Revision date: 09/04/2020 Revision: 8
SAFETY DATA SHEET
TOILET CLEANER & DESCALER
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name TOILET CLEANER & DESCALER
Product number A190 EV
Internal identification Janitorial
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Acidic Descaling Toilet Cleaner and Hard Surface Cleaner for washrooms
1.3. Details of the supplier of the safety data sheet
Supplier Evans Vanodine International plc
Brierley Road
Walton Summit
Preston. UK. PR5 8AH
Tel: 01772 322 200
R and D Lab e-mail:
[email protected]1.4. Emergency telephone number
Emergency telephone New Safety Data Sheets - 01772 322 200 - Mon to Thur 8.30am to 4.30pm - Fri 8.30am to
1.30pm. (Also available 24/7 from our website www.evansvanodine.co.uk) For Technical
Advice about this SDS - 01772 318 818 - Mon to Thu 8.30am to 4.45pm - Fri 8.30am to
1.30pm
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical hazards Not Classified
Health hazards Not Classified
Environmental hazards Not Classified
2.2. Label elements
Hazard statements NC Not Classified
Precautionary statements P102 Keep out of reach of children.
Keep away from other chemicals especially chlorine releasing bleaches as toxic gas will be
evolved.
P301 IF SWALLOWED:
P313 Get medical advice/ attention.
P501 Dispose of contents/ container in accordance with local regulations.
2.3. Other hazards
This product does not contain any substances classified as PBT or vPvB.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
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PHOSPHORIC ACID 3-5%
CAS number: 7664-38-2 EC number: 231-633-2
Spec Conc Limits :- Skin Corr. 1B (H314) ≥ 25%, Skin Irrit. 2 (H315) >10% <25%, Eye Irrit. 2 (H319) >10%
Classification
Skin Corr. 1B - H314
Eye Dam. 1 - H318
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition comments The ingredients are present in non-hazardous concentrations.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation Unlikely route of exposure as the product does not contain volatile substances. If spray/mist
has been inhaled, proceed as follows. Move affected person to fresh air and keep warm and
at rest in a position comfortable for breathing.
Ingestion Do not induce vomiting. Give plenty of water to drink. Get medical attention if any discomfort
continues.
Skin contact Wash with plenty of water.
Eye contact Remove any contact lenses and open eyelids wide apart. Rinse with water.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Inhalation No specific symptoms known.
Ingestion No specific symptoms known. But - May cause discomfort if swallowed.
Skin contact No specific symptoms known. But prolonged or excessively repeated skin contact could lead
to removal of natural oils from skin.
Eye contact No specific symptoms known. Prolonged contact may cause redness and/or tearing.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture
Specific hazards Thermal decomposition or combustion products may include the following substances:
Irritating gases or vapours.
5.3. Advice for firefighters
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions No special protective clothing. (See Sec 8)
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6.2. Environmental precautions
Environmental precautions Spillages or uncontrolled discharges into watercourses must be reported immediately to the
Environmental Agency or other appropriate regulatory body.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Small Spillages: Flush away spillage with plenty of water. Large Spillages: Contain and
absorb spillage with sand, earth or other non-combustible material. Collect and place in
suitable waste disposal containers and seal securely.
6.4. Reference to other sections
Reference to other sections For personal protection, see Section 8.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Usage precautions No specific recommendations.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions Keep only in the original container in a cool, well-ventilated place. Store away from the
following materials: Oxidising materials. (eg Hypochlorite / Bleach)
7.3. Specific end use(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2.
Usage description See Product Information Sheet & Label for detailed use of this product.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters
Occupational exposure limits
PHOSPHORIC ACID
Long-term exposure limit (8-hour TWA): WEL 1 mg/m³
Short-term exposure limit (15-minute): WEL 2 mg/m³
WEL = Workplace Exposure Limit.
8.2. Exposure controls
Appropriate engineering Not relevant.
controls
Eye/face protection No specific eye protection required during normal use.
Hand protection Hand protection not required.
Other skin and body None required.
protection
Respiratory protection Respiratory protection not required.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance Viscous liquid.
Colour Clear. Green.
Odour Pine.
pH pH (concentrated solution): 1.30
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Melting point -1°C
Initial boiling point and range 101°C @ 760 mm Hg
Flash point Boils without flashing.
Relative density 1.025 @ 20°C
Solubility(ies) Soluble in water.
9.2. Other information
Other information None.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity Reacts with alkalis and generates heat.
10.2. Chemical stability
Stability No particular stability concerns.
10.3. Possibility of hazardous reactions
Possibility of hazardous See sections 10.1,10.4 & 10.5
reactions
10.4. Conditions to avoid
Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.
