Shell Evolux Diesel B S10

Version 1.0
Effective Date 11/01/2012

Product Chemical Safety Data Sheet

1. Identification of the product and the company

Material Name Shell Evolux Diesel B S10

Recommended use / Fuel for diesel engines for road use.
Usage Restrictions

Product Code 002D1670

Manufacturer/Supplier Raízen Fuels S.A.

Av. Juscelino Kubitscheck, 1327
PlazaIIBuilding-ItaimBibi
CEP04543-011 - São Paulo - SP

Telephone (11) 2344 6200

Emergency Phone 0800 0251120
Email contact for the : fale@[Link]
FISPQ

2. Hazard identification
GHS Classification Flammable liquids, Category 3
Danger due to aspiration, Category 1
Corrosion/skin irritation, Category 2
Acute toxicity, Category 4, Inhalation
Carcinogenicity, Category 2
Specific toxicity of target organs after exposure
repeated, Category 2, Thymus, Liver, Blood.
Chronic risks to the aquatic environment, Category 2
Acute dangers to the aquatic environment, Category 2

GHS Label Elements

Symbol(s) :

Words of Indication Danger

Danger statements PHYSICAL DANGER:

H226: Flammable liquid and vapor.

DANGERS TO HEALTH:
H304: May be fatal if swallowed and enters airways
respiratory.
H315: Causes skin irritation.
H332: Harmful if inhaled.
H351: Suspected of causing cancer.

1
Date of Preparation 11/01/2012 1/14
 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Safety Data Sheet for Chemical Product

H373: May cause damage to organs after prolonged or repeated exposure

repeated.

ENVIRONMENTAL HAZARDS:
H401: Toxic to aquatic life.
H411: Toxic to aquatic life with long lasting effects
durable.

GHS Warnings
Prevention P210: Keep away from heat/sparks/open flame
open/hot surfaces. - Do not smoke.
P261: Avoid breathing the
dusts/fumes/gases/mists/vapors/aerosols.
P280: Use protective gloves/clothing
protection/eye protection/face protection.

Reaction P301+P310: IN CASE OF INGESTION: Call immediately

for a POISON CONTROL CENTER or for
a doctor.
Do not induce vomiting.

Discard P501: Dispose of contents/container in accordance with local regulations.

through certified entities for this purpose, in accordance with
the national legislation and local regulations.

Other dangers that do not The vapor in the empty space of tanks and containers can
result in ignite and explode at temperatures exceeding those of
Classification auto-ignition, in places where the vapor concentration is
within the flammability range.
It can ignite on surfaces with temperatures above
auto-ignition temperature.
Electrostatic charges can be generated during the
pumping. The electrostatic discharge can cause a fire.

Additional Information This product is intended for use only in closed systems.

3. Composition and information about the ingredients

Preparation description Complex mixture of hydrocarbons consisting of paraffins,

cycloparaffins, aromatic hydrocarbons, and olefins with
number of carbon atoms predominantly in the range of
C9 to C25. It can also contain several additives at < 0.1% v/v
each. May contain cetane improver (Ethyl Hexyl Nitrate) at <
0.2% v/v.

May contain catalytically fractionated oils with compounds

polycyclic aromatics, mainly species of 3, but
also some of 4 and 6 rings.

2
Date of Preparation 11/01/2012 2/14
 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Safety Data Sheet for Chemical Product

Classification of components according to GHS

Chemical Identity CAS Classed Declarations of Conc.

danger danger
(category)
Fuels, diesel 68334-30-5 Flammable Liquid, 3; Flammable liquid and vapour. 94.50% to 95.50%
Asp. Tox., 1; Harmful if inhaled
Acute Tox. Suspected of causing cancer.

4; Pele Corr., H411; H401;

2; Carc., 2;
STOT RE, 2;
Aquatica
Chronic, 2;
Aquatica
Aguda, 2;
Biodiesel, C16-18 67762-38-3 None; None; 4.50% to 5.50%
the C18-unsaturated,
esters

No. UN 1202

Additional Information Dyes and markers can be used to indicate the

tax situation and prevent fraud.

4. FIRST AID MEASURES

Inhalation Remove to the fresh air. If there is no recovery.

quick, light to the nearest health unit to
additional treatment.
Contact with the Skin Remove the contaminated clothing. Wash the skin immediately.
with abundant volumes of water for at least 15 minutes,
continue washing with soap and water if available. If it occurs
redness, swelling, pain and/or blister, mild to the
closest health unit for additional treatment.
During the use of high pressure equipment, incidents may occur
injection of the product under the skin. If injuries occur due to
the high pressure injection, the victim must be sent
immediately to a hospital. Do not wait for the symptoms
appear.
Contact with the Eyes Wash the eye with large amounts of water. If it occurs
persistent irritation, seek medical attention.
Intake If swallowed, do not induce vomiting: take to the unit of
nearest health care for additional treatment. If the vomiting
occur spontaneously, keep your head below the
quadrants to prevent aspiration. If any of the following signs and
late symptoms will appear in the next 6 hours, transport
to the nearest health unit: fever greater than
38.3 °C(101º F), shortness of breath, chest congestion, cough or
Continuous Shiatsu. Do not give anything orally.
Symptoms More If the material enters the lungs, the signs and symptoms may

3
Preparation Date 01/11/2012 3/14
 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Safety Data Sheet for Chemical Product

Important/ Effects, In include cough, choking, wheezing, difficulty breathing,

Short Term and Delayed chest congestion, shortness of breath and/or fever. The onset of symptoms
respiratory issues can be delayed for several hours after the
exposure. Signs and symptoms of skin irritation may include
burning sensation, redness or swelling.
Immediate medical attention: Provide symptomatic treatment.
special treatment

5. Firefighting measures

Remove all non-emergency personnel from the fire area.

Specific dangers of Hazardous combustion products may include: A mixture

combustion of products complex of gases and solid and liquid airborne particulates
chemicals (smoke). Carbon monoxide. Sulfur oxides.
Unidentified organic and inorganic compounds. The
carbon monoxide develops when combustion occurs
incomplete. It will float and may catch fire again in water
superficial. Flammable vapors may be present
even at temperatures below the flash point.
Means of Extinction Foam, spray or mist of water. Dry chemical powder, dioxide of
appropriate carbon, sand or earth can only be used for
small fires.
Extinction Material Do not apply water jets directly to the burning product,
Inadequate because this can cause a steam explosion and spread the
fire. Avoid the simultaneous use of foam and water on it
surface, as water destroys the foam.
Protective Equipment Full protective gear and breathing apparatus
the precaution for autonomous.
Firefighters

Additional Alerts Keep the adjacent containers cool by spraying water.

