21-09-2025

1103CJA101001250038 JA

PHYSICS

SECTION-I (i)

1) Four identical point masses 'm' joined by light string of length 'ℓ' arrange such that they form
square frame. Centre of table is coincide with centre of arrangment. If arrangement rotate with

constant angular velocity 'ω'. Find out tension in each string

(A)

(B) mω2ℓ/2
mω2ℓ /
(C)

(D) mω2ℓ

2) Two roads crossing each other at right angle. Car A is situated 600 m west of car B which is
passing through crossing, at that instant. Then the minimum distance between them during journey

will be

(A) 400 m
(B) 600 m
(C) 300 m

(D)

3) In a water park there is a circular river in which the flow is at a speed u along a circular path. A
small toy beat is steered radially with speed v relative to water. If reaches a diametrically opposite
point B to the other bank in half round (180°). The time to cross the river and reach B is. (r0
is radius of central circle.)

(A)

(B)

(C)

(D) None of these

4) A cylindrical container is having horizontal bottom and vertical walls. A block of mass m is given
an initial velocity of v0 along the tangential direction as shown. If coefficient of friction at each

0
contact surface is . Find ratio of magnitude of acceleration of block when its speed is v and .

(Given )

(A)

(B)

(C)

(D)

5) A particle of mass m oscillate inside the smooth surface of fixed pipe of radius R. The axis of the
pipe is horizontal and the particle moves from point 'B' to point 'A' and back. At an instant the
kinetic energy of the particle is K. The force applied by the particle on the pipe at this instant is
(A)

(B)

(C)

(D)

6) A body of mass 25 kg is dragged on a rough horizontal floor for one hour with a speed of 2km/h.
The coefficient of friction between the body and the surface in contact is 0.5 and half the heat
produced is absorbed by the body. If specific heat of body is 0.1 cal g–1 (ºC)–1, then the rise in
temperature of body is :

(A) 50 K
(B) 23.8 K
(C) 100 K
(D) 11.9 K

SECTION-I (ii)

1) There is a rectangular metal plate in which two cavities in shape of rectangle and circle are made,
as shown in figure, with dimensions. P & Q are centres of these cavities. On heating the plate which

of the following quantities increases.

(A)
(B) ab
(C) R
(D) All of these

2) In a situation, a board is moving with a velocity v with respect to earth, while a man A and man B
are running with a velocity 2v with respect to earth and both men are running from the opposite
ends of the board at the same time, as shown. Length of the board is L. If they meet after time T,

then

(A) Value of T is L/4 v

(B) Value of T is L/2 v
(C) Displacement of man B with respect to board in time T is 3L/4
(D) Displacement of man A with respect to board in time T is L/4

3) A particle is performing circular motion of radius 1m. Its speed is v = (2t2) m/s. Then at t = 1s :

(A) Angular speed is nearly 19.1 rpm

2
(B) Centripetal acceleration, ac = 4m/s
(C) Net acceleration, m/s2
(D) Tangential acceleration,

4) A mass m is attached to a thin light rod of length , velocity given at its lowest position such that
it can freely move in a complete vertical circle . Time taken to complete one revolution is T. The
difference in the tensions in the rod when the mass is at the top and the bottom of the circle

(A) Depends on and m

(B) Depends on but not on T
(C) Depends on m and T
(D) Independent of and T

5) The water equivalent of a copper calorimeter is 4.5 gm. If the specific heat of copper is 0.09
cal/g/°C, (Given latent heat of fusion of ice is 80 Cal/g)

(A) mass of the calorimeter is 0.5 kg

(B) thermal capacity of the calorimeter is 4.5 cal/°C
(C) heat required to raise the temperature of the calorimeter by 8°C will be 36 cal
(D) heat required only to melt 15 g of ice placed in the calorimeter will be 1200 cal

6) A bead of mass m slides on a fixed frictionless wire bent into a horizontal semicircle of radius R
as shown in figure. In addition to any normal forces exerted by the wire, the bead is subjected to an
external force that points directly away from origin and depends on distance r from the origin

according to the formula :-

(A) Given force is a central force.

