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Msds Vk-Wsa Catalyst

The safety data sheet for VK-WSA, a sulphuric acid catalyst produced by Topsoe A/S, outlines its hazardous classifications, including toxicity, eye damage, and potential carcinogenic effects. It provides essential information on handling, storage, first aid measures, and personal protective equipment required due to the risks associated with exposure. The document emphasizes the importance of safety precautions and proper emergency procedures when dealing with this substance.

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0% found this document useful (0 votes)
37 views15 pages

Msds Vk-Wsa Catalyst

The safety data sheet for VK-WSA, a sulphuric acid catalyst produced by Topsoe A/S, outlines its hazardous classifications, including toxicity, eye damage, and potential carcinogenic effects. It provides essential information on handling, storage, first aid measures, and personal protective equipment required due to the risks associated with exposure. The document emphasizes the importance of safety precautions and proper emergency procedures when dealing with this substance.

Uploaded by

kecebonq2
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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Date of first issue: 31.01.

2011
Date of last issue: 19.12.2022
Revision Date: 15.11.2023
Version: 2.13 Page 1 of 15

SAFETY DATA SHEET


according to Regulation (EC) No. 1907/2006

VK-WSA

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name: VK-WSA

Other means of identification:

1.2 Relevant identified uses of the substance or mixture and uses advised against
○ Identified uses: Sulphuric acid catalyst.

1.3 Details of the supplier of the safety data sheet


Manufacture
Company: Topsoe A/S
Address: Haldor Topsøes Allé 1, 2800 Lyngby
Denmark
Telephone: +45 4527 2000
Telefax: +45 4527 2999
E-mail address: [email protected]

1.4 Emergency telephone number


UK: +44 0844 892 0111
Other: +45 4527 2000

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


- Acute Tox. 3; H331
- Eye Dam. 1; H318
- Muta. 2; H341
- Carc. 1B; H350
- Repr. 2; H361fd
- Lact. H362
- STOT RE 2; H373
- Aquatic Chronic 3; H412

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

○ Product identifier: VK-WSA

○ Hazard pictograms

SAFETY DATA SHEET VK-WSA


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Date of last issue: 19.12.2022
Revision Date: 15.11.2023
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○ Signal word: Danger

○ Contains: Divanadium pentoxide


Aluminum sulfate

○ Hazard statements
- H318: Causes serious eye damage.
- H331: Toxic if inhaled.
- H341: Suspected of causing genetic defects.
- H350: May cause cancer.
- H361fd: Suspected of damaging fertility. Suspected of damaging the unborn child.
- H362: May cause harm to breast-fed children.
- H373: May cause damage to organs (Lungs, Respiratory Tract) through prolonged or
repeated exposure if inhaled.
- H412: Harmful to aquatic life with long lasting effects.

○ Precautionary statements
- P201: Obtain special instructions before use.
- P260: Do not breathe dust.
- P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
- P304 + P340 + IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call
P311: a POISON CENTER/ doctor.
- P305 + P351 + IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
P338 + P310: lenses, if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
- P308 + P313: IF exposed or concerned: Get medical advice/ attention.
- P403 + P233: Store in a well-ventilated place. Keep container tightly closed.

2.3 Other hazards


Substance(s) formed under storage
The below listed substance(s) may be released during handling.

Chemical name CAS-No. %w/w


Potassium 7646-93-7 <3
hydrogensulphate

SAFETY DATA SHEET VK-WSA


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Date of last issue: 19.12.2022
Revision Date: 15.11.2023
Version: 2.13 Page 3 of 15

