27-07-2025

1701CJA101029250032 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Figure shows, a glass prism ABC (refractive index 1.5) immersed in water (refractive index 4/3). A
ray of light incident normally on face AB. If it is totally reflected at face AC, then :-

(A)

(B)

(C)
sinθ =

(D) < sin θ <

2) A ray of light strikes a plane mirror at an angle of incidence 45° as shown in the figure. After
reflection, the ray passes through a prism of refractive index 1.5, whose apex angle is 4°. The angle
through which the mirror should be rotated if the total deviation of the ray is to be 90° is :-
(A) 1° clockwise
(B) 1° anticlockwise
(C) 2° clockwise
(D) 2° anticlockwise

3) An object ‘O’ is moving in front of a concave mirror along principal axis with velocity v. The mirror
is also moving with velocity v as shown in figure. The velocity of image with respect to the ground is

(A) 5v
(B) 4v
(C) v
(D) 9v

4) If final image formed after two refractions through the lens of refractive index 1.5 and one
reflection from the mirror forming at same point ‘O’ then d is equal to :-

(A) 100 cm
(B) 120 cm
(C) 90 cm
(D) 80 cm
 SECTION-I (ii)

1) Electric field in a region is given as . A charge particle of mass 5kg and charge
Q (= 1C) is released from origin at rest and free to move in given electric field. Then choose the
CORRECT option(s) (Neglect gravity) :-

(A) Motion of charge particle is Oscillatory.

(B) Maximum displacement of charge particle from origin is 4 SI units.
(C) Maximum velocity gain by charge particle is 2 SI units.
(D) The position of charge particle, when velocity gained by particle is maximum, is 2 SI units.

2) Two concentric metallic shells of radii R and 2R are placed in vacuum. The inner shell is having
charge Q and outer shell is uncharged. If they are connected with a conducting wire. Then :-

(A) Q amount of charge will flow from inner to outer shell.

(B) Q/e number of electrons will flow from outer to inner shell, where ‘e’ is charge on an electron.

(C)
amount of heat is produced in the wire.

(D)
amount of heat is produced in the wire.

3) The diagram shows part of an evacuated tube in which a stream of electrons from an electron gun
passes between a pair of parallel large deflecting plates. The vertical displacement of the electron
beam as it leaves the parallel plates is x. (Do not consider gravity and the electron enters the

deflecting region parallel to the plates) Which

one of A to D below will change the displacement x of the beam as it leaves the parallel plates ?

(A) increasing the accelerating voltage

(B) increasing the deflecting voltage
(C) increasing the distance between the electron gun and the deflecting plates
(D) increasing the distance between the two deflecting plates

SECTION-II (i)

Common Content for Question No. 1 to 2

Figure shows the circuit of a potentiometer. The length of potentiometer wire AB is 50 cm. The emf
of the battery E1 is 4 volt, having negligible internal resistance the values of resistance R1 and R2 are
15 ohm and 5 ohm respectively. When both the keys are open the null point is obtained at distance
of 31.25 cm from end A but when both the keys are closed the balance length reduced to 5 cm only.
RAB = 10 Ω.

1) The emf (in volt) of E2 is _____

2) The balanced length (in cm) when key k2 is open and k1 is closed is given by _______

Common Content for Question No. 3 to 4

In the circuit shown below, the switch S is connected to position P for a long time so that the charge
on the capacitor becomes q1 μC. Then S is switched to position Q. After a long time, the charge on

the capacitor is q2 μC.

3) The magnitude of q1 is ___ .

4) The magnitude of q2 is ___ µC.

SECTION-II (ii)

1) All the capacitors in the given figure has a capacitance C0. The equivalent capacitance between

the points A and O is x µF. Find x, if C = 9 µF.

2) Two identical capacitors having plate separation 1mm are connected parallel to each other across
points A and B as shown in figure. Total charge of 4 µC is imparted to the system by connecting a
battery across A and B and battery is removed. Now first plate of first capacitor and second plate of
second capacitor starts moving with constant velocity 3 m/s towards left. Find the magnitude of

current (in mA) flowing in the loop initially.

3) In the figure as shown mass of both, the spherical body and block is m. Moment of inertia of the
spherical body about COM is 2mR2. The spherical body rolls on the horizontal surface. The ratio of

kinetic energy of spherical body to that of block at any instant is . Then fill the value of x + y.

4) A particle of mass 'm' is moving in time 't' on a trajectory given by

Where α and β are dimensional constants.

The angular momentum of the particle becomes the same as it was for t = 0 at time t =
______seconds.

5)

Find the potential of point A at steady state in the circuit shown in the figure. Capacitance is in µF.

6) In the figure hown the equivalent capacitance (in F) between ' A ' and ' B ' is :
 PART-2 : CHEMISTRY

SECTION-I (i)

1) 100 ml of 0.5 M hydrazoic acid and 400 ml of 0.1 M cyanic acid

are mixed.
Which of the following is (are) true for all the final solution?

(A)
(B)
(C)
(D)

2) In which of the following silicate per tetrahedral unit contain only one oxygen unshared corner ?

