29-06-2025

9610ZJA801896250004 JA

PART 1 : PHYSICS

SECTION-I

1) A child is sitting in a chair connected to a rope that passes over a frictionless pulley. The child
pulls on the loose end of the rope with a force of 250 N. The child’s weight is 320 N and the chair
weighs 160 N. The child is accelerating. The force that the seat of the chair exerts on the child is

approximately

(A) 83 N
(B) 70 N
(C) 13 N
(D) 57 N

2) A particle having mass of '2 kg' is placed on rough horizontal surface and coefficient of friction
between block and surface is 0.75. Minimum force required to pull the block on the horizontal
surface.

(A) 15 N
(B) 12 N
(C) 20N
(D) 10 N

3) Find acceleration of the lower block :

(A) 4 m/s2
(B) 5 m/s2
(C) 0 m/s2

(D)
m /s2

4) A block of mass 5kg is placed on rough inclined having angle of inclination 53° and coefficient of
friction is µ = 1. This 5kg block is connected with light string with an another mass M as shown in
figure. Initially system is at rest. Calculate minimum and maximum value of M so system does not

move.

(A) 1 kg, 7 kg
(B) 0 kg, 8 kg
(C) 2kg, 6kg
(D) 3kg, 5kg

5) If the system in figure is given an acceleration a and sphere of weight w is placed in the wedge.

Assuming no friction. Mark the correct option :

Reaction R2 from vertical wall on sphere is

(A)

Reaction R1 from incline on sphere is

(B)

(C) Reaction R2 from vertical wall on sphere is w

(D)
Reaction R1 from incline on sphere is

6) A block of mass 2 kg is connected with a spring of natural length 40 cm of force constant K = 200
N/m. The coefficient of friction is μ = 0.5. When released from the given position, acceleration of
block will be :-

(A) zero
(B) 2 m/s2
(C) 6 m/s2
(D) 8 m/s2

7) In the given figure, block are at rest and in equilibrium. Acceleration of block A is a and B is b just
after spring (1) is cut then

(A)

(B) a = 0, b = g

(C) a = g , b = g

(D) None of these

8)

A particle (initially in motion) is subjected to different accelerations separately. These acceleration

vary with time as shown. In which of these cases particle will definitely return to its initial position.

(i) (ii) (iii)

(A) (i) only
(B) (ii) & (iii) only
(C) in all cases
(D) in no case

9) A block B moves with a velocity u relative to the wedge A. If the velocity of the wedge is v as

shown in the figure, for the block to move vertically up, θ is :-

(A)

(B)

(C)

(D)
10) A particle is moving along x axis with constant acceleration. At t = 0 sec, the particle is at x = 3

m and = + 4 m/s. The maximum value of x coordinate of the particle is observed 2 sec later.
Starting from t = 0 sec after what time particle reaches its initial position again

(A) 4 sec
(B) 6 sec
(C) 8 sec
(D) 12 sec

11) Ram and Shyam both decided to visit a temple on the hill. Both have the same capability and can
ride up the hill in 3 hrs & down the hill in 1 hr. They decided to start riding at 12 noon, but due to

some reason, Shyam started riding when Ram had already covered of the distance riding up. At
what time will they meet (Assume no stay at the temple)

(A) 2 : 45 pm
(B) 3 : 00 pm
(C) 3 : 15 pm
(D) 3 : 45 pm

12) Two trains, which are moving along different tracks in opposite directions towards each other,
are put on the same track by mistake. Their drivers, on noticing the mistake, start slowing down the
trains when the trains are 300 m apart. Graphs given below show their velocities as function of time
as the trains slow down. The separation between the trains after both have stopped, is :

(A) 120 m
(B) 280 m
(C) 60 m
(D) 20 m

13) A man can swim with a certain speed, in still water to cross a river to a point directly opposite to
the starting point in time t0. When the river flows, he crosses the river directly along the same path
in a time t1. If ‘d’ be the river width, Then the velocity of water current is :

(A)

(B)

(C)
(D)

14) A ball is thrown at angle α(90° > α > θ) on inclined plane as shown in figure then the minimum

speed of the ball during the motion is :

(A) u cos α
(B) u cos θ
(C) u cos (α – θ)
(D) Zero

15) Let , and . The value of is :-

(A) –112.5
(B) –106.5
(C) –118.5
(D) –99.5

16) Two vectors and have equal magnitudes. The magnitude of is 'n' times the

magnitude of . The angle between and is :

