Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS-BT JEE-MAIN Date: 20-09-2025
Time: 09.00Am to 12.00Pm RPTM-11 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point
Pen only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on
the Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 75 Questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Mathematics, Physics and Chemistry
having 25 Questions in each subject and subject having two sections.
(I) Section –I contains 20 Multiple Choice Questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 05 Numerical Value Type Questions.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the Nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is
from 10.5 and less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted Question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any
electron device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________
$
Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
 SRI CHAITANYA IIT ACADEMY, INDIA 20-09-25_ Sr.Super60_ NUCLEUS-BT _Jee-Main_RPTM-11_Q.P
20-09-2025_Sr.Super60_NUCLEUS-BT_Jee-Main_RPTM-11_Test Syllabus
MATHEMATICS : Quadratic Equation and Logarithms
PHYSICS : Current Electricity: Electric current; Ohm’s law; Series and parallel arrangements of
resistances and cells; Kirchhoff’s laws and simple applications; Heating effect of current.
voltmeter, ammeter and their conversions. Experiments: Verification of Ohm’s law using
voltmeter and ammeter, and specific resistance of the material of a wire using meter bridge
and post office box, Resistance and figure of merit of a galvanometer by half deflection
method & RC Circuits with DC sources. Potentiometer-(i) Comparison of emf of two primary
cells. (ii) Determination of internal resistance of a cell. (Deleted for MAINS);
CHEMISTRY : s-Block Elements: General properties,diagonal similarities between Li ,Mg and Be,Al ;
anomalous properties of Li ,Be ; Alkali and alkaline earth metals-reactivity towards air, water,
dihydrogen, halogens, acids; their reducing nature including solutions in liquid ammonia; uses
of these elements; general characteristics of their oxides, hydroxides, halides, salts of
oxoacids; anomalous behaviour of lithium and beryllium; preparation, properties, and uses of
compounds of sodium (sodium carbonate, sodium chloride, sodium hydroxide, sodium
hydrogen carbonate) and calcium (calcium oxide, calcium hydroxide, calcium carbonate,
calcium sulphate).
Group-13: Oxidation state and trends in chemical reactivity of elements of groups 13;
anomalous properties of boron with respect to other elements in their respective
groups,Reactivity towards acids, alkalies, and halogens; preparation, properties and uses of
borax, orthoboric acid, diborane, boron trifluoride, aluminium chloride and alums; uses of
boron and aluminium
NOTE : sBlock Elements:DELETED FROM MAINS SYLLABUS
NOTE: Group-13 to Group18 Elements (ONLY THE FOLLOWING SUB TOPICS ARE IN JEE MAINS
SYLLABUS OF p-BLOCK ELEMENTS) General Introduction: Electronic configuration and general
trends in physical and chemical properties of elements across the periods and down the
groups; unique behaviour of the first element in each group

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MATHEMATICS Max Marks: 100
SECTION-I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. If  ,  are the roots of the equation x2  2 x  3  0 .Then the equation whose roots are
P   3  3 2  5  2 and Q   3   2    5 is
1) x2  3x  2  0 2) x2  3x  2  0
3) x2  3x  2  0 4) 2 x2  3x  1  0
2. Consider the equation x 2  2 x  n  0, where n  N and n 5,100. The total number of
different values of n so that the given equation has integral roots is
1) 8 2) 3 3) 6 4) 4
If  b 2  4ac  1  4a 2   64a 2 , a  0, then the maximum value of quadratic expression
2
3.
ax2  bx  c is always less than
1) 0 2) 2 3) -1 4) -2
 
