12-10-2025

1103CJA101001250020 JA

PHYSICS

SECTION-I (i)

1) From the uniform disc of radius 4R two small disc of radius R are cut off. The centre of mass of

new structure will be :

(A)

(B)

(C)

(D)

2) A piece of paper (shown in figure1) is in form of a square. Two corners of this square are folded
to make it appear like figure.2. Both corners are put together at centre of square 'O'. If O is taken to
be (0,0), the centre of mass of new system will be at

(A)

(B)

(C)

(D)

3) Figure shows a small block of mas m = 1 kg which is given a horizontal velocity v0 = 10 m/s on the
horizontal part of the bigger block of mass M = 9 kg placed on a horizontal floor. The curved part of
the surface shown is semicircular of radius R = 1 m. Find the distance from point B when the block
m lands finally after looping the semicircular part BCD. Neglect friction everywhere. Assume that

the horizontal portion AB is long enough. (g = 10 m/s2)

(A)

(B)

(C)

(D)

4) A 1kg block is being pushed against a wall by a force F = 75 N as shown in the Figure. The

coefficient of friction is 0.25. The magnitude of acceleration of the block is

(A) 10 m/s2
(B) 20 m/s2
(C) 5 m/s2
(D) none

5) A ball is thrown upward with an initial velocity V0 from the surface of the earth. The motion of the
ball is affected by a drag force equal to mgυ2 (where m is mass of the ball, υ is its instantaneous
velocity and γ is a constant). Time taken by the ball to rise to its zenith is :

(A)

(B)

(C)

(D)

6) A particle ‘P’ is moving on a circular under the action of only one force acting always towards the
fixed point ‘O’ on the circumference. Find the ratio of

(A)
(B)

(C)

(D)

SECTION-I (ii)

Common Content for Question No. 1 to 2

Answer the following by appropriately matching the lists based on the information given in
the paragraph.
Acceleration versus x and potenital energy versus x graph of a particle of mass 1 kg moving along x-
axis are shown in figure. Assume that at x = 0, the velocity of the particle is 4 ms-1, match the

following at x = 8 m.

List-I List-II

(I) Kinetic energy (P) 120 J

(II) Work done by conservative force (Q) 240 J

(III) Total work done (R) 128 J

(IV) Work done by external forces (S) –120 J

(T) 125 J

(U) 245 J

1) Which of the following is the correct combination.

(A) (I) → (Q), (II) → (P), (III) → (U), (IV) → (T)

(B) (I) → (R), (II) → (S), (III) → (Q), (IV) → (T)
(C) (I) → (R), (II) → (Q), (III) → (P), (IV) → (S)
(D) (I) → (P), (II) → (Q), (III) → (R), (IV) → (U)

2) Which of the following is only correct combination.

(A) (I) → (P)

(B) (II) → (Q)
(C) (III) → (R)
(D) (IV) → (U)

Common Content for Question No. 3 to 4

Two friends A & B playing a game of collision of balls and throwing balls from the top of the tower
simultaneously as shown in the figure. If the balls collide in air at point P and point O is treated as

origin(g =10 m/s2)

3) Distance D between the towers

(A) 100 m
(B) 200 m
(C) 400 m
(D) 800 m

4) Co–ordinate of the particles at point P

(A) (100,75)
(B) (100,125)
(C) (75,100)
(D) (175,100)

Common Content for Question No. 5 to 6

A ball of mass M attached to a string of length ℓ moves in a circle in a vertical plane as shown below.
At the top of the circular path, the tension in the string is twice the weight of the ball. At the bottom
the ball just clears the ground.
5) Determine the speed v0 of the ball at the lowermost point.

(A)
(B)
(C)
(D)

6) A bead of mass m is free to slide on a fixed horizontal circular wire of radius R. At time t = 0, it is
given a velocity v0 along the tangent to the circle. If the coefficient of kinetic friction between the
bead and the wire is µk, then magnitude of tangential acceleration at t = 0 will be :-

(A) µkg

(B)

(C)

(D)

SECTION-I (iii)

1) The centre of mass of given system is at a distance x from geometrical centre of bigger body.
(Mass density is uniform everywhere)

List–I List–II
 (P) (1) x = 0 or x > R

(Disk with one circular

cavity)

Centre of mass lies outside

(Q) (2)
the body bigger
(Disk with two circular
cavity)

(R) (3) 0 < x < R

(Disk with one square
cavity)

Centre of mass lies within

(S) (4)
bigger body (if any present)
(Disk with one attached
small circular mass)
(A) P → 1;Q → 3;R → 2;S → 4
(B) P → 3;Q → 4;R → 3;S → 4
(C) P → 2;Q → 4;R → 1;S → 2
(D) P → 3;Q → 4;R → 1;S → 2

2) Answer the following by appropriately matching the lists based on the information given
in the paragraph.
Two men of mass 60 kg and 80 kg stand on a plank of mass 20 kg. Both of them can jump with a
velocity of 1 m/s relative to the plank. In each event shown in list-I, find the velocity of plank after

the event.

