Atomic Mass MM, The mass of 3.210 atoms ofan elements 8.0% 10° g. The atomic mass of the element is about (Ny = 6x 10%) (©) 80x10 (@) 30 (M4 = 6.0% 109) . Number of| AQ? ‘Wt (in gm) 13, If (NEERAJ KUMAR’ js written by a graphite pencil, it weighs 3.0 x 10°” g. How many carbon ‘atoms are present in it? (4 = 6 10”) (@ 15x10" () 5x10” (©) 2x10" @ 15x10" 14, The atomic masses of two elements P and Q are 20 ‘and 40, respectively I’ g of Pontains‘# atoms, ‘then how many atoms are present in‘2a'gof Q? (5 @ % 15, 16. v. 1. “The molecular formula of @ compound isX,0, thecompound contains 40% X by mas, then ig isthe atomic mass of X? ou m2 ©» @©B [A quantity of 1 of metallic carbonate js completely converted into a chloride XC, ‘weighing It] p The atomie mass ofthe element is @ 0 ©) 20 © 30 @ 40 ‘An element X has three isotopes X2°,X2! and XP, The perentage abundance of Xi 90%¢and swerage atomic mass of the clement is 20.18. Te percentage abundance of X° should be (2% © 8% © 10% @) 0% A sample of hydrogen gas is collected and & is observed that it contains only hydrogen ad deuterium atoms inthe atoms ratio 6000: 1. Te ‘number of neutrons in 3.0 g of such a sampl| ‘should be nearly. — a (a) 0.0005 (&) 31x10 (© 1805108 ; @ 10 If isotopic distribution of C? and Cis 980% ‘and 2.0%, respectively, then the number of atoms in 12 gof carbon is () 1.032 « 10 () 1.20% 10 (©) 5.88% 10 (a) 6.02 10 ‘Scanned with CamSeannerwir ina sample of (387 hy 388 ining oly CU (atomic weight {o) INS as 34.9 an C1" (aon weet = 369) isotopes bs (6, The erage mass nor of ehlvine is ‘Molecular Mass 21, ‘Twenty molecules of SO, wil sgh as meh 8 —-2K Aono contains 7 eatbon atoms, 2 onyzen osu of oxygen some ta 996% 10° gof other elements, The (a) 100 ws ‘moka aso compound st, = 610") ws wes 2 116 2 Themassof COsthat mua hemined witkangor © MS (a 158 onygensich hat 27mfefastmpleotthetesiing 23-1 the mass of neuton is doubled and that of minturewouldeontsinequataumberof melculss proton is aed, the molecular mass of HO ofeach Bis ontning only Hand 0” atoms will (@ 145¢ ©) 22508 (increase by about 25%. 41258 © 38 (6) decrease by about 258, (@ inerease by aboot 16.67% B.A mine of 2 x 16 molecules of P and (decease abou 16675, 3x 10" molecules of Q weighs 0.60 g. Ifthe molecular massof Pis 4, then the molecular mass 30 Outof Lg diowygen, 0 g atomic oxygen and 1.0 Twili 6x02) fg ozone, the maximum number of oxygen stoms 4s © 180 eeseoniained co ane (@ 1.0 g0f atomic oxyeen. (b) 10 of ozone (10g of oxyzen as (@) Alleontain th same number of atoms. 24, ‘The shape of tobacco mosaic virus (TMV) is cylindrica, having fength 2000 A and diameter 170A. I the specifi volume of virus is 12.8 mil, thea the molecular mass of TMV is (N,=6% 10) 31, Total number of electrons present in 44g oxalate (a) 328 () $44x10™ jon(C,029 8 (@ Sa4x10™ (a) 327x108 (@) 005%, () 238, 2S, The density of a DNA sample is Lgl! and is (9) 22N, (@) 21Ng rnolar mast determined by eyowopic method was 3p, found fo be 6% 10 pine What ste volume Pron (ys oxaidyon DNA nob, = 60") an ae (@) S45x 10m) 183x107? mt ook aa (©) 9.09 107" ml (@) 1.09107 ml ‘Total number of valence electrons present in 64g 38, The umber of F° ions in 42 ¢ AIF, i 26, How many atoms do mercury vapour molecules (enF=1) consist of if the density of mereury vapour elative (@) 005 (b) 9.03 10" toms 6920 The average asso a2 8 per A eee (© 30110 (a 085 @. 