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SW 946

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0% found this document useful (0 votes)
14 views14 pages

SW 946

Uploaded by

paulhoang.itm
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Version: 1.

1
Revision Date: 01/02/2020

SAFETY DATA SHEET


1. Identification

Product identifier: Sprayway 946 Silicone Spray

Other means of identification


SDS number: RE1000007771

Recommended restrictions
Product Use: Lubricant
Restrictions on use: Not known.

Manufacturer/Importer/Distributor Information

Manufacturer

Company Name: Sprayway, Inc.


Address: 1000 INTEGRAM DR.
Pacific, MO 63069
Telephone: 1-630-628-3000
Fax:

Emergency telephone number: 1-866-836-8855

2. Hazard(s) identification

Hazard Classification
Physical Hazards
Flammable aerosol Category 1
Health Hazards
Aspiration Hazard Category 1

Label Elements

Hazard Symbol:

Signal Word: Danger

Hazard Statement: Extremely flammable aerosol.


May be fatal if swallowed and enters airways.

Precautionary
SDS_US - RE1000007771 1/14
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Statements

Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition
source. Do not pierce or burn, even after use.

Response: IF SWALLOWED: Immediately call a POISON CENTER/doctor Do NOT


induce vomiting.

Storage: Protect from sunlight. Do not expose to temperatures exceeding


50°C/122°F. Store locked up.

Disposal: Dispose of contents/container to an appropriate treatment and disposal


facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.

Hazard(s) not otherwise None.


classified (HNOC):

3. Composition/information on ingredients

Mixtures

Chemical Identity CAS number Content in percent (%)*

Butane 106-97-8 50 - <100%


Propane 74-98-6 20 - <50%
Naphtha (petroleum), heavy 64741-65-7 10 - <20%
alkylate
Siloxanes and Silicones, di-Me 63148-62-9 1 - <5%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures

Ingestion: Rinse mouth. Call a physician or poison control center immediately. Never
give liquid to an unconscious person. If vomiting occurs, keep head low so
that stomach content doesn't get into the lungs.

Inhalation: Move to fresh air.

Skin Contact: Wash skin thoroughly with soap and water. Get medical attention if
symptoms occur.

Eye contact: Any material that contacts the eye should be washed out immediately with
water. If easy to do, remove contact lenses. If eye irritation persists: Get
medical advice/attention.

Most important symptoms/effects, acute and delayed

Symptoms: No data available.

Hazards: No data available.

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Indication of immediate medical attention and special treatment needed

Treatment: No data available.

5. Fire-fighting measures

General Fire Hazards: Use water spray to keep fire-exposed containers cool. Fight fire from a
protected location. Move containers from fire area if you can do so without
risk.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials.


media:

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:

Specific hazards arising from Vapors may travel considerable distance to a source of ignition and flash
the chemical: back.

Special protective equipment and precautions for firefighters

Special fire fighting No data available.


procedures:

Special protective equipment Firefighters must use standard protective equipment including flame
for fire-fighters: retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA.

6. Accidental release measures

Personal precautions, Ventilate closed spaces before entering them. ELIMINATE all ignition
protective equipment and sources (no smoking, flares, sparks or flames in immediate area). Keep
emergency procedures: upwind.

Methods and material for Absorb spill with vermiculite or other inert material, then place in a container
containment and cleaning for chemical waste. Dike far ahead of larger spill for later recovery and
up: disposal.

Notification Procedures: Dike for later disposal. Prevent entry into waterways, sewer, basements or
confined areas. Stop the flow of material, if this is without risk. ELIMINATE
all ignition sources (no smoking, flares, sparks or flames in immediate
area). Stop leak if you can do so without risk.

Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or
spillage if safe to do so.

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Version: 1.1
Revision Date: 01/02/2020

7. Handling and storage

Precautions for safe handling: Wash hands thoroughly after handling. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Do not spray
on an open flame or other ignition source. Do not pierce or burn, even after
use.

Conditions for safe storage, Store locked up. Pressurized container: protect from sunlight and do not
including any expose to temperatures exceeding 50°C. Do not pierce or burn, even after
incompatibilities: use. Aerosol Level 3

8. Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source

Butane REL 800 ppm 1,900 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
STEL 1,000 ppm US. ACGIH Threshold Limit Values (03 2018)
TWA 800 ppm 1,900 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Propane REL 1,000 ppm 1,800 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Naphtha (petroleum), heavy PEL 100 ppm 400 mg/m3 US. OSHA Table Z-1 Limits for Air
alkylate Contaminants (29 CFR 1910.1000) (02 2006)
TWA 100 ppm 400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
REL 100 ppm 400 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2010)

Appropriate Engineering No data available.