4. Let      . suppose 1 and 1 are the roots of the equation x2  2 x sec  1  0
6 12
and  2 and  2 are the roots of the equation x2  2 x tan  1  0. If 1  1 and  2   2
then 1   2 equals
1) 2  sec  tan   2) 2sec 3) 2 tan 4) 0
If a  R and the equation 3 x   x   2  x   x  a 2  0 (where,  x denotes the
2
5.
greatest integer  x) has no integral solution, then all possible values of a lie in the
interval
1)  1,0   0,1 2) 1,2 3)  2, 1 4)    2    2,  
6. If three distinct numbers a, b, c are in G. P. and the equations ax2  2bx  c  0 and
dx2  2ex  f  0 have a common root, then which one of the following statements is
correct?
d e f
1) d, e, f are in A. P. 2) , , Are in G.P
a b c
d e f
3) , , are in A.P 4) d, e, f are in G.P
a b c
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The sum of all real values of x satisfying the equation  x 2  5 x  5 

x 2  4 x 60
7.  1 is
1) -4 2) 6 3) 5 4) 3
8. Let  ,  be the distinct roots of the equation x 2   t 2  5t  6  x  1  0, t  R and
a2023  a2025
an   n   n then the minimum value of is
a2024
1 1 1 1
1) 2)  3)  4)
4 2 4 2
9. Let   max 82sin 3 x.44 cos 3 x  and   min 82sin 3 x.4 4 cos 3 x . if 8x2  bx  c  0 is a
xR xR

1 1
quadratic equation whose roots are  5 and  5 , then the value of c – b is equal to
1) 43 2) 42 3) 50 4) 47
10. The sum of all the real roots of the equation  e 2 x  4  6e 2 x  5e x  1  0 is

1) log e 3 2)  log e 3 3) log e 6 4)  log e 6

11. Let a, b, c be in arithmetic progression. Let the centroid of the triangle with vertices
(a, c), (2, b) and (a, b) be  ,  . If  ,  are the roots of the equation ax2  bx  1  0 ,
10 7
 3 3
then the value      is
2 2

71 71 69 69
1)  2) 3)  4)
256 256 256 256
 5  
12. Let S   : log 2  92 4  13  log 2  .32 4  1  2. then the maximum value of  for
 2  
2
 
which the equation x  2     x     1   0 has both real roots, is
2 2

 S   S
1)20 2) 25 3) 15 4) 10
13. Let f : R  0   ,1 be a polynomial of degree 2, satisfying

1 1
f  x  f    f  x   f   . If f  K   2 K , then the sum of squares of all possible
x  x
values of K is:
1) 1 2) 6 3) 9 4) 7
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14. Match the following.
Column-I Column-II
A) The sum of all integral values of a for which one root of the P) 3
equation  a  5  x 2  2ax  a  4  0 is smaller than 1 and
the other is greater than 2 is
B) The number of solutions of the system of equations given Q) 8
 1 
below is x  y  1; x 2  y 2  a 2 ;   a  1
 2 
C)  x 2  x  2    a  3   x 2  x  1 x 2  x  2  R)  19 
2

If has at least  5, 
 3
  a  4   x  x  1  0
2 2

one real root, then the complete set of values of ‘a’ is.
D)  x 
2
S) 261
Number of real solutions of the equation x    
2
8
 x 1
1) A – S, B – Q, C – R, D – P 2) A – Q, B – R, C – S, D – P
3) A – Q, B – S, C – P, D – R 4) A – R, B – P, C –S, D – Q
15. Statement-1: If px 2  qx  r  0 is a quadratic equation  p, q, r  R  such that its roots
are  ,  and p  q  r  0, p  q  r  0 and r  0 then        1 where [.] denotes
greatest integer function.
Statement –2: If for any two real numbers a and b, continuous function f  x  is such
that f  a  f  b   0  f  x  has at least one root lying in  a, b 
1) Statement-1 is true, statement–2 is true;
2) Statement–1 is false, statement–2 is false.
3) Statement–1 is true, Statement–2 is false.
4) Statement–1 is false, statement–2 is true.
16. If the equation x 2  3 px  2q  0 and x2  3ax  2b  0 have a common roots and the
other roots of the second equation is the reciprocal of the other roots of the first, then

 2 q  2b 
2

1) 36 pa  q  b  2) 18 pa  q  b  3) 36bq  p  a  4) 18bq  p  a 
2 2 2 2

3cos 2 x  cos3 2 x
17. The sum of the solution x  R of the equation  x 3  x 2  6 is
cos x  sin x
6 6