2 {MA quanty of 13. gf smn when changes 4 (8) Infinite to Al ion in solution will lose (Al = 27) 2. Vapour desiy of a voile substance is 12 (@) 180% 10eestons {Cig Dy temolecaar mass would be {b) 62> 10? eectons (12 24 (301% 10? electrons (c) 36 (@) 72 (4) 9.03 x 10 electrons: ‘Scanned with CamSeanner TotalOnn 3S. am oz salt contains 1 of KI and a person {akes2 got thes every dy thong ons goin ino his boty everyelay wou be approxi 23.1 Calculation of Mole $6 Dopamine is a newotransites «mola that senes to transmit message inthe brain, The hil formu of dopaine Cth O,N How nay moles are thee! go dopamine! (a) 000654 (183 (0 o0ess (@) None of these 37, Ethanol isa substance, which commonly called alcoho. The densi of liguid seo is 8 gf 88293 K. If 1.2 moles of ethanol is needed for 4 partir experimen, then what lume of «tanol shoud be massed out (@) 352m © s75m1 © Omi @ 99m {3k The volume of one mol of water at 27 Kis 8m (One mi of water conan 20 mp The mde of rolclesinone dro of wae il bey 610°) @ 107x108 0) 1st x108 (9 26710" (@ Lor 10" 38. A given mince consists ony of pure substance X and pare substance Y. The ft mass of the anixtur 3.72 g. The total number of mols is (006. I the mass of one mole of is 48 g and thers .02 mole of Xin the mitre, then what is the mass of one mole of X? @ © Be (@ 45¢ @ 180g 40. Number of gas molecules present ia 1 mal of gas at 0°Cand 1 atm is ealed Loschmidt number Its value is about (@) 2.7% 10" ) 610 (© 27% 107 (@ 13x10" 41, Agquantty of 025 gof asubstance when vaporized displaced 50 em? of air at 0°C and I atm. The gram molecular mass of the substance will be (@) 50g () 100g (@ 1Rg @ 12758 42, Anamount of 6molesof Clatoms at STP occupies volume of a. 8 (72108 9 12x10 to sexo" (a) ose worn ta) 1624 While cesting, an average 70 kg, human male consumes 16428 L of oxygen per hour at 27 fw many moles of oxygen a find 100 KPa Consumed by the 70 kg man while resting for Thou (07 () 667 (@) 666.7 @ os One molecule of haemoglobin wll combine with four molecules of oxygen. If 1.0 gof haemoglobin combines with 1.642 ml of oxygen at body ‘temperature @7°C) and a pressure of 160 tor, then wha is the molar mass of haemoglobin? (@) 690000, ) 150,000 4 15,000 (@) 60.000 A quanity of 2.0 gof a triatomic gaseous element ‘was found to occupy a volume of 48 ml at 76em of Hand 273 K. The mass of ts each atom is (@) 100amw ©) 553x107. @ 23g @ S53am0 ‘The most abundant element dissolved in sea water is chlorine at a concentration of 19 ghkg of set ‘water. The volume of earths ogean is 14 10"L How many g-atoms of chlorine are potently available from the ooeans? The density of 8 waters gil (Ny =6% 102), (@) 75x10" (b) 27% 10" (© 2x10" (@) 75x10 From 2mgealeium, 1.2 10” atoms are removed ‘The number of g-atoms of ealium left is(C8=40) (@) Sx 10% (b) 2x10 (@ 3x10% (@ sxi0* ‘The number of g-molecules of oxygen in 6023 * 10 CO molecules is (@) I g-motecule (6) Se-molecules (b) 05 gmotecule (6) 10g-molecules ‘Scanned with CamSeannerwien’ @ 49, Equal masses of