(B) Given force is a conservative force.
(C)
Work done by external force as bead leaves the track (starting from origin) is

(D)
Speed of bead as it leaves the wire is

SECTION-II

1) A rod of length 1000 mm and coefficient of linear expansion α = 10–4 per degree is placed
symmetrically between fixed walls separated by 1001 mm. The Young’s modulus of the rod is 1011
N/m2. If the temperature is increased by 20°C, then the stress developed in the rod is given by α

MPa. Fill α.

2) Equal volumes of water and alcohol are mixed in calorimeter of negligible heat capacity. The
initial temperature of water is 0°C and that of alcohol is 37°C. The specific gravity of alcohol is 0.8.
If the specific heat capacity of water is 1 cal/g, the specific heat capacity of alcohol is 0.6 cal/g °C. If
the final temperature of mixture is T°C. Then find value of T/2.

3) A rod has variable coefficient of linear expansion α = per °C, where x is distance (in metres)
from one end. If length of the rod is 1m. Determine increase in length of the rod (in cm) on
increasing temperature of the rod by 100°C.

4) A cube of mass m slides down the smooth track from height 4R. Then the force track will exert on

block at point 2 is ____ times the weight of block :-

5) In case of ground to ground projectile graph of slope of trajectory is given if angle of projection is
60°.
(g = 10 m/s2) α = tan-1
Find projection speed.

6) A small cubical block of mass 1 kg is placed inside a rough rectangular groove made in a
circular table as shown in the figure. The table starts rotating with angular acceleration 1 rad/sec2 in
a horizontal plane about its axis. The time is sec after which the block will start motion with
respect to table. Find the value of K. (Take g = 10 m/s2) Assume the size of block slightly smaller

then the width of groove.

CHEMISTRY

SECTION-I (i)

1) Which of the following is NOT non linear?

–
(A) [I(CN)2]
(B) HN3
(C) CH3NCS
(D) All

2)

In which of the following compounds back bonding is not possible :-

(A) Al2H6
(B) Al2F6
(C) Al2Cl6
(D) None of these

3) Choose the CORRECT statement –

(A) Total number of exchange pair for d9 electronic configuration is 16
(B) On moving left to right in a period, Zeff decreases
(C) Spin multiplicity of 3d5 is lesser than spin multiplicity of 3d6
(D) Spin only magnetic moment of Fe2+ is

4) Consider the following sequence of reaction:

If electronic configuration
1
of element X is [Ne]3s , then which of the following order is incorrect regarding given enthalpies.

(A) |ΔH4| = |ΔH5|

(B) |ΔH2| > |ΔH1|
(C) |ΔH2| > |ΔH3|
(D) |ΔH1| = |ΔH6|

5) Cl–O bond order in perchlorate ion will be :-

(A) 1.33
(B) 1.50
(C) 1.66
(D) 1.75

6) Consider the following chemical species CIF3, PH3, P4, S8, , Be2H4, XeF4, NO2, C2H4, SF4. For how
many of the above molecular/ionic species their all atoms are present in a single plane? Select the
correct option.

(A) 4 of the given molecular/ionic species

(B) 5 of the given molecular/ionic species
(C) 6 of the given molecular/ionic species
(D) 7 of the given molecular/ionic species

SECTION-I (ii)

1)

Choose the correct statements :-

(A) dP–F(axial) > dP–F(equatorial) in PF3Cl2

(B) dP–F > dP–Cl in PF2Cl3
(C) dP–Cl(PF2Cl3) > dP–Cl(PF3Cl2)
(D) All dP–Cl (in PF2Cl3) are identical while all dP–F(in PF3Cl2) are not identical

2) Which of the following reactions is/are likely to be impossible ?

(A)
(B)
(C)
(D) All of the above

3) Which of the following molecules have significant ?

a b c d

(A) (a)
(B) (b)
(C) (c)
(D) (d)

4) Hydrogen bonding is present in which of the following species ?

