25-02-2025

1201CJA1010212400114 JM

PART-1 : PHYSICS

SECTION-I

1)

Identify the pair of physical quantities that have same dimensions :

(A) velocity gradient and decay constant

(B) wien's constant and Stefan constant
(C) angular frequency and angular momentum
(D) wave number and Avogadro number

2) Assertion (A): Time period of oscillation of a liquid drop depends on surface tension(S), if density

of the liquid is and radius of the drop is r, then is dimensionally correct, where K
is dimensionless.
Reason (R): Using dimensional analysis we get R.H.S having different dimension than that of time
period. In the light of above statements, choose the correct answer from the options given below.

(A) Both (A) and (R) are true and (R) is the correct explanation of (A)
(B) Both (A) and (R) are true but (R) is not the correct explanation of (A)
(C) (A) is true but (R) is false
(D) (A) is false but (R) is true

3) Two balls A and B are placed at the top of 180 m tall tower. Ball A is released from the top at t = 0
s. Ball B is thrown vertically down with an initial velocity 'u' at t = 2 s. After a certain time, both
balls meet 100 m above the ground. Find the value of 'u' in ms–1 [use g = 10 ms–2] :

(A) 10
(B) 15
(C) 20
(D) 30

4) An object is thrown vertically upwards .At its maximum height ,which of the following quantity
becomes zero?

(A) Momentum
(B) Potential energy
(C) Acceleration
(D) Force
5) A person moved from A to B on a circular path as shown in figure. If the distance travelled by him
is 60 m, then the magnitude of displacement would be : (Given cos135° = –0.7)

(A) 42m
(B) 47m
(C) 19m
(D) 40m

6) Motion of a particle in x-y plane is described by a set of

following equations and y = 4 sin(ωt)m. The path of the particle will be :

(A) circular
(B) helical
(C) parabolic
(D) elliptical

7) A block of mass 2 kg moving on a horizontal surface with speed of 4 ms–1 enters a rough surface
ranging from x = 0.5 m to x = 1.5 m. The retarding force in this range of rough surface is related to
distance by F = –kx where k = 12 Nm–1. The speed of the block as it just crosses the rough surface
will be :

(A) zero
(B) 1.5 ms–1
(C) 2.0 ms–1
(D) 2.5 ms–1

8) A long ladder weighing 10 kg leans on a frictionless wall. Its feet rest on the floor 3 m
away from the wall as shown in the figure. If Ff and Fw are the reaction forces of the floor and the
wall, then ratio of Fw/Ff will be : (Use g = 10 m/s–2)

(A)

(B)

(C)

(D)

9) A bullet is shot vertically downwards with an initial velocity of 100 m/s from a certain height.
Within 10 s, the bullet reaches the ground and instantaneously comes to rest due to the perfectly
inelastic collision. The velocity-time curve for total time t = 20 s will be : (Take g = 10 m/s2)

(A)

(B)

(C)
(D)

10) Sand is being dropped from a stationary dropper at a rate of 0.5 kgs–1 on a conveyor belt moving
with a velocity of 5 ms–1. The power needed to keep the belt moving with the same velocity will be :

(A) 1.25 W
(B) 2.5 W
(C) 6.25 W
(D) 12.5 W

11) The orbital angular momentum of a satellite is L, when it is revolving in a circular orbit at height
h from earth surface. If the distance of satellite from the earth centre is increased by eight times to
its initial value, then the new angular momentum will be

(A) 8 L
(B) 9 L
(C) 3 L
(D) 4 L

12) The distance between Sun and Earth is R. The duration of year if the distance between Sun and
Earth becomes 3 R will be :

(A)
(B) 3 years
(C) 9 years
(D)

13) Two satellites A and B having masses in the ratio 4 : 3 are revolving in circular orbits of radii 3r
and 4r respectively around the earth. The ratio of total mechanical energy of A to B is :