6. Control measures for spill or leakage

Avoid contact with spilled or released material. For guidance in selecting

personal protective equipment refer to Chapter 8 of this information sheet
chemical product safety - SDS. See disposal information in Chapter 13.
Comply with all relevant local and international regulations. Evacuate all non-essential personnel.
essential to the area. Ventilate the contaminated area completely.

Personal Precautions Do not breathe the smoke, the vapor. Do not operate equipment.
Personal Protective Equipment electric
and Procedures of
Emergency
Environmental Precautions Seal the leaks, if possible without personal risk.
Remove all possible sources of ignition in the area.
surrounding. Use appropriate containment (for the product and the
firewater) to prevent environmental contamination. Avoid the

4
Date of Preparation 11/01/2012 April 14
 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Chemical Product Safety Data Sheet

dispersal or entry into drains, ditches or rivers using

sand, soil or other suitable barriers. Try to disperse the
vapor or directing your flow to a safe location, using spray
of fog for example. Take preventive measures against
static discharges. Ensure electrical continuity by connecting
and landing (mass) all the equipment.
Methods and Materials for For small liquid spills (< 1 drum),
Storage and transfer the waste by mechanical means to a container
Cleaning labelable and sealable, for recovery or secure disposal
Let the residues evaporate or soak in a material.
appropriate absorbent and discard it safely. Remove
the contaminated soil and dispose of it safely.
For large liquid spills (> 1 drum), transfer
the waste by mechanical means, such as a vacuum truck,
for a salvage tank, for recovery or disposal
sure Transfer with a spatula to a clearly marked container
identified, for disposal or rescue according to the
local regulations.
Additional Alerts Notify the authorities if any occurrence or potential occurrence happens.
exposure to the general public or to the environment. The
local authorities should be notified if there are leaks
significant could not be contained. maritime spills
they must be handled according to the emergency plan
Shipboard Oil Pollution (SOPEP), according to the requirements of
MARPOL Annex 1 Regulation 26.

7. Handling and storage

General Precautions Avoid contact or breathing the material. Use only in areas
well ventilated. Wash carefully after use. For
guidance on the selection of personal protective equipment
refer to Chapter 8 of this Information Sheet
Chemical Product Safety. Use the information from this.
information sheet as input for an evaluation of
risks of local circumstances, to help determine the
proper controls Dry contaminated clothes with air
in a well-ventilated area before washing. Discard
adequately any contaminated cloths or materials
cleaning to prevent fires. Avoid spills. Use
local exhaust ventilation if there is a risk of inhalation of
vapors, mists or aerosols. Never siphon with your mouth.
Contaminated leather articles, including shoes, cannot
to be decontaminated and must be destroyed to prevent
reuse. For complete handling advice,
product transfer, storage and cleaning
tank, consult the product supplier.
Maintenance and Supply - avoid inhalation of vapors and
contact with the skin.
Precautions for the Avoid inhaling vapor and/or mists. Avoid prolonged contact or
Safe Handling repeated with the skin. Do not eat or drink while using. Erase

Date of Preparation 11/01/2012 May 14

 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Safety Data Sheet for Chemical Product

any flame. Do not smoke. Remove ignition sources. Avoid

sparks. Ground all the equipment. The loads
Electrostatics can be generated during pumping. A
electrostatic discharge can cause fire. The vapor is more
heavier than air, spreads across the ground, making it possible a
remote ignition.
Conditions for Storage of drums and small containers: The
Secure Storage drums must be stacked up to a maximum of 3 heights.
Use identified containers that close properly.
Tank storage: Tanks must be designed
specifically for this product. The tanks of
Bulk storage must be contained.
Keep the tanks away from heat and other sources of ignition.
It must be stored in a contained and well-reserved area.
ventilated, away from sunlight, ignition sources and others
heat sources. The vapors from the tanks should not be
released into the atmosphere. The losses due to evaporation during
the storage must be controlled by a system
adequate steam treatment. The steam is heavier than
the air. Be alert to the accumulation in wells and spaces
confined. Keep in a contained area with a floor
sealed (low permeability), to provide containment
against spillage. Prevent water entry.
Product Transfer: Avoid filling from the top of the container, deposit the material in
bottom. Wait 2 minutes after filling the tank (for tanks
like those of tank trucks) before opening hatches or
inspection entries. Wait 30 minutes after filling the
tank (for large capacity tanks) before opening
hatches or inspection entries. Keep the containers.
closed when not in use. Do not use compressed air to
fill, unload or handle. The resulting contamination
the transfer of the product may give rise to steam of
light hydrocarbons in the empty space of tanks that
previously contained gasoline. This vapor can explode if
there is an ignition source. Partially filled containers
they pose a greater danger than those that are completely full,
therefore the activities of handling, transfer and examination
they need special care.
Recommended Materials For containers or their coating, use mild steel, steel
stainless steel. Aluminum can also be used for
applications where there is no fire risk
unnecessary. Examples of suitable materials are:
high-density polyethylene (HDPE) and Viton (FKM), whose
compatibility was specifically tested with this product.
As a coating for containers, use cured epoxy paint.
with amine adhesive. For seals and gaskets use: graphite, PTFE,
Viton A, Viton B.
Inadequate Materials Some synthetic materials may not be suitable for
containers or their coatings, depending on the
specification of the material and the desired use. Examples of
Materials to avoid are: natural rubber (NR), nitrile rubber
(NBR), ethylene-propylene rubber (EPDM), polymethyl

Date of Preparation 11/01/2012 6/14

 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Chemical Product Safety Information Sheet

methacrylate (PMMA), polystyrene, polyvinyl chloride (PVC)

polybutylene. Meanwhile, some may be suitable for
glove materials.
Packaging Alert The containers, even those that are already empty, may contain vapors.
explosives. Do not cut, puncture, grind, weld or perform operations
similar about the containers or close to them.
Other Advice Ensure that all local regulations for installations of
handling and storage are followed.

8. Exposure control and personal protection

If the value of the American Conference of Governmental Hygienists (ACGIH) is

available in this document, will be for informational purposes only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation

Fuels, ACGIH TWA 100 mg/m3
diesel Fraction how
inalable and hydrocarbons
vapor. totals
ACGIH It can be
Fraction absorbed by
unbreathable and pele.
vapor. how
hydrocarbons
totals

Additional Information The notation 'skin' means that a significant exposure

it can also occur through the absorption of liquid through the skin,
and steam through the eyes or mucous membranes.