oxygen, Iydrogen and methane swith SO, atthe sume temperature and press, ane taken in identent conditions, What is the and again weighed. The weight of oxygen is rato of the volumes of the gases ue identical 2) the sme that of conditions? wn hat of $03, (16:18. () [Link] (b) 5 that of 80, (@ [Link], (21621 (6) twice that of $0, 50, A pre-weighed vessel was filed with oxygen at (8) + that of S0,, [NIP and weighed. It was then evacuated, led 4 ‘Average Molecular Mass 1, Molecular mas of dry aris (@) 308 () 70% (@) less than moist aie (9 0% @ 0% (©) sreter than moist ait, 156, ‘The density in /L) of an equimolar mixture of (6) equal to moist ie, methane and ethane at I atm and 0°C is (@) may be greater or less than moist sit (@ 103 (0) 208 © 094 (@ 12s $2. At room temperature, the molar volume of Inydogen fluoride gas has a mass of about $0 g, $7. ‘n'mol of Np and 005 mol of Ar is enclosed ina ‘The formula weight of hydrogen Buorde is 2. ves of pacity 6Lat laimand27°C. Thevalue ‘Therefor, gaseous hydrogen fluoride at room of nis (R=008 Latm mol K") temperate is probably mixture of (02s 029 (a) Hand, (6) HP and HF, © 00s @o4 (9 Mand HPs (@) FaFLamO SF; gg, gaseous mintre contains 40% Hy and Of He by volume. What i the total numberof moles of 53. A gaseous minture contains 70% Ny and 30% ee unknown gts by volume Ifthe average molecular rmass of gaseous mixture is 3760, then the (a) $ 25 molecular mass of unknown gis 33 (@ 3125 @ a2 oo 59. A sample of ozone gas is found to be 40% oa ox dissociated into oxygen. The average molecular 4 Themasscompositon of unversemaybegivenss mss of sample should be 0% Hy and 10% He. The average moleular mass (a) 41.60 Or) of universe shouldbe © 4238 @ 3840 (@) 220 210 4, The vapour density ofa sample of SO, gs 28. © 380 (364 Its degre of dsccation into SO and Opis SS. A quantity of 10 g of @ mistue of GH and @) 197 0) M6 Giiy oovupy 4480 lat atm and 273K The (67 (0) 28 peoentage of C;H, by mass in the mixtures BSE ee eee eee Percentage Composition 1, The commonly wsed pain liver, aspiia, has the worn () 00717 molecular formula G0, If sample of aspirin © 80008 (0) 06458 Contains 0968 g of eatbon, then what isthe mass of fydrogen inthe sample? ‘Scanned with CamSeannerOo 62, For CuS0,SH,0, which it the comet mole relationship? (@) 9x Mole of Cu» Mote of 0 () 5x Mole of Cu=Mole of 0 (© 9x Mole of Cu=Mole of () Mole of Cu= $% Male of 0 63. ‘The percentage of Fell) present i iron ore egy} Ojai (Fe = 50) (98 ws (2s @is (64. A quantity of 5 of a cepstaline salt when rendered ankydrous lost 18 g of water. The formula mase ofthe anfydrou salt is 160. The numberof molecules of water ofeystalization in the sate ws ws 2 @. 68. Cortsone is a molecular substance containing S1"stoms of carbon. per molecule The: mass percentage of carbon in cortisone s 69 98%. What the molecular mas of cortisone? (@) 18005 () 3601 (3128 @ 2058 6. A polsigtene of formula Br,CH(Cyle) was prepared by heating styrene with teromobeazy! Deronide inthe absence of aiz eas found t0 contin 10-46% bromine mass. The alu of ny rst) ya ® i) 20 aie 2 sre carbon by a8 IT om 30, the is 10 gi 61. compound cota Ag? cots (0 ct eh a mols of compound i @ «07 (o) 045 (© 050 @is