(A) 9 : 16
(B) 16 : 9
(C) 1 : 1
(D) 4 : 3

14) Young’s moduli of the material of wires A and B are in the ratio of 1:4, while its area of cross
sections are in the ratio of 1:3. If the same amount of load is applied to both the wires, the amount
of elongation produced in the wires A and B will be in the ratio of (Assume length of wires A and B
are same)

(A) 1:12
(B) 12:1
(C) 36:1
(D) 1:36

15) Statement (I) : Pressure in a reservoir of water is same at all points at the same level of water.
Statement (II) : The pressure applied to enclosed water is transmitted in all directions equally.
In the light of the above statements, choose the correct answer from the options given below:

(A) Statement I is false but Statement II is true

(B) Both Statement I and Statement II are true
(C) Statement I is true but Statement II is false
(D) Both Statement I and Statement II are false

16) An air bubble of volume 1 cm3 rises from the bottom of a lake 40 m deep to the surface at a
temperature of 12°C. The atmospheric pressure is 1 × 105 Pa, the density of water is 1000 kg /
m3 and g = 10 m / s2. There is no difference of the temperature of water at the depth of 40 m and on
the surface. The volume of air bubble when it reaches the surface will be

(A) 2 cm3
(B) 4 cm3
(C) 5 cm3
(D) 3 cm3

17) A cylinder of fixed capacity of 44.8 litres contains helium gas at standard temperature and
pressure. The amount of heat needed to raise the temperature of gas in the cylinder by 20.0oC will
be :
(Given gas constant R = 8.3 JK–1 – mol−1)

(A) 249 J
(B) 415 J
(C) 498 J
(D) 830 J

18) Following statements are given :

(1) The average kinetic energy of a gas molecule decreases when the temperature is reduced.
(2) The average kinetic energy of a gas molecule increases with increase in pressure at constant
temperature.
(3) The average kinetic energy of a gas molecule decreases with increases in volume.
(4) Pressure of a gas increases with increase in temperature at constant volume.
(5) The volume of gas decreases with increase in temperature at constant pressure.
Choose the correct answer from the options given below :

(A) (1) and (4) only

(B) (1), (2) and (4) only
(C) (2) and (4) only
(D) (1), (2) and (5) only
19) The variation of kinetic energy (KE) of a particle executing simple harmonic motion with the
displacement (x) starting from mean
position to extreme position (A) is given by

(A)

(B)

(C)

(D)

20) A steel wire with mass per unit length 7.0 × 10–3 kg m–1 is under tension of 70 N. The speed
of transverse waves in the wire will be:

(A) 10 m/s
(B) 100 m/s
(C) 200π m/s
(D) 50 m/s

SECTION-II

1) A force on an object of mass 100g at origin is The position of that object at t = 2s is

after starting from rest. The value of will be ____

2) A solid cylinder length is suspended symmetrically through two massless strings, as shown in the
figure. The distance from the initial rest position, the cylinder should fall by unwinding the strings to
achieve a speed of 4 ms–1, is…….cm.

(Take g = 10 ms–2)

3) An ideal fluid of density 800 kgm–3, flows smoothly through a bent pipe (as shown in figure) that

tapers in cross-sectional area from a to . The pressure difference between the wide and narrow

sections of pipe is 4100 Pa. At wider section, the velocity of fluid is for x = ...............(Given

g = 10 ms–2)

4) A guitar string of length 90 cm vibrates with a fundamental frequency of 120 Hz. The length of
the string producing a fundamental
frequency of 180 Hz will be ………..cm.