SECTION 3: Composition/information on ingredients

3.2 Mixture

REACH Registration
Components Classification %w/w
Number
Amorphous Silica 01-2119379499-16- not to be classified 60 - 70
CAS-No.: 7631-86-9 XXXX
EC-No.: 231-545-4
Potassium sulphate 01-2119489441-34- not to be classified 10 - 30
CAS-No.: 7778-80-5 XXXX
EC-No.: 231-915-5
Aluminum sulfate 01-2119531538-36- Eye Dam. 1; H318 5 - 10
CAS-No.: 10043-01-3 XXXX Met. Corr. 1; H290
EC-No.: 233-135-0
Divanadium pentoxide 01-2119531331-54- Acute Tox. 3; H301 5-9
CAS-No.: 1314-62-1 XXXX Acute Tox. 2; H330
EC-No.: 215-239-8 Eye Dam. 1; H318
Muta. 2; H341
Carc. 1B; H350
Repr. 2; H361fd
Lact. H362
STOT SE 3; H335
STOT RE 1; H372
Aquatic Chronic 2; H411
Sodium sulphate 01-2119519226-43- not to be classified 1-7
CAS-No.: 7757-82-6 XXXX
EC-No.: 231-820-9
No crystalline silica forms found.
For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures


○ General advice: IF exposed or if you feel unwell:, Get medical advice/ attention.
○ Inhalation: Remove person to fresh air and keep comfortable for breathing. If
breathing is irregular or stopped, administer artificial respiration. Call a
physician or poison control centre immediately.
○ Skin contact: Take off contaminated clothing and wash it before reuse. Wash with water
and soap.
○ Eye contact: Immediately flush eye(s) with plenty of water. Take victim immediately to
hospital. Continue rinsing eyes during transport to hospital. Remove
contact lenses, if present and easy to do. Continue rinsing.
○ Ingestion: Do not induce vomiting without medical advice. Clean mouth with water
and drink afterwards plenty of water. Get medical advice/ attention if you
feel unwell.

4.2 Most important symptoms and effects, both acute and delayed
○ Inhalation: Toxic by inhalation. May cause damage to organs through prolonged or
repeated exposure if inhaled. Inhalation of excessive amounts of dust may
cause irritation of the respiratory system; symptoms may include coughing
and difficulty in breathing.
○ Skin contact: May cause skin irritation.

SAFETY DATA SHEET VK-WSA


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○ Eye contact: Causes serious eye damage.


○ Chronic effects from long Substances which should be regarded as if they are carcinogenic to man.
term exposure: Substances which cause concern for man owing to possible mutagenic
effects but for which the available information is not adequate for making
a satisfactory assessment. Suspected of causing genetic defects.
Possible risk of irreversible effects. Substances which cause concern for
humans owing to possible developmental toxic effects. Substances which
cause concern for human fertility. Vanadium pentoxide is in EU classified
as a mutagenic substance in category 3 i.e. may cause possible risk of
irreversible effects. Vanadium pentoxide is also in EU classified as toxic
for reproduction in category 3, i.e. possible risk of harm to the unborn
child.

4.3 Indication of any immediate medical attention and special treatment needed
○ Symptoms: None known.

SECTION 5: Firefighting measures

The product itself does not burn.

5.1 Extinguishing media


○ Suitable extinguishing Product is compatible with standard fire-fighting agents.
media:

5.2 Special hazards arising from the substance or mixture


May release toxic SO2 when heated above 400ºC/750ºF.

5.3 Advice for firefighters


Wear full protective clothing and self-contained breathing apparatus.

Further information
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Do not handle until all safety precautions have been read and understood. Ensure adequate
ventilation. Avoid dust formation. Avoid breathing dust. Use personal protective equipment. Follow safe
handling advice and personal protective equipment recommendations.

6.2 Environmental precautions


Do not flush into surface water or sanitary sewer system.

6.3 Methods and materials for containment and cleaning up


Clean up promptly by scoop or vacuum. Use approved industrial vacuum cleaner for removal.
Dispose of as hazardous waste in compliance with local and national regulations.

6.4 Reference to other sections


For personal protection see section 8. For disposal considerations see section 13.