List-I List-II

(P) Ram alone jumps to the left (1)

– m/s

(Q) Shyam alone jumps to the right (2)

– m/s

Ram jumps to left and shyam

(R) (3)
jumps to right simultaneously. m/s
 Ram jumps to left and after that
(S) (4)
shyam jumps to right – m/s
(A) P → 1;Q → 2;R → 4;S → 3
(B) P → 3;Q → 2;R → 4;S → 1
(C) P → 2;Q → 3;R → 4;S → 1
(D) P → 1;Q → 4;R → 3;S → 2

3)

A particle is moving along x-axis. Its position is given by x = (where t is time in

second), then :-

List-I List-II
(P) for 0 < t < 1 second (1) particle accelerates
(Q) for 1 < t < 2 second (2) particle retards
(R) for t > 2 second (3) particle is moving towards origin
(S) for t = 1 second (4) particle changes its direction of motion
(A) P → 1;Q → 2;R → 4;S → 3
(B) P → 4;Q → 2;R → 1;S → 3
(C) P → 2;Q → 3;R → 1;S → 4
(D) P → 2;Q → 3;R → 4;S → 1

4) In the figure shown, all the pulleys are massless and strings are light (g = 10 m/s2)

List–I (Mass of blocks) List–II (Motion of Blocks)

(P) 1 kg block (1) 0 m/s2

(Q) 2 kg block (2) 10/3 m/s2

(R) 3 kg block (3) 5 m/s2

 (S) 4 kg block (4) 10 m/s2
(A) P → 1;Q → 3;R → 2;S → 4
(B) P → 4;Q → 1;R → 2;S → 3
(C) P → 1;Q → 4;R → 2;S → 3
(D) P → 2;Q → 4;R → 4;S → 1

5) List-I gives some situations where a block is given velocity to perform vertical circular motion and
list-II give information about motion of block and force acting on the block match the correct order.

List-I List-II

(P) (1) Block completes circular motion

Block is given velocity v in a smooth circular

loop of radius 2m

(Q) (2) Normal reaction at highest point is zero

(R) (3) Tension at highest point is zero.

Block just fit inside a circular tube of

radius 2m given velocity as shown

Normal reaction at highest point is radially

(S) (4)
outwards.

(A) P → 3;Q → 2;R → 1;S → 4

(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 2;Q → 4;R → 3;S → 1
(D) P → 1;Q → 3;R → 4;S → 2

CHEMISTRY

SECTION-I (i)

1) The CORRECT order of hybridisation of the , P and B in the following species is respectively
N(SiH3)3, PCl3, H3BO3,

(A) sp3, sp3, sp2

(B) sp2, sp3, sp3
(C) sp2, sp3, sp2
(D) sp3, sp2, sp2

2) In figure, A and B are two adiabatic curves for two different gases. Then A and B corresponds to :

(A) Ar and He respectively

(B) He and H2 respectively
(C) O2 and H2 respectively
(D) H2 and He respectively

3) Find the maximum number of plane having maximum number of atoms in CCl4.

(A) 10
(B) 8
(C) 14
(D) 15

4) Select the incorrect graph for Bohr atom -

(A)

(B)
(C)

(D)

5) Which of the following statements is incorrect for a gas?

The mean free path changes to 0.5 times if the pressure of the gas is doubled at
(A)
constant temperature.
(B) The mean free path doubles, if temperature is doubled at constant pressure.
The bimolecular collision frequency of gas is proportional to square root of temperature at
(C)
constant volume.
The velocity possessed by the largest fraction of molecules at a given temperature is known
(D)
as root mean square velocity.

