Table B.

2 Heat Capacitiesa

Form 1: C p [kJ/(mol⭈⬚C)] or [kJ/(mol⭈K)] ⳱ a Ⳮ bT Ⳮ cT 2 Ⳮ dT 3

Form 2: C p [kJ/(mol⭈⬚C)] or [kJ/(mol⭈K)] ⳱ a Ⳮ bT Ⳮ cT ⫺2
Physical Property Example: (C p )acetone(g) ⳱ 0.07196 Ⳮ (20.10 ⫻ 10⫺5 )T ⫺ (12.78 ⫻ 10⫺8 )T 2 Ⳮ (34.76 ⫻ 10⫺12 )T 3 , where T is in ⬚C.
database
Quickly integrates Note: The formulas for gases are strictly applicable at pressures low enough for the ideal gas equation of state to apply.
tabulated heat
capacities Range
Mol. Temp. (Units
Compound Formula Wt. State Form Unit a ⫻ 103 b ⫻ 105 c ⫻ 108 d ⫻ 1012 of T )

Acetone CH3 COCH3 58.08 l 1 ⬚C 123.0 18.6 ⫺30–60

g 1 ⬚C 71.96 20.10 ⫺12.78 34.76 0–1200
Acetylene C2 H2 26.04 g 1 ⬚C 42.43 6.053 ⫺5.033 18.20 0–1200
Air 29.0 g 1 ⬚C 28.94 0.4147 0.3191 ⫺1.965 0–1500
g 1 K 28.09 0.1965 0.4799 ⫺1.965 273–1800
Ammonia NH3 17.03 g 1 ⬚C 35.15 2.954 0.4421 ⫺6.686 0–1200
Ammonium sulfate (NH4 )2 SO4 132.15 c 1 K 215.9 275–328
Benzene C6 H6 78.11 l 1 ⬚C 126.5 23.4 6–67
g 1 ⬚C 74.06 32.95 ⫺25.20 77.57 0–1200
Isobutane C4 H10 58.12 g 1 ⬚C 89.46 30.13 ⫺18.91 49.87 0–1200
n -Butane C4 H10 58.12 g 1 ⬚C 92.30 27.88 ⫺15.47 34.98 0–1200
Isobutene C4 H8 56.10 g 1 ⬚C 82.88 25.64 ⫺17.27 50.50 0–1200
Calcium carbide CaC2 64.10 c 2 K 68.62 1.19 ⫺8.66 ⫻ 1010 — 298–720
Calcium carbonate CaCO3 100.09 c 2 K 82.34 4.975 ⫺12.87 ⫻ 1010 — 273–1033
Calcium hydroxide Ca(OH)2 74.10 c 1 K 89.5 276–373
Calcium oxide CaO 56.08 c 2 K 41.84 2.03 ⫺4.52 ⫻ 1010 273–1173
Carbon C 12.01 c 2 K 11.18 1.095 ⫺4.891 ⫻ 1010 273–1373
Carbon dioxide CO2 44.01 g 1 ⬚C 36.11 4.233 ⫺2.887 7.464 0–1500

Physical Property Tables

Carbon monoxide CO 28.01 g 1 ⬚C 28.95 0.4110 0.3548 ⫺2.220 0–1500
Carbon tetrachloride CCl4 153.84 l 1 K 93.39 12.98 273–343
Chlorine Cl2 70.91 g 1 ⬚C 33.60 1.367 ⫺1.607 6.473 0–1200
Copper Cu 63.54 c 1 K 22.76 0.6117 273–1357
a
Adapted in part from D. M. Himmelblau, Basic Principles and Calculations in Chemical Engineering, 3rd Edition, 䉷 1974, Table E.1. Adapted by
permission of Prentice-Hall, Inc., Englewood Cliffs, NJ.
(continued )
635
 636 Appendix B
Table B.2 (Continued)

Range
Mol. Temp. (Units
Compound Formula Wt. State Form Unit a ⫻ 103 b ⫻ 105 c ⫻ 108 d ⫻ 1012 of T )