Controls

Individual protection measures, such as personal protective equipment

General information: Good general ventilation (typically 10 air changes per hour) should be used.
Ventilation rates should be matched to conditions. Supplementary local
exhaust ventilation, closed systems, or respiratory and eye protection may
be needed in special circumstances, such as poorly ventilated spaces,
heating, evaporation of liquids from large surfaces, spraying of mists,
mechanical generation of dusts, drying of solids, etc.

Eye/face protection: Wear safety glasses with side shields (or goggles).

Skin Protection
Hand Protection: No data available.

Other: Wear suitable protective clothing.

Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from
local supervisor.

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Hygiene measures: Observe good industrial hygiene practices. When using do not smoke.

9. Physical and chemical properties

Appearance
Physical state: liquid
Form: Spray Aerosol
Color: No data available.
Odor: No data available.
Odor threshold: No data available.
pH: No data available.
Melting point/freezing point: No data available.
Initial boiling point and boiling range: No data available.
Flash Point: Estimated -104.4 °C
Evaporation rate: No data available.
Flammability (solid, gas): No data available.
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): Estimated 7 %(V)
Flammability limit - lower (%): Estimated 1 %(V)
Explosive limit - upper (%): No data available.
Explosive limit - lower (%): No data available.
Vapor pressure: No data available.

Vapor density: No data available.


Density: No data available.
Relative density: No data available.
Solubility(ies)
Solubility in water: No data available.
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.

Auto-ignition temperature: No data available.


Decomposition temperature: No data available.
Viscosity: No data available.

10. Stability and reactivity

Reactivity: No data available.

Chemical Stability: Material is stable under normal conditions.

Possibility of hazardous No data available.


reactions:

Conditions to avoid: Avoid heat or contamination.

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Incompatible Materials: No data available.

Hazardous Decomposition No data available.


Products:

11. Toxicological information

Information on likely routes of exposure


Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral
Product: Not classified for acute toxicity based on available data.

Specified substance(s):
Naphtha (petroleum), LD 50: > 2,000 mg/kg
heavy alkylate

Dermal
Product: Not classified for acute toxicity based on available data.

Specified substance(s):
Naphtha (petroleum), LD 50: > 2,000 mg/kg
heavy alkylate

Inhalation
Product:

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Specified substance(s):
Butane LC 50: > 100 mg/l
LC 50: > 100 mg/l

Propane LC 50: > 100 mg/l


LC 50: > 100 mg/l

Naphtha (petroleum), LD 50: > 5 mg/l


heavy alkylate

Repeated dose toxicity


Product: No data available.

Specified substance(s):
Butane LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study
NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
Propane NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study

Skin Corrosion/Irritation
Product: No data available.

Serious Eye Damage/Eye Irritation


Product: No data available.

Respiratory or Skin Sensitization


Product: No data available.

Carcinogenicity
Product: No data available.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:


No carcinogenic components identified

US. National Toxicology Program (NTP) Report on Carcinogens:


No carcinogenic components identified

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):


No carcinogenic components identified

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Germ Cell Mutagenicity

In vitro
Product: No data available.

In vivo
Product: No data available.

Reproductive toxicity
Product: No data available.

Specific Target Organ Toxicity - Single Exposure


Product: No data available.

Specific Target Organ Toxicity - Repeated Exposure


Product: No data available.

Aspiration Hazard
Product: No data available.

Specified substance(s):
Naphtha (petroleum), May be fatal if swallowed and enters airways.
heavy alkylate

Other effects: No data available.

12. Ecological information

Ecotoxicity:

Acute hazards to the aquatic environment:

Fish
Product: No data available.

Specified substance(s):
Butane LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study

Propane LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study

Siloxanes and Silicones, LC 50 (Redear sunfish (Lepomis microlophus), 96 h): 26.27 - 56.73 mg/l
di-Me Mortality

Aquatic Invertebrates
Product: No data available.

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Revision Date: 01/02/2020

Specified substance(s):
Butane LC 50 (Daphnia sp., 48 h): 69.43 mg/l QSAR QSAR, Key study

Siloxanes and Silicones, LC 50 (Water flea (Daphnia magna), 48 h): 44.5 mg/l Mortality
di-Me

Chronic hazards to the aquatic environment:

Fish
Product: No data available.

Aquatic Invertebrates
Product: No data available.

Toxicity to Aquatic Plants


Product: No data available.

Persistence and Degradability

Biodegradation
Product: No data available.

