16-08-2025

1001CJA101023250012 JA

PART-1 : PHYSICS

SECTION-I

1) A gas is undergoing an adiabatic process. At a certain stage, the values of volume and
temperature are V0 and T0 respectively and the modulus of slope of V–T curve is m. Choose the
correct options-

(A)
The value of CV =

(B)
The value of CP =

(C)

(D)

2) A ring of mass m, radius r can oscillate in a vertical plane about is top most point 'O' as shown.
Axis is normal to the plane of ring. Maximum speed of lowest point 'P' of ring is v.

Time period of SHM for small amplitude is

(A)

(B) Acceleration of centre of mass of ring at lowest position is zero

(C)
Hinge force when centre of mass is at lowest point is

(D) Mechanical energy of oscillation is (when potential energy at mean position is taken as
zero)

3) Inside a parallel plate capacitor of capacitance C (without dielectrics) dielectrics are filled which
have dielectric constant k1 and k2 such that k1 > k2 . The capacitor is now connected to a battery of
voltage V then :-

(A)
New capacitance of the capacitor will be .
(B) Field in dielectric 1 will be more than the field in dielectric 2.
(C) Surface charge density on the capacitor plates will be uniform.
(D) Field in both the dielectric regions will be the same.

4) The figure shows a graph of the current in a discharging circuit of a capacitor through a resistor

of resistance 10Ω.

(A) The initial potential difference across the capacitor is 100 volt.

(B)
The capacitance of the capacitor is .

(C)
The total heat produced in the circuit will be Joules.

(D)
The thermal power in the resistor will decrease with a time constant second.

5) In given figure at t = 0, a charged particle of mass m and charge q enters in the region-II.

(A) If q > 0, particle will enter into region-I after leaving region-II.
 If q < 0 the particle will leave region-II at t =
(B)

If q > 0 particle will re-enter in region-II at t =

(C)

(D) Particle will not leave region-II

6) A conductor (shown in the figure) carrying constant current I is kept in the x-y plane in a uniform
magnetic field . If F is the magnitude of the total magnetic force acting on the conductor, then the

correct statement(s) is (are)

(A) If is along , F ∝ (L + R)
(B) If is along , F = 0
(C) If is along , F ∝ (L + R)
(D) If is along ,F=0

7) Two identical moving coil galvanometer have 10 Ω resistance and full scale deflection at 2 µA
current. One of them is converted into a voltmeter of 100 mV full scale reading and the other into an
Ammeter of 1 mA full scale current using appropriate resistors. These are then used to measure the
voltage and current in the Ohm's law experiment with R = 1000 Ω resistor by using an ideal cell.
Which of the following statement(s) is/are correct?

(A) The measured value of R will be 978Ω < R < 982Ω.

(B) The resistance of the Voltmeter will be 100 kΩ.
(C) The resistance of the Ammeter will be 0.02Ω (round off to 2nd decimal place).
If the ideal cell is replaced by a cell having internal resistance of 5Ω then the measured value of
(D)
R will be more than 1000 Ω.

8) A neutral conductor of radius R has a spherical cavity of radius and its centre lies at from

centre of conductor. A charge Q is kept at the centre of cavity.

Electric field due to charges induced on inner surface of cavity at centre of conductor is
(A)

Net field at a radial distance of 2R from centre of sphere is

(B)
(C) Net force on the surface charges of conductor due to all the charges of cavity is zero.
(D) Net force on the charges induced on the surface of cavity is zero.

SECTION-II

1) An electric dipole is placed in a uniform electric field of magnitude 40 N/C. Graph shows the
magnitude of the torque (10–28 Nm) on the dipole versus the angle θ between the field and the
dipole moment . The magnitude of dipole moment is equal to x × 10–30 C-m. Find x.

2) Gravitational acceleration on the surface of a planet is where g is the gravitational

acceleration on the surface of the earth. The average mass density of the planet is times that of the
earth. If the escape speed on the surface of the earth is taken to be 11kms–1, find the escape speed
on the surface of the planet in kms–1.

3) An Earth satellite revolves on a circular orbit at a linear speed v0. A missile device increases the
absolute value of this speed to 1.5v0, and the satellite goes into an unknown path as shown (Fig).
With what speed will the satellite leave the gravitational field of earth? The resistance of the cosmic

dust is not taken into account. Mass of earth is M. If your answer is , then find the value of α.

