05-10-2025

9610ZJA802263250007 JA

PART 1 : PHYSICS

SECTION-I

1) A particle of mass m moving with a speed u strikes a smooth horizontal surface at an angle 45°

the particle rebounds it an angle ϕ with speed v, if coefficient of restitution is , then angle of ϕ is:-

(A) 30°
(B) 45°
(C) 60°
(D) 37°

2) Block A is hanging from a vertical spring and is at rest. Block B strikes the block A with velocity V

and sticks to it. Then the value of V for which the spring just attains natural length is :

(A)

(B)

(C)

(D) None of these

3) The centre of mass of a non-uniform rod of length L whose mass per unit length λ varies as λ =

where k is a constant & x is the distance of any point on rod from its one end, is at distance
(from the same end)
(A)
L

(B)
L

(C)

(D)

4) The rms value of the electric field of the light coming from the sun is 720 N/C. The average total
energy density of the electromagnetic wave is-

(A) 4.58 × 10–6 J/m3

(B) 6.37 × 10–9 J/m3
(C) 81.35 × 10–12 J/m3
(D) 3.3 × 10–3 J/m3

5) For a plane electromagnetic wave propagating in the +Z direction, which one of the following
combination gives the correct possible direction for and field respectively ?

(A)
and

(B)
and

(C)
and

(D)
and

6) A radioactive isotope is being produced at a constant rate X. Half-life of the radioactive substance
is Y. After some time the number of radioactive nuclei become constant. The value of this constant is
:-

(A)

(B) XY
(C) (XY) ln (2)

(D)

7) In the photoelectric experiment, if we use a monochromatic light, the I–V curve is as shown. If
work function of the metal is 2 eV, estimate the power of light used. (Assume efficiency of photo
emission = 10–3 %, i.e. number of photoelectrons emitted are 10–3% of number of photons incident on

metal) :-
(A) 2 W
(B) 5 W
(C) 7 W
(D) 10 W

8) A metal plate is exposed to light with wavelength λ. It is observed that electrons are ejected from
the surface of the plate. When a retarding uniform electric field E is imposed, no electron can move
away from the plate farther than a certain distance d. Then the threshold wavelength λ0 for the
material of plate is (e is the electronic charge, h is Planck's constant and c is the speed of light) :-

(A)

(B)

(C)

(D)

9) A cubical block of mass kg is placed on a rough horizontal surface as shown in the figure. A
force of 1 Newton acts at one of the corners of the block such that it remains at rest. Normal force

exerted by surface on block acts through :-

(A) centre of mass of block

(B) through point A
(C) through point B
(D) through a point 5cm from A

10) A circular platform is mounted on a frictionless vertical axle passing through centre. Its radius R
= 2m and moment of inertia about the axis is 200 kg-m2. It is initially at rest. A 50 kg man stands on
the edge of platform and begins to walk along the edge at speed of 1m/sec relative to the ground.
Time taken by the man to complete one revolution is :-

(A) 2π sec

(B)

(C) π sec

(D)

11) Initial angular velocity of a circular disc of mass M is ω1. Then two small spheres of mass m are
attached gently to two diametrically opposite points on the edge of the disc. What is the final
angular velocity of the disc ?

(A)

(B)

(C)

(D)

12) A fixed pulley of radius 20 cm and moment of inertia 0.32 kg.m2 about its axle has a massless
cord wrapped around its rim. A mass M of 2 kg is attached to the end of the cord. The pulley can
rotate about its axis without any friction. The acceleration of the mass M is : (Assume g = 10 m/s2)

(A) 1 m/s2
(B) 3 m/s2
(C) 2 m/s2
(D) 4 m/s2

13) Figure shows the variation of the moment of inertia of a uniform rod, about an axis passing
through its centre and inclined at an angle θ to the length. The moment of inertia of the rod about an

axis passing through one of its ends and making an angle θ = will be :

(A) 0.45 kg–m2

(B) 1.8 kg–m2
(C) 2.4 kg–m2
(D) 1.5 kg–m2

14) An equilateral triangle ABC is cut from a thin solid sheet of wood. (see figure) D, E and F are the
mid-points of its sides as shown and G is the centre of the triangle. The moment of inertia of the
triangle about an axis passing through G and perpendicular to the plane of the triangle is I0. It the
smaller triangle DEF is removed from ABC, the moment of inertia of the remaining figure about the
same axis is I. Then :

(A)

(B)

(C)

(D)

15) A circular disc of radius b has a hole of radius a at its centre (see figure). If the mass per unit

area of the disc varies as , then the radius of gyration of the disc about its axis passing through

the centre is :

(A)

(B)

(C)

(D)

16) The springs in fig. A and B are identical but length in A is three times each of that in B. The ratio

of period TA/TB is :-

(A)
(B) 1/3
(C) 3
(D) 1/

17) A person of mass M is, sitting on a swing of length L and swinging with an angular amplitude θ0.
If the person stands up when the swing passes through its lowest point, the work done by him,
assuming that his centre of mass moves by a distance ℓ (ℓ < < L), is close to :

