14-09-2025

9610WJA801491250017 JA

PART 1 : PHYSICS

SECTION-I

1) A metal ball falls from a height of 32 meter on a steel plate. If the coefficient of restitution is 0.5,
to what height will the ball rise after second bounce?

(A) 2 m
(B) 4 m
(C) 8 m
(D) 16 m

2) A bullet of '4g' mass is fired from a gun of mass 4 kg. If the bullet moves with the muzzle speed of
50 ms–1, the impulse imparted to the gun and velocity of recoil of gun are :

(A) 0.4 kg ms–1, 0.1 ms–1

(B) 0.2 kg ms–1, 0.05 ms–1
(C) 0.2 kg ms–1, 0.1 ms–1
(D) 0.4 kg ms–1, 0.05 ms–1

3) Three objects A, B and C are kept in a straight line on a frictionless horizontal surface. The
masses of A, B and C are m, 2 m and 2 m respectively. A moves towards B with a speed of 9 m/s and
makes an elastic collision with it. There after B makes a completely inelastic collision with C. All

motions occur along same straight line. The final speed of C is :

(A) 6 m/s
(B) 9 m/s
(C) 4 m/s
(D) 3 m/s

4) Figures (a), (b), (c) and (d) show variation of force with time.
The impulse is highest in figure.

(A) Fig (c)

(B) Fig (b)
(C) Fig (a)
(D) Fig (d)

5) As per the given figure, a small ball P slides down the quadrant of a circle and hits the other ball
Q of equal mass which is initially at rest. Neglecting the effect of friction and assume the collision to
be elastic, the velocity of ball Q after collision will be: (g = 10 m/s2)

(A) 0
(B) 0.25 m/s
(C) 2 m/s
(D) 4 m/s

6) Four rods of equal lengths AB, BC, CD and DA have mass m, 2m, 3m and 5m respectively are
placed in x-y plane (see figure) given AB = BC = CD = DA = 4 meters. The centre of mass of the

system is satisfy (x and y are in meters)

(A) x > 4, y > 4

(B) x < 4, y < 4
(C) x = 0, y > 2
(D) x > 2, y = 0
7) Two particles are projected at the same instant with speeds v1 and v2 making angles a and b with
the horizontal as shown in the figure.
Neglecting air resistance, the trajectory of the mass center the two particles

(A) can be a vertical straight line

(B) can be a horizontal straight line
(C) is a straight line
(D) is a parabola

8) A ball of mass m moving vertically down, collides with inclined surface of the wedge. After the
collision wedge starts moving in horizontal direction with velocity V0. If all the surfaces are smooth

then impulse provided by wedge to ball is given by :-

(A) MV0 sin θ

(B) MV0 cos θ

(C)

(D)

9)

A particle of mass m = 1 kg moves in a circle of radius R = 2m with uniform speed v = 3π m/s. The
magnitude of impulse given by centripetal force to the particle in one second is :-

(A)
(B)
(C)
(D)

10) A bullet of mass m and velocity v passes through a pendulum bob of mass M and emerges with
velocity v/2 (figure). The pendulum bob is at the end of a string of length l. What is the minimum
value of v (in m/s) such that the pendulum bob will swing through a complete circle?
(Take : l = 2m, M = 1kg, m = 10 gm.)

(A) 2000
(B) 1000
(C) 500
(D) 4000

11) A ball of mass m collides another identical ball at rest obliquely as in figure. If velocity of 2nd ball
after the collision is 6m/s, then the value of coefficient of restitution is :

(A) 1

(B)

(C)

(D)

12) For the given situation find out the distance travelled by the boat when both 'A' and 'B' meets in
the middle of Boat ?
[Given → mA = 100kg, mB = 50kg, mBoat = 20kg]

(A)

(B) 25 m

(C)

(D) zero

13) Two men ‘A’ and ‘B’ are standing on a plank. ‘B’ is at the middle of the plank and ‘A’ is at the left
end of the plank. Bottom surface of the plank is smooth. System is initially at rest and masses are as
shown in figure. ‘A’ and ‘B’ start moving such that the position of ‘B’ remains fixed with respect to
ground and ‘A’ meets ‘B’. Then the point where A meets B is located at :

(A) the middle of the plank

(B) 30 cm from the left end of the plank
(C) the right end of the plank
(D) None of these