4) The magnetic flux through a metal ring varies with time t according to ϕB = 3(at3 – bt2)Tm2, with a
= 2 s–3 and b = 6 s–2. The resistance of the ring is 3 Ω. Determine the maximum current (in A)
induced in the ring during the interval from t = 0 to t = 2s.
5) A flexible circular loop 20 cm in diameter lies in a magnetic field of magnitude B = 1 Tesla,
directed into the plane of page as shown. The loop is pulled at the points indicated by the arrows
forming a loop of zero area in 0.314 sec. The average emf induced in the loop is nV. Find 10n.

6) A rectangular loop PQRS is formed by joining the corners of cube of side 20 cm as shown in
figure. If I = 8 A and then the magnitude of torque on loop is P × 10–3 N-m. Find the value

of P.

7) All the capacitors in the given figure has a capacitance C0. The equivalent capacitance between

the points A and O is x µF. Find x, if C = 9 µF.

8) A 10-km-long underground cable extends east to west and consists of two parallel wires, each of
which has resistance 13Ω/km. A short develops at distance x from the west end when a conducting
path of resistance R connects the wires (figure). The resistance of the wires and the short is then
100Ω when the measurement is made from the east end, 200Ω when it is made from the west end.
What is value of R (in ohm) ?

9) A particle having charge q = 2µC and mass 1 kg is projected with speed 3 m/s at an angle 53°
from point A as shown. Speed of the particle when it is at a perpendicular distance 2r from the wire

is . Find value of .

10) For an ideal heat engine, the temperature of the source is 127°C. In order to have 60% efficiency
the temperature of the sink should be T°C, then modulus (|T|) value of T is. (Round off to the Nearest
Integer)

PART-2 : CHEMISTRY

SECTION-I

1) CH3–CH=O + CH3–CH2MgBr +
Which of the following statement(s) is/are correct :

(A) X and Y are geometrical isomers

(B)
X racemic mixture

(C)
Y meso compound
(D) X is more stable than Y

2) Which of the following will give Pentan-3-one.

(A)

(B)

(C)
(D)

3) Select the incorrect statement(s) for certain amount of an ideal gas at constant pressure.

(A) λ is constant
(B) Z1 is directly proportional to T.
2
(C) Z11 is directly proportional to T .
3/2
(D) Z11 is inversely proportional to V .

4)

When ethanol & water are mixed at room temperature then for the process :-

(A) ΔGmix = 0
(B) ΔSsystem > 0
(C) ΔSsurrounding < 0
(D) ΔHmix = 0

5) The order of reaction A → product can be given by the expression (s)

[where r = rate of reaction ; [A]1 = concentration at time t1 ; [A]2 = concentration at time t2]

(A)

(B)

(C)
ln

(D)

6) Extraction of metal from the ore cassiterite (SnO2) involves

(A) carbon reduction of an oxide ore

(B) self-reduction of a sulphide ore
(C) removal of copper impurity
(D) refining by liquation process

7) Poling is employed in refining of

(A) iron
(B) copper
(C) tin
(D) lead

8) Identify the correct statements among the following

(A) EDTA is used in the estimation of hardness of water

(B) EDTA is used in treatment of Lead Poisoning
Chlorophyll is a Mg complex, Haemoglobin is an Iron complex, Vitamin B12 is a
(C)
Cobalt complex and the anti-pernicious anemia factor is a platinum complex
(D) Cis-platin effectively inhibits the growth of tumours

SECTION-II

1)

Find out total number of monochlorinated product 'X'.

2) How may compounds gives conjugated diene as major product by Kolbe electrolysis?

(i) (ii)

(iii)

(iv)

(v)

(vi)
(vii)

3) How many reactions giving Hoffmann product as major product

(a) (b)

(c) (d)

(e)

4) Total number of compounds having higher rate of SN2 reaction than compound CH3—CH2—Cl.

(i) CH3—Cl (ii) CH2 = CH—Cl (iii) (iv) MeO—CH2—Cl

(v) (vi) (vii) CH3 – CH2 – I

(viii) (ix) (x) CH3—CH2—F

5) Calculate ΔG (in bar-L) when a definite mass of a monoatomic ideal gas at 1 bar & 27ºC is
expanded adiabatically against vaccum from 10 L to 20 L (ln2 = 0.7)

6) Calculate the ratio of degree of dissociation (α2/α1) when an acetic acid solution is diluted 100
times. Assume α < < 1, even on dilution. [Given Ka=10–5 M]

7) 100 gm water is heated from 27ºC to 77ºC at constant pressure. Find value of ΔStotal (in JK–1) for
the process.
(i.e., ΔSsystem + ΔSsurrounding), in J K–1, if the process is performed irreversibly.
(Given: Specific heat capacity of water = 4.2 J K–1 gm–1; ln 7 = 1.95; ln 6 = 1.80)

8) Among the following, total number of metals which are extracted by self reduction method ?
Pb, Zn, Cu, Mg, Hg, Fe, Al, Au

9) Find number of process or ore given in Column-I are correctly represented with Column-II. You
have to consider P for P, Q for Q, R for R etc.

