Solution
Solution
1001CJA101023250011 JA
PART-1 : PHYSICS
SECTION-I
1) A potentiometer has a resistance wire of 10 m length and resistance 10Ω as shown in figure. A
circuit is setup as shown. For null deflection in galvanometer length AP is :
(A) 2m
(B) 4.5 m
(C) 6.5 m
(D) None of these
2) An infinite wire has a circular bend of radius a, and carrying a current I as shown in figure. The
magnitude of magnetic field at the origin O of the arc is given by :
(A)
(B)
(C)
(D)
3) Assertion : The total energy of the satellite is always negative irrespective of the nature of its
orbit, i.e. elliptical or circular and it cannot be positive or zero.
Reason : If the total energy is negative the satellite would leave its orbit.
(A) Assertion is true, Reason is true. Reason is the correct explanation of Assertion.
(B) Assertion is true, Reason is true. Reason is NOT the correct explanation of Assertion.
(C) Assertion is true, Reason is false.
(D) Assertion is false, Reason is true.
4) You have two closed containers of equal volume. One is full of helium gas. The other holds an
equal mass of nitrogen gas. Both gases have the same pressure. How does the temperature of the
helium compare to the temperature of nitrogen ? (Assume gases to be have as ideal gas)
(A) 33800 J
(B) 2200 J
(C) 800 J
(D) 1200 J
6) A particle is subjected to two simple harmonic motions, one along the x-axis and the other on a
line making an angle of 45° with the x-axis. The two motions are given by x = x0 sin ωt and s = s0 sin
ωt :-
7) A particle moves along X axis such that its acceleration is given by a = –β (x – 2). Where β is a
positive constant and x is the position coordinate. The time period of oscillation (in sec) :-
(A) π
(B) 2π
(C)
(D)
8)
A metallic rod is placed in a uniform electric field. Select the CORRECT option.
Inside the rod there will be an induced electric field from B to A which cancels external uniform
(A)
field in the rod.
(B) Free electrons will accumulate at the end B of the rod.
(C) The potential of the end A will be more than that at B.
(D) The electric field outside the rod will not change due to the induced charges in the rod.
List-I List-II
10) For a Wheatstone bridge shown; R1 > R2 and R3 = R4. The direction of current in wire AB is :-
(A) From A to B
(B) No current flows in AB
(C) From B to A
(D) Data is not sufficient
11) An ideal gas undergoes a four step cycle as shown in the P-V diagram below. During this cycle,
12) The orbital velocity of an artificial satellite in a circular orbit very close to earth of radius R is V.
The velocity of a satellite orbiting in circular orbit at an altitude of 3R from earth's surface will be :-
(A)
(B)
(C)
(D)
13) In the connection shown in the figure initially the switch K is open and the capacitor is
uncharged. Then the switch is closed and the capacitor is charged up to the steady state and the
switch is opened again. Determine the values indicated by the ammeter and pick up the
INCORRECT statement. [Given : V0 = 30 V, R1 = 10kΩ, R2 = 5kΩ]
(A) Just after closing the switch is zero.
(B) A long time after the switch was closed is 2 mA.
(C) Just after reopening the switch is 2 mA.
(D) Just after opening switch is zero.
14) Figure shows the capacitors in steady state, with S open. When S is closed :-
15) Statement - I : The hysteresis curve for transformer cores must be narrow.
Statement - II : The material for transformer cores must have high retentivity.
16) Identical metal plates are located in air at equal distances d from one another. The area of each
plate is equal to A. If plates are interconnected as shown in figure, then the capacitance of system
(A)
(B)
(C)
17) A current carrying loop is lying on a horizontal plane as shown in figure. Current is anti-
clockwise as seen from above the loop then direction of magnetic field at point P will be
(A)
(B)
(C)
(D)
18) A rectangular loop carrying a current i is situated near a long straight wire such that the wire is
parallel to the one of the sides of the loop and is in the plane of the loop. If a steady current I is
19) A square loop of side 2a and carrying current I is kept in xz plane with its centre at origin. A long
wire carrying the same current I is placed parallel to z-axis and passing through point (0, b, 0), (b
>> a). The magnitude of torque on the loop about z-axis will be :
(A)
(B)
(C)
(D)
20) A non conducting rod AB of length 'ℓ' has a positive linear charge density 'λ'. The rod is rotated
about point 'A' with an angular velocity 'ω' in plane of paper. What is the magnetic moment of rod ?