(A) Mgℓ
(B) Mgℓ (1 + θ0 )
2

(C) Mgℓ (1 – θ0 )
2

(D)
Mgℓ

18) A pendulum is executing simple harmonic motion and its maximum kinetic energy is K1. If the
length of the pendulum is doubled and it performs simple harmonic motion with the same amplitude
as in the first case, its maximum kinetic energy is K2. Then :-

(A)

(B)

(C) K2 = 2K1
(D) K2 = K1

19) Two masses m and are connected at the two ends of a massless rigid rod of length ℓ. The rod
is suspended by a thin wire of torsional constant k at the centre of mass of the rod-mass system(see
figure). Because of torsional constant k, the restoring torque is τ=kθ for angular displacement θ. If
the rod is rota ted by θ0 and released, the tension in it when it passes through its mean position will

be:

(A)

(B)

(C)

(D)

20) A simple pendulum oscillating in air has period T. The bob of the pendulum is completely
immersed in a non-viscous liquid. The density of the liquid is th of the material of the bob. If the
bob is inside liquid all the time, its period of oscillation in this liquid is :

(A)

(B)

(C)

(D)

SECTION-II

1) The total length of a sonometer wire between fixed ends is 110 cm. Two bridges are placed to
divide the length of wire in ratio 6 : 3 : 2. The tension in the wire is 400 N and the mass per unit
length is 0.01 kg/m. What is the minimum common frequency (in Hz) with which three parts can
vibrate ?

2) A one metre long (both ends open) organ pipe is kept in a gas that has double the density of air at
STP. Assuming the speed of sound in air at STP is 300 m/s, the frequency difference between the
fundamental and second harmonic of this pipe is ________ Hz (Nearest integer).

3) An open pipe 40 cm long, and a closed pipe 31 cm long, both are having same diameter. Both are
in unison in their first overtone. Determine end correction of closed pipe in cm.

4) A bat moving at 10 ms–1 towards a wall sends a sound signal of 8000 Hz towards it. On reflection
it hears a sound of frequency f. The value of f in Hz is close to (speed of sound = 320 ms–1)

5) A two slit Young’s interference experiment is done with monochromatic light of wavelength 6000
Å. The slits are 2 mm apart. The fringes are observed on a screen placed 10 cm away from the slits.
Now a transparent plate of thickness 0.5 mm is placed in front of one of the slits and it is found that
the interference pattern shifts by 5 mm. The refractive index of the transparent plate is x/y (x and y
are relatively prime number) then value of x + y:

PART 2 : CHEMISTRY

SECTION-I

1) Identify A and B in the chemical reaction.

(A)

(B)

(C)

(D)

2) The major product formed in the following reaction, is :

(A)

(B)

(C)

(D)

3) Which of the following alkene cannot be prepared by deamination of s-Bu-NH2 with NaNO2/HCl ?

(A) 1-butene
(B) cis-2-butene
(C) trans-2-butene
(D) Iso-butene
4)
Which among the following represent reagent 'A' ?

(A)

(B)

(C)

(D)

5) The numbers of chiral centers present in glucopyranose and fructofuranose are :

(A) 4 and 3
(B) 5 and 4
(C) 4 in each
(D) 5 in each

6) Which of the following biomolecules is insoluble water ?

(A) α-keratin
(B) Haemoglobin
(C) Ribonuclease
(D) Adenine

7) 2 moles of an ideal gas at 27ºC temperature is expanded reversibly from 2 lit to 20 lit. Find
entropy change in cal/mol K (R = 2 cal/mol K)

(A) 92.1
(B) 0
(C) 4
(D) 9.2
8) Identify the product 'Y' in the following reaction sequence

(A) Pentane
(B) Cyclobutane
(C) Cyclopentane
(D) Cyclopentanone

9)
Acid D formed in above reaction is :

(A) Gluconic acid

(B) Succinic acid
(C) Oxalic acid
(D) Malonic acid

10) In which of the following reaction aldol and cannizaro reactions are involved for final major
product :

(A)

(B)

(C)

(D)

11) The increasing order of the following compounds towards HCN addition is :
(A) (iii) < (iv) < (ii) < (i)
(B) (iii) < (iv) < (i) < (ii)
(C) (iii) < (i) < (iv) < (ii)
(D) (i) < (iii) < (iv) < (ii)

12) What is the colour develop when ethyl alcohol treated with base during victor meyer test :-

(A) Blood red colour

(B) Blue colour
(C) No colour
(D) Green colour

13) Noradrenaline is a /an

(A) Neurotransmitter
(B) Antidepressant
(C) Antihistamine
(D) Antacid

14)
Major product (A) is :-

(A)

(B)

(C)

(D)

15) Among the bromides I-III given below, the order of reactivity reaction is :-

(I) (II) (III)

(A) III > I > II
(B) III > II > I
(C) II > III > I
(D) II > I > III

16) The major product of the following reaction is :

(A)

(B)

(C)

(D)

17) End products of the following sequence of reaction is

(A)

(B)

(C)

(D)

18) Consider the reaction whose KC = 36,

if 0.1 mole each of SO2 and NO2 are placed initially in 1 litre container then; What is the
concentration of SO2 at equilibrium ?

