Inductive Effect

Basic points before GOC

s s
0s s

f
2
X Directionproper
Collison effecting
p s
Headin guerlap y
tygnyp.my
3
Dcs
X X
PE
a
energyrufdagram.ee operistefiting
pitt
iii Ea
E
00
POR 15 Riots
5 Fees cFCH2
CH2 CH2 Hz
42

4235 ftp
Explain 55
is 8 O
gf
T é TS 2

IT bend
BIB
shifting of
on demand of reagent
Electromericeffy
 CHECK s
2 oh as
is 1
Hz

EYE ABMO E

FI Ele
FOR

6
CHERN coyote to BE
shifting of o band
on demand of
reagent
Inductomeric
est
É displacement eff

yEfae generate
f eg feels
Inductive elf
Resonance felectomericelf IT
Inductomere off
Hypercong
o
 Electronic effect é displacementeffect
Permanent Temporary
1
Inductive 1 Inductomeric
2 Resonance 2 Electromeric
3
Hyperconjugation
1 Inductive effect effect
Transmission

Polarisation of one bond caused by polarisation

of an adjacent bond is called Inductive eff

X Éi _Yig xig E Inductive

eff through
ᵈᵈ
permanent polarisation
operate
bonds
due to EN difference
1 I effect is permanent effect
2
during effect é does not leave their orbital
I
3 as distance from main source increases Effect decreases
up to 3 ycarbon
Distance is important factor
4 It is a relative effect depends on
following factors
EN SY charge
I Fybridisation
C Phase
EI
1 4g BE 255 5104 8.5 F
3416
caused by EN
5 Br
2.8
charge 216
 Hybridisation
CHz CHz SP3 II Is chaff Icy
cry Cha Sp2 33 2.75
331 Boys
CHECH sp 50 3.25

Phase
cry cis neutral
cry cry 0 anion é releasing tendency
cry cry 8 cation é withdrawing tendency

I effect is of 2 types I effect

I effect
é Ex.si CH3 z also
A I effect releasing
coot c Cmf check CD CH D H
g y

IO JEES E.FI Szero

B I effect é withdrawing

Mandl COOH
r Hz no CN 502A
I OAR COOR
F Ce Br OE
E R SH SR OH CECR Ar CH CHz
sp sp SP
 Application of I effect
I
d a

I 8
I
St 8

2 25 3 88
ve charge
thisIskn
more eves
dispersion
charge
more tves charge
dispersion
ffff
more stability more stability
filly
1
bhy.IE stable

D N P

2
bfy II unstable

D7N P

A
stability of C

is cry Ey CB cry oz effects

ii
3 ED
iii
y as
Iv

stability of
1
ccb 592 CFz Eg
2
cy ctg ca cy ctg.ae cry Eg
gr
3
guy cuz
Ena aug 5Th aug 8th
F
Gs gys

4 cuz Eg cuz Eg
92 g
5
ga Es
82 8s
NO2 92

is iii cooe ii i coo

COE CoE
EEIo i
7

he
8 Cy cool 08 00
to 9 91 guy

No Br
o

10
TO
 11 9000

EE de

12
cha cha 008 chz chz co8 CH cha
qty gyz 91500

02 0000
13
cool
In
9000 400
Icu 7CD3
4000
15
II
Q Identify I or I effect which is presented by
circled group
1

IH
A B H 8
IF IF
D E a

G H CH I CHz CE
J CH K CH CHz
CH2 3

II m 2 Nj city c

0
Cy E P
7 400,4 50310

R CH 5 7
Q Rank the following in increasing stability of
08 anion

400
11g gtfo
A
F
p
P Q

É FEE FEE
B
H3C

M
K L

c
1

40 HE 13

T U
S
Q Inductive effect involves_
A Delocalisation of o electrons
B Partial displacement of o electrons
c Delocalisation of I é
D
Displacement of lone pair electrons

In which the incorrect

of following species
direction of Inductive effect is shown

CH3

EFF
gel 24
B on c

tins
CHS
D 307MHz

Q select correct statement about I effect

A I eff transfer electrons from one carbon atom to
another
B I eff is the polarisation of o bond electrons
c I eff creats net in the molecule
charge
D I eff is distance dependent