(I) (II)
Process/Ore Related to

(P) Matte formation (P) Cu

(Q) Cyanide leaching (Q) Au

(R) Mond's process (R) Reaction of metal + H2

(S) Fused oxide electrolysis (S) Al

(T) Zone refining (T) Si

(U) Van Arkel process (U) Ti

(V) Goldschmidt-Thermite process (V) Reducing agent : Al

(W) Separation of FeWO4 (W) Extraction of Pb

10) Few elements are given as follows :

Cr, Mn, Pb, Cu, Al, Na, Mg, Zn, Hg
(P) Number of elements whose extraction done by self reduction process.
(Q) Number of metals whose extraction is done by electrolytic reduction process.
(R) Number of metals whose purification is done by distillation.
Give your answer P + Q + R.

PART-3 : MATHEMATICS

SECTION-I

1) The slope of tangents to the parabola y2 = 9x which pass through the point (4, 10) are

(A)

(B)

(C)

(D)

2) Let P be any point on the curve but not on the axes. Let M, N be the feet of
the perpendiculars drawn from P on minor and major axes respectively. Let the tangent at P cuts
minor and major axes at R, T respectively. Let the normal at P cuts major axis at G and CF be the
perpendicular from centre C to the normal at P. Then, which of the following is/are true ?
(A) PF . PG = 16
(B) PF . PG = 9
(C) PM . CT = 16
(D) PN . CR = 9

3) Let then is

(A)

(B)

(C) Greater than one

(D) Less than two

4) Consider function f(x) = |xℓnx|. Then

maximum value of f(x) in x ∈ (0, 1) is

(A)

(B) f ′ (x) has local minima at x = 1

(C) Rolle's theorem can be applied to f(x) for an interval of maximum length 1 unit
(D) f ′ (x + 2) – f ′ (x) < 2 for all x > 1

5) If = y2 + 4y + 5, then y can be equal to -

(A) 1
(B)
(C)
(D)

6) The function f(x) = is

(A) continuous at x = 1
(B) differentiable at x = 1
(C) continuous at x = 3
(D) differentiable at x = 3

7) If y = , then the value of (a − b) can be equal to

(A)
(B)

(C)

(D)

8) Consider the equation

Which of the following statement is/are TRUE ?

(A) No 'a' satisfies the above equation

(B) An integer 'a' satisfies the above equation
(C) An irrational number 'a' satisfies the above equation
(D) More than one 'a' satisfy the above equation

SECTION-II

1) Let area of region

be [Link]. Then value of

2) The area bounded by the curves y = x2 + 2x – 3 and the line y = 2x + 1 is λ then value of 3λ is :

3) If , where C is the constant of integration,

then the value of α + β + 20AB is _______.

4) If , then n is equal to

5) If the value of definite integral is equal to

(where N is a natural number), then find the value of N.

6) Let f : → be a thrice differentiable function such that f(0) = 0, f(1) = 1, f(2) = –1, f(3) = 2 and
f(4) = –2. Then, the minimum number of zeros of (3f' f'' + ff"') (x) is …..
7) Suppose an ellipse and a hyperbola have the same pair of foci on the x-axis with centres at the

origin and they intersect at M(2, 2). If the eccentricity of ellipse is and eccentricity of hyperbola is

where m, n are coprime, then find the value of (m + n).

8) Two tangents are drawn from a point (–2, –1) to the curve, y2 = 4x. If α is the angle between them,
then | tan α | is equal to :

9) Let the function ƒ : [0, 1] → be defined by . Then the value of

is______

10) The value of tan2(sec–13) + cot2(cosec–14) is -

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8
A. A,B,C A,D A,D A,B,C,D A,B A,B,C A,C C,D

SECTION-II

Q. 9 10 11 12 13 14 15 16 17 18
A. 125 3 2 6 1 128 20 20 8 113

PART-2 : CHEMISTRY

SECTION-I

Q. 19 20 21 22 23 24 25 26
A. A,B,C A,B,D A,B,C B,C A,C,D A,C,D B,C A,B,D

SECTION-II

Q. 27 28 29 30 31 32 33 34 35 36
A. 8 4 4 4 7 10 3 3 6 8

PART-3 : MATHEMATICS

SECTION-I

Q. 37 38 39 40 41 42 43 44
A. A,B B,C,D A,D A,D B,D A,B,C C,D C,D

SECTION-II

Q. 45 46 47 48 49 50 51 52 53 54
A. 11 32 7 1 64 5 10 3 19 23
 SOLUTIONS

PART-1 : PHYSICS

1)