(A)

(B)

(C)

(D)

17) ABCD is a parallelogram. Choose the correct option :

(A)

(B)

(C)

(D)

18) If where F : force, r : distance, v : velocity and C & k are constants then dimension
of C is :-

(A) Dimensionless
(B) MLT–2
(C) ML2T–3
(D) ML2T–4

19) The value of Stefan's constant in S.I. system is 5.67 × 10–8 Js–1m–2k–4. A new system of unit is
defined known as ALLEN system where one unit of mass in new system is 8kg, and one unit of time
in new system is 2sec. If all other quantities remain same as S.I. system then find new value of
Stefan's constant in ALLEN system :-

(A) 5.67 × 10–8

(B) 5.67 × 2 × 10–8

(C)

(D) 5.67 × 4 × 10–8

20) A particle with mass m and initial velocity v0 is subjected to a velocity dependent force of the
form bvn. Let stopping time t of particle depend on m, v0 and b as t ∝ mαbβv0γ Powers α, β and γ will
be

(A) α = 1, β = –1, γ = 1 – n
(B) α = 2 – n, β = –1, γ = 2
(C) α = 1, β = 1, γ = 1 – n
(D) α = –1, β = –1, γ = 1 – n

SECTION-II

1) Length of a year on a planet is the duration in which it completes one revolution around the sun.
Assume path of the planet known as orbit to be circular with sun at the centre. The length T of a
year of a planet orbiting around the sun in circular orbit depends on universal gravitational constant
G, mass ms of the sun and radius r of the orbit. If one planet A have radius one fourth time to planet
B then find ratio of time period of planet B to planet A.
2) A string is pulled with a force F = 130 N as shown. The force vector comes out to be

Write in OMR sheet.

3) A helicopter is trying to land on a submarine deck which is moving south at 17m/s relative to
water. Wind is blowing at 12 m/s relative to water in west direction. If to the submarine crew the
helicopter is descending vertically at 5 m/s, what is its speed relative to the air assuming sea water

to be still as shown in figure. If your answer is (in m/s) fill the value of

4) A particle is projected horizontally with velocity 10 m/s from a tower and another particle is
projected with velocity 40 m/s with an angle of 45° with the horizontal from another tower as
shown in figure at t = 0. Find angular velocity (in rad/sec) of particle (2) w.r.t. particle (1) as shown

in figure at t = 1 sec.

5) Block of mass "2kg" and "1 kg" are connected with the string and pulley as shown in the diagram.

If all the surfaces are smooth and pulley are ideal then acceleration of "1kg" block is given by

m/s2, the value of n is :-

 PART 2 : CHEMISTRY

SECTION-I

1) The number of molecules present in 67.2 L of NH3 at 1atm & 273 K is -

[Given : NA = 6 × 1023]

(A) 6 × 1023
(B) 3 × 1024
(C) 1.8 × 1024
(D) 3.6 × 1024

2) A sample of protein was analysed for metal content and analysis revealed that it contained
magnesium and titanium. If these are the only metallic species present in the protein and it contains
0.004% Mg by mass and 0.006%. Ti by mass, then the minimum possible molar mass (in gm/mol) of
the protein is : [Mg = 24, Ti = 48]

(A) 6 × 105
(B) 1.5 × 105
(C) 3 × 105
(D) 24 × 105

3) Suppose the elements X and Y combine to form two compounds XY2 and X3Y2. When 0.1 mole of
XY2 weighs 10 gm and 0.05 mole of X3Y2 weighs 9 gm, the atomic weights of X and Y are respectively
:

(A) 20, 30
(B) 30, 20
(C) 40, 30
(D) 60, 40

4) If the atomic masses of X and Y are 10u and 30u respectively, then the mass of XY3 formed when
120 g of Y2 reacts completely with X is
Reaction: X + Y2 → XY3 (unbalanced)

(A) 133.3 g
(B) 200 g
(C) 266.6 g
(D) 167.7 g

5) 0.8 gm of BeCl2 was added to water forming 500 mL solution. 20 mL of this solution is taken and
diluted 10 folds to form final solution. Find moles of ions in 2 mL of final solution :
(Atomic mass Be = 9,Cl = 35.5)

(A) 2 × 10–6
(B) 4 × 10–6
(C) 8 × 10–6
(D) 1 × 10–6

6)

The electrons, identified by quantum number n and ℓ :