(A)
(B)
(C)
(D)

3) Two students tried to prepare t-butyl methyl ether by different ways:

Student-1 :

Student-2 :
Choose the correct option about their major product:

(A) Both get same major product but with different mechanism
(B) Both get different major product but with same mechanism
(C) Both get same major product and with same mechanism
(D) Both get different major product and with different mechanism
4) Two alkenes , X(91% yield) and Y(9% yield) are formed when the following compound is heated.

The structures of X and Y, respectively are :

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) Salt solution
'X' + neutral FeCl3(aq.) → 'Y' (deep red colouration) + 2H+;
Y' 'Z' (Brownish red ppt.)
Correct statement(s) about the above experiment is/are:-

Aqueous solution of 'X' salt gives deep red coluration, with neutral FeCl3 owing to formation of a
(A)
complex ion "Y" is [Fe3(OH)2(CH3CO2)6]+.
(B) The compound Y is Fe(SCN)3.
On boiling the red solution of 'Y' gets decomposed into brownish red precipitate of 'Z', which is
(C)
basic iron (III) acetate.
(D) The ppt. Z is Fe2O3.3H2O.

2)
Which of the following is/are used to explain the above conversion?

(A) It is intermolecular SN2 reaction

(B) One of the step involve product’s formation is acid base reaction
(C) It involve intramolecular SN2 reaction with inversion of configuration.
(D) The product obtained in this reaction is unreactive towards KOH but it reacts with HI

3) Which of the following is / are correct?

(A) All Arrhenius acids are also Bronsted acids.

(B) All Bronsted bases are also Arrhenius bases.
(C) All Bronsted bases are also Lewis bases.
(D) pH of 10–8 M HCl (aq) is 7.04 while that of 10–8 M NaOH (aq) is 6.96.

SECTION-II (i)

Common Content for Question No. 1 to 2

The boiling point of water in a 0.1 molal silver nitrate solution (solution A) is x °C. To this solution A,
an equal volume of 0.1 molal aqueous barium chloride solution is added to make a new solution B.
The difference in the boiling points of water in the two solutions A and B is y × 10–2 °C.
(Assume : Densities of the solutions A and B are the same as that of water and the soluble salts
dissociate completely.)
Use: Molal elevation constant (Ebullioscopic Constant), Kb = 0.5 K kg mol–1; Boiling point of pure
water as 100°C.)

1) The value of |y| is _____ .

2)

The value of x is _______.

Common Content for Question No. 3 to 4

Consider the following reaction.

3) Calculate value of |x2 – y2| where x & y are total no of electrons present in t2g and eg orbitals
respectively in d-block metal ion of compound B.

4) How many of the following statement are correct?

(1) Gas A does not react with sodium nitro prusside in basic medium.
(2) Gas A is identified by reaction with lead acetate.
(3) Gas A gives white PPT after reacting with aq. BaCl2.
(4) Gas A after reacting with moist SO2 gives yellow turbidity.
(5) Gas A is also formed by reaction of Na2SO3 with Zn + NaOH.

SECTION-II (ii)

1) Calculate the pH at which the following conversion (reaction) will be at equilibrium in basic
medium I2(s) I–(aq) + (aq) when the equilibrium concentration at 300 K are (I–) = 0.10 M
and .
{Given that = –50 kJ/mole,
= –123.5 kJ/mole,
= –233 kJ/mole,
(OH–, aq) = –150 kJ/mol,

ideal gas constant = R = J mole–1K–1,

loge 10 = 2.3}

2) In the given following complex compound / ions, how many exist in enantiomeric form ?
[Pt(NH3)3Cl3]+ , [Co(NH3)2(H2O)2Cl2]+ ,
[Cr(H2O)3IBrCl] , [Pt(en)2Cl2]2+ ,
[Cr(bipy)2BrCl]+, [Co(en)3]3+

3) The no. of ores which can be concentrated by froth flotation process among the following ores are
Rutile
Tinstone
Argentite
Copper pyrites
Fluorspar
Sphalerite
Horn silver
dolomite
Cerussite

4) How many of the following compound/ion will give white ppt with AgNO3.

5) Consider the reaction given below :

(R) – 2 – chloropentane monochlorination takes place. If the mixture of products is subjected to

fractional distillation, how many fractions would be obtained?
6) If three reactions:
A Products; Rate = K1[A]X
B Products; Rate = K2[B]Y
C Products; Rate = K3[C]Z

Value of is ?

PART-3 : MATHEMATICS

SECTION-I (i)

1) If ƒ(x) = sin2x + [Link], then ƒ(x) = 0 has

(A) exactly one root in (0, 2π]

(B) atleast two roots in (0, 2π]
(C) atmost one root in (0, 2π]
(D) no root in (0, 2π]

2) Statement-1 : If ƒ (x) = 4x3 – 9x2 + 12x – 12, then ƒ(x) = 0 has atleast one solution in (1, 2).
and
Statement-2 : If ƒ (x) is a differentiable function in [a,b], then ƒ'(x) = 0 has atleast one solution in (a,
b) provided ƒ(a) = ƒ(b).

(A) Statement-1 is True, Statement-2 is True.