(A)
(B)
(C)
(D)
SECTION-II
1) If a = 30 cm , b = 20 cm, q = + 2.0 nC, and Q = – 3.0 nC in the figure, what is the potential
2)
Five identical conductors, each of resistance R, are forming a junction O as shown in the figure.
Potential (in V) at O is:-
3) A particle is projected from point A, that is at a distance 4R from the centre of the Earth, with
speed v1 in a direction making 30° with the line joining the centre of the Earth and point A, as
shown. Find the speed v1 if particle passes grazing the surface of the earth. Consider gravitational
interaction only between these two. (Use = 6.4 × 107 m2/s2) Express you answer in the form
m/s and write the value of X.
4) In the RC circuit shown, switch is closed at t = 0. Graphs showing variation of potential (VR)
across resistor and potential (VC) across capacitor are given. Time constant of circuit is ; (give
5) A neutral spherical conductor has cavity A and B of radius 1cm and 2cm respectively. Radius of
spherical conductor is 10 cm. If cavity ‘A’ contains charge 2µC and ‘B’ contains charge of –1µC,
electric potential at the centre of conductor is k × 104 volt. Then what is the value of k?
PART-2 : CHEMISTRY
SECTION-I
1) Using the data provided, calculate the multiple bond energy (kJ mol–1) of a C ≡ C bond in C2H2.
(Take the bond energy of a C–H bond as 350 kJ mol–1.)
2 C(s) + H2(g) → C2H2(g) ΔH = 225 kJ mol–1
2 C(s) → 2C(g) ΔH = 1410 kJ mol–1
H2(g) → 2H(g) ΔH = 330 kJ mol–1
(A) 1165
(B) 837
(C) 865
(D) 815
2) Consider the following plots of rate constant versus for four different reactions. Which of the
following orders is correct for the activation energies of these reactions? (T = absolute temperature)
List-I List-II
(P) (1)
vs for first order
4) Which of the following is isotonic with 15 % glucose solution if specific gravity of solution is 1.2
?
(A) 1 M CaCl2
(B) 1 N CaCl2
(C) 0.5 M NaCl
(D) 0.5 M urea
5) If same element atoms are assumed to be crystallized in simple cubic and FCC lattice, then ratio
of densities of simple cubic to FCC unit cell is
(A) 1 :
(B)
(C)
(D)
6) In the following conversion of sulphide of phosphorous P4S3 → P2O5 + SO2 Equivalent weight of
P4S3 (molecular weight = M) is :
(A)
(B)
(C)
(D)
7) A student is performing an experiment on fixed mole of ideal gas in the lab for which, he has
drawn the following cycle. [4 → 1 Adiabatic process] The net work done for
the cyclic process can be given as:
(B)
Wnet = nR
Wnet = nR
(C)
Wnet = nR
(D)
(I)
(II)
(III)
(IV)
9) Consider the structure of given alcohol : This alcohol can not be prepared
from :
(A)
and C2H5MgBr followed by HOH / H+
(B)
and C6H5MgBr followed by HOH / H+
(C)
and CH3MgBr followed by HOH / H+
(D)
and C2H5MgBr followed by H3O⊕
10) Assertion : RMgX react with carboxylic acid and form carbonyl compound.
Reason : RMgX shows acid base reaction with carboxylic acid.
(A) Assertion and reason are true and the reason is a correct explanation of assertion.
(B) Assertion and reason are true but reason is not a correct explanation of assertion.
(C) Assertion is true but the reason is false.
(D) Assertion is false but the reason is true.
11) Which of the following is correct about Zeff. for an element (as per Slater's rule)?
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
15) Which of the following statement(s) is/are correct regarding complex ion [Co(en)2(NH3)2]3+
(I) Central metal is sp3d2 hybridised
(II) Complex ion shows geometrical as well as optical isomerism.
(III) It has two N–Co–N bond angles.
(A) I & II
(B) II & III
(C) Only II
(D) Only III
16) During zone refining process a circular heater is passed through a block of impure metal from 'A'
end to 'B' end then which of the following picture is correct representation of end situation :-
(A)
(B)
(C)
(D)
+
(A) [Co(en)2Cl2]
2+
(B) [Co(NH3)5Cl]
+
(C) [Co(NH3)4Cl2]
3–
(D) [Cr(Ox)3]
Major product
(A)
(B)
(C)
(D)
(A)
Product (P) is
Product (Q) is
(B)
Product (R) is
(C)
(D)
Product (S) is
20) In which of the following reactions ethane as major product can be formed ?