(i) n = 3 ; ℓ = 0
(ii) n = 5 ; ℓ = 2
(iii) n = 2 ; ℓ = 1
(iv) n = 4 ; ℓ = 3
can be placed in order of increasing energy from the lowest to highest as :

(A) (iii) < (i) < (iv) < (ii)

(B) (i) < (iii) < (iv) < (ii)
(C) (ii) < (iii) < (iv) < (i)
(D) (ii) < (iv) < (i) < (iii)

7) Which of the following sets of quantum numbers represent an impossible arrangement

n m s

(A) 3 2 -2
+

(B) 4 0 0
+

(C) 3 2 -3
+

(D) 5 3 0
+
(A) A
(B) B
(C) C
(D) D

8) Difference in wavelength of two extreme lines of H-atom in Balmer region is (Where RH is Rydberg
constant)

(A) 7.2 / RH
(B) 0.25 / RH
(C) 3.2 / RH
(D) 4 /RH

9) For orbital of hydrogen atom radial wave function is given as:

The ratio of radial probability density of finding electron r = a0 to radial probability density of finding
electron at the nucleus is given as (x. e–y). Calculate the value of (x + y).

(A) 2
(B) 3
(C) 4
(D) 5

10) The wave function for an orbital is H-atom is given as

The orbital is ;

(A) 2s
(B) 3p
(C) 2p
(D) 3d

11) Which one of the following statements is incorrect in relation to ionisation enthalpy ?

(A) Ionization enthalpy increases for each successive electron

As we move along the period the greatest increase in ionizaiton enthalpy is experienced on
(B)
removal of electron from core of noble gas configuration.
(C) End of valence electrons is marked by a big jump in ionization enthalpy.
Removal of electron from orbitals bearing lower n value is easier than from orbital having
(D)
higher n value.

12) The atom having the valence shell electronic configuration 4s2 4p2 would be in:-

(A) Group II A and period 3

(B) Group II B and period 4
(C) Group IV A and period 4
(D) Group IV A and period 3

13) Incorrect order of radius is :

(A) B < Al < Ga < Tl

(B) V2+ > V3+ > V4+ > V5+
(C) Tl+ > In+ > Sn+2 > Sb+3
(D) K+ > Sc3+ > V5+ > Mn7+

14) The formation of the oxide ion, O2–(g), from oxygen atom requires first an exothermic and then
an endothermic step as shown below :
O(g) + e– → O–(g) ; ΔegH = – 141 kJmol–1
O–(g) + e– → O2–(g) ; ΔegH = + 780 kJmol–1
Thus process of formation of O2– in gas phase is unfavourable even though O2– is isoelectronic with
neon. It is due to the fact that :

(A) oxygen is more electronegative.

(B) addition of electron in oxygen results in larger size of the ion.
(C) electron repulsion outweighs the stability gained by achieving noble gas configuration.
(D) O– ion has comparatively smaller size than oxygen atom.

15) O(g) + 2e⊝ → O(g)2⊝ ; ∆Heg = 603 KJ/mole.

The positive value of ∆Heg is due to :

(A) Energy is released to add 1 e⊝ to O1⊝

(B) Energy is absorbed to add 1 e⊝ to O1⊝
(C) Energy is needed to add 1 e⊝ to O
(D) None of the above is correct

16) In which of the following ionization processes the bond energy has increased and also the
magnetic behaviour has changed from paramagnetic to diamagnetic ?

(A) NO → NO+
+
(B) O2→ O2
+
(C) N2→N2
+
(D) C2 → C2

17) Given below are two statements :

Statement I : o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding.
Statement II : o-Nitrophenol has high melting due to hydrogen bonding.
In the light of the above statements, choose the most appropriate answer from the options given
below:

(A) Statement I is false but Statement II is true

(B) Both statement I and statement II are true
(C) Both statement I and statement II are false
(D) Statement I is true but statement II is false

18) In which of the following pairs the two species are not isostructural ?

3–
(A) AlF6 and SF6
2– –
(B) CO3 and NO3
+
(C) PCl4 and SiCl4
(D) PF5 and BrF5

19) The type of hybridisation and number of lone pair(s) of electrons of Xe in XeOF4, respectively,
are :

(A) sp3d and 1

(B) sp3d and 2
(C) sp3d2 and 1
(D) sp3d2 and 2

20) The correct increasing order for bond angles among BF3, PF3 and ClF3 is :

(A) PF3 < BF3 < ClF3

(B) BF3 < PF3 < ClF3
(C) ClF3 < PF3 < BF3
(D) BF3 = PF3 < ClF3

SECTION-II

1) An element exist in three isotopic form 40X, 41X and 42X.