14) Maximum acceleration of block A after its collision with block B has magnitude (assume the

collision to be elastic and spring is initially relaxed) :-

(A)

(B)

(C)

(D)

15)

Find moment of inertia I of the system (Axis is perpendicular to the the plane passing through O) :

(A)

(B) 5mℓ2

(C)

(D)
16) Moment of inertia of solid sphere of mass m and radius R about axis passing through center of
mass is I as shown in figure–1. The sphere is moulded in the form of disc of radius 'r' and thickness
't'. The moment of inertia of disc about the axis shown in figure 2 is I. The radius of disc is :-

(A)

(B)

(C)

(D)

17) Two uniform semicircular discs, each of radius R are stuck together to form a disc. Masses of the
two semicircular parts are M and 3M. The moment of inertia of the circular disc about an axis
perpendicular to its plane and passing through the centre of the formed disc. (Point 'O' in figure)

(A) 2MR2

(B)

(C)

(D)

18) A body of mass 1 kg starts from the origin with an initial velocity . If a

constant force acts on the body, the time in which the x component of the velocity
becomes zero, is :-

(A) 5s
(B) 20s
(C) 40s
(D) 80s

19) A coin is released inside a lift at a height of 2 m from the floor of the lift. The height of the lift is
10 m. The lift is moving with an acceleration of 9 m/s2 downwards. The time after which the coin will
strike with the floor of lift is : (g = 10 m/s2)

(A) 4 s
(B) 2 s

(C)
s

(D)
s

20) Two small solid cylinders A and B each of mass 1 kg are connected by a thin spring of constant
200 N/m at their axes and are placed on a fixed smooth wedge as shown in figure. There is no
friction between cylinders and wedge. The angle made by the spring AB with the horizontal, in

equilibrium is

(A) 0o
(B) 15o
(C) 30o
(D) None of these

SECTION-II

1) Consider a semi circular ring of mass M and radius R. Moment of inertia about axis passing

through point C and perpendicular to plane of ring is . Then fill value of (a + b).

2) A uniform disc is cut along its diameter and shifted towards right as shown in figure-(b). Moment
of inertia of discs about an axis passing through centre O and perpendicular to the plane is I2, in

figure-(b) and I1 in figure-(a). If , find α.

3) Block A & B are released from rest at t = 0, then power of tension force for block A at t = 2 sec is

given by mg2 then value of x will be :

4)

Power delivered by net force to a particle of mass 1kg moving along x-axis is given by

p=

where x is the x coordinate of particle in meter. If particle starts from rest from origin, then find
velocity of the particle (in m/s) when it reaches at x = 3m.

5) Power supplied to a particle of mass 2kg varies with time as P = 2t watt, t is in second. Velocity
of particle at t = 0 is 6 m/s. What is the velocity (in m/s) of particle at time t = s?

PART 2 : CHEMISTRY

SECTION-I

1) The IUPAC name of

(A) 2-Bromomethyl-3-oxohexanamide
(B) 1-Bromo-2-amino-3-oxohexane
(C) 1-Bromo-2-amino-n-propylketone
(D) 3-Bromo-2-propylpropanamide
2) The IUPAC name of the following compound is :

(A) 3-amino-4-hydroxymethyl-5-nitrobenzaldehyde
(B) 2-nitro-4-hydroxymethyl-5-aminobenzaldehyde
(C) 4-amino-2-formyl-5-hydroxymethylnitrobenzene
(D) 5-amino-4-hydroxymethyl-2-nitrobenzaldehyde

3)

Which of the following is the strongest - I group :

(A)

(B) –

(C)
(D) –F

4) Which of the following has a geometry different from the other three species (having the same
geometry) ?

–
(A) BF4
2–
(B) SO4
(C) XeF4
+
(D) PH4

5) In which of the following arrangements the order is NOT according to the property indicated
against it?