(A) 0.003 M
(B) 0.015 M
(C) 0.085 M
(D) 0.097 M

19) The number of OH– ions in 1 L of solution having pH = 4 is :-

(A) 10–4
(B) 10–10
(C) 6.02 × 1010
(D) 6.02 × 1013

20) The value of enthalpy change (ΔH) for the reaction

C2H5OH(ℓ) + 3O2(g) → 2CO2(g) + 3H2O(ℓ)
at 27°C is –1366.5 kJ mol–1. The value of internal energy change for the above reaction at this
temperature will be :-

(A) –1371.5 kJ
(B) –1369.0 kJ
(C) –1364.0 kJ
(D) –1361.5 kJ

SECTION-II
1)

In lactose C1 of -D-galactose is combining with which carbon of -D-Glucose?

2) Standard enthalpy of vapourisation for CCl4 is 30.5 kJ mol–1. Heat required for vapourisation of
284g of CCl4 at constant temperature is ____kJ. (Nearest integer)
(Given molar mass in g mol–1 ; C = 12, Cl = 35.5)

3) For the reaction H2F2(g) → H2(g) + F2(g), ΔU = –59.6 kJ/mol at 27°C. The enthalpy change of the
above reaction is : (–)____ kJ/mol. (Nearest Integer)

4) What should be the pH for 0.1 M NH4Cl, if Kb = 10–5 ?

5) The vapour density of N2O4 at a certain temperature is 30. Calculate the percentage dissociation
of N2O4 at this temperature. N2O4 (g) ⇌ 2NO2 (g). (Nearest Integer)

PART 3 : MATHEMATICS

SECTION-I

1) Two circles are given as x2 + y2 + 14x – 6y + 40 = 0 and x2 + y2 – 2x + 6y + 7 = 0 with their

centres as C1 and C2 respectively. If equation of another circle whose centre C3 lies on the line 3x
+ 4y–16 = 0 and touches the circle (whose centre is C1) externally and also C1C2 + C2C3 + C3C1 is
minimum is x2 + y2 + ax + by + c = 0 then the value of (a + b + c) is

(A) 2
(B) 8
(C) 16
(D) 0

2) ABCD is a square of side length 2 units and the centre of square is at origin. C2 is a circle passing
through vertices A, B, C, D and C1 is the circle touching all the sides of square ABCD. Line L1 is
tangent at A line L2 is tangent at D on circle C2 which intersect at K, where A, B, C and D lie in 2nd,
1st, 4th, 3rd quadrant. Point Q is variable point on C2 let perpendicular drawn from Q to the lines L1
and L2 meet them at E and F respectively. Given that AB, BC, CD and AD are parallel to the
coordinate axes. The maximum area of quadrilateral QEKF is equal to λ and area of ΔBQC (where Q
is such that the area of quadrilateral QEKF is maximum) is μ then λ – 2μ is

(A) 3
(B) 4
(C) 5
(D) 6

3)
The locus of a point which moves so that the distance between the feet of perpendiculars drawn
from it to the lines 3x2 – 6xy + y2 = 0 is is a circle with radius

(A)
(B) 15
(C)
(D)

4) Let
and

. Then the minimum value of such that

is equal to

(A)

(B)

(C)

(D)

5) As shown in the diagram, the volume of tetrahedron DABC is , also and

, then

(A)
(B)
(C) BC = 2
(D) AC = 2

6) Let Q be the cube with the set of vertices . Let F be the set of
all twelve lines containing the diagonals of the six faces of the cube Q. Let S be the set of all four
lines containing the main diagonals of the cube Q; for instance, the line passing through the
vertices (0, 0, 0) and (1, 1, 1) is in S. For lines ℓ1 and ℓ2, let d(ℓ1, ℓ2) denote the shortest distance
between them. Then the maximum value of d(ℓ1, ℓ2), as ℓ1 varies over F and ℓ2 varies over S, is :
(A)

(B)

(C)

(D)

7) If a line makes angles, α, β, γ, δ with four diagonals of a cube, then the value of sin2α + sin2β +
sin2γ + sin2δ is :-

(A) 4/3
(B) 8/3
(C) 7/3
(D) 1

8) If x2 + y2 + z2 = 1, x, y, z ∈ R and maximum value of (2x – y)2 + (3y – 2z)2 + (z – 3x)2 is λ, then 4λ is

(A) 16
(B) 28
(C) 48
(D) 56

9) Let and be two vectors such that and

If , then the angle between and is equal to :

(A)

(B)

(C)

(D)