Cumene C9 H12 120.19 g 1 ⬚C 139.2 53.76 ⫺39.79 120.5 0–1200

(Isopropyl benzene)
Cyclohexane C6 H12 84.16 g 1 ⬚C 94.140 49.62 ⫺31.90 80.63 0–1200
Cyclopentane C5 H10 70.13 g 1 ⬚C 73.39 39.28 ⫺25.54 68.66 0–1200
Ethane C 2 H6 30.07 g 1 ⬚C 49.37 13.92 ⫺5.816 7.280 0–1200
Ethyl alcohol C2 H5 OH 46.07 l 1 ⬚C 103.1 0
(Ethanol) l 1 ⬚C 158.8 100
g 1 ⬚C 61.34 15.72 ⫺8.749 19.83 0–1200
Ethylene C 2 H4 28.05 g 1 ⬚C Ⳮ40.75 11.47 ⫺6.891 17.66 0–1200
Ferric oxide Fe2 O3 159.70 c 2 K 103.4 6.711 ⫺17.72 ⫻ 1010 — 273–1097
Formaldehyde CH2 O 30.03 g 1 ⬚C 34.28 4.268 0.0000 ⫺8.694 0–1200
Helium He 4.00 g 1 ⬚C 20.8 0–1200
n -Hexane C6 H14 86.17 l 1 ⬚C 216.3 20–100
g 1 ⬚C 137.44 40.85 ⫺23.92 57.66 0–1200
Hydrogen H2 2.016 g 1 ⬚C 28.84 0.00765 0.3288 ⫺0.8698 0–1500
Hydrogen bromide HBr 80.92 g 1 ⬚C 29.10 ⫺0.0227 0.9887 ⫺4.858 0–1200
Hydrogen chloride HCl 36.47 g 1 ⬚C 29.13 ⫺0.1341 0.9715 ⫺4.335 0–1200
Hydrogen cyanide HCN 27.03 g 1 ⬚C 35.3 2.908 1.092 0–1200
Hydrogen sulfide H2 S 34.08 g 1 ⬚C 33.51 1.547 0.3012 ⫺3.292 0–1500
Magnesium chloride MgCl2 95.23 c 1 K 72.4 1.58 273–991
Magnesium oxide MgO 40.32 c 2 K 45.44 0.5008 ⫺8.732 ⫻ 10 10
273–2073
Methane CH4 16.04 g 1 ⬚C 34.31 5.469 0.3661 ⫺11.00 0–1200
g 1 K 19.87 5.021 1.268 ⫺11.00 273–1500
Methyl alcohol CH3 OH 32.04 l 1 ⬚C 75.86 16.83 0–65
(Methanol) g 1 ⬚C 42.93 8.301 ⫺1.87 ⫺8.03 0–700
Methyl cyclohexane C7 H14 98.18 g 1 ⬚C 121.3 56.53 ⫺37.72 100.8 0–1200
Methyl cyclopentane C6 H12 84.16 g 1 ⬚C 98.83 45.857 ⫺30.44 83.81 0–1200
Nitric acid NHO3 63.02 l 1 ⬚C 110.0 25
Nitric oxide NO 30.01 g 1 ⬚C 29.50 0.8188 ⫺0.2925 0.3652 0–3500
Nitrogen N2 28.02 g 1 ⬚C 29.00 0.2199 0.5723 ⫺2.871 0–1500
Nitrogen dioxide NO2 46.01 g 1 ⬚C 36.07 3.97 ⫺2.88 7.87 0–1200
Nitrogen tetraoxide N2 O4 92.02 g 1 ⬚C 75.7 12.5 ⫺11.3 0–300
Nitrous oxide N2 O 44.02 g 1 ⬚C 37.66 4.151 ⫺2.694 10.57 0–1200
Oxygen O2 32.00 g 1 ⬚C 29.10 1.158 ⫺0.6076 1.311 0–1500
n -Pentane C5 H12 72.15 l 1 ⬚C 155.4 43.68 0–36
g 1 ⬚C 114.8 34.09 ⫺18.99 42.26 0–1200
Propane C 3 H8 44.09 g 1 ⬚C 68.032 22.59 ⫺13.11 31.71 0–1200
Propylene C3 H6 42.08 g 1 ⬚C 59.580 17.71 ⫺10.17 24.60 0–1200
Sodium carbonate Na2 CO3 105.99 c 1 K 121 288–371
Sodium carbonate Na2 CO3 286.15 c 1 K 535.6 298
decahydrate ⭈10H2 O
Sulfur S 32.07 c 1 K 15.2 2.68 273–368
(Rhombic)
c 1 K 18.3 1.84 368–392
(Monoclinic)
Sulfuric acid H2 SO4 98.08 l 1 ⬚C 139.1 15.59 10–45
Sulfur dioxide SO2 64.07 g 1 ⬚C 38.91 3.904 ⫺3.104 8.606 0–1500
Sulfur trioxide SO3 80.07 g 1 ⬚C 48.50 9.188 ⫺8.540 32.40 0–1000
Toluene C7 H8 92.13 l 1 ⬚C 148.8 32.4 0–110
g 1 ⬚C 94.18 38.00 ⫺27.86 80.33 0–1200
Water H2 O 18.016 l 1 ⬚C 75.4 0–100
g 1 ⬚C 33.46 0.6880 0.7604 ⫺3.593 0–1500

Physical Property Tables

637