SAFETY DATA SHEET
Sikasil®-403 Fire
Revision Date 08.04.2025 Version 1.2 Print Date 10.07.2025
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name : Sikasil®-403 Fire
1.2 Relevant identified uses of the substance or mixture and uses advised against
1.3 Details of the supplier of the safety data sheet
Company name of supplier : Sika Qatar LLC
Building 144, Street 2, New Industrial Area
P.O.Box 201847, Doha, State of Qatar
Telephone : +974 4016 3366
Telefax : +974 4016 3370
E-mail address of person :
[email protected] responsible for the SDS
1.4 Emergency telephone number
+974 40163366
SECTION 2: Hazards identification
Type of product : Mixture
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Skin irritation, Category 2 H315: Causes skin irritation.
Eye irritation, Category 2 H319: Causes serious eye irritation.
Skin sensitisation, Category 1 H317: May cause an allergic skin reaction.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms :
Signal word : Warning
Hazard statements : H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
Precautionary statements :
Prevention:
P261 Avoid breathing mist or vapours.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face pro-
tection.
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Response:
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 + P364 Take off contaminated clothing and wash it
before reuse.
Hazardous components which must be listed on the label:
butan-2-one O,O',O''-(methylsilylidyne)trioxime
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumula-
tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher.
None known.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Components
Chemical name CAS-No. Classification Concentration
EC-No. (% w/w)
Registration number
Polysiloxanediol 70131-67-8 Skin Irrit. 2; H315 >= 40 - < 60
Not Assigned Eye Irrit. 2; H319
butan-2-one O,O',O''- 22984-54-9 Eye Irrit. 2; H319 >= 2,5 - < 5
(methylsilylidyne)trioxime 245-366-4 Skin Sens. 1; H317
01-2119970560-38- STOT RE 2; H373
XXXX
For explanation of abbreviations see section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice : Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
If inhaled : Move to fresh air.
Consult a physician after significant exposure.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.
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SAFETY DATA SHEET
Sikasil®-403 Fire
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In case of eye contact : Immediately flush eye(s) with plenty of water.
Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Do not induce vomiting without medical advice.
Rinse mouth with water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Allergic reactions
Excessive lachrymation
Erythema
Dermatitis
See Section 11 for more detailed information on health effects
and symptoms.
Risks : irritant effects
sensitising effects
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media : In case of fire, use water/water spray/water jet/carbon diox-
ide/sand/foam/alcohol resistant foam/chemical powder for
extinction.
5.2 Special hazards arising from the substance or mixture
Hazardous combustion prod- : No hazardous combustion products are known
ucts
5.3 Advice for firefighters
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters
Further information : Standard procedure for chemical fires.
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SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Use personal protective equipment.
Deny access to unprotected persons.
6.2 Environmental precautions
Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
6.4 Reference to other sections
For personal protection see section 8.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Advice on safe handling : Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitisation problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Follow standard hygiene measures when handling chemical
products
Advice on protection against : Normal measures for preventive fire protection.
fire and explosion
Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. When using do not eat or drink. When using do not
smoke. Wash hands before breaks and at the end of workday.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage : Keep container tightly closed in a dry and well-ventilated
areas and containers place. Store in accordance with local regulations.
Further information on stor- : No decomposition if stored and applied as directed.
age stability
7.3 Specific end use(s)
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Specific use(s) : Consult most current local Product Data Sheet prior to any
use.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational Exposure Limits
Contains no substances with occupational exposure limit values.
Occupational exposure limits of decomposition products
Components CAS-No. Value type (Form Control parameters Basis
of exposure)
acetic acid 64-19-7 TWA 10 ppm 2017/164/EU
25 mg/m3
Further information: Indicative
STEL 20 ppm 2017/164/EU
50 mg/m3
8.2 Exposure controls
Engineering measures
Maintain air concentrations below occupational exposure standards.
Ensure adequate ventilation, especially in confined areas.
Personal protective equipment
Eye/face protection : Safety glasses with side-shields conforming to EN166
Eye wash bottle with pure water
Hand protection : Chemical-resistant, impervious gloves complying with an ap-
proved standard must be worn at all times when handling
chemical products. Reference number EN 374. Follow manu-
facturer specifications.
Suitable for short time use or protection against splashes:
Butyl rubber/nitrile rubber gloves (> 0,1 mm)
Contaminated gloves should be removed.
Suitable for permanent exposure:
Viton gloves (0.4 mm),
breakthrough time >30 min.
Skin and body protection : Protective clothing (e.g. Safety shoes acc. to EN ISO 20345,
long-sleeved working clothing, long trousers). Rubber aprons
and protective boots are additionaly recommended for mixing
and stirring work.
Respiratory protection : No special measures required.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state : liquid
Appearance : paste
Colour : various
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SAFETY DATA SHEET
Sikasil®-403 Fire
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Odour : characteristic
Melting point/ range / Freez- : No data available
ing point
Boiling point/boiling range : No data available
Flammability (solid, gas) : No data available
Upper/lower flammability or explosive limits
Upper explosion limit / Up- : No data available
per flammability limit
Lower explosion limit / : No data available
Lower flammability limit
Flash point : Not applicable
Auto-ignition temperature : No data available
Decomposition temperature : No data available
pH : No data available
Viscosity
Viscosity, kinematic : No data available
Solubility(ies)
Water solubility : No data available
Partition coefficient: n- : No data available
octanol/water
Vapour pressure : 0,01 hPa
Density : ca. 1,2 g/cm3 (23 °C)
Relative vapour density : No data available
Particle characteristics : No data available
9.2 Other information
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
The product is chemically stable.
10.3 Possibility of hazardous reactions
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SAFETY DATA SHEET
Sikasil®-403 Fire
Revision Date 08.04.2025 Version 1.2 Print Date 10.07.2025
Hazardous reactions : No hazards to be specially mentioned.