1) 0 2) 3 3) -1 4) 1

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18. Some identical balls are arranged in rows to form an equilateral triangle. The first row
consists of one ball, the second row consists of two balls and so on. If 99 more identical
balls are added to the total number of balls used in forming the equilateral triangle, then
all these balls can be arranged in a square whose each side contains exactly 2 balls less
than the number of balls each side of the triangle contains. Then the number of balls used
to form the equilateral triangle is
1) 262 2) 190 3) 157 4) 225
 
19. Let  ,   N be roots of the equation x2  70 x    0 where ,  N . If  assumes
2 3

the minimum possible value, then

 
  1    1    35 
is equal to
 
1) 60 2) 30 3) 20 4) 50
20. The product of all positive real values of x satisfying the equation
16 log x 3 68log x 
  5  5 
x   516 is
1)0 2)2 3)1 4) 3
SECTION-II
(NUMERICAL VALUE TYPE
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal then round
off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. Let a, b  R and ab  1. If 6a 2  20a  15  0 and 15b2  20b  6  0 then the value of
4030b3
is____________
ab 2  9  ab  1
3

22. If there exists at least one real x which satisfies both the equations x 2  2 x sin y  1  0,
where y   0,  / 2  , and ax 2  x  1  0, (a  R) the value of a  sin y is  then 4 
23. If for a positive integer n, the quadratic equation
x  x  1   x  1 x  2   ........   x  (n  1)  x  n   10n has two consecutive integral
solutions, then n is equal to
24. Let f  x  be a quadratic polynomial with leading coefficient 1 such that f  0   p, p  0,
and f 1  1 / 3. if the equations f  x   0 and fofofof  x   0 have a common real root,
then f  3 is equal to______
The number of solutions of the equation log  x 1  2 x 2  7 x  5   log  2 x 5  x  1  4,
2
25.
x  0, is___________

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PHYSICS Max Marks: 100
SECTION-I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
26. What is the reading of ideal ammeter (in A) in the circuit shown in the adjacent figure?

6V
2W 2W 2W
A

6V
1)1 2) 2 3)3 4) 4
27. To get maximum current through a resistance of 2.5 W , one can use m rows of identical
cells, each row having n cells. The internal resistance of each cell is 0.5 W . What are the
values of n and m if the total number of cells is 45?
1) m  3, n  15 2) m  5, n  9 3) m  9, n  5 4) m  15, n  3
28. A battery of emf 1.4 V and internal resistance 2W is connected to a resistance of 100W
 4 
through an ammeter. The resistance of the ammeter is1.33W   W  . A voltmeter is
3  
connected across the 100W resistance. If the current through the battery is 0.02 A, What
is the resistance of voltmeter?

1) 200W 2) 300W 3) 400W 4) 600W

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29. In the given circuit, the potential difference across the 6 F capacitor in the steady state in
volt is
12V 1W

4V

1) 8 2) 1 3) 0 4) 2
30. If a steady current ‘I’ is flowing through a cylindrical element ABC. Whose radii are (2r,
r) choose the correct relationship
B
A
2r C
I r
l /2

l /2
1) V AB  2VBC
2) Power across BC is 4 times the power across AB
3) Current densities in AB and BC are equal
4) Electric field due to current inside AB and BC are equal
31. A heater is designed to operate with a power of 1000 W in a 100 V line. It is connected in
combination with a resistance of 10 W and a resistance R to a 100 V line as shown in
figure. What should be the value of R so that the heater operates with a power of 62.5 W?

1
1) 10 W 2) 62.5 W 3) W 4) 5 W
5
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32. Given below are two statements:
Statement I: The equivalent resistance of resistors in a series combination is smaller than
least resistance used in the combination.
Statement II: The resistivity of the material is independent of temperature. In the light of
the above statements, choose the correct answer from the options given below:
1) Both statement I and statement II are false
2) Both statement I and statement II are true
3) Statement I is false and statement II is true
4) Both statement I is true and statement II is false
33. In figure, when an ideal voltmeter is connected across 4000W resistance, it reads 30V. If
the voltmeter is connected across 3000W resistance, it will read n  4.5volts , then n is__

1) 5 2) 3 3) 8 4) 7
34. The figure shows a meter-bridge circuit with resistors X  12 W and R  18W . The jockey J
is at the null point. If end corrections at left and right ends are 2cm and 3cm respectively,
find the balancing length from point A.