(A) CH3NH2
(B)
(C) CH3COOH
(D) CCl3CH(OH)2

5) There is S – S linkage in :

(A)
(B)
(C)
(D)

6) Which of the following species are correctly matched with their geometries according to the
VSEPR theory?

(A) octahedral.
(B) trigonal bipyramidal.
(C) linear.
(D) see-saw.

SECTION-II

1) Number of molecules in which lone pair of electrons on the central atom is present in pure s-
orbital.
(i)NH3 (ii) N2H4 (iii) HN3 (iv) PH3
(v) H2S (vi) AsH3 (vii) SbH3 (viii) H2Se
(ix) H2Te

2) Maximum number of atoms present in one plane in PF2(CH3)3 :

3) Find the % ionic character in Li-F bond from the given data?
μLiF = 6.32 D dLiF = 0.156 nm

4) In the molecule CF3Cℓ, the number of planes consisting of maximum number of atoms where at
least two atoms are same is :

5) BrF3 is a liquid which considerably undergoes self ionization to form cationic and anionic species.
Based on VSEPR theory, number of 90 degree F–Br–F bond angles is ......................... in anionic
species.

6) How many hydrogen bonded water molecule(s) are associated in CuSO4.5H2O.

MATHEMATICS

SECTION-I (i)

1) If both roots of quadratic equation are positive and distinct then

complete set of values of θ in [0, 2π] is -

(A)

(B)

(C)

(D)
2) If equation x4 + kx3 + x2 + kx + 1 = 0 (where k ∈ R) has exactly 2 distinct negative roots then
complete set of values of k is

(A)

(B)

(C) (1, ∞)
(D) (–∞, –1)

3) The roots of x2 – 3x + 3 = 0 are . Then is

(A) –27
(B) 27
(C) 0
(D) 81

4) If r, s, t are prime numbers and p, q are the positive integers such that their HCF is rs2t and their
LCM is r2s3t, then the numbers of ordered pair of (p, q) is -

(A) 4
(B) 18
(C) 36
(D) 72

5) Consider 4 boxes, where each box contains 3 red balls and 2 blue balls. Assume that all 20 balls
are distinct. In how many different ways can 10 balls be chosen from these 4 boxes so that from each
box at least one red ball and one blue ball are chosen ?

(A) 21816
(B) 85536
(C) 12096
(D) 156816

6) Number of ways in which the letters of the word ‘’NATION’’ can be filled in the given figure such
that no row remains empty and each box contains not more than one letter, are:

(A)
(B)

(C)
(D)

SECTION-I (ii)

1) Given that x2 – 3x – 4 < 0, < 0 and 2sin2x + 3sinx – 2 > 0. Then x can be

(A)

(B)

(C) π

(D)

2) Suppose a, b, c are positive integrals and f(x) = ax2 − bx + c = 0 has two distinct roots in (0, 1),
then

(A) a ≥ 5
(B) b ≥ 5
(C) abc ≥ 25
(D) abc ≥ 250

3) The smallest positive integral value of a for which the greater root of the equation x2 – (a2 + a +
1)x + a(a2 + 1) = 0 lies between the roots of the equation x2 – a2x – 2(a2 – 2) = 0, is less than:

(A)

(B)

(C)

(D)

4) The kindergarten teacher has 25 kids in her class. She takes 5 of them at a time, to zoological
garden as often as she can, without taking the same 5 kids more than once. Then the number of
visits, the teacher makes to the garden exceeds that of a kid by :

25 24
(A) C5 – C4
24
(B) C5
25 24
(C) C5 – C5
 24
(D) C4

5) Lines y = x + i & y= –x + j are drawn in x – y plane such that i ∈ {1, 2, 3, 4} & j ∈ {1, 2, 3, 4,
5,6}. If m represents the total number of squares formed by the lines and n represents the total
number of triangles formed by the given lines & x-axis, then correct option/s is/are-