(A) Al3+ < Mg2+ < Na+ < F– - increasing ionic size
(B) B < C < N < O - increasing first ionization energy
(C) I < Br < F < Cl - increasing electron affinity
(D) Li < Na < K < Rb - increasing metallic radius

6) If the bond energies of H–H, Br–Br and H–Br are 433, 192 and 364 kJ mol–1 respectively for
the reaction

(A) – 261 kJ
(B) + 103 kJ
(C) + 261 kJ
(D) – 103 kJ

7) Calculate the heat of combustion (kJ) of propane, C3H8 using the listed standard enthalpy of
reaction data :
C3H8(g) + 5 O2(g) → 3 CO2(g) + 4 H2O(g)
3 C(s) + 4 H2(g) → C3H8(g) ΔfHo/kJ = – 103.8
C(s) + O2(g) → CO2(g) ΔfHo/kJ = – 393.5
H2(g) + 1/2 O2(g) → H2O(g) ΔfHo/kJ = – 241.8

(A) – 2043.9
(B) – 1532.9
(C) – 1021.9
(D) – 739.1

8) Standard Gibb’s free energy change (ΔG°) for a reaction is zero. The value of the equilibrium
constant will be:

(A) 10
(B) 1
(C) 100
(D) ∞

9) A 0.5 dm3 flask contains gas A and 1 dm3 flask contains gas B at the same temperature. If density
of A = 3 g/dm3 and that of B = 1.5 g/dm3 and the molar mass of A = 1/2 of B, the ratio of pressure
exerted by gases is:

(A)

(B)

(C)

(D)

10) Calculate the mass of anhydrous oxalic acid (H2C2O4), which can be oxidised to CO2 (g) by 100 ml
of an MnO4¯ solution, 10 ml of which is capable of oxidising 50 ml of 1N I– to I2 in acidic medium

(A) 45 gm
(B) 22.5 gm
(C) 30 gm
(D) 12.25 gm

11) A solution of Na2S2O3 is standardized iodometrically against 0.1262 g of KBrO3 where BrO3–
changes to Br–. This process requires 45 mL of the Na2S2O3 solution. What is the normality of the
Na2S2O3? [Mw. of KBrO3 = 167]
(A) 0.2
(B) 0.1
(C) 0.05
(D) 0.01

12) For the reaction: 7A + 13B + 15C 17P

If 15 moles of A, 26 moles of B & 30.5 moles of C are taken initially then limiting reactant is

(A) A
(B) B
(C) C
(D) None of these

13) If 0.5 moles of BaCl2 is mixed with 0.2 moles of Na3PO4, the maximum amount of Ba3(PO4)2 that
can be formed is

(A) 0.7 mol

(B) 0.5 mol
(C) 0.2 mol
(D) 0.1 mol

14) What is the shortest wavelength line in the paschen series of Li2+ ion ? Where R is Rydberg
constant.

(A)

(B)

(C)

(D)

15) Which of the following order is correct for the property as directed?

+ –
(A) Li < Li < Li : order of Zeff
(B) Sc < Y < La : order of size
(C) Zn < Cd < Hg : order of ionisation energy
(D) V < Cr < Mn : order of magnetic moment

16) The sum of total number of P–O–P bonds and P = O bonds in penta poly phosphoric acid is :-

(A) 8
(B) 9
(C) 10
(D) 7
17) In which of the following compound resonance is not present.

(A)

(B)

(C) H2B–CH = CH2

(D)

18) Which one of the following species is diamagnetic in nature ?

–
(A) O2
+
(B) O2
(C) O2
2–
(D) O2

19)

Assume that the decomposition of HNO3 is

and the reaction approaches equilibrium at 400K & 30 atm pressure. At equilibrium the partial
pressure of HNO3 is 2atm. Find KC at 400 K
(R = 0.08 ℓ – atm/K–mol)

(A) 4
(B) 8
(C) 16
(D) 32

20) The equilibrium constant Kc at 298 K for the reaction A + B ⇌ C + D is 100. Starting with an
equimolar solution with concentrations of A, B, C and D all equal to 1M, the equilibrium
concentration of D is_____ × 10–2 M. (Nearest integer)

(A) 150
(B) 168
(C) 182
(D) 210
 SECTION-II

1) Find the number of molecules which are planar and having non-zero dipole moment :
SF4 , PCl3F2 , PCl2F3 , BrF3 , XeF4 , XeO3 , CO, O3

2) The entropies of H2(g) and H(g) are 60 and 50 J mole–1 K–1 respectively at 300 K. Using the data
given below calculate the bond enthalpy of H2 (g) in Kcal mole–1.
H2 (g) → 2H (g) ; ΔGº = 21.6 kJ mole–1