Material Source Risk Designation

Fuels, diesel ACGIH Confirmed animal carcinogen,
with unknown relevance
in humans.

Biological Exposure Index (BEI) - consult the reference for complete details

No biological limit allocated.

Engineering Controls The level of protection and the types of control needed will
appropriate vary depending on the potential exposure conditions.
Select the controls based on a risk assessment
the local circumstances. Appropriate measures include: Use
sealed systems whenever possible. An adequate
ventilation to control air concentrations below the
limits/guidelines for exposure. Ventilation is recommended

Date of Preparation 01/11/2012 July 14

 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Chemical Product Safety Data Sheet

exhaustion on site. Eyewash stations and showers for use

emergency.
Protection Measures Personal protective equipment (PPE) must
Individual obey the recommended standards in the country, which must be
verified with the PPE suppliers.
Respiratory Protection If the engineering controls do not maintain the
air concentrations at a level that is suitable for
protect the health of workers, select equipment
adequate respiratory protection for the conditions
specific uses that comply with the relevant legislation.
Check with the respiratory equipment suppliers
for protection. Where the air-filtering respirators will be
inadequate (e.g. high airborne concentrations, risk of
oxygen deficiency, confined space) use apparatus to
appropriate positive pressure breathing. Where the
respirators with air filters are suitable, select one
appropriate combination of mask and filter. All the
respiratory protection equipment and its use must
comply with local regulations.
Hand Protection Personal hygiene is a key element for effective care of
hands. Gloves should only be worn over clean hands.
After using gloves, hands should be washed and dried.
completely. The application of an unscented cream is
recommended. The usefulness and durability of a glove
it depends on your usage, e.g. frequency and duration of contact,
chemical resistance of the glove material, thickness of the glove,
skill. Always consult the manufacturer's recommendations.
from the glove. Contaminated gloves should be replaced.
Select gloves according to the current legal standard. When
in case of prolonged or frequent contact, it is recommended to use
of nitrile gloves. (Breakthrough time > 240 minutes). For
protection against incidental contact/splashes is recommended
use of Neoprene or PVC gloves.
Eye protection Eye protection against chemicals (full face, against
chemicals). According to the current legal regulation.
Skin and protection of Short/long cuff gloves, boots, and durable aprons
body chemicals (where there is a risk of sneezing).
Thermal Hazards Not applicable.
Methods of Monitor the concentration of substances in the area of
monitoring breathing of workers or throughout the workplace
it may be necessary to confirm compliance with the LEO
(Operational Exposure Limit). For some substances
biological monitoring may also be appropriate.
Exposure Controls The local guidelines for emissions limits of substances
Environmental volatiles must be followed in relation to air discharge of
exhaust containing vapors.

9. Physicochemical properties

Appearance Clear liquid, ranging from yellowish to orange, up to shades of brown.

Odor Characteristic.

Date of Preparation 11/01/2012 August 14

 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Chemical Product Safety Data Sheet

Odor limit Data not available.

pH Not applicable
Initial Boiling Point : 141 - 462°C/ 286 - 864 Fahrenheit
The Boiling Range
Point of fluidity <= 6 °C/ 43 °F
Flash point 38 °C/ 100 °F (ASTM D-93 / PMCC)
Limits of Data not available.
inflammability or
inferior explosions
/superiors
Self-temperature > 225 °C/ 437 °F
ignition
Vapor pressure 0.4 kPa at 40 °C / 104 °F
Relative Density Data not available.
Density @ 20 ºC 0.820 to 0.850 g/cm3
Solubility in water Data not available.
Solubility in others Data not available.
solvents

Partition coefficient: Data not available.

n-octane/water
Dynamic viscosity Data not available.
Kinematic viscosity Data not available.
Vapor density Data not available.
Speed of
evaporation (nBuAc=1) Data not available.
Temperature of
decomposition Data not available.
Inflammability Flammable liquid.

10. STABILITY AND REACTIVITY

Chemical Stability Stable under normal conditions of use.

Possibility of Reactions: Data not available.
Dangerous
Conditions to Avoid Avoid heat, sparks, flames, and other ignition sources.
Incompatible Materials Strong oxidation agents.
Hazardous products from It is not expected that hazardous products will form from
decomposition decomposition during normal storage. A
Thermal decomposition depends heavily on the conditions. A
complex mixture of solids, liquids, and gases in suspension,
including carbon monoxide, carbon dioxide and
other unidentified organic compounds will develop
when this material undergoes combustion or by
thermal or oxidative degradation.

11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Date of Preparation 11/01/2012 9/14

 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Chemical Product Safety Data Sheet

Evaluation Base The information provided is based on data from

product, in knowledge about the components and in
toxicology of similar products.
Likely Routes of : Contact with the skin and eyes are primary routes of
Exhibition exhibition, although the exhibition can occur through the
inhalation or after accidental ingestion.
Acute oral toxicity Low toxicity: LD50 > 5000 mg/kg, Rat

Dermal Toxicity Low toxicity: LD50 >2000 mg/kg, Rabbit

Sharp
Inhalation Toxicity Harmful by inhalation. LC50 > 1.0 - <= 5.0 mg/l, 4 h, Rat High
Acute concentrations can cause depression of the nervous system
central, resulting in headaches, dizziness, and nausea; the
continuous inhalation results in loss of consciousness and/or
death.

Corrosion/Irritation of Irritating to the skin.

Pele
Serious Damage/Irritation of Slightly irritating.
Eyes
Respiratory Irritation Inhaling vapors or mists can cause irritation to
respiratory system.

Skin Sensitization or It is not expected to be a skin sensitizer.

Respiratory
Danger of aspiration The aspiration into the lungs when swallowed or vomited can
to cause chemical pneumonia, which can be fatal.

Mutagenicity in In-vitro mutagenicity studies show that the activity

germ cells mutagenic is related to the content of polycyclic aromatics
of 4-6 rings.
Positive in in vitro mutagenicity tests, but negative
in vivo.

Carcinogenicity Limited evidence of carcinogenic effect.

Repeated contact with the skin resulted in irritation and cancer
of skin in animals.

Reproductive toxicity and It is not expected to compromise fertility. It is not expected

of development that it is a toxin for development.