10) Consider the points and and another point D are coplanar
for all t ∈ R

(A) if D is ( ) then f(x) = 2 + c ln(2x), c ∈ R

(B) if D is ( ) then f(x) = c ln(2x), c ∈ R
(C) if D is ( ) then f(x) = 2 + ce2x, x ∈ R
(D) if D is ( ) then f(x) = 2 + c ln(2x), c ∈ R
11) If are not perpendicular to each other and , then =

(A)

(B)

(C)

(D)

12) Let S = {(x, y) ∈ × : x ≥ 0, y ≥ 0, y2 ≤ 4x, y2 ≤ 12 – 2x and 3y + x≤5 }. If the area

of the region S is , then α is equal to

(A)

(B)

(C)

(D)

13) Let the functions f : R → R and g : R → R be defined by

f (x) = ex – 1 – e–|x–1| and g(x) =

Then the area of the region in the first quadrant bounded by the curves y = f(x), y = g(x) and x = 0 is

(A)

(B)

(C)

(D)

14) Let f : (0, ∞)→R be continuous function such that f(x) = 6 (ln x)2 – .

Let Δ be area of triangle formed by tangent at x = to curve y = f(x) + 1 and co-ordinate axes. Then

the value of is equal to _______. [where [.] represents G.I.F.]

(A) 3
(B) 4
(C) 6
(D) 9

15) Let the solution curve of the differential equation

pass through the origin. Then y(1) is equal to :

(A)

(B)

(C)

(D)

16) A function f(x) satisfying = nf(x), where x > 0, is

(A) f(x) = c ·

(B) f(x) = c ·

(C) f(x) = c ·
(D) f(x) = c · x(1 – n)

17) If = 6π, then is equal to

(A) 0
(B) e4 + e–4

(C)

(D) e4 – e–4

18) Suppose then value of is:

(A) 3
(B) 4
(C) 5
(D) 6

19) The integral is equal to : (where C is a constant of integration)

(A)

(B)

(C)

(D)

20) If , for a suitable chosen integer m and a function

A(x), where C is a constant of integration then (A(x))m equals

(A)

(B)

(C)

(D)

SECTION-II

1) If and , then

is equal to

2) If f(x) is a polynomial function such that f(x) + f'(x) + f''(x) + f'''(x) = x3 and and g(1)
= 1, then is (where [.] denotes greatest integer function and e is Napier's constant)

3) Let , such that

(where C is integration constant), then value

of is

4) Let f(x) is continuous function. If f(1) = 1 and then the value of

is equal to

5) Consider the curve given by set S as follows:

There is a unique equilateral triangle whose vertices belong to set S. If be the area of such

triangle then equals

 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B A A B A C B B A C C B D D C B C D A

SECTION-II

Q. 21 22 23 24 25
A. 1000 106 2 8516 11

PART 2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D D D A B A D C B B C A A A A A C B D C

SECTION-II

Q. 46 47 48 49 50
A. 4 56 57 5 53

PART 3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C D C A A B D C C A B A D A A A C B B

SECTION-II

Q. 71 72 73 74 75
A. 1 0 5 3 9
 SOLUTIONS

PART 1 : PHYSICS

1)

Explain Question: To find angle of rebound with surface.

Concept: Use of coefficient restitution.

Solution:

In y direction
v sin ϕ = e u sin45º ....(i)
In x direction
v cos ϕ = u cos 45° ....(ii)
eq. (i) ÷ eq. (ii)

tan ϕ = ; ϕ = 30°
Final Answer: (A)

2)

Explain Question: To find speed of block before collision

Concept: Conservation of linear momentum and Mechanical energy.

Solution:

After collision from momentum conservation vel = v/2

For Min. V velocity of combined mass is zero at natural length.

Apply energy conservation
ΔK + ΔVg + ΔUs = 0

Final Answer: (B)

 3)

Explain Question: To find location of centre of mass.

Concept: Use formula for calculation of CM in case of variable linear mass density.

Solution:

Xcm =

Final Answer: (A)

4)

Explain Question: To find total energy density.

Concept: Use to formula for average electric energy density.

Solution:

Uav = ∈0E2rms

Final Answer: (A)

5)

Explain Question: To find direction of and .

Concept: Direction of direction of propagation and and is always perpendicular.

Solution:

Final Answer: (B)

6)

Explain Question: To find constant number of radioactive nuclei.

Concept: Series disintegration of radioactive sample.

 Solution:

Given = X – lN

for N to be constant

= 0 = X – lN

Final Answer: (A)

7)

Explain Question: To find power of light source used.

Concept: Use of saturation current and stopping potential to calculate power of source.

Solution:

The energy of each incident photon

hv = KEmax + ϕ = 2 + 5 = 7eV
and saturation current

is = × e = 10–5 e P= = =7W

Final Answer: (C)

8)

Explain Question: To find threshold wavelength of metal plate.

Concept: Use of einstien's relation and work energy theorem

Solution:

KEmax = = (eE)d

0
⇒ λ =

Final Answer: (B)

9)

Explain Question: To find position of point at which normal force acts.

Concept: Concept of toppeling.