Percentange abundance of 40X = 30% by mole.
If average atomic mass of ‘X’ is 41.25. Find out percentage abundance of 41X.

2) The work function for a metal is 40 eV. To emit photo electrons of zero velocity from the surface
of the metal the wavelength of incident light should be x nm. (h = 6.62 × 10–34 Js, c = 3 × 108 m/s)

3) Based on Heisenberg's uncertainty principle, the uncertainty in the velocity of the electron to be
found within an atomic nucleus of diameter 10–15 m is ______× 109 ms–1 (nearest integer)
[Given : mass of electron = 9.1 × 10–31 kg, Plank's constant (h) = 6.626 × 10–34 Js] (Value of π = 3.14)

4) The group number is (a) and period number is (b) of the element with atomic number Z = 100.
Report value of (10a + b).

5) Number of σ–bonds in CO2 = x

Number of π-bonds in SO3 = y
Find the value of (x + y).

PART 3 : MATHEMATICS

SECTION-I

1) Let a,b,c ∈ N such that a < b < c satisfying the relation abc + 2bc + 2ac + 2ab + 4a + 4b + 4c =
202. The number of possible values of a + b + c is

(A) 3
(B) 4
(C) 5
(D) 6
2) If x and y both are non-negative integral values for which then find the sum of
all possible value of x

(A) 7
(B) 10
(C) 13
(D) 14

3) At least one of the equations x2 + ax + b = 0 and x2 + cx + d = 0 has real roots if :

(A) ac = 2 (b + d)
(B) ad = 2(b + c)
(C) bc = 2(a + d)
(D) ab = 2(c + d)

4) If α,β are the roots of the equation ax2 + bx + c = 0, then the roots of the equation
a(2x + 1)2 + b(2x + 1) (x – 1) + c(x – 1)2 = 0 are

(A)

(B)

(C)

(D)

5) If for all real x, then :

(A) m < – 1
(B) –5 < m < 1
(C) –1 < m < 5
(D) m > 6

6) The minimum value of x2 + 2xy + 3y2 – 6x – 2y (where x, y ∈ R) is equal to

(A) –9
(B) –11
(C) –12
(D) –10

7) Let U be the universal set and A ∪ B ∪ C = U, then {(A – B) ∪ (B – C) ∪ (C–A)}' is equal to :-

(A) A ∪ B ∪ C
(B) A ∪ (B ∩ C)
(C) A ∩ B ∩ C
(D) A ∩ (B ∪ C)

8) For all sets S, let |S| denotes number of elements of S and n(S) denotes number of subsets of S
including empty set and the set itself. If A, B, C are three sets satisfying n(A) + n(B) + n(C) =
n(A∪B∪C) and |A| = |B| = 100 then the value of |A∪B∪C| – |C|

(A) 100
(B) 1
(C) 2
(D) 200

9) Product of all values of x satisfying the equation is :

(A)

(B) 3

(C)

(D)

10) Let Then n(S) is equal to

(A) 2
(B) 4
(C) 6
(D) 0

11)

Solve for x :
then

(A) (0, 3)
(B)
(C)
(D)

12) The value of is

(A) 2
(B) 4
(C) 8
(D) 16

13) If x > 1, y > 1 and logxy + logyx2 = 4 and x > y, then logxy is

(A) 2
(B)
(C)
(D)

14) logaN = α1 + β1, logbN = α2 + β2, logcN = α3 + β3, where α1, α2, α3 are integers and β1, β2, β3 ∈
[0,1).

If for a = 3, c = 7, α1 = 5, α2 = 3, α3 = 2 and b is such that the largest integral value of N is 342, then
sum of integral values of b is (a < b < c)

(A) 15
(B) 11
(C) 10
(D) 9

15) If the product of all solutions of equation can be expressed in the

lowest form as then find the value of (m + n)

(A) 1204
(B) 1
(C) 24
(D) 4041

16) Along a road lies an odd number of stones placed at intervals of 10 m. These stones have to be
assembled around the middle stone. A person can carry only one stone at a time. A man carried out
the job starting with the stone in the middle, carrying stones in succession, thereby covering a
distance of 4.8 km. Then the number of stones is