Specific toxicity of: Not classified.

target organs after
unique exhibition
Target organ toxicity Affects the organs after prolonged or repeated exposure.
specific – exhibition Blood. Thymus. Liver.
repeated

12. ECOLOGICAL INFORMATION

Date of Preparation 11/01/2012 October 14

 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Chemical Product Safety Information Sheet

Evaluation Base The information provided is based on knowledge.

two components and the ecotoxicology of similar products.
Fuels are typically made from a mixture of several
refining products. Ecotoxicological studies were conducted
in a variety of mixtures and lines of hydrocarbons,
but not in those that contain additives.

Acute Toxicity (LL/EL50 expressed as the nominal amount of the product

necessary to prepare the aqueous test extract.
Fish Considered toxic: LL/EL/IL50 > 1 <= 10 mg/l
Invertebrates Considered toxic: LL/EL/IL50 > 1 <= 10 mg/l
Aquatic
Algae Considered toxic: LL/EL/IL50 > 1 <= 10 mg/l
Microorganisms Considered practically non-toxic: LL/EL/IL50 > 100 mg/l
Chronic Toxicity
Fish NOEC/NOEL expected > 0.01 - <=0.1 mg/l (based on the
modeled data
Invertebrates NOEC/NOEL expected > 0.1 - <=1.0 mg/l (based on the
Aquatic modeled data
Mobility Floats on the water. Partially evaporates from the surface of the water.
the ground, but a significant proportion remains after
one day. Large volumes can penetrate the soil and
contaminate the groundwater. Contains volatile components
Partially evaporates from the surface of the water or soil, but
a significant proportion remains after a day. If the
product entering the soil, one or more of its components will be
permeable and may contaminate the water table. It floats on
water. Large volumes can penetrate the soil and contaminate
the water table.
Persistence/degradation The main components are inherently biodegradable.
The volatile components will oxidize rapidly through reactions
photoquimicals in the air. Promptly biodegradable.
Potential Bioaccumulative: Contains components with bioaccumulation potential
Other adverse effects : Films formed in water can affect the transfer of
oxygen and harm organisms.

13. Considerations on treatment and disposal

Material Disposal Recover or recycle if possible. It is the responsibility of

waste generator determine the toxicity and properties
physical properties of the generated material, to determine the classification and
proper disposal methods, in accordance with the
applicable regulations. Do not dispose of in the environment, in
drains or watercourses. Do not discard the liquid from the bottom of
tanks draining them into the ground. This will result in
soil and groundwater contamination. The waste resulting from
a spill or tank cleaning must be disposed of
according to the prevailing regulations, of
preference with a recognized collector or supplier. A
the competence of the collector or supplier must be established

Date of Preparation 11/01/2012 11/14

 Shell Evolux Diesel B S10
Version 1.0
Effective Date 01/11/2012

Chemical Product Safety Information Sheet

in advance.
Packaging Disposal Send to the drum recovery or metal recycling.
Completely drain the container. After draining, ventilate in
a safe place, free from sparks and fire. The waste can
may cause explosion hazard if heated above the point of
brightness. Do not puncture, cut or solder unclean drums. Do not
pollute the soil, water or the environment with the container
discarded. Comply with any local regulations
recovery or disposal of waste.
Local Legislation The disposal must comply with laws and regulations
regional, national and local regulations applicable. The regulations
local regulations may be more stringent than regional requirements or
national, and must be followed.

14. Transportation information

ADR
Class 3
Packaging group III
Identification number of the 30
risk.
No. UN 1202
Danger label (risk 3
primary)
Appropriate name for DIESEL
boarding
Environmental Danger Dangerous for the environment

RID
Class 3
Packaging group III
Classification code F1
Identification number of 30
risk.
No. UN 1202
Danger label (risk 3
primary)
Appropriate name for DIESEL
boarding
Environmental Danger Dangerous for the environment

IMDG
Identification number UN 1202
Appropriate name for DIESEL FUEL
boarding
Class / Division 3
Packaging group III
Marine pollutant Yes

Date of Preparation 11/01/2012 12/14

 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Chemical Product Safety Data Sheet

IATA (there may be variations by country)

UN No. 1202
Appropriate name for Diesel fuel
boarding
Class / Division 3
Packaging group III

Additional Information The MARPOL rules apply to maritime shipments.

bulk.

15. Regulations

It is not intended for the regulatory information to be complete. Other regulations may
to be applied to this material.

16. OTHER INFORMATION

Danger declarations
H226 Flammable liquid and vapor.
H304 It can be fatal if ingested and penetrated into the respiratory tract.
H315 Causes skin irritation.
H332 Harmful by inhalation.
H351 Suspected of provoking.
H373 It can affect the organs after prolonged or repeated exposure.
H401 Toxic to aquatic life.
H411 Toxic to aquatic life with long-lasting effects.

Additional Information This document contains important information to ensure

the safe storage, handling, and use of this product. The
Information in this document should be brought to attention.
the person from your organization, responsible for providing guidance
in security matters.
Version Number of 1.0
FISPQ
Effective Date of the SDS 01/11/2012

Reviews of the Safety Data Sheet A vertical bar (|) on the left margin indicates a
change of the previous version.
Regulations of FISPQ The content and format of this Information Sheet
Chemical Product Safety is in accordance with the
requirements of ABNT 14725-1:2009.
Uses and Restrictions This product should not be used in applications other than those
recommended in Section 1, without first seeking the opinion of
supplier.
This product should not be used as a solvent or agent of
cleaning; to ignite or rekindle fire; as a cleaner for the
pele.

Date of Preparation 11/01/2012 13/14

 Shell Evolux Diesel B S10
Version 1.0
Effective Date 11/01/2012

Chemical Product Safety Data Sheet

Distribution of the Safety Data Sheet The information contained in this document must be
made available to everyone who can handle the product
Resignation This information is based on our current knowledge, and
it is only intended to describe the product in terms of requirements
in terms of health, safety, and environment. It should not put
both interpreted as a guarantee of any property
specific to the product.

Date of Preparation 01/11/2012 14/14

 Shell Evolux Diesel B S500
Version 2.0
Effective Date 01/07/2012

Chemical Product Safety Information Sheet

1. Identification of the product and the company

Material Name Shell Evolux Diesel B S500

Recommended use Fuel for diesel engines for road use.
Usage Restrictions

Product Code 002D1651

Manufacturer/Supplier Raízen Fuels S.A.