Solution:
 ....(1)

....(2)

x = 10 cm

Final Answer: (B)

10)

Explain Question: To find time in which man completes one revolution wrt. platform.

Concept: Conservation of angular momentum and relative angular velocity.

Solution:

Applying conservation of angular momentum

L i = LF
0 = Iω – mvr

200 × ω = 50 × 2 × 1 ⇒ ω =

ωplatform = , ωman =
ωrel = ωplatform + ωman = 1

Δθrel = 2π, t =

Final Answer: (A)

11)

Explain Question: To find angular velocity of disc after particles are attatched.

Concept: Conservation of angular momentum.

Solution:

J i = Jf
ωf =

Final Answer: (C)

12)

Explain Question: To find acceleration of body for inertial pulley.

Concept: Use of torque, force and constraint relation.

Solution:

For motion of block 2g – T=2a

For motion of pulley τ = TR = Iα
a = αR

∴T=

⇒ 2g – = 2a

⇒a=

⇒a= = = =2 ms–2

Final Answer: (C)

13)

Explain Question: To find moment of inertia of a rod using graph.

Concept: MOI of rod about and end is and about axis passing through mid point

is .

Solution:
 at

Final Answer: (B)

14)

Explain Question: To find MOI of remaining portion

Concept: Calculation of MOI of truncated bodies.

Solution:

Suppose M is mass and a is side of larger triangle, then and will be mass and side length
of smaller triangle.

So,

Final Answer: (D)

15)

Explain Question: To find radius of gyration.

Concept: mK2 = I where k is radius of gyration.

Solution:
dI = (dm)r2 = (σdA)r2

= = (σ0 2π)r2dr

m = σ0 2π (b-a)
Radius of gyration

Final Answer: (D)

16)

Explain Question: To find time period of SHM.

Concept: Parallel combination of springs.

Solution:

For A if spring const = K for B if spring const for each = 3K

TA = 2π Keq = 9K

so TB = 2π

Final Answer: (C)

17)

Explain Question: To find work done by person in process

Concept: Conservation of angular momentum and WET.

Solution:
Angular momentum conservation.

⇒
wg + wp = ΔKE

Now, ℓ << L
By, Binomial approximation

here, V0 = maximum velocity

=ω×A=

so,

Final Answer: (B)

18)

Explain Question: To find ratio of K.E. in SHM.

Concept: Conservation of mechanical energy.

Solution:

Maximum kinetic energy at lowest point B is given by

K = mgl (1 – cos θ)
where θ = angular amp.

K1 = mg (1 – cos θ)
K2 = mg(2ℓ) (1 – cos θ)
K2 = 2K1.

Final Answer: (C)

 19)

Explain Question: To find tension in rod.

Concept: SHM in case of torsional wire.

Solution:

Ω = ωθ0 = average velocity

T = mΩ2r1

Final Answer: (D)

20)

Explain Question: To find time period of simple. pendulum.

Concept: Calculation of geff when bob is kept in a liquid.

Solution:

For a simple pendulum T = 2π

situation 1 : when pendulum is in air → geff = g

situation 2 : when pendulum is in liquid

→ geff =

So,
Final Answer: (A)

21)

Explain Question: To find minimum common frequency

Concept: Normal modes of vibration in string fixed at both ends.

Solution:

ℓ1 : ℓ2 : ℓ3 = 6 : 3 : 2

so ℓ1 = 60 cm
ℓ2 = 30 cm
ℓ3 = 20 cm
60, 30, 20

= 10 cm

f= = 1000 Hz

Final Answer: (1000)

22)

Explain Question: To find freq. difference between fundamental and second harmonic in
open organ pipe.

Concept: Use of formula for natural frequencies of open organ pipe.

Solution:

Now
⇒ Δn = 106.06 Hz

Final Answer: (106)

23)

Explain Question: To find end correction of closed organ pipe.

Concept: Equate frequencies of open and closed pipe with end correction.
 Solution:

⇒
⇒ 120 + 6e = 124 + 4e
2e = 4
e = 2 cm

Final Answer: (2)

24)

Explain Question: To find frequency in case of doppler effect.

Concept: Calculation of frequency in case of reflection from of wall.

Solution:

0
f"=f = 8000 × = 8516

Final Answer: (8516)

25)

Explain Question: To find refractive index of transparent slab in case of YDSE.

Concept: Interference pattern shifts by (μ – 1)t on insertion of transparent slab in YDSE.

Solution:

= 5 × 10–3

(μ – 1) = =

μ=1+ = =
∴ A + B = 6 + 5 = 11

Final Answer: (11)

PART 2 : CHEMISTRY

26) Explain Question: Identify product A & B

Concept: Addition of alkene followed by Finkelstein reaction.
Solution:
⇒ Ist reaction marcovnikov's addition of HCl on double bond while 2nd reaction is halide
substitution by finkestein reaction.
Final Answer: (D)

27) Explain Question: Identify the product of given reaction.