1) 42.4 cm 2) 37.6 cm 3) 40 cm 4) 30 cm

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35. 12 Wires each of resistance R form a cubical wire frame as shown in figure. Match the
following.

Column – I Column - II
A) Resistance across AB p) 5R
6
B) Resistance across AC q) 7R
12
C) Resistance across AE r) 3R
4
D) Resistance across AB, if the wire s) 7R
AB is removed 5
1) A  s, B  q, C  p, D  s 2) A  r , B  q, C  s, D  p
3) A  q, B  r , C  p, D  s 4) A  p, B  q, C  r , D  s
1 1
36. The charge flowing in a conductor varies with time as Q  at  bt 2  ct 3 where a, b and c
2 6
are positive constants. If at time t, the current in the conductor is i, which of the following
graphs is correct?
i
a i

a
1) 2)

b/c t b/c t
i i
a

3) 4) a

t b/c t

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37. In the shown circuit, the reading of the voltmeter is V1 when only S1 is closed, reading of
voltmeter is V2 when only S2 is closed and its reading is V3 when both S1 and S2 are
closed. Then:

3R S1

R
6R S2


1) V3  V2  V1 2) V2  V1  V3 3) V3  V1  V2 4) V1  V2  V3
38. In the circuit shown. The potential difference between point A and B, When capacitors in
SteadyState
10 F
10 
A
>>
>

>>
>

>
>

10 
5 F >
>
>10 
> >
> 10 
>
B
100 V
>>
>
>

10 
1) 25 V 2) 50 V 3) 100 V 4) 0 V
39. Given below are two statements
Assertion (A): For measuring the potential difference across a resistance of 600W the
voltmeter with resistance1000W , will be preferred over voltmeter with resistance 4000W
Reason (R): Voltmeter with higher resistance will draw smaller current than voltmeter with
lower resistance. Choose the appropriate answer from the given option below
1) A is not correct but R is correct
2) Both A and R are correct and R is the correct explanation of A
3) Both A and R are correct and R is not the correct explanation of A
4) A is correct but R is not correct

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40. Find the charge in  C on capacitor in steady state
1W A 2W
D
1W
4 F
6V B C
1W
1W
4V
2W 2W

1)5 2)6 3)8 4) 10

41. The resistance per centimeter of meter bride wire is r, with X W resistance in left gap.
Balancing length from left end is at 40 cm with 25 W resistance in right gap. Now the wire
is replaced by another wire of 2r resistance per centimeter. The new balancing length from
left for same settings will be
1) 20 cm 2) 40 cm 3) 80 cm 4) 10 cm
42. In the given electric circuit what is the magnitude of current passing through the metallic
wire AB
2W
A C
2W 2W

1W 1W
B 1W D

6V

1) 3A 2) Zero 3) 1A 4) 2A
43. In meter-bride (fig), the balance point is found to be at 39.5 cm from the end A, when the
resistor S is 12.5 W .

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Statement I: If R and S are interchanged, the balance point will lie at a distance of 60.5 cm
from the end A.
Statement II: If the galvanometer and cell are interchanged at the balance point of the
bride, the galvanometer shows no deflection.
1) Both Statement I and Statement II are true
2) Both Statement I is false, but Statement II is true
3) Both Statement I is true, but Statement II is false
4) Both Statement I and Statement II are false
44. Given below are two statement: one is labelled as Assertion A and the other is labelled as
Reason R.
Assertion A: Alloys such as constantan and manganin are used in making standard
resistance coils.
Reason R: Constantan and manganin have very small value of temperature coefficient of
resistance.
1) A is not correct but R is correct
2) Both A and R are correct and R is the correct explanation of A
3) Both A and R are correct and R is not the correct explanation of A
4) A is correct but R is not correct
45. In the circuit shown below, a battery of emf E = 36v is connected between P and Q. What
is the potential difference between a and b?