(A) 15
(B) 29
(C) 31
(D) 35

17) Let bi > 1 for i = 1, 2, ....., 101. Suppose logeb1, logeb2,.....,logeb101 are in Arithmetic Progression
(A.P.) with the common difference loge2. Suppose a1, a2,......, a101 are in A.P. such that a1 = b1 and a51
= b51. If t = b1 + b2 + ..... + b51 and s = a1 + a2 + .... + a51 then
(A) s > t and a101 > b101
(B) s > t and a101 < b101
(C) s < t and a101 > b101
(D) s < t and a101 < b101

18) The sum of the following series

up to 15 terms, is

(A) 7820
(B) 7830
(C) 7520
(D) 7510

19) Let a = 12 + 42 + 82 + 132 + 192 + 262 +.........10 terms

b = 14 + 24 + 34 + ..........104
and 4a – b = 353λ + μ, then λ + μ equal to

(A) 353
(B) 55
(C) 40
(D) 95

20) Let a1, a2, a3 .......... a11 be real numbers satisfying a1 = 15, 27 – 2a2 > 0 and ak = 2ak–1 – ak–2 for k =

3,4.........11. If , then the value of is equal to -

(A) 0
(B) 1
(C) 2
(D) 3

SECTION-II

1) Let α, β (α > β) be the roots of the quadratic equation x2 – x – 4 = 0. If Pn = αn – βn, n ∈ N, then

is equal to

2) Let A = {n ∈ N | n2 ≤ n + 10,000}, B = {3k +1 | k ∈ N} and C = {2k | k ∈ N}, then the sum of all

the elements of the set A ⋂(B – C) is equal to M, then the value of .

3) The number of integral value of ‘p’ for which the inequality

 is valid for all real ‘x’.

4) If and kA = 9, then the value of is equal to

5) The minimum value of the sum of real numbers a–5, a–4, 3a–3, 1, a8 and a10 with a > 0 is
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B C A A C A D D A C D B C C C A D A A

SECTION-II

Q. 21 22 23 24 25
A. 8 5 2 1 2

PART 2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C D C A C A C C B B D C A C B A D D C C

SECTION-II

Q. 46 47 48 49 50
A. 15 31 58 37 5

PART 3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A D A C C B C B D B B B C B D C B A D A

SECTION-II

Q. 71 72 73 74 75
A. 16 8 0 5 8
 SOLUTIONS

PART 1 : PHYSICS

1)

T + N – mg = ma ... (i)

T – N – Mg = Ma ... (ii)

2) Ans. (2)

N + Fsin(θ) = Mg
N = Mg – Fsin(q)
µN = Fcosθ
µmg = Fcosθ + µFsin(θ)

3) Ans. (3)
a50 = 0

4) For maximum M

Mg = T = 40 + µN1
Mg = T = 40 + 1 × 30
Mmax = 7 kg
For minimum M

T + f = 40
Mg = 40 – 30 = 10
Mmin = 1kg

5)
6) kx = 20N, N1 = 8N,

f = 4N;

7)

At equilibrium

As spring 2 is not
wt. ∴ kx
will not change
Hence A stays at rest
At equilibrium

when 1 is cut
then
Hence force on B is
4g + kx2 = 4a
4g + 2g = 4a
6g = 4a

8) In question it is clearly written that "definitely return". Since scaling is not done, in all the
cases we can find atleast a situation in which the particle can not return to its initial position.

9)
=
for in vertically upward direction

v = u cos θ ⇒ θ =

10)

t = 4s

11)

⇒x=

12)

Final separation
= Initial separation – |Relative displacement|
= 300 – [(1/2) × 40 × 10 + (1/2) × 20 × 8]
= 20 m

13)

0
t =

t1 =
vr = vbr sin θ
 vr =

14) Horizontal component of velocity at point of projection will be minimum velocity during
motion.

15)

54 + 5 × 3 × 5

= 54 – 150 – = –118.5

16) ___(1)

___(2)

17) ....(1)
....(2)
Adding (1) & (2)

18)

[C] = [M1L2T–4]

19) n1u1 = n2u2

20) t ∝ mαbβv0γ

0 0

M L T1 =
= Mα[MLT–2]β[LT–1]γ–nβ
α+β=0 ...(A)
β + γ – nβ = 0 ...(B)
–2β – (γ – nβ) = 1 ...(C)
–β = 1
β = –1
From (B) γ + n – 1 = 0
γ=1–n.