SAFETY DATA SHEET VK-WSA


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Date of last issue: 19.12.2022
Revision Date: 15.11.2023
Version: 2.13 Page 5 of 15

SECTION 7: Handling and storage

7.1 Precautions for safe handling


Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Avoid contact with eyes. Minimize dust generation and accumulation.
Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces. Avoid
breathing dust. Avoid breathing gas. Use only outdoors or in a well-ventilated area. Do not eat, drink or
smoke when using this product. Handle in accordance with good industrial hygiene and safety
practice. For personal protection see section 8.

7.2 Conditions for safe storage, including any incompatibilities


Store in original container.
Keep locked up or in an area accessible only to qualified or authorised persons. Keep container tightly
closed. Product may be damaged by water.

7.3 Specific end use(s)


Sulphuric acid catalyst.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Exposure Limit Values


Exposure limits may vary. It is recommended that information about locally applicable exposure limits
is obtained.

Components Exposure Limit Values Source

Amorphous Silica (7631-86-9)


- inhalable dust TWA 6 mg/m3 EH40 (2011:12)
- Respirable dust TWA 2,4 mg/m3 EH40 (2011:12)

Aluminum sulfate (10043-01-3)


TWA 2 mg/m3 EH40 (2011:12)

Divanadium pentoxide (1314-62-1)


TWA 0,05 mg/m3 EH40 (2011:12)

Additional exposure limits for substance(s) that may be released during handling

Components Exposure Limit Values Source

DNEL /PNEC
Amorphous Silica(7631-86-9)
Workers: DNEL: - No data available
Environment: PNEC: No data available
Potassium sulphate(7778-80-5)
Workers: DNEL: - No data available
Environment: PNEC: No data available

SAFETY DATA SHEET VK-WSA


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Divanadium pentoxide(1314-62-1)
Workers: DNEL: - No data available
Environment: PNEC: No data available
Sodium sulphate(7757-82-6)
Workers: DNEL: - No data available
Environment: PNEC: No data available

8.2 Exposure controls


Individual protection measures, such as personal protective equipment
○ Eye/face protection Safety goggles
○ Skin protection
- Hand protection Wear protective gloves.
Glove material: Nitrile rubber
- Body Protection Dust impervious protective suit Safety shoes recommended when handling
heavy containers.
○ Respiratory protection Wear respiratory protection. Suitable mask with particle filter P3 (European
Norm 143)
○ Other protection Wash hands thoroughly after handling. Remove contaminated clothing and
protective equipment before entering eating areas. Contaminated work
clothing should not be allowed out of the workplace. Change working
clothes after each workshift.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Property Value
Appearance
○ Physical state: solid
○ Form: Extruded pellets.
○ Colour: Greenish yellow.
Odour: odourless
Odour Threshold: Not relevant.
pH: Not applicable
Melting point/freezing point: Silica above 1600 °C/2910 °F ; alkali sulphates above approx 400
°C/750°F.
Initial boiling point and No data available
boiling range:
Flash point: Not relevant.
Evaporation rate: Not relevant.
Flammability (solid, gas): The product is not flammable.
Upper/lower flammability or explosive limits
○ Lower explosion limit / Lower Not explosive
flammability limit:
○ Upper explosion limit / Upper Not relevant.
flammability limit:
Vapour pressure: Not applicable

SAFETY DATA SHEET VK-WSA


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Date of first issue: 31.01.2011
Date of last issue: 19.12.2022
Revision Date: 15.11.2023
Version: 2.13 Page 7 of 15

Vapour density: Not relevant.


Density: Not applicable
Solubility(ies)
○ Water solubility: Alkali-sulphates soluble. Vanadium compounds partly soluble.
○ Solubility in other solvents: Not relevant.
Partition coefficient: n- Not applicable
octanol/water:
Auto-ignition temperature: Not applicable
Decomposition temperature: No information available.
Viscosity: Not relevant.
Explosive properties: Not explosive
Oxidizing properties: The substance or mixture is not classified as oxidizing.
9.2 Other information No information available.

