01 M HCl
(iv)Mixture of 50 mL of 0.02 M H2SO4 and 50 mL of 0.02 M NaOH
a) (i), (ii) b) (i), (iii) c) (ii), (iv) d)(i), (iv)
13. At 3000 K, the equilibrium pressure of CO2, CO and O2 are 0.6, 0.4 and 0.2 atm respectively. 𝐾𝑝
for the reaction 2CO2⇌2CO + O2, is
a) 0.089 b) 0.098 c) 0.189 d)0.198
14. The p𝐾𝑎 of weak acid H𝐴 is 4.5. The pOH of an aqueous buffer solution of H𝐴 in which 50% of
the acid is ionised:
a) 7.0 b) 4.5 c) 2.5 d)9.5
15. An amphoteric buffer solution in which conc. of H and H𝑋 is same. The value of 𝐾𝑎
+
of H𝑋 is 10―8, then pH of buffer solution is
a) 3 b) 8 c) 10 d) 14
16. In the reaction, 3𝐴 + 2𝐵→2𝐶, the equilibrium constant 𝐾𝑐 is given by
[3𝐴] × [2𝐵] [𝐴]3 × [𝐵] [𝐶]2 [𝐶]
a) [𝐶]
b) c) 3 2
d) [3𝐴][2𝐵]
[𝐶] [𝐴] × [𝐵]
17. Which reaction is not affected by change in pressure?
a) H2 + I2⇌2HI b) N2 + 3H2⇌2NH3
c) PCl5⇌PCl3 + Cl2 d) 2C + O2⇌2CO
18. Three reactions involving H2PO4 are given below
―
(i)H3PO4 + H2O→H3O+ + H2PO― 4
(ii)H2PO4 + H2O→HPO4 + H3O+
― 2―
(iii)H2PO― ―
4 + OH →H3PO4 + O
2―
In which of the above does H2PO― 4 act as an acid?
a) (ii) only b) (i)and (ii) c) (iii) only d) (i) only
19. pH for the solution of salt undergoing anionic hydrolysis (say CH3COONa) is given by:
1
a) pH = [p𝐾𝑤 + p𝐾𝑎 + log 𝑐]
2
1
b) pH = [p𝐾𝑤 + p𝐾𝑎 ― log 𝑐]
2
1
c) pH = [p𝐾𝑤 + p𝐾𝑏 ― log 𝑐]
2
d) None of the above
20. For the reactions, 𝐴 + 𝐵 + 𝑄⇌𝐶 + 𝐷, if the temperature is increased then concentration of the
products will
a) Increase b) Decrease c) Remains the same d)Become zero