(A) m + n = 50
(B) m – n = 2
(C) m + n = 48
(D) m – n = 4

6) If the 4 letter words are formed by using the letters of the word "MATHEMATICS" then which of
the following is/are correct

(A) Number of words in which all letters are different in 1680

(B) The total number of words is 2454
(C) Number of words in which exactly two letters are identical is 756
(D) Total number of such words is greater than 2436

SECTION-II

1) If n be the number of words formed by using all letters of the word STATISTICS, such that no 'T'
is present anywhere on the right of any 'S' and n = 2a . 3b . 5c . 7d (a, b, c d ∈ N), then the value of a
+ b + c + d is

2) Let b1b2b3b4 be a 4-element permutation with bi ∈ {1, 2, 3, .......,, 100} for 1 ≤ i ≤ 4 and bi ≠ bj for
i ≠ j, such that either b1, b2, b3 are consecutive integers or b2, b3, b4 are consecutive integers.
Then the number of such permutations b1b2b3b4 is equal to λ, then sum of digits at even places in λ is
equal to

3) A number is called a palindrome if it reads the same backward as well as forward. For example
285582 is a six digit palindrome. The number of six digit palindromes, which are divisible by 55, is
_________.

4) If a + b + c = 8, ab + bc + ca = 12 (where a, b, c ∈ R), then number of possible integral values of

a is

5) Find the value of

6) If x2 – 9ax – 10β = 0 have roots γ and δ, x2 – 9γx – 10d = 0 have roots α and β. (α, β, γ, δ are

distinct real numbers), then the value of is

 ANSWER KEYS

PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. B D A C B D

SECTION-I (ii)

Q. 7 8 9 10 11 12
A. A,B,C,D A,C,D A,B D B,C,D A,B,C

SECTION-II

Q. 13 14 15 16 17 18
A. 100.00 6.00 1.00 3.00 4.00 2.00

CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A B A C D C

SECTION-I (ii)

Q. 25 26 27 28 29 30
A. A,B,D B,C C,D A,C,D A,B,C A,B,C,D

SECTION-II

Q. 31 32 33 34 35 36
A. 6.00 7.00 84.00 7.00 4 1

MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. B B C A A C

SECTION-I (ii)

Q. 43 44 45 46 47 48
A. A,B,D A,B,C B,C A,B A,B A,B,C,D
 SECTION-II

Q. 49 50 51 52 53 54
A. 7.00 9.00 100.00 7.00 12.00 3.00
 SOLUTIONS

PHYSICS

1)

2)

3)

4) When speed is V0

fi = f1 + f2 = µmg + µ = 2µmg

ff = µmg + µ

atotal f =

5) Ans. (2)
Let velocity of particle at point P be v.
From conservation of mechanical energy

Let N be the normal between particle and pipe then

N – mgsinθ =

But = and sinθ =

∴ N = mg × =

N= (∵ mgh = k)

N=

6) Friction force = 0.5 × 25 ×10 = 125 N

distance moved = 2 × 103
∴ work done against friction = 250 × 103 J
∴ Heat given to the body = 125 × 103 J

∴T=

= = = 11.9 K

7)

(A)
(B) ab
(C) R
(D) All of these

8)

At the plane VAB = 4V

9) Question Explanation: We are given, speed of particle as a function of time in circular
motion. We have to choose correct options.

Concept: This question is based on kinematics of circular motion.

Solution: Speed v = 2t2

∴ tangential acceleration = at = 4t
then at t = 1 sec at = 4 m/s2

and centripetal acceleration 4 m/s2

Net acceleration =

Final answer: The correct option are (1) and (2).

10)

11)

B- Thermal capacity of the calorimeter is 4.5 cal°C–1

C- Heat required to raise the temperature of the calorimeter by 8°C will be 36 cal
D- Heat required to melt 15 gm of ice placed in the calorimeter will be 1200 cal

(b) Thermal capacity = ms

(c)
(d)

12) is a central force, because direction of force is always away from the fix

point origin & work done by this force is zero in any close loop force is
conservative

Work done by the force on bead

13)
14) Heat gain = Heat lost

15) dℓ = α 0ΔT

= dx

Total expansion = = 1 cm.