10.4 Conditions to avoid
Conditions to avoid : No data available
10.5 Incompatible materials
Materials to avoid : No data available
10.6 Hazardous decomposition products
Hazardous decomposition : acetic acid, acetic anhydride, butanone oxime
products
SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity
Not classified based on available information.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
Skin sensitisation
May cause an allergic skin reaction.
Respiratory sensitisation
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
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SAFETY DATA SHEET
Sikasil®-403 Fire
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11.2 Information on other hazards
Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components consid-
ered to have endocrine disrupting properties according to
REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.
SECTION 12: Ecological information
12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..
12.6 Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components consid-
ered to have endocrine disrupting properties according to
REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.
12.7 Other adverse effects
Product:
Additional ecological infor- : There is no data available for this product.
mation
SECTION 13: Disposal considerations
13.1 Waste treatment methods
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Product : The generation of waste should be avoided or minimized
wherever possible.
Empty containers or liners may retain some product residues.
This material and its container must be disposed of in a safe
way.
Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor.
Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.
Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.
SECTION 14: Transport information
14.1 UN number or ID number
ADR : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA : Not regulated as a dangerous good
14.2 UN proper shipping name
ADR : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA : Not regulated as a dangerous good
14.3 Transport hazard class(es)
ADR : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA : Not regulated as a dangerous good
14.4 Packing group
ADR : Not regulated as a dangerous good
IMDG : Not regulated as a dangerous good
IATA (Cargo) : Not regulated as a dangerous good
IATA (Passenger) : Not regulated as a dangerous good
14.5 Environmental hazards
Not regulated as a dangerous good
14.6 Special precautions for user
Not applicable
14.7 Maritime transport in bulk according to IMO instruments
Not applicable for product as supplied.
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Sikasil®-403 Fire
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SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
International Chemical Weapons Convention (CWC) : Not applicable
Schedules of Toxic Chemicals and Precursors
REACH Information: All substances contained in our Products are
- registered by our upstream suppliers, and/or
- registered by us, and/or
- excluded from the regulation, and/or
- exempted from the registration.
REACH - Restrictions on the manufacture, placing on : Conditions of restriction for the fol-
the market and use of certain dangerous substances, lowing entries should be considered:
mixtures and articles (Annex XVII) Number on list 3
REACH - Candidate List of Substances of Very High : None of the components are listed
Concern for Authorisation (Article 59). (=> 0.1 %).
REACH - List of substances subject to authorisation : Not applicable
(Annex XIV)
Regulation (EU) No 2024/590 on substances that de- : Not applicable
plete the ozone layer
Regulation (EU) 2019/1021 on persistent organic pollu- : Not applicable
tants (recast)
Regulation (EU) No 649/2012 of the European Parlia- : Not applicable
ment and the Council concerning the export and import
of dangerous chemicals
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.
Not applicable
Volatile organic compounds : Law on the incentive tax for volatile organic compounds
(VOCV)
no VOC duties
Directive 2010/75/EU of 24 November 2010 on industrial and
livestock rearing emissions (integrated pollution prevention
and control)
Not applicable
15.2 Chemical safety assessment
No Chemical Safety Assessment has been carried out for this mixture by the supplier.
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SAFETY DATA SHEET
Sikasil®-403 Fire
Revision Date 08.04.2025 Version 1.2 Print Date 10.07.2025
SECTION 16: Other information
Full text of H-Statements
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H319 : Causes serious eye irritation.
H373 : May cause damage to organs through prolonged or repeated
exposure.
Full text of other abbreviations
Eye Irrit. : Eye irritation
Skin Irrit. : Skin irritation
Skin Sens. : Skin sensitisation
STOT RE : Specific target organ toxicity - repeated exposure
2017/164/EU : Europe. Commission Directive 2017/164/EU establishing a
fourth list of indicative occupational exposure limit values
2017/164/EU / STEL : Short term exposure limit
2017/164/EU / TWA : Limit Value - eight hours
ADR : European Agreement concerning the International Carriage of
Dangerous Goods by Road
CAS : Chemical Abstracts Service
DNEL : Derived no-effect level
EC50 : Half maximal effective concentration
GHS : Globally Harmonized System
IATA : International Air Transport Association
IMDG : International Maritime Code for Dangerous Goods
LD50 : Median lethal dosis (the amount of a material, given all at
once, which causes the death of 50% (one half) of a group of
test animals)
LC50 : Median lethal concentration (concentrations of the chemical in
air that kills 50% of the test animals during the observation
period)
MARPOL : International Convention for the Prevention of Pollution from
Ships, 1973 as modified by the Protocol of 1978
OEL : Occupational Exposure Limit
PBT : Persistent, bioaccumulative and toxic
PNEC : Predicted no effect concentration
REACH : Regulation (EC) No 1907/2006 of the European Parliament
and of the Council of 18 December 2006 concerning the Reg-
istration, Evaluation, Authorisation and Restriction of Chemi-
cals (REACH), establishing a European Chemicals Agency
SVHC : Substances of Very High Concern
vPvB : Very persistent and very bioaccumulative
Further information
Classification of the mixture: Classification procedure:
Skin Irrit. 2 H315 Calculation method
Eye Irrit. 2 H319 Calculation method
Skin Sens. 1 H317 Calculation method
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SAFETY DATA SHEET
Sikasil®-403 Fire
Revision Date 08.04.2025 Version 1.2 Print Date 10.07.2025
The information contained in this Safety Data Sheet corresponds to our level of knowledge at
the time of publication. All warranties are excluded. Our most current General Sales Condi-
tions shall apply. Please consult the product data sheet prior to any use and processing.
Changes as compared to previous version !
QA / EN
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