10.5. Incompatible materials
Materials to avoid Strong alkalis. Chlorine releasing materials will liberate toxic chlorine gas.
10.6. Hazardous decomposition products
Hazardous decomposition No known hazardous decomposition products.
products
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological effects We have not carried out any animal testing for this product. Any ATE figures quoted below are
from Toxicity Classifications that have been carried out using ATE (Acute Toxicity Estimate)
Calculation Method using LD50 or ATE figures provided by the Raw Material Manufacturer.
Other health effects Low oral toxicity, but ingestion may cause irritation of the gastro-intestinal tract.
SECTION 12: Ecological information
Ecotoxicity The product may affect the acidity (pH) of water which may have hazardous effects on aquatic
organisms.
12.1. Toxicity
Toxicity We have not carried out any Aquatic testing, therefore we have no Aquatic Toxicity Data
specifically for this product. The Aquatic Toxicity Data, where provided by the raw material
manufacturer for ingredients with aquatic toxicity, can be made available on request.
12.2. Persistence and degradability
Persistence and degradability The surfactant(s) contained in this product complies(comply) with the biodegradability criteria
as laid down in Regulation (EC) No. 648/2004 on detergents.
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12.3. Bioaccumulative potential
Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.
12.4. Mobility in soil
Mobility Not known.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment
12.6. Other adverse effects
Other adverse effects Not known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Disposal methods Discharge used solutions to drain. Small amounts (less than 5 Litres) of unwanted product
may be flushed with water to sewer. Larger volumes must be sent for disposal by approved
waste contractor. Rinse out empty container with water and consign to normal waste.
SECTION 14: Transport information
General 1L & 5L As supplied, this product is consigned under the Limited Quantities provisions.
14.1. UN number
UN No. (ADR/RID) 3264
UN No. (IMDG) 3264
UN No. (ICAO) 3264
14.2. UN proper shipping name
Proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (phosphoric acid solution)
(ADR/RID)
Proper shipping name (IMDG) CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (phosphoric acid solution)
Proper shipping name (ICAO) CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (phosphoric acid solution)
14.3. Transport hazard class(es)
ADR/RID class Class 8: Corrosive substances.
IMDG class Class 8: Corrosive substances.
ICAO class/division Class 8: Corrosive substances.
Transport labels
14.4. Packing group
ADR/RID packing group III
IMDG packing group III
ICAO packing group III
14.5. Environmental hazards
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Environmentally hazardous substance/marine pollutant
No.
14.6. Special precautions for user
EmS F-A, S-B
Tunnel restriction code (E)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not relevant. for a packaged product.
Annex II of MARPOL 73/78
and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Safety Data Sheet prepared in accordance with REACH Commission Regulation (EU) No
2015/830 (which amends Regulation (EC) No 453/2010 & 1907/2006).
The product is as classified under GHS/CLP- Regulation (EC) No 1272/2008 classification,
labelling & packaging of substances & mixtures.
Ingredients are listed with classification under GHS/CLP - Regulation (EC) No 1272/2008
classification, labelling & packaging of substances & mixtures.
15.2. Chemical safety assessment
No chemical safety assessment has been carried out as not applicable as this product is a mixture.
SECTION 16: Other information
Abbreviations and acronyms vPvB: Very Persistent and Very Bioaccumulative.
used in the safety data sheet PBT: Persistent, Bioaccumulative and Toxic substance.
ATE: Acute Toxicity Estimate.
ADR: European Agreement concerning the International Carriage of Dangerous Goods by
Road.
IMDG: International Maritime Dangerous Goods.
ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
(EC) No 1907/2006.
GHS: Globally Harmonized System.
Spec Conc Limits = Specific Concentration Limits.
Classification abbreviations Eye Dam. = Serious eye damage
and acronyms Eye Irrit. = Eye irritation
Skin Corr. = Skin corrosion
Skin Irrit. = Skin irritation
NC (Not Classified)
Key literature references and Material Safety Data Sheet, Miscellaneous manufacturers. CLP Class - Table 3.1 List of
sources for data harmonised classification and labelling of hazardous substances. ECHA - C&L Inventory
database.
Classification procedures Calculation Method.
according to Regulation (EC)
1272/2008
Revision comments New formulation leading to change in product classification
Revision date 09/04/2020
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SDS status The Hazard Statements listed below in this Section No 16 relate to the Raw Materials
(Ingredients) in the Product (as listed in Section 3) and NOT the product itself. For the Hazard
Statements relating to this Product see Section 2.
Hazard statements in full H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
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