SAFETY DATA SHEET

According to OSHA Hazard Communication Standard, 29 CFR

1910.1200

Version 2.0 Revision Date: 04/29/2015 Print Date: 05/21/2015

SECTION 1. IDENTIFICATION

Product name : Shell Diala S2 ZX-A

Product code : 001D8374

Manufacturer or supplier's details
Manufacturer/Supplier : Shell Oil Products US
P.O. Box 4427
Houston TX 77210-4427
USA
SDS Request : (+1) 877-276-7285
Customer Service :

Emergency telephone number

Spill Information : 877-504-9351
Health Information : 877-242-7400

Recommended use of the chemical and restrictions on use

Recommended use : Insulating oil.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Aspiration hazard : Category 1

Chronic aquatic toxicity : Category 3

GHS Label element

Hazard pictograms :

Signal word : Danger

Hazard statements : PHYSICAL HAZARDS:

Not classified as a physical hazard under GHS criteria.
HEALTH HAZARDS:
H304 May be fatal if swallowed and enters airways.
ENVIRONMENTAL HAZARDS:
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements : Prevention:

P273 Avoid release to the environment.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P331 Do NOT induce vomiting.
Storage:
P405 Store locked up.
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Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Hazardous components which must be listed on the label:

Contains Distillates (petroleum), hydrotreated light naphthenic.

Other hazards which do not result in classification

Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin result-
ing in disorders such as oil acne/folliculitis.
Used oil may contain harmful impurities.
Not classified as flammable but will burn.

The classification of this material is based on OSHA HCS 2012 criteria.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : Highly refined mineral oils and additives.

The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346.

Hazardous components
Chemical Name Synonyms CAS-No. Concentration (%)
Distillates (petroleum), Distillates (petro- 64742-53-6 95 - 100
hydrotreated light naph- leum), hydrotreated
thenic light naphthenic
Butylated hydroxytoluene 2,6-di-tert-butyl-p- 128-37-0 0.25 - 0.5
cresol

SECTION 4. FIRST-AID MEASURES

If inhaled : No treatment necessary under normal conditions of use.

If symptoms persist, obtain medical advice.

In case of skin contact : Remove contaminated clothing. Flush exposed area with wa-
ter and follow by washing with soap if available.
If persistent irritation occurs, obtain medical attention.

In case of eye contact : Flush eye with copious quantities of water.

If persistent irritation occurs, obtain medical attention.

If swallowed : If swallowed, do not induce vomiting: transport to nearest

medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical facili-
ty: fever greater than 101° F (38.3°C), shortness of breath,
chest congestion or continued coughing or wheezing.

Most important symptoms : If material enters lungs, signs and symptoms may include
and effects, both acute and coughing, choking, wheezing, difficulty in breathing, chest
delayed congestion, shortness of breath, and/or fever.
The onset of respiratory symptoms may be delayed for sever-
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al hours after exposure.

Defatting dermatitis signs and symptoms may include a burn-
ing sensation and/or a dried/cracked appearance.
Ingestion may result in nausea, vomiting and/or diarrhoea.

Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.

Immediate medical attention, : Treat symptomatically.

special treatment Call a doctor or poison control center for guidance.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon dio-
xide, sand or earth may be used for small fires only.

Unsuitable extinguishing : Do not use water in a jet.

media

Specific hazards during fire- : Hazardous combustion products may include:

fighting A complex mixture of airborne solid and liquid particulates and
gases (smoke).
Carbon monoxide may be evolved if incomplete combustion
occurs.
Unidentified organic and inorganic compounds.

Specific extinguishing me- : Use extinguishing measures that are appropriate to local cir-
thods cumstances and the surrounding environment.

Special protective equipment : Proper protective equipment including chemical resistant

for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Avoid contact with skin and eyes.

tive equipment and emer-
gency procedures

Environmental precautions : Use appropriate containment to avoid environmental contami-

nation. Prevent from spreading or entering drains, ditches or
rivers by using sand, earth, or other appropriate barriers.