16)

N = 3 mg

17) y = x tan θ

slope = = tan θ – ×x

= tan α ⇒
2
u = 16 ∴ u = 4 m/sec

18) Relative motion between block and table will start when

... (i)
... (ii)
 solving (i) and (ii) sec.

CHEMISTRY

19) (A) Linear

(B) Non-linear in one resonating structure.

(C) Non-linear
θ ≠ 180º
(A) is not non-linear
(A) is answer.

20)

Al2F6

21)

Ans is (A) d9

(A)
Total exchange pairs 4 + 3 + 2 + 1 + 3 + 2 + 1 = 16
(B) Zeff = Z – screening constant
Z inc. by 1 unit
Screaning Constant inc. by 0.3 unit
∴ Zeff inc. left to right
(C) No. of unpaired e– in 3d5 =
 No. of unpaired e– in 3d6 =
Spin multiplicity
∴ spin multiplicity of 3d5 > 3d6
(D) Fe2+ is 3d6 no. of unpaired e– = 4
Mag. Momentum

22)
ΔH3 > ΔH2
IE3 > IE2 > IE1

23) B.O =

24)

CIF3, , Be2H4, XeF4, NO2 and C2H4

25)

axial bond are weakes than equational bonds.

26) can acts as lewis base but (SiH3)2O and (SiH3)3N can not, as lone pairs on O
and N are delocalised into empty orbitals of Si.

27)

Owing to the lone pairs & H present on OH & SH in c & d

28) Hydrogen bonding is possible in CH3NH2, CH3COOH, CCl3CH(OH)2

29)
In structure of there is one S – O – S linkage but no S – S linkage.

30)
 31) PH3, H2S, AsH3, SbH3, H2Se, H2Te
Follow drago's rule.

32)

New Solution

Maximum atoms in one plane = 7

Ans. 7.00

OLD Solution
A. Question Explanation:
The question asks for the maximum number of atoms that can lie in the same plane in the
PF₂(CH₃)₃ molecule.

B. Given Data:
The molecule is PF₂(CH₃)₃.

C. Concept:
Planarity in molecules depends on the hybridization of the central atoms and the geometry
they adopt.

D. Solution:

1. Structure : Phosphorus (P) is the central atom. It is bonded to two fluorine atoms (F) and three
methyl groups (CH₃).

2. Geometry around Phosphorus : Phosphorus has 5 valence electrons. In PF₂(CH₃)₃, it forms 5

single bonds (2 with F and 3 with C). This suggests sp³d hybridization. The electron geometry would
be trigonal bipyramidal.
3. Arrangement : To maximize the number of atoms in one plane, we should consider the
equatorial plane of the trigonal bipyramidal structure. This plane contains the phosphorus atom and
three other atoms.

4. Planar Atoms:

A. P atom is in the plane.

B. Two carbon atoms of two methyl groups can be in the same plane as P (equatorial positions).
C. The two F atoms cannot both be in the same plane as the two methyl C atoms and P.
D. The third methyl group will be out of the plane (axial position).

5. Maximum Planar Atoms: The phosphorus atom, two carbon atoms from two methyl
groups, and their directly bonded hydrogen atoms will be in the same plane. This gives us 1 (P)
+ 2 (C) + 2 (H) = 5 atoms. The other two methyl groups and F atoms will be out of this plane.
6. Another possibility: If the two F atoms and one C atom are in the equatorial plane, then
two C atoms will be in the axial positions. In this case also, 1(P)+2(F)+1(C)+2(H) = 6 atoms
can be in the same plane.
7. Maximum: If one F, one C of one methyl group, and one C of another methyl group are in
the plane with P, then 1(P) + 1(F) + 2(C) + 2(H) = 6 atoms can be in the same plane.
8. Consideration of the methyl groups: Each methyl group (CH₃) has 4 atoms. While the C
atom can be in the plane, all three H atoms cannot be simultaneously in the same plane with P
and the other atoms. Only one H from each methyl group in the plane can be in the plane.