ing of exygen in compound is 45. Tum molar mas wil be (@) 100 400 © 2 2 TnDamss method, 0:2 gf an organic nog wa peru ave 28 ml of Ny (ome reduced 0 Eat. What the percentage trogen Sy musta he compound? ons @ 815 (0 380 @ 40 10. quant of 02 ¢ of an organic compound eating ©. Hand © on combustion yited {i117 g COs and 012 g water The percentage of oven @ 1B29% ore () 78.45% (@) 89.50% oe Empirical and Molecular Formula ‘71. The empires! formula of an organic gaseous compound containing carbon and hydrogen is CH, The volume occupied by certain mass of this gas is exall hall of the volume eccupied by the same mas of nitrogen gas under identical Conditions The molsclar formal of the organic mse 6) Gy cH (0 Gis GH 72 A compound has carbon, bytogen and oxygen 3:31 atomic ratio Ifthe umber of moles in |g ofthe compound ie 606 x 10", then the ‘molecular formal of te compound wil be @ GO (6) GH,0, (9 CHO, (8) CH.0, 7B. A compound having. the empial formula, Gyno bes 2 molecular weight OF 170 3. The rocco frmala ofthe compound i @ oH.o &) CaHy0, © Ca, @ Gin, 7A, Ita found fom the chemical analysis of «sa ta ta hon some for xh exon stom. ACO'C and I atm is density is 125 8 Per lige The formula ofthe fas would be @ oH, © GH © GH @ Cat, 75. A quantity of 14 g of a hydrocarbon gives 18 fg water on complete combustion. The empiteal Formula of hydrocarbon is @ cH () CH © CH, @ CH, ‘Scanned with CamSeannerAnswer Keys Laws of Chemical Combinations L@ 2@ 3@ 40 5% 6@ 7©@ &@ %@ 10) Atomic Mass 11. (b) 12.) 13. @) 14. (&) 15. (@) 16. @) 17. (@)_ 18. (db) 19. (b) 20. (by Molecular Mass 21. (b) 22. (b) 23. (c) 24. (d) 25. (©) 26. (a) 27. (©) 28. (a) 29. () 30. (d) 31. (b) 32. @) 33. (b) 34.) 35. (b) Calculation of Mole 36. (a) 37. (©) 38. () 39. @) 40. (@) 41.) 42.) 43. (@) 44. (d) 45. (b) 46. (a) 47. (©) 48. (©) 49. (b) 50. (b) Average Molecular Mass 51. (b) 52. d) 53. (b) 54. (6) 55. (a) 56. (2) 57. (b) 58.) 59. (b) 60. (c) Percentage Composition 61. (b) 62. (a) 63. (d) 64. (b) 65. (b) 66. (©) 67. (b) 68. (b) 69. (@) 70. (a) nal and Manlactlar Earmula ‘Scanned with CamSeanneroe HINTS AND EXPLANATIONS EXERCISE I (JEE MAIN) Laws of Chemical Combinations 1. Masof CO, formed 275g 6 tm 100 of weak tg the ms fetid ‘From mass conservation, mass of water formed bears i ee or sara ee eee 4 g. If ‘x' g water is evaporated, the 2 Total mass of reactants taen Fs - 10.8 + (50x 1.2)=70.8g Ce WOO errr Hens mast of HS pressed 1. Mas of water molecules in ite of stam = deniers doe 1000.6 Avior HO ss he mon ded i. ‘condensed state is liquid water, we may assume ence, volume of H, gs released thats ete the ineoscicalarspace fs nog fa compariton tothe slum cose ty tetgud mote Hence he volume osspiod 3. Masso ro exe amen (5.4 + 18.5) — (11.24 10.2)=2.5g beeline 10 5 4. Density of thetiquid in bote = 222.1487 gem? Mass of bates should bs ten ps day 5, Let the mass of ethanol in the solution be’ ascigeae AS, Matuion = Vetanat * Veer 9. Aluminium has a variable valency. x, S08 , EB oa ee 10, Incompund"Y"4 gf A wilcombine wi see =28 g of and hen 8g A wil smbie wi ence as per ent of smect peda Atomic Mass Haase 13, NunberotCatons= 32220 610? 