21)

, ,
It is given that
4rA = rB
T = K(r)3/2

22)
A(5, 0, 6) B(2, 12, 2)

23)

vhel/water = vhel/sub + vsub/water = m/s

vhel/air = vhel/water + vwater/air = vhel/water – vair/water = m/s

 24)

25)
1g – T = 1a ......(i)

2T = 2 × .....(ii)
from (i) & (ii)

a=

PART 2 : CHEMISTRY

26)

Explanation:

A. Determine the number of molecules present in a given volume of ammonia gas (NH3) at
standard temperature and pressure (STP).

Given Data:

A. Volume of NH3 gas = 67.2 L

B. Temperature = 273 K
C. Pressure = 1 atm

Concept:

A. Avogadro's Law: Equal volumes of all gases at the same temperature and pressure contain
 the same number of molecules.
B. Molar Volume: One mole of any gas at STP occupies a volume of 22.4 liters.
C. Avogadro's Number: One mole of any substance contains Avogadro's number (NA) of
particles, which is approximately 6.022 x 1023 particles per mole.

Mathematical Calculation:

A. Calculate the number of moles of NH3:

A. Number of moles of NH3 = Volume of NH3 / Molar volume of a gas at STP
B. Number of moles of NH3 = 67.2 L / 22.4 L/mol
C. Number of moles of NH3 = 3 moles
B. Calculate the number of molecules of NH3:
A. Number of molecules of NH3 = Number of moles of NH3 * Avogadro's number
B. Number of molecules of NH3 = 3 moles * 6.022 x 1023 molecules/mole
C. Number of molecules of NH3 = 1.8066 x 1024 molecules

Final Answer:

A. The number of molecules present in 67.2 L of NH3 at 1 atm and 273 K is 1.8066 x 1024
molecules.

27)

We have to find, minimum possible molar mass of protein :

Mass ratio of 'Mg' and 'Ti' =

Mole ratio of 'Mg' and 'Ti' =

It means, 1 mole of protein contains,
4 mole of Mg and 3 mole of Ti
4 mole of Mg = 24 × 4 = 96 g
3 mole of Ti = 3 × 48 = 144 g
Total mass of metal = (96 + 144)g = 240 g

∴ % Mass of metal =

⇒ 0.01 =
∴ Molar mass of protein = 2400000 g/mol

28) = 100 = X + 2Y

= 180 = 3X + 2Y
On solving X = 40, Y = 30

29)

Balanced reaction is 2X + 3Y2 → 2XY3

 Moles of Y2 =

Moles of XY3 formed =

Mass of XY3 formed =

30)

Molar mass of BeCl2 = 9 + 71 = 80 g/mol

⇒ Moles of BeCl2 = = 0.01

∴ Molarity =

Now, take 20 mL of 0.02 M and dilute it 10 times

So final volume = 20 × 10 = 200 mL
Hence final molarity of this solution can be calculated as
∴ M1V1 = M2V2
⇒ 0.02 × 20 = 200 × M2 (final molarity)
⇒ M2 = 2 × 10–3 M
⇒ BeCl2 → Be+2(aq) + 2Cl–(aq)
2× 10–3 M – –
– 2×103 M (2×2×103)M
[Cl–] = 4 × 10–3 M

In 2 mL solution or
∴ Moles of = molarity × volume in litre

=
= 8 × 10–6 moles

31)

Energy is given by (n + ℓ) value. When (n + ℓ) value is equal, the orbital with greater n-value
has greater energy.

Energy Thus, energy

(i) 3+0=3

(ii) 5+2=7
(iii) < (i) < (iv) < (ii)
(iii) 2 + 1 = 3

(iv) 4 + 3 = 7

32)
33)

= 3.2/RH

34)

1s-orbital

Comparing = e–2 = x.e–y

x = 1, y = 2
So x + y = 3

35)

n-l-1=1
n-1-1=1
n=3
l=1
So orbital is 3p.

36) Orbitals bearing lower value of n will be more closer to the nucleus and thus electrons will
experience greater attraction from nucleus and so its removal will be difficult not easier.

37)
n=4, period no-4 element belongs to p-block group no =12+2=14
Group IV-A
Option is C

38)

Due to shielding, r : Ga < Al

Correct order is B < Ga < Al < Tl

39) There is electrostatic repulsion between the two species having same type of charge. So
energy has to be given for the addition of additional electron to O–.
40)

41)

NO ⇒ 1 unpaired e– ⇒ B.O = 2.5

NO+ ⇒ 0 unpaired e– ⇒ B.O = 3
So, paramagnetic to diamagnetic & Bond energy increased.