Local authorities should be advised if significant spillages

cannot be contained.

Methods and materials for : Slippery when spilt. Avoid accidents, clean up immediately.
containment and cleaning up Prevent from spreading by making a barrier with sand, earth
or other containment material.
Reclaim liquid directly or in an absorbent.
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Soak up residue with an absorbent such as clay, sand or other

suitable material and dispose of properly.

Additional advice : For guidance on selection of personal protective equipment

see Chapter 8 of this Safety Data Sheet.
For guidance on disposal of spilled material see Chapter 13 of
this Safety Data Sheet.

SECTION 7. HANDLING AND STORAGE

Technical measures : Use local exhaust ventilation if there is risk of inhalation of

vapours, mists or aerosols.
Use the information in this data sheet as input to a risk as-
sessment of local circumstances to help determine appropri-
ate controls for safe handling, storage and disposal of this
material.

Precautions for safe handling : Avoid prolonged or repeated contact with skin.
Avoid inhaling vapour and/or mists.
When handling product in drums, safety footwear should be
worn and proper handling equipment should be used.
Properly dispose of any contaminated rags or cleaning mate-
rials in order to prevent fires.

Avoidance of contact : Strong oxidising agents.

Product Transfer : This material has the potential to be a static accumulator.

Proper grounding and bonding procedures should be used
during all bulk transfer operations.

Storage
Other data : Keep container tightly closed and in a cool, well-ventilated
place.
Use properly labeled and closable containers.

Store at ambient temperature.

Packaging material : Suitable material: For containers or container linings, use mild
steel or high density polyethylene.
Unsuitable material: PVC.

Container Advice : Polyethylene containers should not be exposed to high tem-

peratures because of possible risk of distortion.

SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
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exposure) concentration
Oil mist, mineral Not Assigned TWA ((inhal- 5 mg/m3 US. ACGIH
able frac- Threshold
tion)) Limit Values
(Mist) 5 mg/m3 OSHA_TRA
NS
Biological occupational exposure limits
No biological limit allocated.
Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure con-
trols. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and sam-
ples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or con-
tact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
[Link]
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
[Link]
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
[Link]
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
[Link]
L'Institut National de Recherche et de Securité, (INRS), France [Link]
Engineering measures : The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
Adequate ventilation to control airborne concentrations.

Where material is heated, sprayed or mist formed, there is

greater potential for airborne concentrations to be generated.

General Information:
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control meas-
ures relevant to normal activities associated with this product.
Ensure appropriate selection, testing and maintenance of
equipment used to control exposure, e.g. personal protective
equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or mainten-
ance.
Retain drain downs in sealed storage pending disposal or
subsequent recycle.
Always observe good personal hygiene measures, such as
washing hands after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard con-
taminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.

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Personal protective equipment

Respiratory protection : No respiratory protection is ordinarily required under normal
conditions of use.
In accordance with good industrial hygiene practices, precau-
tions should be taken to avoid breathing of material.
If engineering controls do not maintain airborne concentra-
tions to a level which is adequate to protect worker health,
select respiratory protection equipment suitable for the spe-
cific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are suitable, select an appro-
priate combination of mask and filter.
Select a filter suitable for the combination of organic gases
and vapours [Type A/Type P boiling point >65°C (149°F)].

Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. PVC, neoprene or nitrile rubber
gloves Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical re-
sistance of glove material, dexterity. Always seek advice from
glove suppliers. Contaminated gloves should be replaced.
Personal hygiene is a key element of effective hand care.
Gloves must only be worn on clean hands. After using
gloves, hands should be washed and dried thoroughly. Appli-
cation of a non-perfumed moisturizer is recommended.
For continuous contact we recommend gloves with break-
through time of more than 240 minutes with preference for >
480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same, but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Glove thickness should be typically greater than 0.35 mm
depending on the glove make and model.