6) Define the correct order of bond length in given compound :

(A) x > y
(B) x < y
(C) x = y
(D) can't say

SECTION-I (ii)

Common Content for Question No. 1 to 2

Read the following passage carefully and answer the questions.
Iodine is an important substance needed by the body of a human being. We consume it in the form of
salt which has very-very small % content of I2. Iodine has various industrial application also. The
following process has been used to obtain iodine from oil-field brines in California.
Nal + AgNO3 → Agl + NaNO3; Agl + Fe→ Fel2+ Ag
Fel2 + Cl2 → FeCl3 + I2
[Atomic mass Ag-108, I-127, Fe-56, N-14, Cl-35.5]

1) If 381 kg of iodine is produced per hour, then mass of AgNO3 required per hour will be:

(A) 170 kg
(B) 340 kg
(C) 255 kg
(D) 510 kg

2) If above reaction is carried out by taking 150 kg of Nal and 85 kg of AgNO3, then number of moles
of iodine formed is:

(A) 0.5
(B) 500
(C) 250
(D) 0.25

Common Content for Question No. 3 to 4

One mole of an ideal gas of CV = 20 JK–1 mol–1 initially at STP is put through the following reversible

cycle (ABCA). Where AB = Isochoric path

BC = Adiabatic path
CA = Isothermal path

3) What is ΔH for cycle ABCA ?

(A) zero
(B) +5.46 kJ
(C) +1.58 kJ
(D) –2.86 kJ

4) Find the approx. work done in whole cycle.

(A) zero
(B) 10 kJ
(C) –4 kJ
(D) –5.46 kJ
Common Content for Question No. 5 to 6
For an ideal monoatomic gas, an illustration of three different paths I, II and III from an initial state

Pi, Vi, Ti to a final state Pf, Vf, Tf is shown in the given figure. Path I
represents a reversible isothermal expansion from Pi, Vi to Pf, Vf, path II represents a reversible
adiabatic expansion followed by reversible heating of the gas at constant volume. Path III represents
a reversible expansion at constant pressure followed by a reversible cooling at constant volume.

5) What is ΔS for path II ?

(A)
nR ln
– nR ln
(B)

(C) Zero
(D) nR(Vf – Vi)

6) What is ΔS for III ?

(A) Zero

(B)

(C)
– nR ln

(D)
nR ln

SECTION-I (iii)

1)

List-I List-II

(A) ΔH < O (Exothermic) (P) N+(g) → N+2(g)

(B) ΔH > O (Endothermic) (Q) N(g) → N–(g)

(C) (R) N(g) → N+2(g)

(D) (S) N–(g) → N–2(g)

 (T) F–(g) → F–(aq)
(A) A → T;B → PQRS;C → P;D → Q
(B) A → T;B → P;C → PQRS;D → Q
(C) A → T;B → P;C → Q;D → PQRS
(D) A → PQRS;B → T;C → P;D → R

2) One mole of an ideal gas undergoing from state A to State-B through different processes column-I
shows graph of the process & column-II shows change in parameter in these process. Match the
following

Column-I Column-II

(A) (P) q > 0

(B) (Q) W > 0

(C) (R) ΔU > 0

(D) (S) W < 0

(A) A → PRS;B → PS;C → PRS;D → Q

(B) A → PRS;B → PR;C → PQS;D → P
(C) A → PRS;B → PQ;C → PQR;D → S
(D) A → PRS;B → QP;C → PQS;D → R

3)

Column-I Column-II
(Process) (Entropy Change)

(A) Reversible isothermal ideal gas expansion (p) ΔSsurrounding = 0

(B) Reversible adiabatic ideal gas compression (q) ΔSsurrounding < 0

(C) Adiabatic free expansion (Pext = 0) of an ideal gas (r) ΔSsurrounding > 0

(D) Irreversible isothermal ideal gas compression (s) ΔSsystem = 0

(A) A → r;B → p,s;C → p;D → q
(B) A → q;B → p;C → p,s;D → r
(C) A → q;B → p,s;C → p;D → r
(D) A → q;B → r;C → p;D → p,s
4) H2O is subjected to different phase change at different temperatures and pressures as shown in
List-I. The entropy change of system, surrounding and total in shown in List-II.