5) In the circuit shown, the energy stored in the capacitor is n μJ. The value of n is

PART-2 : CHEMISTRY

SECTION-I

1)
Consider the above reaction, the limiting reagent of the reaction and number of moles of NH3 formed
respectively are:

(A) H2, 1.42 moles

(B) H2, 0.71 moles
(C) N2, 1.42 moles
(D) N2, 0.71 moles

2) The shortest wavelength of hydrogen atom in Lyman series is λ. The longest wavelength in
Balmer series of He+ is

(A)

(B)

(C)

(D)

3) The correct increasing order of the ionic radii is

(A)

(B)
(C)

(D)

4) Given below are the oxides:

Na2O,As2O3, N2O, NO and Cl2O7
Number of amphoteric oxides is:

(A) 0
(B) 1
(C) 2
(D) 3

5) Order of Covalent bond :

A) KF > KI; LiF > KF
B) KF < KI; LiF > KF
C) SnCl4 > SnCl2 ; CuCl > NaCl
D) LiF > KF; CuCl < NaCl
E) KF < KI; CuCl > NaCl
Choose the correct answer from the options given below :

(A) A, B only
(B) B, C only
(C) B, C, E only
(D) C, E only

6) The magnetic behavior of Li2O, Na2O2 and KO2, respectively, are.

(A) Paramagnetic, diamagnetic and paramagnetic
(B) Diamagnetic, diamagnetic and paramagnetic
(C) Diamagnetic, paramagnetic and diamagnetic
(D) Paramagnetic, paramagnetic and diamagnetic

7) Assertion (A) : The amphoteric nature of water is explained by using Lewis acid/base concept.
Reason (R) : Water acts as an acid with NH3 and as a base with H2S.
Choose the correct answer from the options given below :

(A) Both A and R are true and R is the correct explanation of A

(B) Both A and R are true but R is NOT the correct explanation of A.
(C) A is true but R is false.
(D) A is false but R is true.

8) 50mL of 0.2M KOH is added to 40mL, 0.5M HCOOH. The pH of the resultant solution (if Ka of
HCOOH is 10-4)

(A) 3
(B) 4
(C) 5
(D) 7

9) Match List I with List II

LIST I
LIST II
Type of
Example
Hydride
Electron
A) deficient I) MgH2
hydride
Electron rich
B) II) HF
hydride
Electron
C) precise III) B2H6
hydride
Saline
D) IV) CH4
hydride
Choose the correct answer from the options given below:
(A) A-II, B-III, C-I, D-IV
(B) A-III, B-II, C-I, D-IV
(C) A-III, B-II, C-IV, D-I
(D) A-II, B-III, C-IV, D-I

10) The entropy change when two moles of ideal monoatomic gas is heated from 200oC to 300oC
reversibly and isochorically?
(A)

(B)

(C)

(D)

11) The correct reaction profile diagram for a positive catalyst reaction.

(A)

(B)

(C)

(D)

12) In which of the following processes the bond order has increased and paramagnetic character
has changed to diamagnetic ?

(A)
(B)

(C)

(D)

13) Thin layer chromatography of a mixture shows the following observation:

The correct order of elution in the silica gel column chromatography is

(A) C, A, B
(B) B, A, C
(C) A, C, B
(D) B, C, A

14) The complex that dissolves in water is

(A) [Fe3(OH)2(OAc)6] CI
(B) Fe4[Fe(CN)6]3
(C) (NH4)3[As(Mo3O10)4]
(D) K3[Co(NO2)6]

15) Decreasing order of reactivity towards electrophile substitution for the following compounds is :

(A) d > a > e > c > b

(B) a > d > e > b > c
(C) e > d > a > b > c
(D) c > b > a > d > e

16) In the following given reaction, ‘A’ is

(A)

(B)

(C)

(D)

17)

Electrode potential data are given below.

Based on the data given above, reducing power of Fe2+, AL and Br– will increase in the order:

(A)
(B)
(C)
(D)

18) Benzyl isocyanide can be obtained by

(A)

(B)

(C)

(D)
Choose the correct answer from the options given below

(A) Only B
(B) A and C
(C) A and B
(D) A and D

19) Find out the major product form the following reaction

(A)

(B)

(C)
(D)

20) Major product P formed in the following reaction is :

(A)

(B)

(C)

(D)

SECTION-II

1) Values of work function (W0) for a few metals are given below

Metal Li Na K Mg Cu Ag
W0/ev 2.4 2 2.3 3.7 5 4
The number of metals which will show photoelectric effect when light of wavelength 400nm falls on
it is ____
Given :
h = 6. 6 × 10−34 J s
c = 3 × 108 ms–1
e = 1.6 × 10–19C

2) Amongst BeF2, BF3, H2O, NH3, CCl4 and HCl, the number of molecules with non-zero net dipole
moment is_____.