TVγ-1 = constant

⇒ ⇒

⇒ ⇒ Cp= Cv+1=

2) Maximum velocity for C.M. =

mechanical energy is equal to maximum K.E.

and time period is given by =

3)

4) 1. Question Explain (in 30 words): This problem involves a discharging capacitor

through a resistor. The goal is to calculate the initial voltage, capacitance, heat produced, and
time constant based on the provided current-time graph.
2. Concept Based (Subtopic Name in 30 words):
The problem deals with the exponential discharge of a capacitor through a resistor, where the
current decays over time, and the formulas governing voltage, capacitance, heat, and time
constant are crucial.
3. Formula Used:
• Initial Voltage Across the Capacitor:
V0 = i0 R
Where i0 is the initial current and R is the resistance.
• Current Decay Equation:

• Capacitance from Current Decay:

Where t is the time, i0 is the initial current, and i is the current at time t.
• Heat Produced:

• Thermal Power:
P=I2R
4. Calculation (in brief):
Step 1: Calculate Initial Voltage Across the Capacitor
From the graph, the initial current i0 = 10A and the resistance R = 10 Ω. Using V0 = i0R, we
calculate:

Step 2: Calculate Capacitance

Using the current decay equation , we solve for C. From the graph, at t =
2 seconds, i = 2.5 A. Using the equation:

Step 3: Calculate Heat Produced

The heat produced is equal to the energy stored in the capacitor, which is:

Substituting and :

Step 4: Calculate Thermal Power and Time Constant

The thermal power is given by P = i2R, and using the decay formula, the time constant is τ
=RC.
From the current equation, the time constant is:

5)
If q > O
θ = 60°

At

Hence particle will enter region I from II for first time at

Option (A) is correct option (C) is incorrect

Case (2) q < O

Hence option (B) is correct.

6)
As magnetic field is uniform

When is along y or z axis

F ∝ (L + R)
When is along x-axis
F=0
∴ (A,B,C)

7)
0.1 = 2 × 10–6 (10 + RV)
∴ RV = 49990 Ω

2 × 10–6 × 10 = 10–3 RA
y 50000 = (x – y) 1000
∴ 51y = x

Reading = ≈980
8)

(A)

(B)
(C) Electric field outside the conducting cavity due to charges kept inside the cavity and
induced charges on the inner surface of the cavity is always zero. (electrostatic sheilding)
(D) Because the charge at the surface of conductor is uniformly distributed so electric field
due to them inside conductor will be zero so net force on the charges induced on the surface of
cavity is zero.

9)
τmax = p E
⇒ 50 × 10–28 = p.40
⇒ p = 1.25 × 10–28 C-m

10) Since,

⇒
Also,

⇒
⇒ vp = 3 kms–1

11)

Ki + Uf = Kf + Uf

12)

ϕB = 3at3 – 3bt2
for iind to be maximum

6at – 2b = 0

= 6 Ampere

13) =

14) As we known
.... (i)

Here

15) Using the parallel axis symmetry it can be reduced to the following circuit.

Solving this circuit will give us equivalent capacitance between A and O as

16) 13(2x) + R = 200

13(2 (10 – x) + R = 100
260 + 2R = 300
R = 20 Ω
 17)
= +(2 × 10–6)
× 2kλ ℓn2
v2 – 9 = 8 × 9 × 103 × 1 × 10–3 ℓn2

18) n = 0.60 = 1 –

⇒ TL = 0.4 × 400
TL = 160 K = –113°C
|T| = 113

PART-2 : CHEMISTRY

19)

The correct answer is option (A,B,C)

P⇒
X ⇒ cis-2-Butene
Y ⇒ trans-2-Butene

20)

21)

The correct answer is (A), (B) and (C)

22)
(A) Incorrect → mixing is spontaneous so ΔG < 0.
(B) Correct → Positive deviation means vapour pressure of solution is more. This means
randomness increases on mixing the two.
So, ΔS sys > 0
[ΔS sys for mixture always increases]
(C) Correct :- As ΔS sys > 0, so ΔS surr <0.
(D) Incorrect : For positive deviation, ΔHmix > 0.
23) A → Product
Let the order of rxn. = P

R = K[A]P ⇒
Taking log at both sides

P= OR =P
AT two different rates

24) Tin is obtained by reducing the ore cassiterite with coal in a reverberatory furnace;
Limestone is added to produce a slag with the impurities, which can be separated.
SnO2​ +2C ⟶ Sn + 2CO
Crude tin so obtained is contaminated with iron, copper, lead and other metals. It is, therefore,
remitted on an inclined furnace. The process is called liquation.
The easily fusible tin melts away and the less fusible impurities are left behind. Molten tin is
finally stirred with green poles of wood in contact with air. In this process, any remaining
metal impurities are oxidized forming a scum, which rises to the surface and is removed. This
process is called poling.