3) 'x' g of molecular oxygen (O2) is mixed with 200 g of neon (Ne). The total pressure of the non-
reactive mixture of O2 and Ne in the cylinder is 25 bar. The partial pressure of Ne is 20 bar at the
same temperature and volume. The value of 'x' is_____.
[Given: Molar mass of O2 = 32 g mol–1.
Molar mass of Ne = 20 g mol–1]

4) 10 ml pure H2O (d = 1 g ml–1) is mixed with 5 ml pure CH3OH (d = 0.8 g ml–1) and if the final
solution have density = 1.1 g ml–1. Calculate molarity of CH3OH (nearest integer)

5) When BrO3– ions reacts with Br– in acidic medium, Br2 is liberated. The equivalent mass of Br2 in

this reaction is X × . Then find the value of X : (M = molecular weight of Br2 )

PART 3 : MATHEMATICS

SECTION-I

1) If , then :-

(A) x ∈ [–3, –2) ∪ [1, 3] ∪ (4, ∞)

(B) x ∈ [2, 3] ∪ (4, ∞)
(C) x ∈ (–3, –2) ∪ (1, 3) ∪ (4, ∞)
(D) x ∈ (–∞, –3] ∪ (–2, 1] ∪ [3, 4)

2) The value of

(A)
(B)
(C)
(D)
3) If roots of the equation ax2 + bx + c = 0 are α,β. Then is equal
to -

(A) a2
(B) c2

(C)

(D)

4) If α, β are the roots of cx2 + bx + a = 0, then the roots of equation

a(x + 1)2 + b(x + 1) + c = 0 are -

(A) α – 1, β – 1

(B)

(C) α + 1, β + 1

(D)

5) Let α and β be the roots of the quadratic equation x2 sin θ – x (sin θ cos θ + 1) + cos θ = 0 (0 < θ

< 45º), and α < β. Then is equal to :-

(A)

(B)

(C)

(D)

6) The product of all the solutions of the equation is -

(A) 10
(B) 105
(C) 10–5
(D) 1

7) If and log1/4β = –1 then is equal to -

(A)
(B) 5
(C) 25
(D) 625

8) Let A be the sum of the first 20 terms and B be the sum of the first 40 terms of the series

If B – 2A = 100I, then I is equal to :

(A) 232
(B) 248
(C) 464
(D) 496

9) If x, 2y and 3z are in A.P. where the distinct numbers x, y and z are in G.P. then the
common ratio of G.P. is

(A)

(B)

(C)

(D)

10) The sum of the following series

up to 15 terms, is :

(A) 7820
(B) 7830
(C) 7520
(D) 7510

11) If , where α, β, γ, δ are positive real numbers, then the minimum

value of α + β + γ + δ is:-

(A) 2
(B) 3
(C) 6
(D) 9

12) In the inequality below, the value of the angle is expressed in radian measure. Which of the
inequalities below is true ?

(A) sin 1 < sin 2 < sin3

(B) sin 3 < sin 2 < sin 1
(C) sin 2 < sin 1 < sin 3
(D) sin 3 < sin 1 < sin 2

13) Let , then is

(A) 1

(B)

(C) 2

(D)

14) If tanθ + sinθ = m and tanθ – sinθ = n, then value of (m2 – n2)2 is:

(A) 16 mn
(B) 3
(C) 2
(D) 0

15) The number of solution(s) of trigonometric equation 4cos2x + tan2x + cot2x + sec2x = 6 in [0, 2π]
is (are)

(A) 2
(B) 4
(C) 8
(D) 16

16) The number of ways in which the letters of the word ' LONDON' can be rearranged if the two 'O'
s are together but the two 'N's are seperated is

(A) 72
(B) 71
(C) 36
(D) 35

17) If all the words (with or without meaning) having five letters, formed using the letters of the
word SMALL and arranged as in a dictionary; then the position of the word SMALL is :

(A) 58th
(B) 52th
(C) 60th
(D) 46th

18) If the coefficient of in the expansion of is equal to the coefficient of in

the expansion of , where a and b are positive real numbers, then for each such
ordered pair (a, b) :

(A) a = b
(B) ab = 1
(C) a = 3b
(D) ab = 3

19) is equal to

(A)

(B)

(C) 0

(D)

20) When a = 2015 & b = 2016, the value of is :

(A) 0
(B) 1
(C) (2015)2
(D)