Avenue Juscelino Kubitschek, 1327
Plaza II Building – Itaim Bibi
CEP04543-011

Telephone (11) 2344-6200

Emergency Phone 0800 0251120
Email contact for the : fale@[Link]
FISPQ

2. Hazard identification
GHS Classification Flammable liquids, Category 3
Aspiration hazard, Category 1
Corrosion/skin irritation, Category 2
Acute toxicity, Category 4, Inhalation
Carcinogenicity, Category 2
Specific toxicity of target organs after exposure
repeated, Category 2, Thymus, Liver, Blood.
Chronic risks to the aquatic environment, Category 2
Acute hazards to the aquatic environment, Category 2

GHS Label Elements

Symbol(s) :

Indication Words Danger

Hazard statements PHYSICAL DANGER:

H226: Flammable liquid and vapor.

DANGERS TO HEALTH:
H304: It may be fatal if swallowed and enters airways.
respiratory.
H315: Causes skin irritation.
H332: Harmful if inhaled.
H351: Suspected of causing cancer.

Date of Preparation of the Safety Data Sheet: 03/21/2011 1/14

/
 Shell Evolux Diesel B S500
Version 2.0
Effective Date 01/07/2012

Safety Data Sheet for Chemical Product

H373: May cause damage to organs after prolonged or repeated exposure

repeated.

Environmental hazards:
H401: Toxic to aquatic life.
H411: Toxic to aquatic life with long-lasting effects
durable.

GHS Warnings
Prevention P210: Keep away from heat/sparks/open flames
open/hot surfaces. - No smoking.
P261: Avoid breathing the
dusts/smokes/gases/mists/vapors/aerosols.
P280: Use protective gloves/clothing
protection/eye protection/face protection.

Reaction P301+P310: IN CASE OF INGESTION: Call immediately

for a POISON CONTROL CENTER or for
a doctor.
Do NOT induce vomiting.

Discard P501: Dispose of the content/container in accordance with local regulations.

through certified entities for this purpose, in accordance with
the national legislation and local regulations.

Other Dangers that are not The vapor in the empty space of the tanks and containers can
result in ignite and explode at temperatures exceeding those of
Classification auto-ignition, in places where the vapor concentration is
within the flammability range.
It can ignite on surfaces with temperatures above
auto-ignition temperature.
Electrostatic charges can be generated during the
Pumping. Electrostatic discharge can cause fire.

Additional Information This product is intended for use only in closed systems.

3. Composition and information about the ingredients

Preparation description Complex mixture of hydrocarbons consisting of paraffins,

cycloparaffins, aromatic hydrocarbons and olefins with
number of carbon atoms predominantly in the range of
C9 to C25. It may also contain various additives at < 0.1% v/v
each. May contain cetane improver (Ethyl Hexyl Nitrate) at <
0.2% v/v.

It may contain catalytically fractionated oils with compounds

polycyclic aromatic compounds, mainly species of 3, but
also some with 4 and 6 rings.

Date of Preparation of the MSDS: 03/21/2011 February 14

/
 Shell Evolux Diesel B S500
Version 2.0
Effective Date 01/07/2012

Product Chemical Safety Data Sheet

Classification of components according to GHS

Chemical Identity CAS Classified Declarations of Conc.

danger danger
(category)
Fuels, diesel 68334-30-5 Flammable Liquid, 3; Flammable liquid and vapor. 94.50% to 95.50%
Asp. Tox., 1; Harmful if inhaled
Tox. Acute, Suspected of causing cancer.

4; Pele Corr., H411; H401;

2; Carc., 2;
STOT RE, 2;
Aquatica
Cronic, 2;
Aquatica
Sharp, 2;
Biodiesel, C16-18 67762-38-3 None; None; 4.50% to 5.50%
the C18-unsaturated,
esters

No. UN 1202

Additional Information Dyes and markers can be used to indicate the

tax situation and avoid fraud.

4. FIRST AID MEASURES

Inhalation Remove to the fresh air. If recovery does not occur.

quick, light to the nearest health unit to
additional treatment.
Contact with the Skin Remove the contaminated clothing. Wash the skin immediately.
with abundant volumes of water for at least 15 minutes,
keep washing with soap and water if available. If it occurs
redness, swelling, pain and/or blister, mild to the
closest health unit for additional treatment.
During the use of high-pressure equipment, incidents may occur
injection of the product under the skin. If injuries occur due to
the high-pressure injection, the victim should be sent
immediately to a hospital. Don't wait for the symptoms
appear.
Contact with the Eyes Wash the eye with large amounts of water. If it occurs
persistent irritation, seek medical attention.
Ingestion If swallowed, do not induce vomiting: take to the unit of
closer healthcare for additional treatment. If the vomiting
happen spontaneously, keep your head below the
quadrants to prevent aspiration. If any of the following signs and
late symptoms appear in the next 6 hours, transport
to the nearest health unit: fever higher than
38.3 °C(101º F), shortness of breath, chest congestion, cough or
continuous crying. Do not give anything orally.
More Symptoms If the material enters the lungs, the signs and symptoms may

Date of Preparation of the Safety Data Sheet: 03/21/2011 March 14

/
 Shell Evolux Diesel B S500
Version 2.0
Effective Date 07/01/2012

Chemical Product Safety Information Sheet

Important/ Effects, In include cough, choking, wheezing, difficulty breathing,

Short Term and Delayed chest congestion, shortness of breath and/or fever. The onset of symptoms
respiratory issues can be delayed for several hours after the
exhibition. Signs and symptoms of skin irritation may include
burning sensation, redness or swelling.
Immediate medical attention: Provide symptomatic treatment.
special treatment

5. Fire fighting measures

Remove all non-emergency personnel from the fire area.

Specific dangers of Hazardous combustion products may include: A mixture

combustion of products complex of gases and solid and liquid airborne particles
chemicals (smoke). Carbon monoxide. Sulfur oxides.
Unidentified organic and inorganic compounds. The
carbon monoxide develops when combustion occurs
incomplete. It will float and can ignite again in water
superficial. Flammable vapors may be present
even at temperatures below the flash point.
Means of Extinction Foam, spray or mist of water. Dry chemical powder, dioxide of
appropriate carbon, sand or soil can only be used for
small fires.
Extinguishing Material Do not spray water jets directly on the burning product.
Inadequate because this can cause a steam explosion and spread the
fire. Avoid the simultaneous use of foam and water on the same
surface, as the water destroys the foam.
Protective Equipment Complete protective clothing and breathing apparatus
Precaution for autonomous.
Firefighters

Additional Alerts Keep the adjacent containers cool by spraying water.

6. Control measures for spills or leaks

Avoid contact with spilled or released material. For guidance on selection of

personal protective equipment refer to Chapter 8 of this information sheet
chemical product safety - Safety Data Sheet. See disposal information in Chapter 13.
Obey all relevant local and international regulations. Evacuate all non-personnel.
Essentials of the area. Ventilate the contaminated area completely.