List-I List-II

(P) H2O(ℓ, 100°C, 2 atm) → H2O(g, 100°C, 2 atm) (1) ΔSsys < 0, ΔSsur > 0, ΔStotal > 0

(Q) H2O(g, 100°C, 0.5 atm) → H2O(ℓ, 100°C, 0.5 atm) (2) ΔSsys > 0, ΔSsur < 0, ΔStotal > 0

(R) H2O(ℓ, –10°C, 1 atm) → H2O(s, –10°C, 1 atm) (3) ΔSsys > 0, ΔSsur > 0, ΔStotal > 0

(S) H2O(s, 0°C, 2 atm) → H2O(ℓ, 0°C, 2 atm) (4) ΔSsys > 0, ΔSsur < 0, ΔStotal < 0

(5) ΔSsys < 0, ΔSsur > 0, ΔStotal < 0

Match List-I with List-II and choose the correct option :

(A) P → 4;Q → 5;R → 1;S → 2
(B) P → 1;Q → 4;R → 2;S → 5
(C) P → 5;Q → 2;R → 1;S → 3
(D) P → 1;Q → 2;R → 3;S → 4

5) Matching List :

List-I
List-II
(Process)

n moles of ideal gas undergoes adiabatic

(P) irreversible expansion from temperature (1) ΔSsurrounding < 0
T1 to T2 and volume V1 to V2

n moles of ideal gas undergoing reversible

(Q) expansion from temperature T1 to T2 and (2)
volume V1 to V2 (non-adiabatic) ΔSsystem = n CV,m ℓn

n moles of ice at 0°C (T1) change to water

(R) (3)
vapour at 100°C (T2) at 1 bar ΔSsystem = n CP,m ℓn

'n' moles of liquid benzene at 25°C (T1)

changes to benzene vapours at 78°C (T2)
(S) (4) ΔSsurrounding = 0
[where boiling point of benzene = 78°C]
at 1 bar

(5)
Work =
Select the incorrect option :
(A) P → 2;Q → 2;R → 3;S → 1
(B) P → 5;Q → 4;R → 1;S → 1
(C) P → 2;Q → 2;R → 5;S → 4
(D) P → 4;Q → 2;R → 3;S → 5

MATHEMATICS

SECTION-I (i)
1) All the values of m for which both roots of the equation x2 – 2mx + m2 – 1 = 0 are greater than –2
but less than 4, lie in the interval-

(A) –1 < m < 3

(B) 1 < m < 4
(C) –2 < m < 0
(D) m > 3

2) The equation of a straight line passing through (–3, 2) and cutting an intercept equal in magnitude
but opposite in sign from the axes is given by

(A) x – y + 5 = 0
(B) 2x – y – 4 = 0
(C) 2x – y + 4 = 0
(D) 2x + y + 7 = 0

3)

A point P(x,y) moves so that the sum of the distance from P to the coordinate axes is equal to the
distance from P to the point A(1,1). The equation of the locus of P in the first quadrant is -

(A) (x + 1) (y + 1) = 1
(B) (x + 1) (y + 1) = 2
(C) (x – 1)(y – 1) = 1
(D) (x – 1)(y – 1) = 2

4) If m is the A.M. of two distinct real numbers l and n(l, n > 1) and G1, G2 and G3 are three
geometric means between l and n, then equals -

(A) 4 lmn2
(B) 4 l 2m2n2
(C) 4 l 2mn
(D) 4 lm2n

5) Number of integral solution(s) of the inequality 2sin2x – 5sinx + 2 > 0 in x ∈ [0, 2π], is -

(A) 3
(B) 4
(C) 5
(D) 6

6) A belt is tied up across two circular pulleys of radii 5m and 1m respectively whose centres are
separated at a distance 8m. (as shown). Find the length of the belt required.
(A)

(B)

(C)

(D)

SECTION-I (ii)

Common Content for Question No. 1 to 2

Let be integers and let be the roots of the equation, , where . For
let
FACT : If a and b are rational numbers and , then .

1)

(A)
(B)
(C)
(D)

2) If , then

(A) 14
(B) 7
(C) 12
(D) 21

Common Content for Question No. 3 to 4

Comprehension–2
If ai > 0, i = 1, 2, 3, ..... n and m1, m2, m3, ....., mn be positive rational numbers, then

≥ ≥
is called weighted mean theorem

where A* = = Weighted arithmetic mean

G* = = Weighted geometric mean

and H* = = Weighted harmonic mean

i.e., A* ≥ G* ≥ H*
Now, let a + b + c = 5(a, b, c > 0) and x2y3 = 243(x > 0, y > 0)