3) Amongst SF4, XeF4, CF4 and H2O, the number of species with two lone pairs of electrons on
central atom are _______ .

4) Which of the amino group in semi carbazide will react with Ph – CH = O carbonyl group :

5) Number of major organic products obtained on hydrolysis of

PART-3 : MATHEMATICS

SECTION-I

1) Let

If then T + n(S) is equal

(A)
(B) 9
(C)
(D) 10

2) The number of integral values of k, for which one root of the equation 2x2 – 8x + k = 0 lies in
the interval (1, 2) and its other root lies in the interval (2, 3), is:

(A) 2
(B) 3
(C) 0
(D) 1

3) Let Then ∑ |z|2 ; z ∈ S is equal to

(A) 5/2
(B) 4
(C) 3
(D) 7/2

4) The number of integers, greater than 7000 that can be formed, using the digits 3, 5, 6, 7, 8
without repetition, is
(A) 48
(B) 120
(C) 168
(D) 220

5) Among the statements:

(S1) : 20232022 – 19992022 is divisible by 8
(S2) : 13(13)n – 11n – 13 is divisible by 144 for infinitely many

(A) both (S1) and (S2) are incorrect

(B) only (S1) is correct
(C) both (S1) and (S2) are correct
(D) only (S2) is correct

6) Let a, b, c and d be positive real numbers such that a + b + c + d = 11. If the maximum value of
a5b3c2d is 3750 β, then the value of β is

(A) 55
(B) 90
(C) 110
(D) 108

7) Let a1, a2, a3,........be a G.P. of increasing positive numbers. Let the sum of its 6th and 8th terms be
2, the product of its 3rd and 5th terms be 1/9. Then 6(a2 + a4)(a4 + a6) a is equal to

(A)
(B) 2
(C)
(D) 3

8) The combined equation of the two lines ax + by + c = 0 and a'x + b'y + c' = 0 can be written
as (ax + by + c) (a'x + b'y + c') = 0.
The equation of the angle bisectors of the lines represented by the equation 2x2 + xy – 3y2 = 0 is

(A) 3x2 + 5xy + 2y2 = 0

(B) x2 – y2 – 10xy = 0
(C) 3x2 + xy – 2y2 = 0
(D) x2 – y2 + 10xy = 0

9) Let R be the point (3, 7) and let P, Q be two points on the line x + y – 5 = 0 such that PQR is an
equilateral triangle. Then the area of triangle PQR is :

(A)

(B)
(C)

(D)

10) If the tangents drawn at the points O(0, 0) and on the circle x2 + y2 – 2x – 4y =
0 intersect at the point Q, then the area of the triangle OPQ is

(A)

(B)

(C)

(D)

11) Let the tangent to the circle

C1 : x2 + y2 = 2 at the point M(–1, 1) intersect the circle
C2 : (x – 3)2 + (y – 2)2 = 5, at two distinct points A and B. If the tangents to C2 at the points A and
B intersect at N, then the area of the triangle ANB is equal to :

(A)

(B)

(C)

(D)

12) If the radius of the largest circle with centre (2,0) inscribed in the ellipse x2 + 4y2 = 36 is r, then
12r2 is equal to

(A) 69
(B) 115
(C) 72
(D) 92

13) The equations of the sides AB and

AC a triangle ABC are
(λ + 1)x + λy = 4 and
λx + (1 – λ)y + λ = 0
respectively. Its vertex A is on the y-axis and its orthocentre is (1, 2). The length of the tangent from
the point C to the part of the parabola y2 = 6x in the first quadrant is

(A) 2
(B)
(C)
(D) 4

14) is equal to

(A)
(B)

(C)

(D)