1) 16 V 2) 12 V 3) 24 V 4) 18 V
SECTION-II
(NUMERICAL VALUE TYPE
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
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46. For what value of R (in W ) in the circuit shown, the current through 4 W will be zero?

4W
2W R

6V

10V 4V
47. In order to measure the internal resistance r1 of a cell of emf E a meter bridge of wire
resistance R0  50W
A resistance R0 / 2 , another cell of emf E / 2 (internal resistance r) and a galvanometer G
is used in a circuit, as shown in the figure. If the null point is found at l=72 cm, then the
value of r1  ______ W

48. Two cell A and B each of 2V are connected in series (Supporting each other) to an
external resistance R = 1ohm. The internal resistance of A is rA  1.9ohm and B is
rB  0.9ohm. Find the potential difference between the terminals of A.
49. In the following circuit, 5W resistor develops power 45 J/s due to current flowing
through it. The power developed across 12W resistor in Watt is

50. A uniform heating wire of resistance 36 W is connected across a potential difference of

240 V. the wire is then cut into half and a potential difference of 240 V is applied across
each half separately. The ratio of power dissipation in the first case to the total power in
the second case would be 1: x where x is

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CHEMISTRY Max Marks: 100
SECTION-I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. The inorrect orders among the following are:
A) Atomic radius: B  Al  Ga  In  Tl
B) Electronegativity: Al  Ga  In  Tl  B
C) Density: Tl  In  Ga  Al  B
D) 1st lonisation energy: In  Al  Ga  Tl  B
1) A and B only 2) A and C only
3) B and D only 4) C and D only
52. Which is correct about given character
1) BCl3  AlCl3 (Lewis acid strength)

2) In 1  In 3 (Stability)
3) Tl 3  Tl 1 (Stability)
4) Ortho Boric acid is tribasic acid
53. The incorrect statement from the following for borazine is
1) It has electronic delocalization. 2) It is a cyclic compound
3) It is polar compound 4) It contains banana bonds
54. The correct statements from the following are:
A) Tl 3 Is a powerful oxidising agent.
B) Al 3 Does not get reduced easily
C) Both Al 3 and Tl 3 are very stable in solution
D) Al is a least electronegative element in group 13
E) Al 3 And Tl  are highly stable.
Choose the correct answer from the options given below:
1) (B), (D) and (E) only 2) (A), (C) and (D) only
3) (A), (B), (D) and (E) only 4) (A), (B), (C), (D) and (E) only
55. Which has strong back donation of electron pair from halide to boron is expected
1) BI 3 2) BCl3 3) BF3 4) BBr3

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56. Assertion: Atomic radius of Gallium (135 Pm) is less than that of aluminum (143 Pm)
Reason: The presence of additional 10 d – electrons offer only poor screening effect for
outer electrons from increased nuclear charge in gallium.
1) Assertion and reason are correct Reason correct explanation of assertion
2) Assertion and reason are correct Reason is not correct explanation of assertion
3) Assertion is correct. Reason is incorrect
4) Assertion is incorrect. Reason is correct
57. Which of the following element belongs to Group 13
1) Og 2) Lv 3) Mc 4) Nh
58. Number of Lone pairs of electrons in anion of Tl 1I 3 is ___________
1) 3 2) 6 3) 2 4) 9
59. Statement – I: Ga is used in high temperature thermometers
Statement – II: A thermometer containing gallium is not useful for measuring the
freezing point (256K) of NaCl
1) Statement – I and Statement – II is correct
2) Statement – I and Statement – II is are incorrect
3) Statement – I is correct and Statement – II is incorrect
4) Statement – I is incorrect and Statement – II is correct
60. Which is basic oxide
1) B2O3 2) Ga2O3 3) Al2O3 4) Tl2O3
61. Statement –I: Al  OH 3 is amphoteric in nature
Statement – II: Al – O and O – H bonds can be broken with equal ease in Al  OH 3
1) Statement – I and II are true. Statement II is correct explanation of Statement I
2) Statement – I and II are true. Statement II is not correct explanation of Statement I
3) Statement – I is true but statement – II is false
4) Statement – I is false. Statement – II is true
62. Incorrect statement is
1) Al  CH 3 3 has the three centred two electron bonds in its dimeric structure
2) BH 3 has the three centred two electron bonds in its dimeric structure
3) Lewis acidity decreases down the group among tri chlorides of group 13 elements.
4) AlCl3 has the three centred two electron bonds in its dimeric structure