Concept: Rection of alcohols with unsaturated ethers.
Solution:

Final Answer: (D)

28) Explain Question: Elimination product of S-BuNH2 with NaNO2/HCl

Concept: Elimination by diazonium mechanism
Solution:
Formation of iso butene (branched alkene) do not takes place by using S-BuNH2 (structure
chain)

Final Answer: (D)

29) Explain Question: Identify the orange red dye in the reaction.
Concept: Based on diazo coupling reaction.
Solution:

Final Answer: (A)

30) Explain Question: Calculate chiral center in cyclic structures of glucose & fructose.
Concept: Draw the glucopyranose & fructofuranose structures.
Solution:

from C1 to C5 carbon, total (5) carbon are chiral in Glucopyranose.

from C2 to C5 carbon, total (4) carbon are chiral in fructofuranose.

Final Answer: (B)

31) Explain Question: Find water insoluble Biomolecule.

Concept: Fibrous proteins are water insoluble.
Solution:
α-keratin is fibrous protein hence it is water insoluble.
Final Answer: (A)

32) Explain Question: Find entropy change in given process.

Concept: ΔS for reversible isothermal expansion =

Solution:
Entropy change at constant temperature

= 2.303nRlog = 2.303 × 2 × 2 log = 9.2 cal K–1mol–1

Final Answer: (D)

33) Explain Question: Find product 'Y'

Concept: Decarboxylation followed by Clemmensen reduction.
Solution:

Final Answer: (C)

34) Explain Question: Identify product A,B,C & D

Concept: Elimination followed by anti addition of Br2 then substitution by KCN and hydrolysis
of cyanide.
Solution:

Final Answer: (B)

35) Explain Question: Identify aldol & Cannizaro reactions.

Concept: Apply aldol & Cannizaro reaction methods.
Solution:

Final Answer: (B)

36) Explain Question: Identify Reactivity order of HCN addition with carbonyl compounds.
Concept: Check the electrophilicity of carbonyl group.
Solution:
Increasing order of reactivity towards HCN addition

Greater the electrophilicity on group greater the reactivity in nucleophilic addition.

(iii) < (i) < (iv) < (ii)

Final Answer: (C)

37) Explain Question: Identify colour when ethyl alcohol react with base.
Concept: Victor meyer test
Solution:
CH3CH2OH → blood red colour

because 1° alcohol
2° alcohol → blue colour
3° alcohol → colourless
in victor meyer test.
Final Answer: (A)

38) Explain Question: Which type of drug noradrenaline is

Concept: Noradrenaline is one of the neurotransmitter.
Solution:
Noradrenaline is one of the neurotransmitters that plays a role in mood changes. If the level of
noradrenaline is low for some reason then signal sending activity becomes low and person
suffers depression. In such situation antidepressant drugs are required.
Final Answer: (A)

39) Explain Question: Identify product A in the given reaction.

Concept: Allylic Halogenation by using NBS
Solution:

Final Answer: (A)

40) Explain Question: SN1 reactivity order for given compounds.

Concept: SN1 rate ∝ stability of carbocation.
Solution:
Reactivity for SN1 reaction α stability of carbocation.

Final Answer: (A)

41) Explain Question: Find product for the given reaction.

Concept: E2 Elimination is followed by free radical Polymerization.
Solution:
Final Answer: (A)

42) Explain Question: Identify product for the given Sequence of reaction.
Concept: Iodoform reaction is followed by acidification and heating
Solution:

Adipic acid CO2H–(CH2)4–CO2H 7 membered cyclic anhydride (Very unstable)

Final Answer: (C)

43) Explain Question: Calculate concentration of SO2 at equilibrium.

Concept: Write expression of KC and calculate the concentration.
Solution:
SO2(g) + NO2(g) SO3(g) + NO(g)
t = 0 0.1 mole 0.1 mole 0 0
t = teq (0.1 – x) (0.1 –x) x x

∴ [SO2] = 0.1 – 0.085 = 0.015 M

Final Answer: (B)

44) Explain Question: Calculate number of –OH ion in the solution

Concept: pH = –log H+ , pH + pOH = 14
pOH = –log [–OH]
Solution:
pOH = 10 ; [OH–] = 10–10 M
Number of OH– ion = 10–10 mole
–10 23
= 10 × 6.02 × 10
= 6.02 × 1013
Final Answer: (D)
45) Explain Question: Calculate enthalpy change for the given reaction.
Concept: ΔH = ΔU + ΔngRT
Solution:
ΔH = ΔU + ΔngRT (Δng = –1)

–1366.5 kJ/mole = ΔU
–1366.5 = ΔU – 2.5
– 1366.5 + 2.5 = ΔU
ΔU = –1364.0
Final Answer: (C)

46) Explain Question: Identify the glycosidic linkage of galactose & glucose in lactose
Concept: Draw the structure of 1 unit of lactose
Solution:

Final Answer: (4)

47) Explain Question: Calculate require heat for vapourisation of 284 g CCl4
Concept: ΔHvap = × number of moles
Solution:

Mass of CCl4 = 284 gm

Molar mass of CCl4 = 154 g/mol

Moles of CCl4 = = 1.844 mol

ΔHvapº for 1 mole = 30.5 kJ/mol
ΔHvapº for 1.844 mol = 30.5 × 1.844
= 56.242 kJ
Final Answer: (56)

48) Explain Question: Calculate enthalpy change in given reaction.