33) μCal = (1.602 × 10–19C) × (0.156 × 10–9m)

μCal = 2.496 × 10–29 C.m

% ionic character =

% ionic character = 84.32%

34)

35)
 36)

MATHEMATICS

37) sinθ + cosθ < 0

38) x4 + kx3 + x2 + kx + 1 = 0

let
t2 + kt – 1 = 0
has exactly one root less than –2

f(t) = t2 + kt – 1
⇒ f(–2) < 0
⇒ 4 – 2k – 1 < 0
39)

...(1)

....(2)
from (1) – (2)
⇒ (α8 – α7) + (β8 – β7) = –81 + 81
⇒ α7(α – 1) + β7(β – 1) = 0

40)

41)
Case-I : when exactly one box provides four balls (3R 1B or 2R 2B)
Number of ways in this case 5C4 (3C1 × 2C1)3 × 4
Case-II : when exactly two boxes provide three balls (2R 1B or 1R 2B) each
Number of ways in this case (5C3 – 1)2 (3C1 × 2C1)2 × 6
Required number of ways = 21816
Language ambiguity : If we consider at least one red ball and exactly one blue ball, then
required number of ways is 9504. None of the option is correct.

42)

43)
We have,
x2 – 3x – 4 < 0 –1 < x < 4 …(i)
Also,

…(ii)
2
and 2 sin x + 3 sinx – 2 > 0
(sinx + 2) (2 sinx – 1) > 0

[ (sin x + 2) > 0]

…(iii)

44)

(A) a ≥ 5
(B) b ≥ 5
(C) abc ≥ 25

45)

(B)

(C)

46)

Total no. of visits that a teacher goes is = 25C5

(selection of 5 different kids each time & teacher goes every time)
Number of visits of a boy = select one particular boy & 4 from rest 24 = 24C4
So extra visits of a teacher from a boy is = 25C5 – 24C4 = 24C5

47)
m = 15 + 8 + 3 = 26
n = 4C1 . 6C4 = 24
48)

(A) Number of words in which all letters are different in 1680

(B) The total number of words is 2454
(C) Number of words in which exactly two letters are identical is 756
(D) Total number of such words is greater than 2436

49)

50)
Let A = set when b1, b2, b3, are consecutive

Similarly when b2 b3 b4 are consecutive

N(A) = 97 × 98

Similarly when b2 b3 b4 are consecutive

n(B) = 97 × 98

Number of permutation = 18915

51)
It is always divisible by 5 and 11
So, required number = 10 × 10 = 100

52) a + b + c = 8
ab + bc + ca = 12
c = 8 – (a + b)
ab + b(8 – (a + b)) + a(8 – (a + b)) = 12
ab + 8b – ab – b2 + 8a – a2 – ab – 12 = 0
b2 + b(a – 8)+ a2 – 8a + 12 = 0
D≥0
(a – 8)2 – 4(a2 – 8a + 12) ≥ 0
a2 – 16a + 64 – 4a2 + 32a – 48 ≥ 0
3a2 – 16a – 16 ≤ 0
number of integral values of a is 0, 1, 2, 3, 4, 5, 6

53)
54)

γ + δ = 9α
γδ = –10β
α + β = 9γ
αβ = –10δ
αβγδ = 100βδ
αγ = 100
α + β + γ + δ = 9(α + γ) ...(1)
2
⇒ γ – 9αγ – 10β = 0
α2 – 9αγ – 10δ = 0
add α2 + γ2 – 18αγ – 10(β + δ) = 0
(α + γ)2 – 20αγ – 80(α + γ) = 0
2
(α + γ) – 80(α + γ) – 2000 = 0
α + γ = 100
⇒ α + β + γ + δ = 900.