3) The greatest value of ab3c is -

(A) 3
(B) 9
(C) 27
(D) 81

4) Which statement is correct -

(A)
≥

(B)
≥

(C)
≥

(D)
≥

Common Content for Question No. 5 to 6

Let ABC be an acute angled triangle and AD, BE and CF are its medians, where E and F are the
points (3, 4) and (1, 2) respectively and centroid of ΔABC is G(3, 2), then answer the following
questions :

5) The equation of side AB is

(A) 2x + y = 4
(B) x + y – 3 = 0
(C) 4x – 2y = 0
(D) None of these

6) Co-ordinates of D are

(A) (2, 3)
(B) (2, 5)
(C) (5, 0)
(D) (1, 3)

SECTION-I (iii)

1)

Match List-I with List-II and select the correct answer using the code given below the list.
 List-I List-II

(P) (1) 2
is

Let ƒ(x) = ax2 – bx – c, (a, b, c ∈ N) has

(Q) minimum value of –4 at x = 1. If a, b, c are in A.P., (2) 3
then abc is not equal to

If the sum of all solution(s) of the equation

(R) (3) 6
where x ∈ (–π, π), is kπ and number of solution(s) of
given equation is n, then |2nk| is

In ΔABC, let G is centroid and area of ΔAGB is 3

(S) (4) 9
then area of ΔABC is

(5) 10

(6) 11
(A) P → 2;Q → 1,2,4,5,6;R → 3;S → 1
(B) P → 1,2;Q → 1,3,4,5,6;R → 3;S → 1
(C) P → 1;Q → 1,3,4,6;R → 4;S → 3
(D) P → 2;Q → 1,2,4,5,6;R → 2;S → 4

2) Let (p2 – 4)x2 – (p2 – 5p + 6)x + (p2 – 6p + 8) = 0. Match List-I with List-II and select the correct
answer using the code given below the list.

List-I List-II

(P) Number of value(s) of 'p' for which above is an identity in x (1) 5

(Q) Number of value(s) of 'x' for which above is an identity in p (2) 4

Number of value(s) of 'p' for which above quadratic

(R) equation in x have roots equal in magnitude & opposite in (3) 0
sign

Number of integral value(s) of 'p' for which roots of

(S) (4) 1
above quadratic equation in x are of opposite sign

(5) 6
(A) P → 4;Q → 3;R → 4;S → 2
(B) P → 4;Q → 2;R → 4;S → 3
(C) P → 3;Q → 2;R → 4;S → 1
(D) P → 4;Q → 2;R → 1;S → 4

3)

List-I List-II

(P) If sinθ – cos2θ = 0, then cos4θ + cos2θ + 7 is equal to (1) 4

 (Q) If and , then log5N is equal (2) 9
to

(R) 8 + 3(sin4θ + cos4θ) – 2(sin6θ + cos6θ) is equal to (3) 6

If log22(x – 4) + log22(2 + log2y) = 0 then value of x +

(S) (4) 7
2y is equal to

(5) 8
(A) P → 5;Q → 1;R → 3;S → 2
(B) P → 1;Q → 5;R → 3;S → 2
(C) P → 5;Q → 3;R → 2;S → 1
(D) P → 5;Q → 1;R → 2;S → 3

4)

Match the complete interval of x satisfying the given inequalities :

List-I List-II

(P) (1)

(Q) (2) (0,3)

(R) (3) (0,1] ∪ {2}

(S) (4) ϕ

(5) [1, 2]
(A) P → 2;Q → 1;R → 3;S → 5
(B) P → 3;Q → 1;R → 4;S → 2
(C) P → 2;Q → 1;R → 4;S → 3
(D) P → 2;Q → 3;R → 1;S → 2

5) Match Column-I with Column-II and select the correct answer using the code given below the list.

Column-I Column-II

If a, b, c are positive real numbers then minimum

(A) (P) 3
value of (a + b + c) is

If a1, a2, a3 ... an are in increasing G.P. such that

(B) (Q) 4
a6 = 4a4 and a9 = a7 + 192 then value of (a1 + a2 + a3) is

Harmonic mean of the roots of equation

(C) (R) 7
, is
(D) (S) 9
upto ∞ terms, is equal to

(T) 5
(A) A → P;B → Q;C → S;D → T
(B) A → S;B → R;C → Q;D → P
(C) A → Q;B → P;C → R;D → S
(D) A → T;B → S;C → P;D → R
 ANSWER KEYS

PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. D D B B B A

SECTION-I (ii)

Q. 7 8 9 10 11 12
A. C B B A C C

SECTION-I (iii)