Personal precautions Do not breathe the smoke, the vapor. Do not operate equipment.
Protection Equipment electric.
and Procedures of
Emergency
Environmental Precautions Seal the leaks, if possible without personal risk.
Remove all possible ignition sources in the area.
surrounding. Use appropriate containment (for the product and the
fire water) to prevent environmental contamination. Avoid the

Date of Elaboration of the Safety Data Sheet: 03/21/2011 4/14

/
 Shell Evolux Diesel B S500
Version 2.0
Effective Date 01/07/2012

Chemical Product Safety Data Sheet

spreading or entry into drains, ditches or rivers using

sand, earth or other suitable barriers. Try to disperse the
vapor or directing its flow to a safe location, using spray
of fog for example. Take preventive measures against
static discharges. Ensure electrical continuity by connecting
and landing (mass) all the equipment.
Methods and Materials for For small liquid spills (< 1 drum),
Storage and Transfer the waste by mechanical means to a container.
Cleaning labelable and sealable, for recovery or safe disposal
Let the residue evaporate or soak it in a material
appropriate absorbent and dispose of safely. Remove
the contaminated soil and dispose of it safely.
For large liquid spills (> 1 drum), transfer
the waste by mechanical means, such as a vacuum truck,
for a salvage tank, for recovery or disposal
sure Transfer with a spade to a clearly marked container
identified, for discard or rescue according to the
local regulations.
Additional Alerts Notify the authorities if any occurs or may occur
exposure to the general public or the environment. The
local authorities should be notified if there are leaks
significant cannot be contained. maritime spills
they must be handled according to the emergency plan
Shipboard Oil Pollution (SOPEP), according to the requirements of
MARPOL Annex 1 Regulation 26.

7. Handling and storage

General Precautions Avoid contact or breathing the material. Use only in areas
well ventilated. Wash carefully after use. For
guidance on the selection of personal protective equipment
consult Chapter 8 of this Information Sheet
Chemical Product Safety. Use this information from
information sheet as input for an evaluation of
risks of local circumstances, to help determine the
proper controls Dry contaminated clothes with air
in a well-ventilated area before washing. Discard
properly any contaminated rags or materials
cleaning to prevent fires. Avoid spills. Use
local exhaust ventilation if there is a risk of inhalation of
vapors, mists or aerosols. Never siphon with your mouth.
Contaminated leather articles, including shoes, cannot
be decontaminated and must be destroyed to prevent
reuse. For comprehensive handling advice,
product transfer, storage and cleaning
tank, consult the product supplier.
Maintenance and Supply - avoid inhalation of vapors and
contact with the skin.
Precautions for the Avoid inhaling vapor and/or mists. Avoid prolonged contact or
Safe Handling repeated with the skin. When using do not eat and do not drink. Delete

Date of Preparation of the Safety Data Sheet: 03/21/2011 May 14

/
 Shell Evolux Diesel B S500
Version 2.0
Effective Date 01/07/2012

Chemical Product Safety Information Sheet

any flame. Do not smoke. Remove ignition sources. Avoid

sparks. Land all the equipment. The loads
Electrostatics can be generated during pumping.
Electrostatic discharge can cause fire. The vapor is more
heavier than air, spreads over the ground, making it possible a
distant ignition.
Conditions for Storage of drums and small containers: The
Secure Storage drums must be stacked to a maximum height of 3.
Use identified containers that close properly.
Storage in tank: Tanks must be designed
specifically for this product. The tanks of
Bulk storage must be contained (restrained).
Place the tanks away from heat and other sources of ignition.
It must be stored in a confined (enclosed) area and well
ventilated, away from sunlight, ignition sources, and others
heat sources. The vapors from the tanks should not be
released into the atmosphere. The losses due to evaporation during
the storage must be controlled by a system
adequate steam treatment. Steam is heavier than
the air. Stay alert for accumulation in wells and spaces
confined. Keep in a contained area with a floor
sealed (low permeability), to provide containment
against spillage. Prevent water entry.
Product Transfer: Avoid filling to the top of the container, deposit the material in the
ground. Wait 2 minutes after filling the tank (for tanks
like those of tank trucks) before opening hatches or
inspection entries. Wait 30 minutes after filling the
tank (for large capacity tanks) before opening
hatches or inspection openings. Keep the containers
closed when not in use. Do not use compressed air to
fill, unload or handle. The resulting contamination
the transfer of the product can give rise to vapor of
light hydrocarbons in the empty space of tanks that
previously contained gasoline. This vapor can explode if
there will be an ignition source. Partially filled containers
present greater danger than those that are completely full,
therefore the activities of handling, transfer, and examination
they need special care.
Recommended Materials For containers or their coating, use mild steel, steel
stainless. Aluminum can also be used for
applications where there is no fire risk
unnecessary. Examples of suitable materials are:
high-density polyethylene (HDPE) and Viton (FKM), which
compatibility was specifically tested with this product.
As a coating for containers, use cured epoxy paint.
with amine adduct. For seals and gaskets use: graphite, PTFE.
Viton A, Viton B.
Inappropriate Materials Some synthetic materials may not be suitable for
containers or their coatings, depending on the
material specification and intended use. Examples of
Materials to avoid are: natural rubber (NR), nitrile rubber
(NBR), ethylene-propylene rubber (EPDM), polymethyl

03/21/2011 6/14
 Shell Evolux Diesel B S500
Version 2.0
Effective Date 07/01/2012

Chemical Product Safety Information Sheet

methacrylate (PMMA), polystyrene, polyvinyl chloride (PVC),

polybutylene. However, some may be suitable for
glove materials.
Packaging Alert The containers, even those that are already empty, may contain vapors
explosives. Do not cut, puncture, grind, weld or perform operations
similar to the containers or near them.
Other Advice Ensure that all local regulations for facilities are followed.
handling and storage should be followed.

8. Exposure control and personal protection

If the value of the American Conference of Governmental Industrial Hygienists (ACGIH) is

available in this document will be for information only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation

Fuels, ACGIH TWA 100 mg/m3
diesel Fraction how
uninhabitable and hydrocarbons
vapor. totals
ACGIH It can be
Fraction absorbed by
inalable and ball.
vapor. how
hydrocarbons
totals

Additional Information The notation 'skin' means that a significant exposure

it can also occur through the absorption of liquid through the skin,
and vapor through the eyes or mucous membranes.