Concept: ΔH = ΔU + ΔngRT
Solution:
H2F2(g) → H2(g) + F2(g),
 ΔU = –59.6 kJ/mol at 27°C
ΔH = ΔU + ΔngRT

= –57.10 kJ/mol.
Final Answer: (57)

49) Explain Question: Calculate pH for given salt

Concept: pH = pKw –
Solution:

pH = 7 –

=7–
= 7 – 2.5 + 0.5 = 5.0
Final Answer: (5)

50) Explain Question: Calculate % α for the dissociation of N2O4

Concept:
Solution:
N2O4 ⇌ 2NO2

= 1 + (n – 1)α
n=2

=1+α

α=
%α = 53.33% ≈ 53%
Final Answer: (53)

PART 3 : MATHEMATICS

51) Explain Question : Two circle are given, we have to find equation of third circle whose
centre lie on given line and touch given circle.
Concept : Reflection of point.
Solution :
To minimize C1C2 + C2C3 +C3C1
C3 must lie on line segment joining C1C2.
But C3 lies on line 3x+ 4y–16 = 0
∴ C3 is point of Intersection of 3x+ 4y– 16 = 0 and Line C1M
where M is mirror Image of C2 in 3x + 4y –16 = 0
To find M(x, y)

x = 7, y = 5 ⇒ M (7, 5)
Equation of C1 M is x – 7y + 28 = 0
C3 = (0,4)
C3C1 = r + 3

x2 + (y– 4)2 = 8 ⇒ x2 + y2 – 8y +8 = 0 ⇒ a + b + c = 0
Final Answer : (D)

52) Explain Question : Two circles one of them inscribed in a square and another one
circumscribing the square. We have to find the maximum area quadrilateral and area of a
related triangle formed by tangents to one of the circles.
Concept : Director circle.
Solution :
Equation of circle C2 is x2 +y2 = 2
Equation of tangent at A is –x +y =2
equation of tangent at D is –x–y = 2
For maximum area of the rectangle QEKF, Q is

Area of rectangle
Area of ΔBQC =
Final Answer : (C)

53) Explain Question : Question based on pair of straight lines passing through origin.
Concept : Angle between pair of straight lines.
Solution :
Let θ is the angle between pair of straight line 3x2 – 6xy + y2 = 0
i.e. θ is the angle between OA and OB line
⇒ ...(1)

∴ OP is diameter
AD = BD = r sinθ
AB = 2r sinθ =

Locus of P(h, k) is x2 + y2 = 45
r=
Final Answer : (D)

54)

Explain Question : Three set are given. We have to find minimum value of |r|.
Concept : Direct and transverse common tangent.
Solution :

; C2 : (0,2)

S3 : x2 + y2 – 4x –2y + 5 – r2 = 0

C3 : (2,1)
Final Answer : (C)

55) Explain Question : Volume of tetrahedron is given and ∠ACB is given.

Concept : Volume of tetrahedron and AM ≥ GM

Solution :

So,

Equality holds if and only if

So AD is perpendicular to the face

Final Answer : (A)

56) Explain Question : Cube is given and set contains various diagonals are given. We have
to find maximum value of d(ℓ1, ℓ2)
Concept : Shortest distance between two lines.
Solution :

DR'S of OG = 1, 1, 1
DR'S of AF = –1, 1, 1
DR'S of CE = 1, 1, –1
DR'S of BD = 1, –1, 1

Equation of OG ⇒
Equation of AB ⇒
Normal to both the line's

S.D. =
Final Answer : (A)

57) Explain Question : A line make angles α, β, γ, δ with four diagonal of cubes. We have to
find the value of given expression.
Concept : a.b = (a)(b)cosθ
Solution :

Let the given line be :

Also, diagonal vectors of cube are : i + j + k, i – j + k, i + j – k, –i + j + k

∴ ; ;

;
∴ sin α + sin β + sin γ + sin δ = 4 – (cos2α + cos2β + cos2γ + cos2δ)
2 2 2 2

Final Answer : (B)

58) Explain Question : x2 + y2 + z2 = 1 is given we have to find maximum value of (2x – y)2 +
(3y – 2z)2 + (z – 3x)2
Concept : |a × b|2 ≤ |a|2|b|2
Solution :
Let
maximum value is 14
Final Answer : (D)

59) Explain Question : and are given such that , we have to find
angle between b and c
Concept : Scalar triple product
Solution :

Given

Dot product with on both sides

…..(1)
Dot product with on both sides
…..(2)

Final Answer : (C)