Q. 13 14 15 16 17
A. B B C B B

CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21 22 23
A. C B A D D B

SECTION-I (ii)

Q. 24 25 26 27 28 29
A. D C A C A D

SECTION-I (iii)

Q. 30 31 32 33 34
A. A A C A A

MATHEMATICS

SECTION-I (i)

Q. 35 36 37 38 39 40
A. A A B D C A

SECTION-I (ii)

Q. 41 42 43 44 45 46
A. C C C C A C
 SECTION-I (iii)

Q. 47 48 49 50 51
A. D A D C B
 SOLUTIONS

PHYSICS

1) Question Explanation:
From uniform disc, two small disc of radius R are cut off. It is asked to find the centre of mass.

Concept:
This question is based on centre of mass.

Solution:

Final Answer:
The correct option is (4)

2)

The COM of triangular part lies at distance of a/3 to the right of O.

3)

4) Question Explanation:
The problem asks to find the magnitude of acceleration of a 1 kg block being pushed against a
wall by a force F = 75 N, with a coefficient of friction of 0.25.

Concept:
This question is based on Newton's second law and friction.

Solution:
As the upward force (45 N) is greater than total downward force (25 N).
Hence, it has an upward acceleration.
Σfx = 0 ⇒ N = 60 N
Σfy = may
Fsin37° – mg – μFcos37° = ma 45 – 10 – 0.25 × 60 = 1.a
a = 20 m/s2

Final answer: The correct option is (2).

5) –(g + γv2) =

–gdt =
Integrating 0 → t & V0 → 0 :-

–gt = ;

t=

6) Explanation Question: A particle is moving on a circle under a given force which acts

towards O as seen in the figure. Then we have to find the ration of and .
Concept:
This question is based on kinematics of circular motion.

Solution:

F cosθ = mRω2, Fsinθ = mat

Angular velocity ω of line joining P and C is

Tangential acceleration of particle

so,

Final answer : option (1) : 2tanθ

7) (I) → (R), (II) → (Q), (III) → (P), (IV) → (S)

8) (II) → (Q)

9) x1 + x2 = D ⇒ ucosθt + u't = D ⇒ 40t=D ..(i)

For y–co–ordinate 300 –

⇒ 100 = 20 t ⇒ t = 5 ..(ii)
On using in equation (i) D = 200 m.

10) Co–ordinate x = ucosθt ⇒ ⇒ x = 100

and = y = 300 – 100 – 125 = 75

Co–ordinate (100, 75)

11) At the heighest point T = 2mg

T + mg =
vH2 = 3ℓg
Energy conservation at heighest and lowest point
 v0 =

12)
Net normal force

fk = µN

13) Centre of mass of system lies inside the bigger body so 0 < x < R

14)

For ram alone

60(V – 1) + 100 V = 0

For shyam alone

80(V + 1) + 80V = 0

15)

v = t2 – 3t + 2 = (t – 1) (t – 2)
0 < t < 1 sec, v = +ve but decreasing because at t = 1 sec, v = 0 and particle is changing its
direction.
1 < t < 2 sec, v = – ve ⇒ Particle is moving towards origin.
t > 2 particle accelerates

16) Question Explanation:

This problem involves a multi-block pulley system, where we need to determine the
acceleration of each block.

Concept:
This question is based on constrained motion.

Solution:
a(1kg) =
a(2kg) = 0

a(3kg) = =

a(4kg) = = 5 m/s2(↓)
Final Answer:
The correct option is (2)

17)

(P)
Applying Energy conservation between A & B :-

m(4 )2 = mg (4) + mv2

⇒ 40 = 40 + V2 ⇒
so, Block will just leave the circular path at Highest point & stands to fall.
so ........ (2)

(Q)
for complete circular motion v > ⇒v>
But there v = 2 =
so do not complete circular motion
Now, at Highest point, when Block
 Reaches, its velocity becomes zero and so it starts to fall. Then mg sin θ

(R)
for complete circle,
V> ⇒V> , given v =
Block will not complete

Clearly, N = mg cos θ
so, Normal is Radially outward. (4)

(S)
for complete circular motion,
v> ⇒v>

Here v = 4 = =
so, Here Rod will complete circular motion. (1)

CHEMISTRY

18)
Hybridisation of O is sp2. Lone pair is involved in B.B.

19) Slope
As slope of A > slope of B
∴ γ of A > γ of B
or A → Helium
B → Hydrogen

20)

21)

22)

N = no. of molecules present in given volume

23) In PCl3F2 hybrid orbital's length at axial position is more than hybrid orbital's length at
equitorial position.