25) Poling is a metallurgical method employed in the purification of copper which contains
copper oxide as an impurity and also in the purification of tin ("Sn") which contains tin oxide
(stannic oxide or "SnO2") as an impurity (impurity of same oxide). Freshly cut ("green") trees
were used as wooden poles. The sap in these poles acted as the reducing agent. The heat of
the copper makes the pole emit wood gas (CO2 and H2) that reduces the cuprous oxide to
copper.

26) the anti-pernicious anemia factor is cobalt complex

27)
Total product : 8

28)
 (i), (ii), (iii), (vii)

29)

(a), (b), (c), (e)

30)

(i), (iv), (v), (vii)

31) q = 0 ; w = 0 ; ΔU = 0 = T → constant

ΔG = nRT ln = P1V1 ln

= 1 × 10 ln
= 10 × 0.7 = 7 bar.L

32)

33) ΔSsystem = m.s. ln = 100 × 4.2 × ln = 63 J K–1

ΔSsurrounding = =

= = – 60 J K–1
∴ ΔStotal = ΔSsys + ΔSsurr = 63 + (–60) = 3 J K–1

34) Pb, Cu, Hg Can be extracted by self-reduction

35)

The correct answer is 6

36) P ⇒ Pb, Hg, Cu

Q ⇒Al, Na, Mg
R ⇒ Zn, Hg
So, P = 3, Q = 3 & R = 2
So answer is 3 + 3 + 2 = 8

PART-3 : MATHEMATICS
37) y2 = 9x

(Equation of tangent)
Latus rectum
4a = 9

⇒
at point (4, 10)

⇒
⇒ 16m2 – 40m + 9 = 0

= =

∴ ,

∴ ,
Equation of tangent :

38) P(4cosθ, 3sinθ) ; Tangent at

Normal at p is ,

CM = PN = 3 sinθ, CT =

CN = PM = 4cosθ, CR =

PF = , PG =

39)
40)

41) y2 + 4y + 5 =

42) (A) (B) Here,

f(x) =
∴ R.H.L. at x = 1,

⇒ =2
L.H.L. at x = 1

= = =2
∴ f(x) is continuous at x = 1 :
again,

f(x) =

∴ f′(x) =
∴ differentiable at x = 1.
again,

not differentiable at x = 3.

43)

44) Let I =
Let a – (loge x)3/2 = t

2 = 3a2 – 3a
3a2 – 3a – 2 = 0

or
45)
Area of shaded region

46) y = x2 + 2x – 3 and y = 2x + 1
both curves intersect when x2 + 2x – 3 = 2x + 1
⇒ x = ±2

47)

⇒ t–4/5+1
 α=β=1

α + β + 20AB = 2 + 20 ×

48)

n2 + 3n + 2 = 6
n2 + 3n – 4 = 0
(n + 4)(n – 1) = 0
n=1

49) I =

Using King , I =

Now add, 2I = (ℓn 2) = (ℓn 2)

Put 2θ = t

2I = (ℓn 2) =

∴I= ≡
⇒ N = 64. Ans.

50)

min. roots of f(x) → 4

∴ min. roots of f '(x) → 3
∴ min. roots of →7
51) Let and

⇒ ; ⇒

So, and b2 = 7

Now, slope of tangent at M(2, 2) on hyperbola ⇒

So, slope of tangent at M(2, 2) on hyperbola ⇒

As, ⇒

So, . [Note that ellipse and hyperbola are confocal].

52) Let equation of tangent from (– 2, –1) be

y + 1 = m (x + 2)
⇒ y = mx + (2m – 1)

Condition of tangency,

i.e., 2m – 1 =
⇒ 2m2 – m – 1 = 0
(2m + 1) (m – 1) = 0

m=

Now,

53)

=1

so,
54) sec2(sec–1(3))–1 + cosec2(cosec–1(4))–1
= 9 – 1 + 16 – 1
= 23