60) Explain Question : Three point A, B, C are given. We have to find point D such that it
is coplanar.
Concept : Condition for coplanarity
Solution :

If D is then
If D is then

Now, I.F. = e–2x

Final Answer : (C)

61) Explain Question : is given

Concept : Solving vector equation
Solution :
Therefore, vector and are collinear
.... (1)
Now taking dot product with vector

put in equation 1

Final Answer : (A)

62)

Explain Question : We have to find area bound in the first quadrant by x-axis, y-axis two
parabolas and a straight line
Concept : Area bound by two or more curves.
Solution :

Point of intersection of all curves is

Area = A1+ A2
Final Answer : (B)

63) Explain Question : Two curves f(x) & g(x) are given. We have to find area bounded in
first quadrant

Concept : Area =
Solution :

Here &

solve f(x) & g(x) ⇒ x =

So bounded area =

=
Final Answer : (A)

64) Explain Question : Function f(x) is given. We have to find area bounded between
coordinate axis and tangent to curve y = f(x) + 1
Concept : Get slope of tangent and equation of tangent

Solution : f(x) = 6 (ln x)2 –

f(x) = 6 (ln x)2 – α ...(1) ​ ​

Now, α =
=

=
= 2 ⋅ (13 – 03) – α(1 – 0)
=2–α
⇒α=1
So, f(x) = 6 (ln x)2 – 1
Let y = g(x) = f(x) + 1 = 6 (ln x)2

g'(x) = 6 ⋅ 2 ⋅ (ln x) ⋅ = 12 ⋅

= 12e ⋅ (–1) = –12e

= = 6 ⋅ (–ln e)2 = 6

T : y – 6 = –12e
T : y – 6 = –12ex + 12
y + 12ex = 18
x = 0 ⇒ y = 18

y=0⇒x=

Δ= =

Final Answer : (D)

65) Explain Question : We have to solve given differential equation.

Concept : Linear differential equation
Solution :

Solution of differential equation

Also it passes through origin
c=0

Final Answer : (A)

66) Explain Question : We have to solve given equation

Concept : Newton Leibnitz formula

Solution :
Put tx = v upper limit
xdt = 1⋅dv t=1⇒v=x

lower limit
t=0⇒v=0

Diff. both side

f(x) = n[xf' (x) + f(x)]
⇒ (1 – n) f(x) = nxf' (x)

⇒
Integration both side

⇒
⇒
Final Answer : (A)
67) Explain Question : We have to solve given integration.
Concept : Property of definite integration
Solution :

= 6π ⇒ x1 = x2 = x3 = x4 = 1 & y1 = y2 = y3 = y4 = –1

hence (as f(x) is an odd function)

Final Answer : (A)

68) Explain Question : We have to solve given integration

Concept : Integration by parts.

Solution : I =

= ...(1)

I1 =

as cosec x = & sec x =

So, I1 =
Using integration by parts,

I1 = cosec7x

= cosec7x · tan x – (–cosec x cot x) tan x dx

7
= cosec x tan x + 7

as tan x =

I1 =

I1 – 7 ...(2)
From eq. (1)

I = I1 – ...(3)
On comparing eq. (2) & eq. (3)

I=
Hence g(x) = tan (x) ...(4)
2
g'(x) = sec x
g'(0) = 1
g '' (x) = 2 sec x sec x tan x
= 2 sec2x tan x
g '' = 4

Hence g '(0) + g '' =1+4=5

Final Answer : (C)

69) Explain Question : We have to solve given integration

Concept : Integration by substitution

Solution :

Let =t

⇒
Final Answer : (B)

70) Explain Question : We have to solve given integration.

Concept : Integration by substitution.
Solution :

Put
Case-1 x ≥ 0

A(x) = – and m = 3

Case–II x ≤ 0

We get
Final Answer : (B)

71) Explain Question : I1 and I2 is given. We have to find the value of given expression
Concept : Integration by parts
Solution : Let 1 – x3 = t

(Using integration by parts)

So,
Final Answer : (1)

72) Explain Question : Function f(x) and g(x) is given. We have to find value of
Concept : Integration by substitution
Solution :

= x – ℓn|f(x) + f′(x) + f′′(x) + f′′′(x)| + c

= x – 3ℓn|x| + c
Now, g(1) = 1 ⇒ c = 0
∴ g(e) = e – 3 ⇒ |g(e)| = 3 – e
[|g(e)|] = 0
Final Answer : (0)

73) Explain Question : I(m,n) is given we have to find value of A, B in given expression
Concept : Integration by parts

Solution :
Final Answer : (5)

74) Explain Question : Function f(x) is given which satisfy given condition. We have to find

Concept : Newton Leibniz formula

Solution : Put 2x – t = y
–dt = dy

⇒ =

⇒ =
Differentiating both sides

⇒
Put x=1

⇒
Final Answer : (3)

75) Explain Question : Vertices of equilateral triangle lie on the given curve. We have to find
area of equilateral triangle.
Concept : Sum of squares.

Solution :
Final Answer : (9)