24) Moles of I2 produced =

for this much moles I2, moles of AgNO3 required = x 2 x 103

∴ mass of AgNO3 required = 3 x 170 x 103 = 510 kg

25) moles of Nal =

moles of AgNO3 = x 103 = 5 x 102

clearly AgNO3 is limiting reagent

∴ moles of I2 formed =

26) ΔH = 0 → Cyclic process

27)
m = 1 mole
CV = 20 JK–1 mol–1 ideal gas (reversible process)

• = 1 × 20 × (273 – 546)
= –20 × 273 = –5460

• = –1 × r × 273 × ℓN = 273 R × ℓn2

WC→A = 1573.25
Wnet = –3886.74 J = –3.8 kJ ≈ –4 kJ

28)

nR ln

29)
nR ln

30) (A) ΔH < 0 (Exothermic) only for F–(g) → F–(aq)

(B) ΔH > 0 (Endothermic) For →
N+(g) N+2(g) I.E. (ΔH = +ve)
–
N(g) N (For halffiled ΔHeg= +ve)
(g)

E.G.E. → Electron gain enthalpy

N(g) → N+2(g) ΔH = +ve
N(g) → N–2(g) ΔH = +ve
(C) ΔHIE2(N) ⇒ N+(g) N+2(g)
(D) ΔHIE1(N) ⇒ N(g) N–(g)
Ans. A→T; B→P,Q,R,S; C→P; D→Q

32)
Reversible process

33) Theoretical.

34) (P) Initial state (V1, T1) to final state (V2, T2), entropy change for Ideal gas

ΔSsystem = nCV ℓn + nR ℓn ≠0

ΔSsurrounding = (qsurrounding = 0)
Since process is adiabatic.
w = nCV (T2 – T1)

w= (T2 – T1)
(Q) Initial state (V1, T1) to final state (V2, T2)

ΔSsystem = nCv ℓn + nR ℓn ≠0
Since process is reversible
ΔSuniverse = 0 = ΔSsystem + ΔSsurrounding
ΔSsurrounding = –ΔSsystem
(R)
Ice at 0°C water vapour 100°C

Water at 0°C water at 100°C

nCP ℓn

ΔSsystem =
 ΔSsurrounding < 0
(S)

MATHEMATICS

35) x2 – 2mx + m2 – 1
Roots are between –2 and 4

(i) –2 <

–2 <
–2 < m < 4
(ii) f(–2) > 0, 4 + 4m + m2 – 1 > 0
m2 + 4m + 3 > 0
(m + 1)(m + 4) > 0
So m < –4 or m > –1
f(4) > 0
2
16 – 8m + m – 1 > 0
m2 – 8m + 15 > 0
(m – 3)(m – 5) > 0
m < 3 and m > 5
(iii) D>0
4m2 – 4(m2 – 1) > 0
4m2 – 4m2 + 4 > 0
4>0
so from (i), (ii) and (iii)
–1 < m < 3

36)
m=1
pass through (–3, 2)
y–2 = 1(x+3)
x–y+5=0
37) Question Explanation: Find the locus of a point P(x,y) in the first quadrant where the
sum of its distances from the axes equals its distance from A(1,1).
Concept: Locus, Distance Formula, and Simplification
Solution: In the first quadrant, the distances from the axes are x and y. Set up the equation
x+y=PA and square both sides to find the locus equation.
Calculation: P(x,y) in the first quadrant (x>0,y>0). A(1,1). Distance from x-axis is ∣y∣=y.
Distance from y-axis is ∣x∣=x.

x+y=PA ⟹
Square both sides:
(x+y)2=(x−1)2+(y−1)2
x2+y2+2xy=x2−2x+1+y2−2y+1
2xy=−2x−2y+2.
xy=−x−y+1.
xy+x+y−1=0.
Add 1 to both sides and factor:
xy+x+y+1=2.
(x+1)(y+1)=2.
Final Answer: (x+1)(y+1)=2

38) ℓ, G1, G2, G3, n in G.P.

