Reaction kinetics

,
1 I

① order of reaction ② pseudo -

zero order

N21-3HZ -72MHz larger on top

⑨
•

reaction ath
NIA )
:
coefficient in
At B > CTD

& Rate __
KFA ] "EB ] "[ c. It
"

fate of reaction Rate =

KEAJ "[ B) Y[ C) 2- A B
'

exp
•

Rate equation " " When it is easy to see

exp2nave I 1 I

/
math / inspection more than / reagan -1 changing
constant -14 2 1 10

{
VA VB Vc Vitro 2
I 10 10 10
Hwisto makeup -10-191 > overall order Of reaction is 2
-

'
volume -10 be the same -1 /
overall order of reaction
20 is
2 so to -

concentration y ,
so -1ha-1
" " " excess
is proportional to volume
3 -

Bis in large
↓
30
-

4 10 30
pseudo zero order
Graph method °
Rate : Its .VE B+c
ATB >

mate
>
A
NR9H KEAJ '
Rate
'

[B ]
-_
Rate
/ a
^ rate

fixed amount
'

unfair
' " exp [A ] EBI
" "" """
Rat" " '
of product / experiment 1) soy IU > overall order '
K is

)s%
,
^^ "=k[A ] .

reactant -10 2 0.5 9.5 -4=3005

[A ]
be formed ' > [A)
2

→ overall order
>
> [A ] W is /
[A ] 3 I
( same end
2nd order
th -150s
-

point )
-

ten order
-

gradient __ K
-

2nd order -

"
large excess
-
first order .

gradient -4k .

gradient
-_
K
who ofthereagantis
-

n'A) not ) NEAJ

.

relatively constant
-

rate is independent of
constant
concentration
☆
-

It acts as pseudo zero .

changing -10

first order
n[A ]
-4=1%2--1
> t "
> > to
t KEB ]

constant -4
Rate --K'[ A ]
you;ra
'
"
-3005 order
= K '= KX5B ]
EXPI
1505 exp }
> to