Material Source Risk Designation

Fuels, diesel ACGIH Confirmed animal carcinogen,
with unknown relevance
in humans.

Biological Exposure Index (BEI) - consult the reference for complete details

No biological limit allocated.

Engineering Controls The level of protection and the types of controls needed will
appropriate vary depending on the potential exposure conditions.
Select controls based on a risk assessment
the local circumstances. Appropriate measures include: Use
sealed systems whenever possible. An adequate
ventilation to control air concentrations below the
exposure limits/guidelines. Ventilation is recommended.

Date of Preparation of the Safety Data Sheet: 21/03/2011 7/14

 Shell Evolux Diesel B S500
Version 2.0
Effective Date 07/01/2012

Chemical Product Safety Data Sheet

exhaustion on site. Eyewash stations and showers for use

emergency.
Protection Measures Personal protective equipment (PPE) must
Individual to obey the recommended standards in the country, which should be
verified with PPE suppliers.
Respiratory Protection If the engineering controls do not maintain the
air concentrations at a level that is suitable for
protect the health of workers, select equipment
adequate respiratory protection for the conditions
specific to use and that comply with the relevant legislation.
Check with the respiratory equipment suppliers
of protection. Where the respirators with air filtering will be
inadequate (e.g. high airborne concentrations, risk of
oxygen deficiency, confined space) use apparatus of
appropriate positive pressure breathing. Where the
respirators with air filters are suitable, select one
appropriate combination of mask and filter. All the
respiratory protective equipment and its use must
to comply with local regulations.
Hand Protection Personal hygiene is a key element for effective care of
hands. Gloves should only be worn over clean hands.
After using gloves, hands should be washed and dried.
completely. The application of a non-scented cream is
recommended. The usefulness and durability of a glove
it depends on its use, e.g. frequency and duration of contact,
chemical resistance of the glove material, thickness of the glove,
skill. Always consult the manufacturer's recommendations
from the glove. Contaminated gloves should be replaced.
Select gloves according to the current legal standard. When
in case of prolonged or frequent contact, it is recommended to use
of nitrile gloves. (Breakthrough time > 240 minutes). For
protection against incidental contact/splashing is recommended
use of Neoprene or PVC gloves.
Eye protection Eye protection against chemicals (full face, against
(chemicals). In accordance with the current legal regulation.
Protection of the skin and of Short/long cuff gloves, boots, and resistant aprons
body chemicals (where there is a risk of sneezing).
Thermal Hazards Not applicable.
Methods of Monitor the concentration of substances in the area of
monitoring breathing of workers or throughout the workplace
it may be necessary to confirm compliance with the LEO
(Operational Exposure Limit). For some substances
biological monitoring may also be appropriate.
Exposure Controls Local guidelines for limits on the emission of substances
Environmental volatile substances must be followed regarding the air discharge of
exhaust containing vapors.

9. Physicochemical properties

Appearance Clear liquid, red in color.

Odor Characteristic.

Date of Preparation of the Safety Data Sheet: 03/21/2011 August 14

 Shell Evolux Diesel B S500
Version 2.0
Effective Date 01/07/2012

Safety Data Sheet for Chemical Product

Odor limit Data not available.

pH Not applicable
Initial Boiling Point 141 - 462 °C/ 286 - 864 °F
The Boiling Range
Fluidity point less than or
°Cequal
/ 43 to°F
6

Flash point 38 °C/ 100 °F (ASTM D-93 / PMCC)

Limits of Data not available.
inflammability or
lower explosions
/superiores
Temperature of self- > 225 °C/ 437 °F
ignition
Vapor pressure 0.4 kPa at 40 °C / 104 °F
Relative Density Data not available.
Density 0.84 g/cm3 at 15 ° /C
59 Fahrenheit
Solubility in water Data not available.
Solubility in others Data not available.
solvents

Partition coefficient: Data not available.

n-octane/water
Dynamic viscosity Data not available.
Kinematic viscosity Data not available.
Density of vapor Data not available.
Speed of
evaporation (nBuAc=1) Data not available.
Temperature of
decomposition Data not available.
Inflammability Flammable liquid.

10. STABILITY AND REACTIVITY

Chemical Stability Stable under normal conditions of use.

Possibility of Reactions: Data not available.
Dangerous
Conditions to Avoid Avoid heat, sparks, flames, and other sources of ignition.
Incompatible Materials Strong oxidizing agents.
Hazardous products from It is not expected that hazardous products will be formed from
decomposition decomposition during normal storage. The
thermal decomposition depends a lot on the conditions. A
complex mixture of solids, liquids, and gases in suspension,
including carbon monoxide, carbon dioxide and
other unidentified organic compounds will develop
when this material goes through combustion or by
thermal or oxidative degradation.

11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Date of Preparation of the Safety Data Sheet: 03/21/2011 9/14

 Shell Evolux Diesel B S500
Version 2.0
Effective Date 07/01/2012

Chemical Product Safety Data Sheet

Basis for Evaluation The information provided is based on data from

product, in knowledge about the components and in
toxicology of similar products.
Likely Routes of : Contact with the skin and eyes are primary routes of
Exhibition exhibition, although the exhibition may occur through the
inhalation or after accidental ingestion.
Acute oral toxicity Low toxicity: LD50 > 5000 mg/kg, Rat

Dermal Toxicity Low toxicity: LD50 >2000 mg/kg, Rabbit

Sharp
Inhalation Toxicity Harmful by inhalation. LC50 > 1.0 - <= 5.0 mg/l, 4 h, Rat High
Sharp concentrations can cause depression of the nervous system
central, resulting in headaches, dizziness, and nausea; the
continuous inhalation results in loss of consciousness and/or
death.

Corrosion/Irritation of Irritant to the skin.

Pele
Serious Harm/Irritation of Considered mildly irritating.
Eyes
Respiratory Irritation The inhalation of vapors or mists can cause irritation to
respiratory system.

Skin Sensitization or It is not expected to be a skin sensitizer.

Respiratory
Danger of aspiration The aspiration into the lungs when swallowed or vomited can
to cause chemical pneumonia, which can be fatal.

Mutagenicity in In vitro mutagenicity studies show that the activity

germ cells Mutagenicity is related to the content of polycyclic aromatics.
from 4-6 rings.
Positive in in vitro mutagenicity tests, but negative
in vivo.

Carcinogenicity Limited evidence of carcinogenic effect.

Repeated contact with the skin resulted in irritation and cancer
of skin in animals.