Eye protection : If material is handled such that it could be splashed into eyes,
protective eyewear is recommended.

Skin and body protection : Skin protection is not ordinarily required beyond standard
work clothes.
It is good practice to wear chemical resistant gloves.

Protective measures : Personal protective equipment (PPE) should meet recom-

mended national standards. Check with PPE suppliers.

Environmental exposure controls

General advice : Take appropriate measures to fulfill the requirements of rele-
vant environmental protection legislation. Avoid contamination
of the environment by following advice given in Chapter 6. If

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According to OSHA Hazard Communication Standard, 29 CFR
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necessary, prevent undissolved material from being dis-

charged to waste water. Waste water should be treated in a
municipal or industrial waste water treatment plant before
discharge to surface water.
Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid at room temperature.

Colour : clear

Odour : Slight hydrocarbon

Odour Threshold : Data not available

pH : Not applicable

pour point : -57 °C / -71 °FMethod: ASTM D97

Initial boiling point and boiling : > 280 °C / 536 °Festimated value(s)
range

Flash point : 150 °C / 302 °F

Method: ASTM D92

Evaporation rate : Data not available

Flammability (solid, gas) : Data not available

Upper explosion limit : Typical 10 %(V)

Lower explosion limit : Typical 1 %(V)

Vapour pressure : < 0.5 Pa (20 °C / 68 °F)

estimated value(s)

Relative vapour density : > 1estimated value(s)

Relative density : 0.890 (15 °C / 59 °F)

Density : 890 kg/m3 (15.0 °C / 59.0 °F)

Method: ASTM D1298

Solubility(ies)
Water solubility : negligible

Solubility in other solvents : Data not available

Partition coefficient: n- : Pow: > 6(based on information on similar products)

octanol/water

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Auto-ignition temperature : >

320 °C / 608 °F

Viscosity
Viscosity, dynamic : Data not available

Viscosity, kinematic : 60 mm2/s (0 °C / 32 °F)

Method: ASTM D445

2.2 mm2/s (100 °C / 212 °F)

Method: ASTM D445

9 mm2/s (40.0 °C / 104.0 °F)

Method: ASTM D445

Conductivity : This material is not expected to be a static accumulator.

Decomposition temperature : Data not available

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : Stable.

Possibility of hazardous reac- : Reacts with strong oxidising agents.

tions

Conditions to avoid : Extremes of temperature and direct sunlight.

Incompatible materials : Strong oxidising agents.

Hazardous decomposition : Hazardous decomposition products are not expected to form

products during normal storage.

SECTION 11. TOXICOLOGICAL INFORMATION

Basis for assessment : Information given is based on data on the components and
the toxicology of similar [Link] indicated otherwise,
the data presented is representative of the product as a
whole, rather than for individual component(s).

Information on likely routes of exposure

Skin and eye contact are the primary routes of exposure although exposure may occur following
accidental ingestion.
Acute toxicity

Product:
Acute oral toxicity : LD50 (rat): > 5,000 mg/kg
Remarks: Expected to be of low toxicity:

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Remarks: Aspiration into the lungs may cause chemical

pneumonitis which can be fatal.

Acute inhalation toxicity : Remarks: Not considered to be an inhalation hazard under

normal conditions of use.

Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg

Remarks: Expected to be of low toxicity:

Skin corrosion/irritation

Product:
Remarks: Expected to be slightly irritating., Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis.

Serious eye damage/eye irritation

Product:
Remarks: Expected to be slightly irritating.

Respiratory or skin sensitisation

Product:
Remarks: Not expected to be a skin sensitiser.

Germ cell mutagenicity

Product:
: Remarks: Not considered a mutagenic hazard.

Carcinogenicity

Product:
Remarks: Not expected to be carcinogenic.

Remarks: Product contains mineral oils of types shown to be non-carcinogenic in animal skin-
painting studies., Highly refined mineral oils are not classified as carcinogenic by the Internation-
al Agency for Research on Cancer (IARC).