42)

thus it is more volatile due to intramolecular H-bonding. Melting point depends on packing
efficiency not on H-bonding thus statement II is false

43) pentagonal Bipyramidal

square pyramidal

44) sp3d2 ⇒ [5σ-bond +1 l.p.]

45)

Order of bond angle is

ClF3 < PF3 < BF3
 46)
X =4140 – 4125 = 15%

47)

0
W +K= =

40 × 1.6 × 10–19 =
λ = 31 nm

48)

49) [Rn]7s25f126d7p
Group number = 3
Block = f
Period = 7

50) O = C = O
σ-bond = 2

x+y=2+3=5

PART 3 : MATHEMATICS

51) Consider
x3 + (a+ b + c)x2 + (Σab) x + abc
= (x+a)(x+b)(x+c)
put x = 2

∴ (2+a) (2+b) (2+c) = 210 =2×3×5×7

=3×7×10
=3×5×14
=5×6×7
∴ a + b + c = 14, 16, 12
Hence, number of possible values of a + b + c is 3.
52)

Case-I

on solving
Case-II

On solving
In all other cases negative solutions are obtained hence solution set is (3,4), (4, 3), (7,0), (0,7)
sum of all possible values of x is 3+4+7+0=14

53) Suppose both the equations have imaginary roots and ac = 2 (b + d). Then equations have
imaginary roots and ac = 2(b + d). Then a2 – 4b < 0 and c2 – 4d < 0.
a2 + c2 – 2ac < 0
(a – c)2 < 0
Which is impossible therefore ac = 2 (b + d) implies that at least one of a2 – 4b and c2 – 4d is
greater than or equal to 0.

54)

2x + 1 = tx- t
t + 1 = (t -2) x

55) we have

Therefore
– 3(x2 + x + 1) < x2 + mx + 1 < 3 (x2 + x + 1)
4x2+ (m + 3) x + 4 > 4 and 2x2 + (3 – m) x + 2 < 0 for all real x
(m + 3)2 – 64 < 0 and (3 – m)2 – 16 < 0
(m + 3 + 8) (m + 3 – 8) < 0 and (3 – m + 4) (3 – m – 4) < 0
(m + 11) (m – 5) < 0 and (m – 7) (m + 1) < 0
– 11 < m < 5 and – 1 < m < 7
This gives – 1 < m < 5.

56) (x + y – 3)2 + 2(y + 1)2 – 11

∴ minimum value is –11
57)

58) ∵ n(A) + n(B) + n(C) = n(A∪B∪C)

⇒ 2|A| + 2|B| + 2|C| = 2|A∪B∪C|
⇒ 2100 + 2100 + 2|C| = 2|A∪B∪C|
⇒ 2101 + 2|C| = 2|A∪B∪C|
Clearly |C| = 101 and |A∪B∪C| = 102
∴ |A∪B∪C| – |C| = 1

59) (Moderate)

Products of roots

60)

Let

x2 – 4 = 2, –2 or x2 = 6, 2

61)

Here

So
So

62) As,

(as y > 0)

so, 6 +

63) logxy + 2logyx = 4

⇒
⇒ a2 – 4a + 2 = 0

⇒
⇒
∵x>y ∴ logxy < 1
a<1
Hence

64) a = 3, α1 = 5 ⇒ log3N = 5 + β1
N ∈ [35, 36)
c = 7, α3 = 2 ⇒ log7N = 2 + β3
N ∈ [72, 73)
α2 = 3
⇒ N = [b3, b4)

N ∈ [35, 36)

N ∈ [72, 73)
N = [243, 343)
if b = 4 ⇒ N ∈ [243, 256)
⇒ rejected only b = 4, 5 and 6 can be accepted

65)
⇒ log2021 2020 + log2021x – 1 = logx 2021 . log2021 2020

Suppose log2021x = t, then logx 2021 =

Then, log2021 2020 + t – 1 = log2021 2020

t . log2021 2020 + t2 – t – log2021 2020 = 0
⇒ (t – 1) log2021 (2020) + t(t – 1) = 0
⇒ (t – 1) (log20212020 + t) = 0
⇒ t = 1 or t = –log2021 2020
⇒ log2021x = 1 or log2021x = log2021 (2020)–1