SECTION 10: Stability and reactivity

10.1 Reactivity
Stable under normal conditions.

10.2 Chemical stability


Stable under normal conditions.

10.3 Possibility of hazardous reactions


No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid


No data available

10.5 Incompatible materials


Water and moisture for catalyst integrity.

10.6 Hazardous decomposition products


Heating above 400°C/750°F may result in emission of SO2

SECTION 11: Toxicological information

○ Inhalation: Toxic by inhalation. Inhalation of dust may cause shortness of breath,


tightness of the chest, a sore throat and cough. Dust and fumes from
vanadium compounds can irritate the respiratory system; symptoms
may include nose bleeding, sore throat, cough, bronchitis,
expectoration, chest pain; serious exposure may cause pneumonia
and pulmonary oedema. The symptoms of pulmonary oedema often
do not become manifest until several hours have passed and they are
aggravated by physical effort. Rest and medical observation is
therefore essential. Vanadium compounds may cause green
discoloration of the tongue. May cause damage to organs through
prolonged or repeated exposure if inhaled.
○ Eye contact: Causes serious eye damage.
○ Skin contact: May cause skin irritation.

SAFETY DATA SHEET VK-WSA


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Date of first issue: 31.01.2011
Date of last issue: 19.12.2022
Revision Date: 15.11.2023
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○ Ingestion: Ingestion may cause irritation of the mouth and throat and may cause
discomfort.
○ Long term effects: Substances which should be regarded as if they are carcinogenic to
man. Substances which cause concern for man owing to possible
mutagenic effects but for which the available information is not
adequate for making a satisfactory assessment. Suspected of
causing genetic defects. Possible risk of irreversible effects.
Substances which cause concern for human fertility. Substances
which cause concern for humans owing to possible developmental
toxic effects. Prolonged or repeated inhalation may cause damage to
the lungs. Vanadium pentoxide is in EU classified as a mutagenic
substance in category 3 i.e. may cause possible risk of irreversible
effects. Vanadium pentoxide is also in EU classified as toxic for
reproduction in category 3, i.e. possible risk of harm to the unborn
child. IARC: (International Agency for Research on Cancer) Group
2B: Possibly carcinogenic to humans

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity
Assessment: Toxic if inhaled.
» Oral
Amorphous Silica: LD50 Oral(Rat): > 5.000 mg/kg
Method: OECD Test Guideline 401
Potassium sulphate: LD50(Rat): > 2.000 mg/kg
Method: OECD Test Guideline 425
Aluminum sulfate: LD50(Rat): > 2.000 mg/kg
Method: OECD Test Guideline 401
Divanadium pentoxide: LD50(Rat): 221,1 mg/kg
Method: OECD Test Guideline 401
Sodium sulphate: LD50(Rat): > 2.000 mg/kg
Method: OECD Test Guideline 423
Mixture: Acute toxicity estimate: 2.785 mg/kg
Method: Calculation method
Remarks: Not classified due to data which are conclusive although
insufficient for classification.

» Dermal
Amorphous Silica: LD50 Dermal(Rabbit): > 2.000 mg/kg
Potassium sulphate: LD50 Dermal(Rat): > 2.000 mg/kg
Aluminum sulfate: LD50(Rat): > 5.000 mg/kg
Method: OECD Test Guideline 402
Divanadium pentoxide: LD50 Dermal(Rat): > 2.500 mg/kg
Method: OECD Test Guideline 402
Remarks: No adverse effect has been observed in acute toxicity tests.