SECTION-II

1) Let P(x) = x2 + bx + c where b, c ∈ R. If P(P(1)) = 0, P(P(2)) = 0 and P(1) ≠ P(2) then the absolute
value of (b + c) is equal to

2) The expression then the value of k is ___

3) Numbers are grouped as {1, 1, 1}, {3, 32, ....., 35}, {6, 62,....., 67}, {10, 102, ....., 109}. If the sum of
the numbers in 10th bracket is A such that then is

4) Let P = , then the value of 24P is :

5) If number of all possible five digits numbers using 1,2,3,4,5 such that sum of digits is 21, is a two
digits number XY, then (X + Y) is equal to (Repetition is allowed)
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B D B C B A C D A B A C A D A A A B C

SECTION-II

Q. 21 22 23 24 25
A. 6 5 8 6 7

PART 2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A D A C B D A B C B B B D C B B A D D C

SECTION-II

Q. 46 47 48 49 50
A. 3 8 80 10 3

PART 3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B B C B A D D B C A C D C A B C A B B B

SECTION-II

Q. 71 72 73 74 75
A. 2 1 1 6 7
 SOLUTIONS

PART 1 : PHYSICS

1)

2) By momentum conservation

4 × 10–3 (50 – v) – 4v = 0

Impulse J = mv = 4 × .05 = 0.2 kgms–1

3) Collision between A and B

m × 9 = mv1 + 2m v2 (from momentum conservation)

⇒ v2 = 6 m/sec., v1 = –3 m/sec.
Collision between B and C

2m × 6 = 4mv (from momentum conservation)

v = 3 m/s

4)

Impulse = Area under F = t curve

(a)
(b) 0.5 × 2 = 1 N.s (maximum)

(c)

d) N.s

5)
The velocities will be interchanged after collision.
Speed of P just before collision

6) For centre of mass 0 < xcm < 4, 0 < ycm < 4

7) If then centre of mass will move in straight line.

8)
According to impulse momentum theorem,
I sin θ = MV0

∴ I=

9)

The angular displacement of the particle in t = 1 sec is

∴ The magnitude of impulse by centripetal force in t = 1 second is

= change in momentum = mv = .

10) mv = Mv1 + mv/2

⇒ v1 = =

v=

v= = = 2000 m/s
11)

By momentum conservation along line of impact,

⇒
m × 8 = m × v1 + m × 6
⇒ v1 = 2 m/s

12) 20x + 50(5+x) = 100(5–x)

2x + 25 + 5x = 50 – 10x

17x = 25 ⇒ x =

13) Taking the origin at the centre of the plank.

m1Δx1 + m2Δx2 + m3Δx3 = 0 ( ΔxCM = 0)

(Assuming the centres of the two men are exactly at the axis shown.)
60(0) + 40(60) + 40 (–x) = 0 , x is the displacement of the block.
⇒ x = 60 cm i.e. A & B meet at the right end of the plank.
14)
At maximum compression, a is maximum

F = k = ma

15) Question Explanation:

We need to find the moment of Inertia I of the system about an axis perpendicular to the plane
and passing through point O.

Concept:
This question is based on moment of Inertia, parallel axis theorem.

Solution:

where x2 = ℓ2 + ℓ2/4

Final Answer:
The correct option is (4)

16) Question Explanation:

The problem asks to find the radius of the disc when a solid sphere is molded into a disc and
the moment of inertia the same.

Concept:
This question is based on moment of inertia.

Solution:

Now, ⇒ r2t =

Now, ⇒

⇒ ⇒ t = 5R

Final Answer:
The correct option is (1)
17) Ans. (1)

(i) The MOI of a uniform semicircular disc about axis AOB shown in figure is and of

another disc =
So MOI of the composite disc about
AOB is

0
I =

18)
vx = ux + axt
0 = 30 – 6t ⇒ t = 5 sec

19) Relative acceleration of coin w.r.t. lift = 1 m/s2 ↓

t= =2s

20)
Fspring cos (60o − θ) = mg sin 60o
Fspring cos (30o + θ) = mg sin 60o
On solving θ = 30o

21)

Explanation Question: Considering a semicircular ring and we have to find its moment of
inertia

Concept: This question is based on rotational inertia

Solution:
ICOM + M

ICOM + M

IC = =
Final Answer: 6

22) In figure (a)

In figure (b)

23)

2mg – T = 2ma
T – mg = ma
mg = 3 ma

24)
 ∴
v = 6m/s

25)

⇒ v2 = 49 ⇒ v = 7

PART 2 : CHEMISTRY

26) Question Explanation:

To write the IUPAC name of the given compound.