(A)
(B)
(C)
(D)
SECTION-II
1) For a real gas at 25°C temperature and high pressure (99 bar) the value of compressibility factor
is 2, so the value of Vander Waal's constant 'b' should be_________ × 10–2 L mol–1 (Nearest integer)
(Given R = 0.083 L bar K–1 mol–1)
2) 5 moles of an ideal gas at 350K is in a 2.0 L vessel of thermally conducting walls, which are in
contact with the surroundings. It undergoes isothermal reversible expansion from 2.0 L to 3.0 L. The
change in entropy of the surroundings (ΔS) is __________ cal K–1
5) Find total number of correct statement(s) related to the metal extraction processes
(i) A mixture of PbS and PbO undergoes self-reduction to produce Pb and SO2.
(ii) Liquation method is used for the refining of metals having high melting point and are associated
with low melting impurities.
(iii) Partial oxidation of sulphide ore of copper by roasting, followed by self-reduction produces
blister copper.
(iv) In cyanide process, zinc powder is utilized to precipitate gold from Na[Au(CN)2]
(v) Refining of blister copper is done by carbon reduction
PART-3 : MATHEMATICS
SECTION-I
1) The value of is :-
(A) π2/4
(B) π2/2
(C) 3π2/2
(D) π2/3
2) is equal to-
(A)
(B) 4
(C) 1
(D)
(A) π/2
(B) 1
(C) π/4
(D) None of these
5) is equal to-
(A)
(B)
(C) 1
(D) 2
6) =
200
(A)
(B) 400
(C)
(D) 200
7) Let f : R → R.
If ,
(A) 5/2
(B) 3/2
(C) 5
(D) 3
(A)
(B)
(C)
(D)
9)
List-I List-II
(A) (I)
(B) (II)
(C) (III)
dx
(D) (IV)
10)
(A) 24
(B) 0
(C) 18
(D) 20
12) α, β, γ are roots of x3 + x2 – 5x – 1 = 0, then value of [α] + [β] + [γ] is (where [.] denotes greatest
integer function)
(A) 3
(B) – 3
(C) – 2
(D) 2
13) The area bounded by y = (sin–1(sinx))2, x axis and the two ordinates x = 0 and x = 2π is-
(A)
(B)
(C) π3
(D)
14) Find the area of the region bounded by y = {x} and 2x – 1 = 0, y = 0, ({ } stands for fraction
part)
(A)
(B)
(C)
(D)
should be equal to .
16) If the normal at (ap2, 2ap) on the parabola y2 = 4ax, meets the parabola again at (aq2, 2aq), then
(A) p2 + pq + 2 = 0
(B) p2 – pq + 2 = 0
(C) q2 + pq + 2 = 0
(D) p2 + pq + 1 = 0
17) The locus of middle point of chord of ellipse , which are parallel to the line y = 2x +
3 is
(A) x2 + y2 – 7x = 0
(B) 25x + 18y = 0
(C) 7x – 3y = 0
(D) x2 + y2 – 9y = 7
18) Let be the equation of an ellipse. If m be the minimum value of the segment of a
tangent to the ellipse intercepted by the coordinate axes and M be the maximum distance of the
centre of the ellipse from the normal, then the value of m.M is equal to
(A) 63
(B) 225
(C) 21
(D) 108
19) The equation of the common tangent to the curves and xy = –1, is
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
SECTION-II
1) then (p – r) = ______.
2) Let A be the area bounded by the curve y = x|x – 3|, the x-axis and the ordinates x = – 1 and x = 2.
Then 12A is equal to _____.
3) Let P and Q be distinct points on the parabola y2 = 4x such that circle, for which PQ is diameter
passes through vertex of the parabola. If area of ΔOPQ (O is origin) is 20 and the diameter of
circumcircle of ΔOPQ is d, then is equal to
4) A triangle is formed by the points A(0, 0), B(3, 0) and C(3, 4). A and C are foci of ellipse and B lies
5) If two tangents drawn from a point (α, β) lying on the ellipse 25x2 + 4y2 = 1 to the parabola y2 =
4x are such that the slope of one tangent is four times the other, then the value of
equals __________
ANSWER KEYS
PART-1 : PHYSICS
SECTION-I
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D B C C C A D A C C C C D D A B C C D D
SECTION-II
Q. 21 22 23 24 25
A. 60 4 8 143 9
PART-2 : CHEMISTRY
SECTION-I
Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D C A C A C D C D D A D B B C D A A D A
SECTION-II
Q. 46 47 48 49 50
A. 25 4 7 9 3
PART-3 : MATHEMATICS
SECTION-I
Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A D C C B C D C A A C B A C C A B A D A
SECTION-II
Q. 71 72 73 74 75
A. 11 62 5 6 2929
SOLUTIONS
PART-1 : PHYSICS
1) As secondary battery have P.D. more than potential diffrence across wire AB. Therefore
balance point will not be achieved on wire AB.