» Inhalation
Amorphous Silica: LC0(Rat, 4 h): > 2,08 mg/l
Method: OECD Test Guideline 403
Potassium sulphate: LC0(Rat, 4 h): 3,6 mg/m³

SAFETY DATA SHEET VK-WSA


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Revision Date: 15.11.2023
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Aluminum sulfate: LC50(Rat, 4 h): > 5 mg/l


Method: OECD Test Guideline 403
Divanadium pentoxide: LC50(Rat, 4 h): 0,05 mg/l
Test atmosphere: dust
Method: OECD Test Guideline 403
Sodium sulphate: LC50(Rat, 4 h): > 2,4 mg/l
Method: OECD Test Guideline 436
Mixture: Acute toxicity estimate: 0,63 mg/l
Method: Calculation method

Repeated dose toxicity


Amorphous Silica: No observed adverse effect level: 4000 - 4500 mg/kg bw/day
Exposure routes: Oral
Method: OECD Test Guideline 408
No observed adverse effect concentration: < 1,3 mg/m3
Exposure routes: Inhalation
Method: OECD Test Guideline 413
Lowest observed adverse effect concentration: 5,9 mg/m3
Exposure routes: Inhalation
Method: OECD Test Guideline 413
Divanadium pentoxide: Lowest observed adverse effect level: 5,36 mg/kg bw/day
Exposure routes: Oral
Exposure time: 103 d
Lowest observed adverse effect level: 0,5 mg/m3
Exposure routes: Inhalation
Test atmosphere: aerosol
Exposure time: 2 y
Target Organs: Lungs

Skin corrosion/irritation
Assessment: Not classified based on available information.
Amorphous Silica: Result: No skin irritation
Species: Rabbit
Exposure time: 4 h
Method: OECD Test Guideline 404
Aluminum sulfate: Result: No skin irritation
Species: Rabbit
Exposure time: 4 h
Method: OECD Test Guideline 404
Divanadium pentoxide: Result: No skin irritation
Species: reconstructed human epidermis (RhE)
Method: Regulation (EC) No. 440/2008, Annex, B.46

SAFETY DATA SHEET VK-WSA


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Revision Date: 15.11.2023
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Serious eye damage/eye irritation


Assessment: Causes serious eye damage.
Amorphous Silica: Result: No eye irritation
Species: Rabbit
Exposure time: 24 h
Method: OECD Test Guideline 405
Aluminum sulfate: Result: Irreversible effects on the eye
Species: Rabbit
Method: OECD Test Guideline 405
Divanadium pentoxide: Result: Irreversible effects on the eye
Method: OECD Test Guideline 405

Respiratory sensitisation
Assessment: Not classified based on available information.
Amorphous Silica: Exposure routes: Inhalation
Remarks: study scientifically unjustified
Divanadium pentoxide: Exposure routes: Inhalation
Remarks: Not classified due to lack of data.

Skin sensitisation
Assessment: Not classified based on available information.
Amorphous Silica: Exposure routes: Dermal
Remarks: study scientifically unjustified
Divanadium pentoxide: Exposure routes: Dermal
Test Type: Maximisation Test
Species: Guinea pig
Result: negative
Method: OECD Test Guideline 406

Germ cell mutagenicity


Assessment: Suspected of causing genetic defects.
Amorphous Silica: Genotoxicity in vitro
Test Type: Ames test
Result: negative
Test system: Salmonella typhimurium
Method: OECD Test Guideline 471
Genotoxicity in vivo
Test Type: gene mutation test
Result: negative
Species: Rat
Method: No information available.
Divanadium pentoxide: Genotoxicity in vitro
Test Type: gene mutation test
Result: negative
Test system: mammalian cells
Method: OECD Test Guideline 476
Genotoxicity in vivo
Test Type: Chromosome aberration test in vitro
Result: negative
Species: Rat
Method: OECD Test Guideline 474

SAFETY DATA SHEET VK-WSA


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Revision Date: 15.11.2023
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Carcinogenicity
Assessment: May cause cancer.
Amorphous Silica: No observed adverse effect level: 1.800 - 3.000 mg/kg bw/day
Application Route: Oral
Species: Rat
Result: negative

Divanadium pentoxide: Not classified due to inconclusive data.