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63. The bond dissociation energy of B – F in BF3 is 646 kJ mol 1 whereas that of C – F in
CF4 is 515kJ mol 1 . The correct reason for higher B – F bond dissociation energy as
compared to that of C – F is
1) Smaller size of B-atom as compared to that of C- atom
2) Stronger  bond between B and F in BF3 as compared to that between C and F in CF4
3) Significant p  p interaction between B and F in BF3 whereas there is no
possibility of such interaction between C and F in CF4 .
4) Lower degree of p  p interaction between B and F in BF3 than that between c and
F in CF4
64. Which is correct.
1) BF6 3 Formed by boron
2) White fumes appear around the bottle of anhydrous AlCl3 is moist atmosphere due to
formation of HCl gas.
3) Born forms BH 63 ion.
4) BF4 1 , boron uses Sp 2 hybridisation
65. Match List – I with List – II
List – I List –II
P Boiling point (K) I B  Al  Ga  I n  Tl
3
Q Ionic radius M / pm  II Tl  In  Ga  Al  B

R Atomic radius (pm) III Tl  In  Al  Ga  B

 3
S Density g / cm at 298 K IV B  Al  Tl  In  Ga
The correct match is
1) P – I, Q – II, R – III, S – II 2) P – IV, Q – II, R – III, S – IV
3) P –I, Q – III, R – II, S – IV 4) P – IV, Q – III, R – II, S – I
Cl Cl
Cl Z y Al x
Al
Cl
Cl Cl
66.
Identify bond angles of x, y, z respectively
1) 118o ,79o ,101o 2) 120o ,79o ,104.5o
3) 118o ,101o ,79o 4) 115o ,80o ,101o
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67. Which is correct.
1) Boron forms cation B 3  
2) Tl 3 is strong reducing agent due to inert pair effect?
3) Melting point decreases as B  Al  Tl  Ga  In
4) Boron is extremely hard indicating its high lattice energy
68. Standard reduction potentials of some of group 13 elements given below. Predict the one
with the strongest reducing agent.
1) E o Al 3 / Al  1.66V 2) E oGa 3 / Ga  0.56V
3) E o In 3 / In  0.34V 4) E oTl 3 / Tl  1.26V
69. Which element having lowest sum of I .P1 , I .P2 and I .P3 values.
1) B 2) Ga 3) Tl 4) Al

70. AlCl3 

Acidified aqueous
Solution
 x  cation 
The hybridization of central metal atom in cation (x) is ____________
1) sp 3 2) sp 3d 3) dsp 2 4) sp3d 2
SECTION-II
(NUMERICAL VALUE TYPE
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
71. Total number of 2 centred -2 electron bonds in Al2  CH 3 6 and B2 H 6 are x and 3 centred

– 2 electron bonds in Al2  CH 3 6 is y. value of x  y is ________

72. In the following how many species using SP 3 hybridisation by central atom
1) AlCl3 (Anhydrous)

2) Borane  BH 3 
3) Dimer of aluminum chloride
4) Al2  CH 3 6 With respect to Al only

5)  AlH 3 n

6)  AlCl3 n (Crystalline solid)

7) Dimer of Borane
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X
73. Equivalent weight (g) of Boric Acid in water is X. The value of is __________
2
(B = 11, O = 16, H = 1)
74. Total number of SP 3 and SP 2 hybrid Boron atoms in tincal (Borax) are x and number of
water molecules in Na2 B4O5  OH  4 . yH 2O (kernite) as y. sum of x  y is ____________

75. Number of species contains  -bonds are

a) B3 N 3 H 6 b) B2 H 6 c) B  OH 3 d) BF4  e) BF3

f) Al2 Br6 g) Al2 I 6

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