Department of Chemical Engineering
Assignment - 1
Class: TE Chemical Academic Year: 2023-24 Term: I
Subject: Chemical Engineering Thermodynamics Max. Marks: 20
Instructor: Dr M Baingne Date: 24/08/2023
Applicable Course Outcomes (CO):
CO-1: Students will be able to understand fundamentals of solution thermodynamics.
CO-2: Students will be able to understand various aspects of solution thermodynamics.
Instructions:
1. Attempt questions according to the allotted group based on your roll number.
2. Assume suitable data wherever necessary.
Group Roll Number Group Roll Number
1 21CH001 To 21CH011 4 21CH035 To 21CH044
2 21CH012 To 21CH024 5 21CH045 To 22CH306
3 21CH025 To 21CH034 6 22CH307 To 22CH314
Group Questions M CO BL
1. Explain phase rule for non-reacting systems with the help of an 5 1 2
example.
1 2. For N2 gas, the compressibility factor is the function of pressure and 5 2 2
is given by 𝑍 = 1 − 0.0036𝑃. Calculate fugacity of N2 gas at 10
atm and 50 atm.
1. Determine the degree of freedom for the following non-reacting 5 1 2
systems:
(a) A solution of two miscible liquids
2
(b) Two miscible materials in vapour-liquid equilibrium
(c) A mixture of methane and air in contact with a solid adsorbent
(d) Liquid water in equilibrium with water vapour and Nitrogen
(e) A vapour phase containing ammonia and air and a liquid phase
containing ammonia and water
2. Calculate the fugacity of CO at 50 bar and 400 bar if the following 5 2 2
data are applicable at 273 K.
P (bar) 25 50 100 200 400 800 1000
Z 0.989 0.9792 0.9741 1.0196 1.2482 1.8057 2.0819
1. Define chemical potential. Show that chemical potential for a 5 1 2
component must be same in all the phases at equilibrium.
3 2. Determine the fugacity of liquid water at 30℃ and at pressures 10 5 2 3
bar and 100 bar. Given: at 30℃, 𝑃 = 0.0424 bar; molar volume
is 0.01809 m3/kmol.
1. Derive Maxwell Relations from fundamental property relations. 5 1 3
4 2. Define fugacity and fugacity coefficient. Derive the expression for 5 2 3
fugacity in terms of compressibility factor Z.
1. Derive fundamental property relations for closed system. 5 1 3
2. The molar enthalpy of a binary solution at constant T and P is given 5 2 3
by the relation:
ℎ = 500𝑥 + 1000𝑥 + (50𝑥 + 40𝑥 )𝑥 𝑥 where h is in J/mol.
5
Determine
(a) partial molar enthalpies as function of 𝑥
(b) molar enthalpy of pure components
(c) partial molar enthalpy at infinite dilution
1. Write a short note on fugacity of pure liquids. 5 1 2
2. A 30% by mole methanol-water solution is to be prepared. How 5 2 3
many cubic meters of pure methanol (molar volume 40.727×10-6
6 m3/mol) and pure water (molar volume 18.068×10-6 m3/mol) are to
be mixed to prepare 2 m3 of desired solution? The partial molar
volumes of methanol and water in a 30% solution are 38.632×10-6
m3/mol and 17.765×10-6 m3/mol, respectively.
BL – Bloom’s Taxonomy Levels (1 - Remembering, 2 - Understanding, 3 - Applying, 4 - Analysing, 5 -
Evaluating, 6 - Creating)
Subject Teacher Module / PAQIC Coordinator HOD