⇒ x = 2021 or x =
Product of solutions

⇒
⇒ m + n = 2021 + 2020 = 4041

66) Let there be 2n + 1 stones. So, there will be n stones each side of middle stone
If the person started the job from middle,
Distance covered for first stone = 2 × 10 m
Similarly, distance covered for second stone = 2 × 20 m
So, the distance covered in bringing stones to centre from one side
= 2[10 + 20 + 30 +…..+ 10n]
Distance covered in brining stones from both side = 4[10 + 20 + 30….. +10n]
Person started from middle the total distance covered
4800 = 4(10 + 20 + 30 +…. + 10n)
4800 = 40(1 + 2 + 3 +…… + n)

67) If logeb1, logeb2......logeb101 → AP ; d = loge2

⇒ b1 b2 b3....b101 → GP ; r = 2
∴ b1,2b1, 22b1,........., 2100b1...... GP
a1, a2, a3 .......a101 ..... AP
Given, a1 = b1 & a51 = b51
⇒ a1 + 50D = 250b1
∴ a1 + 50D = 250a1 (As b1 = a1)

Now, t = b1(251 – 1) ;
⇒ t < a1.251 ....(i);
⇒ s > a1.251 ....(ii)
clearly s > t (from equation (i) and (ii))
Also a101 = a1 + 100D ; b101 = b1.2100

b101 = 2100a1 ....(iii)

a101 = a1 + 251a1 – 2a1 ⇒ a101 = 251a1 – a1 ⇒ a101 < 251a1 ....(iv)
clearly b101 > a101 (from equation (iii) and (iv))

68)

= 7820

69) Consider
α = 1 + 4 + 8 + 13+.....+n terms
Let tn = an2 + bn + c
t1 = a + b + c = 1
t2 = 4a + 2b + c = 16
t3 = 9a + 3b + c = 64

On solving we get a = , b = , c = –1

a=

4a =

4a – b =

where n = 10
= 55(353) + 40
λ = 55
μ = 40
λ + μ = 95

70)
a1 = 15
27 – 2a2 > 0
ak = 2ak – 1 – ak –2 ∀ k = 3, 4, 5 .... 11
all ai (i = 1, 2, ........ 11) are in A.P.
Let the numbers are (a6 + 5d), (a6 + 4d), ......., a6, ....., (a6 – 4d), (a6 – 5d)
a6 = 15 – 5d
(15 – 5d)2 + 10d2 = 90

⇒ 7d2 – 30d + 27 = 0 ⇒ d =
for d = 3 ⇒ a2 = 12 (possible)
for d = 9/7 ⇒ a2 = 13.7 (not possible since a2 < 13.5)

a6 = 0 ⇒ = a6 = 0

71) Pn = αn – βn x2 – x – 4 = 0

....(1)
n n n–1 n–1
As Pn – Pn–1 = (α – β ) – (α –β )
= αn–2(α2 –α) – βn–2 (β2 – β)
= 4(αn–2 – βn–2)
Pn – Pn–1 = 4 Pn–2
Hence Expression (1)

= = 16

72)

B – C ≡ {7, 13, 19, ...97, ....}

Now, n2 – n ≤ 100 × 100
⟹ n(n – 1) ≤ 100 × 100
⟹ A = {1, 2, ...., 100}.
So, A ⋂ (B – C) = {7, 13, 19, ..., 97}

Hence, sum =

73)

Let log2
(2 – t)x2 + 2(1 + t)x – 2(1 + t) > 0 ∀ x ∈ R
Since this is quadratic in 'x' is true ∀ x ∈ R
∴ (2 – t) > 0 & 4 (1 + t)2 + 8 (2 – t) (1 + t) < 0 (D < 0)
t < 2 & t2 + 1 + 2t + 2(–t2 + t + 2) < 0
–t2 + 4t + 5 < 0
t2 – 4t – 5 > 0
(t – 5) (t + 1) > 0
⇒ t < –1

log2

P ∈ (–1, 1)

& checking domain ⇒

⇒ P ∈ (0, 1)
∴ No integral value of 'P'

74) A =
given kA = 9
⇒

Now

75) As a > 0
and all the given terms are positive
hence considering A.M. ≥ G.M. for given numbers :

⇒ =7
–5 –4 –3 8 10
where a = a = a = a = a i.e. a = 1
⇒ (a–5 + a–4 + 3a–3 + a8 + a10 + 1)min = 8
when a = 1