2)
B3 = 0
3)
Theoritical
4) T = pV/nR. Pressure and volume are the same, but n differs. The number of moles in mass
M is n = M/Mmol. Helium, with the smaller molar mass, has a larger number of moles and
thus a lower temperature.]
= 2 × 102 × 4 Nm = 800 J
6) Net,
8)
Theoretical
9) Factual
10)
As
∴ VB > VA ⇒ current from B to A
11)
Process 1
P = constant, Volume increases and temperature also increases
⇒ W = positive, ΔU = positive
⇒ Heat is positive and supplied to gas
Process -2
V = constant, Pressure decrease
⇒ Temperature decreases
ΔT is negative and ΔU = nR T
⇒ U in negative
ΔQ = ΔU + W
∴ ΔQ → Heat is negative and rejected by gas
Process 3
P = constant, Volume decreases
⇒ Temperature also decreases
W = PΔV = negative
ΔU = nR T = negative
ΔQ = W + ΔU = negative
Heat is negative and rejected by gas.
Process 4
V = constant, Pressure increases
W=
PV = nRT ⇒ Temperature increase
⇒ ΔU = is positive
ΔQ = ΔU + W = positive
Ans. (C) step 1 and step 4
0 0
12) V = ⇒V ∝
= , V2 =
13)
15) Conceptual
16)
C(y – V) + C(y – x) + Cy = 0
3y – x = V
C(x – 0) + C(x – y) + C(x – V) = 0
3x – y = V
⇒ 8x = 4V ⇒ x = ,y=
⇒ ΔQ =
17)
18)
Since F1 > F2 hence loop ABCD will move towards the long wire.
19)
If b >> a then
20) M = iA
A = πx2
21)
= = 60 V
22)
23)
⇒ Þ
24) VR = ε.e–t/RC
VC = ε[1 – e–t/RC]
At t = 100 ms
VR = VC
⇒ e–t/RC = 1/2
25)
PART-2 : CHEMISTRY
πglucose =
1N ⇒ = iCRT =
1M ⇒ = iCRT = 3 × 1 × RT = 3RT
0.5 ⇒ πurea = iCRT = 1 × 0.5 RT = 0.5RT
30)
31)
33)
34)
38)
40)
Co+3 → [Ar], 3d6
Hybridisation d2sp3 in presence of strong field ligand.
Total 15 N–Co–N bond angles
41) Explanation - Asking about the segregation of impurities during "Zone refining process".
Concept - The solubility of impurities is more in melts than in solids.
Solution - Melt moved with circular heater so impurities also towards the final end/tail in the
direction of circular heater
43)
44)
47)
49)
PART-3 : MATHEMATICS
51)
⇒ (cos x = t)
52)
Put
54)
ƒ'(x) = 0 ⇒ ƒ(x) = c
55)
56)
⇒
⇒ =
57)
– [x] = {x}
x – [x +1] ={x} x – 1
= =3
Hence (D) is the correct answer.
58)
Let then
Put
59) (A)
(B)
(C)
(D)
60) f(x) = 2x + cot–1 x + ln
∵ f '(x) = 0 ⇒ at x = 0
Sign scheme for f '(x)
If g is decreasing in (0, α)
Therefore
Then .
62) f(x) = x3 + x2 – 5x – 1
f'(x) = 3x2 + 2x – 5 = (x – 1)(3x + 5)
x → ∞ : f(n) → ∞
x → – ∞ : f(x) → – ∞
∴ f(1) = – 4
f(0) = – 1 < 0
63)
66) We have
67)
25x + 18y = 0
68) Tangent
A(12secθ, 0) B(0,9cosecθ)
Normal
P(0,0) = M =
Mm = 63
69)
70) LHS =
(a + 1) + 1 = c
⇒a+2=c
RHS =
=
= ⇒C= a= b∈R
71)
72)
⇒
∴ 12A = 62
t1 – t2 = 5 ⇒ t1 = 1, 4
74) AC = 5 = 2aℓ
⇒ 2ae = 5 .....(1)
Also AB + BC = 2a
⇒ 2a = 7
⇒
∴ ⇒ ⇒b=
∴P=6
75)
Equation of tangent to y2 = 4x
y = mx +
It passes through (α,β)