Concept:
This question is based on nomenclature of poly functional group containing compound.

Solution:

2-Bromomethyl-3-oxohexanamide

27) Explanation Question: Write the IUPAC name of the given compound
Concept: This question is based on Nomenclature of aromatic compounds
Solution:

5-amino-4-hydroxymethyl-2-nitrobenzaldehyde

28)

Explanation Question: Asking about the strongest –I group

Concept: This question is based on inductive effect
Solution:
A-I group (negative inductive group) is an atom or group of atoms that pulls electron density
away from the carbon chain it is attached to. The strength of the –I effect depends on the
electronegativity and positive charge of the atom. More electronegative atoms exert a stronger
pull electrons.
for the given groups decreasing –I order is :

Among the given is the strongest –I group.

Final Answer
The correct option is (1)

29)

SO42– / PH4+/BF4– – Tetrahedral

XeF4 – Square planar

30) Option B is Wrong

B < C < O < N → Ist IE

31) Enthalpy of reaction

= Bond enthalpies of reactants – Bond enthalpies of products.
= [433 + 192] –2[364]
= 625 – 728
= –103 kJ

32) ΔrH = ΔCH(C3 H8, g)

= 3 × ΔfH(CO2) + 4 × ΔfH(H2O) – ΔfH(C3H8)
= 3 (– 393.5) + 4 (– 241.8) + 103.8
= – 2043.9 kJ

33) ΔG° = –2.303 RT log K When K = 1, ΔG° = 0

34)

dA = 2dB (given)
 35) Number of eq. of
= 0.05 equivelents.
'N' of is :

Number of eq. of

Eq. Wight of
∴ mass of

36)

Eq. of Na2S2O3 ⇒ Eq. of KBrO3

N × 45 =
N = 0.1

M=

37) 7A + 13B + 15C 17P

for L.R.

So, B is min. that is L.R.

38) 3BaCl2 + 2 Na3PO4 → Ba3(PO4)2↓ + 6NaCl

To react with 0.2 mol of Na3PO4, the moles of BaCl2 required would be

0.2 × = 0.3.
Since BaCl2 is 0.5 mol, we can conclude that Na3PO4 is the limiting reagent.

Moles of Ba3(PO4)2 formed is 0.2 × = 0.1 mol.

39)

For shortest wavelength, ΔE should be maximum.

40) Correct orders :
Li+ > Li > Li– : Order of Zeff
with increase in positive charge density value of Zeff also increases.
Cd < Zn < Hg : Order of IE
for d-block elements, order of IE is generally 5d > 3d > 4d due to lanthanoid contraction.
V < Mn < Cr : order of magnetic moment.
Element No. of unpaired electrons (n) Magnetic moment
V (3d3) 3
5
Mn (3d ) 5
5 1
Cr (3d 4s ) 6

41)

Question Explanation:

Question is asking to the sum of total number of P–O–P bonds and P = O bonds in penta poly
phosphoric acid.

Concept:

This question is based on 5 units of phosphoric acid structure.

Solution:

P–O–P → 4
P=O → 5
Total 9

42)

43) O22– is diamagnetic (MOT)

44)

45)

A + B ⇌ C + D : Keq = 100
1M 1M 1M 1M
First check direction of reversible reaction.

Since QC = ⇒ reaction will move in forward direction to attain equilibrium

state.
⇒ A + B ⇌ C + D : Keq = 100
to 1 1 1 1
teq. 1–x 1–x 1+x 1+x

Now : Keq = 100 =

(i)
⇒ 10 – 10x = 1+x
⇒ 11 x = 9

(ii)
⇒ –10 + 10x = 1 + x
⇒ –9x = –11

→ 'x' cannot be more than one, therefore not valid.

therefore equation concretion of (D) = 1 + x
= 1.8181 = 181.81 × 10–2
= 182 × 10–2

46)

47)

ΔGº = ΔHº – TΔSº

21.6 = ΔHH–H – 300

⇒ 21.6 = ΔHH–H –300 (2 × 50 – 60)
⇒ 21.6 = ΔHH–H –12 kJ
ΔHH–H = 33.6 kJ mole–1 = 8 kcal mole–1

48) Partial pressure of O2 = 25 – 20 = 5 bar

mass = 2.5 × 32 = 80g

49) = 0.8 × 5 = 4g
= 10 × 1 = 10g
Wsolution = 4 + 10 = 14g
dsolution = 1.1 gmL–1

50) 2BrO3– + 12H+ + 10Br– → 6Br2 + 6H2O

10 mole e– are required for formation of 6 moles of Br2.