0x10 a 2 x6x 1015 ace Soa Ls! 14 AS the moe of stoms is same. the numer of 2. ‘atoms is also same. | ona 1, $= 4s atomicmus of X ty ‘Number of 9 60/16 bin a 1 LL w% te atedede ” Hass . Atomic mass of X. Ay =40. Slope» i sxe 2090+ 92214 (10=s)%22 Tronic mast se anann OADOEIMAUO AI? gg = Atomic mass = 40 00 ‘Scanned with CamSeannerNS i 5 re] zB 4 @ 4 = Dison Number of atoms 18, Number of neutrons 3 x 6.022% 107" x 2 22% 10° pamele 20, Average ass number = 0.635 + 04% 370359 19. Average atomic mass of C= 12X98 +1442, Molecular Mas a 29, Nowmoleeular mass of HO=2405+ 120-2) 100 = 16.67 % a 5 4 I cg =0.6 = Mg=90 Bae + fron 06-9250 an sane mn es 24, Volume of each virus partick a Len 31. Number of electrons tax Bxio* en?) coms - 680610" em es 2 Naat whan = SI sect Ones ox Semens Motorist ins si. Nemteret Fone ot wane x meade 1027 1h = 25, Yun of cach noel : cece Nant denne BE 682103 26, fami of meen hen 28 : 235 Number ais wo =692%2 = x= I, reece sax" 27, Molecular mass=12330=36 28. Molecular mass=7x 12 +2x 16+ 096 x10" 6x 108) = 122 Calculation of Mole ‘Number of water molecules in one drop = axa" = co 18 36. 3B, STD=OMX Ay + OX A8 = a. 1 anessll wh 10 2668xI Taxon 0" ‘Scanned with CamSeanner2, 6 oes of chlorine ats i 3 moles of chlorine rolvuesand henee the volume» 3%22.7= 681 ene BE, 10x10 16,628 10°" Boar 314% 300 1(1.682/1000) 067 = M=c0n00 Hap oszixa00 f (448/000) cmans Aw 1 48 Ge Doar > Aomicmans A» Hence, mas of each aon 00 a“ 100 16610 © 160 S33x 0g Average Molecular Mass 51, As the molar mass of H,0 is es than that of Oy land Ns, the molar mass f moist ai less than ‘tha of ya. ‘2, The average molar mass of HF, and HyF, may be 50. sh sre DA28430eM 100 100 _ 90 , 10 10090 4 10 yer, ss, BLD 1s 55, Average molar mass ofthe mixture = Mass per cet of Cyl Percentage Composition 61. Masso drogen 1 5 0.968 = 06717 Je Moles of Outoms=9 x Moles of Cu Jo. ey Gye 093~ ay x GEL = s=014 46. 4 ”. waicaean Q [Number of g-atoms ofehorine _ bao 19 355 49.210" 2a" _ Lato” 060x108 x? Number of patems lft = Number of emolcies of oxygen 02210" 1 “Gonzi “2 Vo, Vin Hen, M2, eo 8. 998 = 1x6 ait = nnn 0.08300 o (n+ 0.05) Average molar mass ofthe mixture = Mx + 604 10 amber of me of espns #0 =32 su Ba) 80-56 6 04: = Maw Peventage of iron as Feit) 1B S18 y itu * To Bx S100 => Ae 3601 ‘Scanned with CamSeanner UIE Msc ae arto22 100 ene, moles of compound Mass of nitrogen in the compound Now $6514 x n= n=4 Hence, the molecular formula of compound Empirical formula mas. 12+ 3x1 +116 3 and hence, the molecular Formula =(C3HO}s= C410, = Molecular formula =(C3H,0); 1254224=(1 124 2 I)en op n=? = Motecular ere Hy Mass percent of yrogen = and mas percent of carbon = 100 ~ HINTS AND EXPLANATIONS: Percentage of nitrogen the compound = 2035 100 = 17.5% 02 Mass pr esnt of carbon 12,047 100 =2005 a Mass percent of oo 12,012 i802" ene, mass percent of oxygen = 100-2005 + 667) ‘Now atomic ratio of Cand H = 07 , 10/7 Era T ence empisa omula=CH, 12 Mass percent of oxygen 100 ~ (0 + 657) Now, Ne: Ny: 2 = Enpitial formula = CHO MyiMy:Now AM Ne® 25 a5 * 0” = Empirical formula = A,B,C, 63:2 ). Molecular mas of oxide = 1 514 504 Hence, density of oxide lative to one | dase Ma dem” Monge 71 Lette oxidesbeFe,0, and Fe,0,, Frome! ‘Scanned with CamSeanner