IARC No component of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

ACGIH No component of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential carcino-
gen by ACGIH.

OSHA No component of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential carcino-
gen by OSHA.

NTP No component of this product present at levels greater than or

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equal to 0.1% is identified as a known or anticipated carcinogen

by NTP.

Reproductive toxicity

Product:
:
Remarks: Not expected to impair fertility., Not expected to be
a developmental toxicant.

STOT - single exposure

Product:
Remarks: Not expected to be a hazard.

STOT - repeated exposure

Product:
Remarks: Not expected to be a hazard.

Aspiration toxicity

Product:
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which
can be fatal.

Further information

Product:
Remarks: Used oils may contain harmful impurities that have accumulated during use. The con-
centration of such impurities will depend on use and they may present risks to health and the
environment on disposal., ALL used oil should be handled with caution and skin contact avoided
as far as possible.

Remarks: Slightly irritating to respiratory system.

SECTION 12. ECOLOGICAL INFORMATION

Basis for assessment : Ecotoxicological data have not been determined specifically
for this product.
Information given is based on a knowledge of the components
and the ecotoxicology of similar products.
Unless indicated otherwise, the data presented is representa-
tive of the product as a whole, rather than for individual com-
ponent(s).(LL/EL/IL50 expressed as the nominal amount of
product required to prepare aqueous test extract).
Ecotoxicity

Product:
Toxicity to fish (Acute toxic- :
ity) Remarks: Expected to be harmful:
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LL/EL/IL50 10-100 mg/l

Toxicity to daphnia and other :

aquatic invertebrates (Acute Remarks: Expected to be harmful:
toxicity) LL/EL/IL50 10-100 mg/l

Toxicity to algae (Acute toxic- :

ity) Remarks: Expected to be harmful:
LL/EL/IL50 10-100 mg/l

Toxicity to fish (Chronic toxic- : Remarks: Data not available

ity)

Toxicity to daphnia and other : Remarks: Data not available

aquatic invertebrates (Chron-
ic toxicity)

Toxicity to bacteria (Acute : Remarks: Data not available

toxicity)

Components:
Butylated hydroxytoluene:
M-Factor (Acute aquatic tox- : 1
icity)

Persistence and degradability

Product:
Biodegradability : Remarks: Expected to be not readily biodegradable.
Major constituents are expected to be inherently biodegrada-
ble, but contains components that may persist in the environ-
ment.

Bioaccumulative potential

Product:
Bioaccumulation : Remarks: Contains components with the potential to bioac-
cumulate.

Mobility in soil

Product:
Mobility : Remarks: Liquid under most environmental conditions.
If it enters soil, it will adsorb to soil particles and will not be
mobile.

Remarks: Floats on water.

Other adverse effects

no data available
Product:
Additional ecological informa- : Product is a mixture of non-volatile components, which are not

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tion expected to be released to air in any significant quantities.

Not expected to have ozone depletion potential, photochemi-
cal ozone creation potential or global warming potential.

Poorly soluble mixture.

May cause physical fouling of aquatic organisms.

Mineral oil is not expected to cause any chronic effects to

aquatic organisms at concentrations less than 1 mg/l.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Recover or recycle if possible.
It is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to
determine the proper waste classification and disposal me-
thods in compliance with applicable regulations.
Do not dispose into the environment, in drains or in water
courses

Contaminated packaging : Dispose in accordance with prevailing regulations, preferably

to a recognized collector or contractor. The competence of
the collector or contractor should be established beforehand.
Disposal should be in accordance with applicable regional,
national, and local laws and regulations.

Local legislation
Remarks : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.

SECTION 14. TRANSPORT INFORMATION

National Regulations

US Department of Transportation Classification (49 CFR Parts 171-180)

Not regulated as a dangerous good
International Regulation

IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution category : Not applicable
Ship type : Not applicable
Product name : Not applicable
Special precautions : Not applicable
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Special precautions for user

Remarks : Special Precautions: Refer to Chapter 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.

Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea.

SECTION 15. REGULATORY INFORMATION

OSHA Hazards : Aspiration hazard

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ., Shell classifies this material
as an "oil" under the CERCLA Petroleum Exclusion, therefore releases to the environment are not
reportable under CERCLA.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Immediate (Acute) Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting

requirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Clean Water Act

This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
Pennsylvania Right To Know
Distillates (petroleum), hydrotreated light 64742-53-6
naphthenic

California Prop 65 This product does not contain any chemicals known to State
of California to cause cancer, birth defects, or any other re-
productive harm.
The components of this product are reported in the following inventories:
EINECS : All components listed or polymer exempt.

TSCA : All components listed.

DSL : All components listed.

SECTION 16. OTHER INFORMATION

Further information

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NFPA Rating (Health, Fire, Reac- 1, 1, 0

tivity)

Due to the conversion of this product to GHS classification and labelling, there has been a
significant change to the nature of the information presented in chapter 2.
A vertical bar (|) in the left margin indicates an amendment from the previous version.
Abbreviations and Acronyms : The standard abbreviations and acronyms used in this docu-
ment can be looked up in reference literature (e.g. scientific
dictionaries) and/or websites.

ACGIH = American Conference of Governmental Industrial

Hygienists
ADR = European Agreement concerning the International
Carriage of Dangerous Goods by Road
AICS = Australian Inventory of Chemical Substances
ASTM = American Society for Testing and Materials
BEL = Biological exposure limits
BTEX = Benzene, Toluene, Ethylbenzene, Xylenes
CAS = Chemical Abstracts Service
CEFIC = European Chemical Industry Council
CLP = Classification Packaging and Labelling
COC = Cleveland Open-Cup
DIN = Deutsches Institut fur Normung
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
DSL = Canada Domestic Substance List
EC = European Commission
EC50 = Effective Concentration fifty
ECETOC = European Center on Ecotoxicology and Toxicolo-
gy Of Chemicals
ECHA = European Chemicals Agency
EINECS = The European Inventory of Existing Commercial
Chemical Substances
EL50 = Effective Loading fifty
ENCS = Japanese Existing and New Chemical Substances
Inventory
EWC = European Waste Code
GHS = Globally Harmonised System of Classification and
Labelling of Chemicals
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IC50 = Inhibitory Concentration fifty
IL50 = Inhibitory Level fifty
IMDG = International Maritime Dangerous Goods
INV = Chinese Chemicals Inventory
IP346 = Institute of Petroleum test method N° 346 for the
determination of polycyclic aromatics DMSO-extractables
KECI = Korea Existing Chemicals Inventory
LC50 = Lethal Concentration fifty
LD50 = Lethal Dose fifty per cent.
LL/EL/IL = Lethal Loading/Effective Loading/Inhibitory loading
LL50 = Lethal Loading fifty
MARPOL = International Convention for the Prevention of
Pollution From Ships
NOEC/NOEL = No Observed Effect Concentration / No Ob-

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served Effect Level

OE_HPV = Occupational Exposure - High Production Volume
PBT = Persistent, Bioaccumulative and Toxic
PICCS = Philippine Inventory of Chemicals and Chemical
Substances
PNEC = Predicted No Effect Concentration
REACH = Registration Evaluation And Authorisation Of
Chemicals
RID = Regulations Relating to International Carriage of Dan-
gerous Goods by Rail
SKIN_DES = Skin Designation
STEL = Short term exposure limit
TRA = Targeted Risk Assessment
TSCA = US Toxic Substances Control Act
TWA = Time-Weighted Average
vPvB = very Persistent and very Bioaccumulative

Revision Date : 04/29/2015

This information is based on our current knowledge and is intended to describe the product for
the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

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