∴ n-factor of Br2 =

eq. wt. =
PART 3 : MATHEMATICS

51)
Here is always positive and defined when x ≥ 2 ....(a)

So,

x ∈ [–3, –2) ∈ [1, 3] ∈ (4, ∞) ....(b)

from (a) and (b)
x ∈ [2, 3] ∪ (4, ∞)

52)
from (i), (ii), (iii)

53) ax2 + bx + c = 0
x(ax + b) = –c

ax + b =

54) Roots of the equation cx2 + bx + a = 0 are α,β

then roots of the equation ax2 + bx + c = 0

are
then roots of the equation

a(x + 1)2 + b(x + 1) + c = 0 are

55) D = (1+ sinθ cosθ)2–4sinθcosθ= (1–sinθ cosθ)2

⇒ roots are β = cosecθ and α = cosθ
56)
Taking log on both sides to base 10 :
(1 + log10x) (log10x) = 5 + log10x
log10x = t ⇒ t(1 + t) = 5 + t
⇒ t2 + t = 5 + t
or
⇒
Product = 10º = 1

57)

γ = logα8 = log1/48 =

Now

∴ =

58) = (2n terms)

= = [(2n terms)]

=
=
B – 2A = S40 – 2S20 = 20.412 – 2.10.212

=
= 20 · 20 · 62 = 100 α
α = 248

59) x,2y,3z.........AP
4y = x + 3z ............(1)
x, y, z are in GP
y2 = xz............(2)
On solving common ratio

60)

= 7820

61)

given
... (i)
A.M. G.M. {where α, β, γ, δ

(from equ. (i)

min. value of is 6

62) We have, sin1 – sin2

sin1 < sin 2

∴ sin 1 < sin 2
Similarly sin 1 – sin 3
= – cos 2 sin 1 > 0 .......(i)
⇒ sin 1 > sin 3 .......(ii)
From Eq. (i) and (ii), we get
sin 3 < sin 1 sin 2

63)

64) 2tanθ = m + n ⇒

2sinθ = m – n ⇒ sin θ =
⇒ mn = tan2θ – sin2θ
= sin2 θ.

⇒ mn =
⇒ (m2 – n2)2 = 16 mn

65)

∴ and tan2x = 1

66)
Number of ways =

67)

Number of words beginning with

(i) A is = 12
(ii) L is 4! = 24

(iii) M is = 12

(iv) SA is =3
(v) SL is 3! =3
(vi) SM (ALL) is = 1

68)

Coefficient of in

Coefficient of

Coefficient of in
Coefficient

69)

70)

When a = 2015 & b = 2016, the value of is 1.

71) p(x) = x2 + bx + c
p(p(1)) = p(p(2)) = 0
⇒ p(1) & p(2) are roots of x2 + bx + c = 0
–b = p(1) + p(2) ⇒ –b = 5 + 3b + 2c ...(1)
c = p(1)p(2) ⇒ (1 + b + c)(4 + 2b + c) = c ...(2)
from (1) & (2)

get ;

72)

Also,
 73)

Number of terms = 3, 5, 7, 9, 11, 13, 15, 17, 19, 21

21 terms in 10th bracket.
1, 3, 6, 10, 15, 21, 28, .....
Tr = ar2 + br + c
1=a+b+c ...(1)
3 = 4a + 2b + c ...(2)
6 = 9a + 3b + c ...(3)
(2) – (1) ⇒ 2 = 3a + b
(3) – (2) ⇒ 3 = 5a + b

,c=0

A = Sum = 551 + ..... + 5521

74)

75) 55551 ⇒ numbers

55533 ⇒ numbers

55542 ⇒ numbers

55443 ⇒ numbers

54444 ⇒ numbers
Total = 70 numbers