Reproductive toxicity
Assessment: Suspected of damaging fertility. Suspected of damaging the unborn
child. May cause harm to breast-fed children.
Amorphous Silica: Reproductive Toxicity/Fertility
This information is not available.
Reproductive Toxicity/Development/Teratogenicity
Result: No adverse effects
Test Type: reproductive and developmental toxicity study
Species: Rat
Application Route: Oral
Divanadium pentoxide: Reproductive Toxicity/Fertility
LOAEL: 4 mg/m3
Test Type: Fertility
Species: Rat
Application Route: Inhalation
Symptoms: Effect on estrous cycle
NOAEL: 15 mg/kg bw/day
Test Type: Multi-generation study
Species: Rat
Application Route: Oral
Symptoms: Effects on mating performance, Effects on fertility, Effects
on reproduction parameters

Reproductive Toxicity/Development/Teratogenicity
NOAEL: 7,41 mg/kg bw/day
Species: Mouse
Symptoms: Effects on foetal development
Remarks: Read-across (Analogy)

Specific target organ toxicity - single exposure


Assessment: Not classified based on available information.
Amorphous Silica: Not classified due to data which are conclusive although insufficient for
classification.
Divanadium pentoxide: Assessment: May cause respiratory irritation.
Exposure routes: Inhalation
Target Organs: Lungs

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Specific target organ toxicity - repeated exposure


Assessment: May cause damage to organs (Lungs, Respiratory Tract) through
prolonged or repeated exposure if inhaled.
Amorphous Silica: Not classified due to data which are conclusive although insufficient for
classification.
Divanadium pentoxide: Assessment: Shown to produce significant health effects in animals at
concentrations of 0.2 mg/l/6h/d or less.
Exposure routes: Inhalation
Target Organs: Lungs

Aspiration hazard
Assessment: Not classified based on available information.

11.2 Information on other hazards


Product: No information available.

SECTION 12: Ecological information

12.1 Toxicity
Harmful to aquatic life with long lasting effects.

» Acute toxicity
No information available.
» Chronic toxicity
No information available.
» Other organisms relevant to the environment
No information available.

12.2 Persistence and degradability


The methods for determining the biological degradability are not
applicable to inorganic substances.
Amorphous Silica: The methods for determining biodegradability are not applicable to
inorganic substances.
Divanadium pentoxide: The methods for determining biodegradability are not applicable to
inorganic substances.

12.3 Bioaccumulative potential


Amorphous Silica: Not applicable
Aluminum sulfate: This information is not available.
Divanadium pentoxide: Bioconcentration factor (BCF): 12,3

12.4 Mobility in soil


Amorphous Silica: The product is insoluble and sinks in water.
Aluminum sulfate: This information is not available.
Divanadium pentoxide: log Kd: 2,66
Test Type: Adsorption/Soil
Medium: Soil

12.5 Results of PBT and vPvB assessment

SAFETY DATA SHEET VK-WSA


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Amorphous Silica: Not applicable


Aluminum sulfate: Not applicable
Divanadium pentoxide: Not applicable

12.6 Endocrine disrupting properties

12.7 Other adverse effects


Product: No data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods


Dispose of as hazardous waste in compliance with local and national regulations. Topsoe A/S takes no
responsibility for the classification of used or contaminated material.
Can be offered for metal recovery.

SECTION 14: Transport information

14.1 UN number or ID number: 3288

14.2 UN proper shipping name: Toxic solid, inorganic, n.o.s. (Divanadium pentoxide)

14.3 Transport hazard class(es)


ADR/RID: Class: 6.1; Labels: 6.1
IMDG: Class: 6.1; Labels: 6.1
IATA: Class: 6.1; Labels: 6.1
49 CFR: Class: 6.1; Labels: 6.1
TDG: Class: 6.1; Labels: 6.1

14.4 Packing group: III

14.5 Environmental hazards


ADR/RID: Not classified
IMDG: Not classified
IATA: Not classified
49 CFR: Not classified
TDG: Not classified

14.6 Special precautions for user: No special precautions are needed in handling this material.

14.7 Maritime transport in bulk Not applicable for product as supplied.


according to IMO instruments:

Further information for transport


ADR/RID: Tunnel restriction code: (E)
IMDG: EmS: F-A, S-A
IATA: Packing instruction (cargo aircraft) : 677
Packing instruction (passenger aircraft) : 670

SAFETY DATA SHEET VK-WSA


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Revision Date: 15.11.2023
Version: 2.13 Page 14 of 15

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
○ Take note of Dir 94/33/EC on the protection of young people at work.
○ Take note of Dir 92/85/EEC on the safety and health at work of pregnant workers.