15) Let a be an integer such that exists, where [t] is greatest integer < t. Then a is
equal to :

(A) –6
(B) –2
(C) 2
(D) 6

16) The mean and standard deviation of 50 observations are 15 and 2 respectively. It was found that
one incorrect observation was taken such that the sum of correct and incorrect observations is 70. If
the correct mean is 16 , then the correct variance is equal to:

(A) 10
(B) 36
(C) 43
(D) 60

17) The mean and variance of the data 4, 5, 6, 6, 7, 8, x, y where x < y are 6, and respectively.
Then x4 + y2 is equal to

(A) 162
(B) 320
(C) 674
(D) 420

18) The maximum area of a rectangle that can be inscribed in a circle of radius 2 units is

(A)
(B)
(C)
(D)
19) If M is the matrix then M – M2 + M3 ……+ Mn+1 + …∞

= , Where is equal to

(A) 0
(B) 4
(C) 5
(D) 3

20) If f : R → R be a continuous function satisfying

then the value of α is

(A)
(B)
(C)
(D)

SECTION-II

1) For , consider the real valued function

and q > 0. Let a1, a2, a3 and a4 be in an arithmetic progression with mean p
and positive common difference.
If for all i = 1, 2, 3, 4 then the absolute difference between the roots of f(x) = 0 is

2) The sum of all the four digit numbers that can be formed using all the digits 2,1,2,3 is , find the
value of x.

3) If the constant term in the binomial expansion of is –84 and the coefficient of x–3l is 2αβ
where β < 0 is an odd number, then is equal to ______

4) Let {ak} and {bk}, k N be two G.P.s with common ratios r1 and r2 respectively such that a1 = b1 =

4 and r1 < r2. Let ck = ak + bk, k N. If c2 = 5 and c3 = then is equal to_____.

5) Let the equation of two diameters of a circle x2 + y2 – 2x + 2fy + 1 = 0 be 2px – y = 1 and 2x + py

= 4p. Then the slope of the tangent to the hyperbola 3x2 – y2 = 3 passing through the
centre of the circle is equal to _______.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A D D A B A C C A D C D B B B C C A C B

SECTION-II

Q. 21 22 23 24 25
A. 2 120 363 60 75

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B C B C B D B C C B A C A C A A C D B

SECTION-II

Q. 46 47 48 49 50
A. 3 3 2 3.00 3.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B D B C B B D B D C C D C D A C B D D C

SECTION-II

Q. 71 72 73 74 75
A. 50 6666 98 9 2
 SOLUTIONS

PART-1 : PHYSICS

PART-2 : CHEMISTRY

33) KOH + HCOO HCOOK + H2O

10mmol 20mmol __ __
0 10 10 __

=4

36) By using positive catalyst :

(i) ΔH does not change
(ii) Activation energy decreases

37) Bond order is NO is 2.5 (paramagnetic) while that of NO+ is 3 (diamagnetic).

The bond order has increased and paramangetic character has changed to diamangetic.
(B) O2 has bond order 2 whereas O2+ has bond 2.5 both are paramangnetic.
(C) N2 has bond order 3 whereas N2+ has 2.5 bond order is decreasing.
(D) C2 has bond order 2 whereas C2+ has 2.5, diamagnetic character changes to paramangetic.

42)

Reducing power refers to the ability of a species to donate electrons and reduce another
species. A higher oxidation potential indicates a stronger reducing agent.
The given reduction potentials are:

To find the reducing power, we need to convert the reduction potentials to oxidation
potentials. The oxidation potential is the negative of the reduction potential:

– For Al:

– For

The reducing power increases with the increase in oxidation potential. Therefore, the order of
reducing power from weakest to strongest is:
1. (oxidation potential : – 1.08 V)
2. (oxidation potential : – 0.77 V)
3. Al (oxidation potential : + 1.66 V)
The reducing power of will increase in the order:
PART-3 : MATHEMATICS

68)

69)

Let N = M - + …… ∞

⇒ N= =

=
∴ α = –9, β = –3