Let r be the common ratio

⇒ r4 =

Here =
= nℓ[ℓ + 2ℓn + n2] = nℓ(ℓ + n)2 = nℓ4m2
2

= 4m2nℓ
(∵ 2m = n + ℓ)

39) Question Explanation: Find the number of integral solutions of a trigonometric

inequality in a given interval.
Concept: Solving quadratic inequalities.
∵ 2sin2x – 5sinx + 2 > 0
⇒(2sinx – 1)(sinx – 2) > 0

⇒
integral values of x are {0,3,4,5,6}
Final Answer: 4

40)
We have AB = 8m, AD = AF=5m, BC=1m
∴ BC = AE = 1 m and ∴ DE = AD – AE = 5 – 1 = 4 m and ∠EDC = 90 as tangent on circle

∴ ∠DEC = θ ∴ cos θ = ∴θ= = ∠DEC = ∠DAB, ∠ABC =

∴ ∠DAF = (bigger arc) and ∠GBC = (Smaller arc) ,

DC =

arc length DF in belt = m, arc length GC =

Hence total distance of belt = =

41)

α2 = α + 1 ⇒ αn = αn – 1 + αn – 2
⇒ p αn + q βn = p(αn – 1 + αn – 2) + q(βn – 1 + βn – 2)
n = n–1 + n–2

⇒ 12 = 11 + 10

42)

α2 = α + 1 ⇒ α4 = 3α + 2
∴ α4 = 28 ⇒ p α4 + q β4 = p(3α + 2) + q(3β + 2) = 28
⇒ p(3α + 2) + q(3 – 3α + 2) = 28
⇒ α(3p – 3q) + 2p + 5q = 28 (as α ∈ Qc)
⇒ p = q, 2p + 5q = 28 ⇒ p = q = 4
∴ p+ 2q = 12

43) (AM ≥ GM)

ab3c ≤ 27

44) (AM ≥ HM)

⇒
45) Question Explanation: Find the equation of side AB (case study, assume coordinates
from the implicit solution to a previous question).
Concept: Equation of a Straight Line
Solution: Assuming the vertices derived from Q100 of the original PDF: A(−1,6),B(3,−2). Use
the two-point form of a straight line equation y−y1​=m(x−x1​). Calculation: A(−1,6),B(3,−2).
Slope m=(−2−6)/(3−(−1))​=−8/4​=−2.
y−6=−2(x−(−1))
y−6=−2x−2
2x+y=4.
Final Answer: 2x+y=4

46) Question Explanation: Find the coordinates of D (case study, assume coordinates from
the implicit context).
Concept: Finding Coordinates from Midpoints
Solution: Assuming the context involves D as the midpoint of AB where the other vertices are
found from a set of midpoints of a larger triangle (similar to Q66 of the PDF source). The
original PDF's implicit solution implies D(5,0) from a set of midpoints.
Calculation: Assuming a previous step yielded midpoints for △ABC leading to vertices
A(−1,6),B(3,−2),C(7,2), and D is the midpoint of BC.
D={(3+7)/2,(−2+2​)/2}=(5,0).
Final Answer: (5,0)

47) (P) tan260° = 3

(Q) ⇒ b = 2a ...(1)
ƒ(1) = a – b – c = –4
b+c–a=4 ...(2)
2b = a + c ...(3)
a = 1, b = 2, c = 3
abc = 6

(R)

or

as x ∈ (–π, π)

Sum = ; ,n=3
(S) ΔABC = 3(ΔACB) = 9

48) (A) (p2 – 4)x2 – (p2 – 5p + 6)x + (p2 – 6p + 8) = 0 identity, then p = 2

(B) p2(x2 – x + 1) + p(5x – 6) + 8 – 4x2 – 6x = 0
⇓
not possible that x2 – x + 1 = 0
(C) SOR = 0 ⇒ p = 3

(D) POR < 0 ⇒

⇒
49) (P) sinθ = cos2θ
Then cos4θ + cos2θ + 7
= sin2θ + cos2θ + 7
=1 + 7 = 8
(Q)

N = (25)2 ⇒ (5)4
log5N = 4

(R)

(S)
and
x–4=1 2 + log2y = 1

x=5
x + 2y = 6

50)

(P) but x > 0

⇒ x ∈ (0,3)

(Q) not possible ⇒ x ∈ ϕ

(R)
but x ≠ 0, x = 2
⇒

51) (A) A.M. ≥ G.M. ≥ H.M.

(B) Let common ratio = r > 0

a6 = 4a4 ⇒ a1r5 = 4a1r3 ⇒ r = 2
a9 = a7 + 192 ⇒ a1 = 1
(C) Let roots are α, β

H.M. of α, β =
(D)

⇒S=3