Specified substance(s):
Butane 100 % (385.5 h) Detected in water. Experimental result, Key study

Propane 100 % (385.5 h) Detected in water. Experimental result, Key study


50 % (3.19 d) Detected in water. QSAR, Weight of Evidence study

BOD/COD Ratio
Product: No data available.

Bioaccumulative potential
Bioconcentration Factor (BCF)
Product: No data available.

Partition Coefficient n-octanol / water (log Kow)


Product: No data available.

Mobility in soil: No data available.

Known or predicted distribution to environmental compartments


Butane No data available.
Propane No data available.
Naphtha (petroleum), heavy No data available.
alkylate
Siloxanes and Silicones, di- No data available.
Me

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Other adverse effects: No data available.

13. Disposal considerations

Disposal instructions: Discharge, treatment, or disposal may be subject to national, state, or local
laws.

Contaminated Packaging: No data available.

14. Transport information

DOT

UN Number: UN 1950
UN Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es)
Class: 2.1
Label(s): –
Packing Group: II
Marine Pollutant: No

Environmental Hazards: No
Marine Pollutant No

Special precautions for user: Not regulated.

IMDG
UN Number: UN 1950
UN Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es)
Class: 2
Label(s): –
EmS No.:
Packing Group: –

Environmental Hazards: No
Marine Pollutant No

Special precautions for user: Not regulated.

IATA
UN Number: UN 1950
Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es):
Class: 2.1
Label(s): –
Packing Group: –

Environmental Hazards: No
Marine Pollutant No

Special precautions for user: Not regulated.

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15. Regulatory information

US Federal Regulations

Restrictions on use: Not known.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)


US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
None present or none present in regulated quantities.

CERCLA Hazardous Substance List (40 CFR 302.4):


Chemical Identity Reportable quantity
Butane lbs. 100
Propane lbs. 100

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories
Fire Hazard
Immediate (Acute) Health Hazards
Flammable aerosol
Aspiration Hazard

SARA 302 Extremely Hazardous Substance


None present or none present in regulated quantities.

SARA 304 Emergency Release Notification


Chemical Identity Reportable quantity
Butane lbs. 100
Propane lbs. 100

SARA 311/312 Hazardous Chemical


Chemical Identity Threshold Planning Quantity
Butane 10000 lbs
Propane 10000 lbs
Naphtha (petroleum), 10000 lbs
heavy alkylate
Siloxanes and Silicones, 10000 lbs
di-Me
SARA 313 (TRI Reporting)
None present or none present in regulated quantities.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
US State Regulations

US. California Proposition 65


No ingredient requiring a warning under CA Prop 65.

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Revision Date: 01/02/2020

US. New Jersey Worker and Community Right-to-Know Act


Chemical Identity
Butane
Propane
Naphtha (petroleum), heavy alkylate

US. Massachusetts RTK - Substance List


No ingredient regulated by MA Right-to-Know Law present.

US. Pennsylvania RTK - Hazardous Substances


Chemical Identity
Butane
Propane
Naphtha (petroleum), heavy alkylate

US. Rhode Island RTK


No ingredient regulated by RI Right-to-Know Law present.

International regulations

Montreal protocol
Not applicable

Stockholm convention
Not applicable

Rotterdam convention
Not applicable

Kyoto protocol
Not applicable

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Version: 1.1
Revision Date: 01/02/2020

Inventory Status:
Australia AICS: On or in compliance with the inventory

Canada DSL Inventory List: On or in compliance with the inventory

EINECS, ELINCS or NLP: Not in compliance with the inventory.

Japan (ENCS) List: Not in compliance with the inventory.

China Inv. Existing Chemical Substances: On or in compliance with the inventory

Korea Existing Chemicals Inv. (KECI): On or in compliance with the inventory

Canada NDSL Inventory: Not in compliance with the inventory.

Philippines PICCS: On or in compliance with the inventory

US TSCA Inventory: On or in compliance with the inventory

New Zealand Inventory of Chemicals: On or in compliance with the inventory

Japan ISHL Listing: Not in compliance with the inventory.

Japan Pharmacopoeia Listing: Not in compliance with the inventory.

Mexico INSQ: On or in compliance with the inventory

Ontario Inventory: On or in compliance with the inventory

Taiwan Chemical Substance Inventory: On or in compliance with the inventory

16.Other information, including date of preparation or last revision

Issue Date: 01/02/2020

Revision Information: No data available.

Version #: 1.1

Further Information: No data available.

Disclaimer: This information is provided without warranty. The information is believed to


be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.

SDS_US - RE1000007771 13/14


Version: 1.1
Revision Date: 01/02/2020

SDS_US - RE1000007771 14/14

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