15.2 Chemical safety assessment


No information available.

SECTION 16: Other information

Key or legend to abbreviations and acronyms used in the safety data sheet
○ DNEL Derived No Effect Level
○ PNEC Predicted No Effect Concentration
○ Acute Tox. Acute toxicity
○ Aquatic Chronic Long-term (chronic) aquatic hazard
○ Carc. Carcinogenicity
○ EH40 EH40/2005 Workplace exposure limits
○ Eye Dam. Serious eye damage
○ Lact. Effects on or via lactation
○ Met. Corr. Corrosive to metals
○ Muta. Germ cell mutagenicity
○ Repr. Reproductive toxicity
○ STOT RE Specific target organ toxicity - repeated exposure
○ STOT SE Specific target organ toxicity - single exposure
○ TWA Long-term exposure limit

Key literature references and sources for data


○ RTECS (Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety
and Health, 4676 Columbia Pkwy., Cincinnati, Ohio 45226, USA).
○ HSDB (Hazardous Substances Data Bank - TOXNET (Toxicology Data Network)).
○ IUCLID (European Commission, Joint Reserch Centre, Institute for Health and consumer Protection,
European Chemicals Bureau).

Classification and procedure used to derive the classification for mixtures according to
Regulation (EC) No. 1272/2008:

Classification Classification procedure:

- Acute Tox. 3; H331 Calculation method


- Eye Dam. 1; H318 Calculation method
- Muta. 2; H341 Calculation method
- Carc. 1B; H350 Calculation method
- Repr. 2; H361fd Calculation method
- Lact. H362 Calculation method
- STOT RE 2; H373 Calculation method
- Aquatic Chronic 3; H412 Calculation method

SAFETY DATA SHEET VK-WSA


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Date of first issue: 31.01.2011
Date of last issue: 19.12.2022
Revision Date: 15.11.2023
Version: 2.13 Page 15 of 15

Full text of H-Statements


○ H290 May be corrosive to metals.
○ H301 Toxic if swallowed.
○ H318 Causes serious eye damage.
○ H330 Fatal if inhaled.
○ H331 Toxic if inhaled.
○ H335 May cause respiratory irritation.
○ H341 Suspected of causing genetic defects.
○ H350 May cause cancer.
○ H361fd Suspected of damaging fertility. Suspected of damaging the
unborn child.
○ H362 May cause harm to breast-fed children.
○ H372 Causes damage to organs through prolonged or repeated
exposure if inhaled.
○ H373 May cause damage to organs through prolonged or repeated
exposure if inhaled.
○ H411 Toxic to aquatic life with long lasting effects.
○ H412 Harmful to aquatic life with long lasting effects.

Training advice
Provide adequate information, instruction and training for operators.

NFPA 704: National Fire Protection Association

Health 3 Fire 0 Reactivity 0

0= minimal hazard, 1=slight hazard, 2=moderate hazard, 3=severe hazard,4=extreme hazard

The above information is believed to be accurate and is based on our present state of knowledge and experience. However, no
warranty or representation with respect to such information is intended or given. This information is intended to be used for
safety and environmental purposes only and should not be relied upon for any other purposes.
Information contained herein is confidential; it may not be used for any purpose other than for which it has been issued, and may
not be used by or disclosed to third parties without written approval of Topsoe A/S.

SAFETY DATA SHEET VK-WSA


Great Britain

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