Reproductive toxicity and It is not expected to compromise fertility. It is not expected

of development that it be a toxin for development.

Specific toxicity of: Not classified.

target organs after
unique exhibition
Target organ toxicity Affects the organs after prolonged or repeated exposure.
specific - exhibition Blood. Thymus. Liver.
repeated

12. ECOLOGICAL INFORMATION

Date of Preparation of the Safety Data Sheet: 03/21/2011 October 14

 Shell Evolux Diesel B S500
Version 2.0
Effective Date 07/01/2012

Safety Data Sheet for Chemical Product

Base for Evaluation The information provided is based on knowledge

two components and the ecotoxicology of similar products.
Fuels are typically made from a mixture of several
refining products. Ecotoxicological studies were conducted
in a variety of mixtures and lines of hydrocarbons,
but not those that contain additives.

Acute Toxicity (LL/EL50 expressed as the nominal quantity of the product

necessary to prepare the aqueous test extract).
Fish Considered toxic: LL/EL/IL50 > 1 <= 10 mg/l
Invertebrates Considered toxic: LL/EL/IL50 > 1 <= 10 mg/l
Aquatic
Algae Considered toxic: LL/EL/IL50 > 1 <= 10 mg/l
Microorganisms Considered practically non-toxic: LL/EL/IL50 > 100 mg/l
Chronic Toxicity
Fish Expected NOEC/NOEL > 0.01 - <= 0.1 mg/l (based on the
modeled data
Invertebrates Expected NOEC/NOEL > 0.1 - <=1.0 mg/l (based on the
Aquatic modeled data
Mobility Floats on the water. Partially evaporates from the surface of the water.
of the soil, but a significant proportion remains after
one day. Large volumes can penetrate the soil and
contaminate the groundwater. Contains volatile components
Partially evaporates from the surface of the water or soil, but
a significant proportion remains after a day. If the
product entering the soil, one or more of its components will be
permeable and could contaminate the water table. It floats on
water. Large volumes can penetrate the soil and contaminate
the groundwater.
Persistence/degradation The main components are inherently biodegradable.
The volatile components will quickly oxidize through reactions.
photochemicals in the air. Promptly biodegradable.
Potential Bioaccumulative: Contains components with bioaccumulation potential
Other adverse effects Movies formed in water can affect the transfer of
oxygen and harm organisms.

13. Considerations on treatment and disposal

Material Disposal Recover or recycle if possible. It is the responsibility of

waste generator determine the toxicity and properties
physical properties of the generated material, to determine the classification and
proper disposal methods, in compliance with the
applicable regulations. Do not dispose of in the environment, in
drains or watercourses. Do not dispose of the liquid from the bottom of
tanks draining them into the ground. This will result in
soil and groundwater contamination. The waste resulting from
a spill or tank cleaning must be disposed of
according to the prevailing regulations, of
preference for a recognized collector or supplier. A
the competence of the collector or supplier must be established

Date of Preparation of the Safety Data Sheet: 03/21/2011 11/14

 Shell Evolux Diesel B S500
Version 2.0
Effective Date 01/07/2012

Safety Data Sheet for Chemical Product

in advance.
Packaging Disposal Send to the drum collector or metal recycler.
Completely drain the container. After draining, ventilate in
a safe place, free from sparks and fire. The waste can
can cause explosion hazard if heated above the point of
brightness. Do not puncture, cut or weld unclean drums. Do not
pollute the soil, water or the environment with the container
discarded. Comply with any local regulations
recovery or disposal of waste.
Local Legislation The disposal must comply with laws and regulations.
applicable regional, national, and local regulations. The regulations
local regulations may be stricter than regional requirements or
national, and must be followed.

14. Transportation information

ADR
Class 3
Packing group III
Identification number of the 30
risk.
No. UN 1202
Danger label (risk 3
primary)
Appropriate name for DIESEL
boarding
Environmental Danger Dangerous to the environment

RID
Class 3
Packing group III
Classification code F1
Identification number of 30
risk.
No. UN 1202
Danger label (risk 3
primary)
Appropriate name for DIESEL
boarding
Environmental Danger Dangerous for the environment

IMDG
Identification number UN 1202
Appropriate name for DIESEL FUEL
boarding
Class / Division 3
Packaging group III
Marine pollutant Yes

Date of Preparation of the Safety Data Sheet: 03/21/2011 December 14

 Shell Evolux Diesel B S500
Version 2.0
Effective Date 01/07/2012

Chemical Product Safety Data Sheet

IATA (there may be variations by country)

UN No. 1202
Appropriate name for Diesel fuel
boarding
Class / Division 3
Packing group III

Additional Information The MARPOL regulations apply to maritime transport.

bulk

15. Regulations

It is not intended for the regulatory information to be complete. Other regulations may
to be applied to this material.

16. OTHER INFORMATION

Danger declarations
H226 Flammable liquid and vapor.
It can be deadly by ingestion and penetration into the respiratory tract.
H315 Causes skin irritation.
H332 Harmful by inhalation.
H351 Suspected of provoking.
H373 It can affect the organs after prolonged or repeated exposure.
H401 Toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.

Additional Information This document contains important information to ensure

the storage, handling and safe use of this product. The
information in this document must be brought to attention
from the person in your organization responsible for providing guidance
on security matters.
Version Number of the 2.0
Safety Data Sheet
Effective Date of the MSDS 01/07/2012

MSDS revisions A vertical bar (|) on the left margin indicates a

change from the previous version.
Regulations of Safety Data Sheets (SDS) The content and the format of this Information Sheet
Chemical Product Safety is in accordance with the
requirements of ABNT 14725-1:2009.
Uses and Restrictions This product should not be used in applications other than those
recommended in Section 1, without first seeking the opinion of
supplier.
This product should not be used as a solvent or agent of
cleaning; to ignite or rekindle fire; as a cleaner for the
football

Date of FISPQ Preparation: 03/21/2011 13/14

 Shell Evolux Diesel B S500
Version 2.0
Effective date 01/07/2012

Chemical Product Safety Information Sheet

Distribution of the Safety Data Sheet The information contained in this document must be
made available to everyone who can handle the product
Resignation This information is based on our current knowledge, and
is intended solely to describe the product regarding the requirements
in terms of health, safety and environment. It should not put
so much to be interpreted as a guarantee of any property
specific to the product.

Revisões:
On 07/01/2012 - revision 2.0 - Color change, as per ANP Resolution No. 65, dated 12/09/2011.

Date of Preparation of the Safety Data Sheet: 03/21/2011 14/14