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Advanced Inorganic and Physical Chemistry

The document outlines the structure of the B.Sc. VI Semester Degree Examination in Chemistry for September/October 2024, focusing on Advanced Inorganic and Physical Chemistry. It includes three sections: Section A with short answer questions, Section B with longer questions requiring detailed responses, and Section C with in-depth essay questions. The exam covers topics such as stability constants, geometrical isomerism, and thermodynamic functions.

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51 views2 pages

Advanced Inorganic and Physical Chemistry

The document outlines the structure of the B.Sc. VI Semester Degree Examination in Chemistry for September/October 2024, focusing on Advanced Inorganic and Physical Chemistry. It includes three sections: Section A with short answer questions, Section B with longer questions requiring detailed responses, and Section C with in-depth essay questions. The exam covers topics such as stability constants, geometrical isomerism, and thermodynamic functions.

Uploaded by

gowthu1307
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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21BSC6C13CHL
21BSC6C13CHL

!21BSC6C13CHL!

B.Sc. VI Semester Degree Examination, Sept./Oct. - 2024


CHEMISTRY
DSC-7 : Advanced Inorganic and Physical Chemistry
(NEP)

Time : 2 Hours Maximum Marks : 60

Note : Answer all sections.

SECTION - A
Answer the following sub-questions. Each sub-question carries one mark. 10x1=10
1. (a) Define stepwise stability constant. 1
(b) What is kinetic stability of metal complexes ? 1
(c) Write the structure of trans-isomer of co-ordination number 4. 1
(d) Give an example of weak field ligand. 1
(e) What is Spectroscopic ground state ? 1
(f) What is Racah parameter ? 1
(g) Define partial molar volume. 1
(h) Define activity coefficient. 1
(i) What is ionic atmosphere ? 1
(j) When ion pair formation is possible according to Bjerrum mode ? 1

SECTION - B
Answer any four of the following questions. Each question carries five marks.
4x5=20
2. Write a note on determination of binary formation constant by Polarigraphic 5
method.

3. Explain the geometrical isomerism in co-ordination number 6 with example. 5

4. Discuss the colour of transition metal complexes on the basis of CFT. 5

5. Write a note on Tanaubo-Sugano diagrams. 5

!21BSC6C13CHL! P.T.O.
21BSC6C13CHL 2

6. Explain the following excess thermodynamic functions. 5


(a) Excess Gibbs free energy
(b) Excess Entropy

7. Explain Debye-Huckel theory for the problem of activity coefficient. 5

SECTION - C

Answer any three of the following questions. Each question carries ten marks.
3x10=30
8. (a) Discuss briefly the factors affecting the stability of metal complexes with 6
reference to nature of metal ion and ligand.
(b) Derive the relationship between stepwise formation constants and overall 4
formation constant.

9. (a) Draw crystal field splitting diagram in tetrahedral and square planar geometry. 6
(b) Discuss the magnetic properties of octahedral complexes on the basis of 4
CFT.

10. (a) Explain the determination of magnetic susceptibility of complexes by Gouy 6


method.
(b) Write a note on orbital contribution to magnetic property. 4

11. (a) Define phase rule. Derive the phase rule from the concept of chemical 6
potential.
(b) Discuss the ideal and non-ideal systems in thermodynamics. 4

12. (a) Derive an expression for electro capillary Lippmann’s equation. 6


(b) Explain briefly activation over potential. 4

-o0o-

!21BSC6C13CHL!

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