(B) Statement-1 is False, Statement-2 is False.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

3) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

The value of c in (0, 1) satisfying the mean value theorem

(A) (I)
for the function ƒ(x) = x(x + 1)2

(B) (II)

ƒ(x) = attains maximum at

 Minimum value
(C) (III)
of is

(D) Function on ƒ : R → R, (IV)

is decreasing at x = α, then α can be
(A) A → I; B → II; C → III; D → IV
(B) A → III; B → I; C → II; D → III
(C) A → II; B → IV; C → III; D → I
(D) A → I; B → III; C → III; D → II

4) The shortest distance between the curve y = x2 + 3x + 2 and the line y = x is :

(A)
(B) 2

(C)

(D) 1

SECTION-I (ii)

1) If the circle x2 + y2 + 2gx + 2fy + c = 0 bisects the circumference of the circles x2 + y2 = 6,

x2+y2–6x –4y + 10 = 0 and x2 + y2 + 2x – 2y – 2 = 0, then

(A) c = –6
(B) g +f – c = 4
(C) gf = 1
(D) g2 +f2 – c = 8

2) If the line (y – 1) = m(x – 1) is a chord of the circle x2 + y2 – 3x – 4y – 1 = 0, then the value of m

can be equal to -

(A) 1
(B) 2
(C) 3
(D) 4

3) If , where C is constant of integration and α, β >

0, then

(A) |α – β| = 1
(B) β, α, 2010 (in order) are in arithmetic progression
(C) |α – β| = 2
(D) α, β, 2010 (in order) are in arithmetic progression
 SECTION-II (i)

Common Content for Question No. 1 to 2

Consider ƒ(x) = x4 – 3x3 + 2 and h(x) = be a rational function.

(i) infinite

(ii)
(iii) h(x) is continuous ∀ x ∈ R – {1, 2}
(iv) g(x) does not have any repeated factors.

1) Number of solutions of equation |g(|x|)| = is -

2) Number of points where P(x) = sgn(g(x)) is non differentiable in R is (where sgn(x) denotes
signum function of x)

Common Content for Question No. 3 to 4

Consider a function . Let , where constant of integration is zero.

3) The number of local maxima of g(x) in (0,8π) are -

4) The number of points of inflection of g(x) is (10π,22π) are -

SECTION-II (ii)

1) The value of expression is

(where [.] denotes greatest integer function & {.} denotes fractional part function respectively)

2) Let f(x) = (x – 1)100 (x – 2)2(99) (x – 3)3(98) ... (x – 100)100, then the value of is

3) If the integral = A cos 8x + k, where k is an arbitrary constant, then |A| is

equal to :

4) If dx = ℓn + c, then k is equal to :
5) If the pair of lines (x – 2)2 – (m1 + m2) (x – 2) (y + 2) + m1m2(y + 2)2 = 0 is tangent to circle (x – 1)2
+ (y – 1)2 = 2 (where m1 > m2) then match List-I with List II

List-I List-II

P 1 1
is equal to

Q |m2| is equal to 2 7

Square of radius of circumcircle of

R triangle formed by tangents and chord of 3
contact, is

If O is centre of circle and A,B are point

of contact of tangents, P is point of
S 4 4
intersection of tangents then area of
quadrilateral AOBP is

6) Let f(x) be differentiable for all x. If f(1) = –2 and f'(x) ≥ 2 for all x in [1, 4], then the least value of
f(4) is :
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A B D D

SECTION-I (ii)

Q. 5 6 7
A. A,B,C,D A,B,C A,B,D

SECTION-II (i)

Q. 8 9 10 11
A. 1 12.5 1.33 0.67

SECTION-II (ii)

Q. 12 13 14 15 16 17
A. 20 6 11 10 15 2

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. A D D C

SECTION-I (ii)

Q. 22 23 24
A. A,C B,C,D A,C

SECTION-II (i)

Q. 25 26 27 28
A. 2.50 100.10 36.00 3.00

SECTION-II (ii)

Q. 29 30 31 32 33 34
A. 8 5 2 3 7 25

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. B A B C

SECTION-I (ii)

Q. 39 40 41
A. A,B,C,D A,B,C,D A,B

SECTION-II (i)

Q. 42 43 44 45
A. 6.00 2.00 4.00 12.00

SECTION-II (ii)

Q. 46 47 48 49 50 51
A. 5 5050 0 1 2134 4
 SOLUTIONS

PART-1 : PHYSICS

1) Since TIR occurs at surface AC, thus

1.5 sin θ = ⇒ sin θ =

Therefore

2)

r = A(H – 1) = 4 × = 2°
∴ total deviation = 90° (due to reflection) + 2° (due to prism) = 92°
but net deviation should be 90°
∴ due to reflection = 88° = π – 2i
⇒ i = 46°

3)

Mirror formula :
Differentiate mirror formula w.r.t time

VI = 9v

4)
∴ flens = 40 cm
Thus image will be formed at +2f
The ray will retrace if d = 2f or d = 2f + 30

5)
m = 5kg

(a) F ∝ – x
so motion of charge particle is oscillatory
(b) F = 0 at x = 2
oscillation about x = 2
so maximum displacement is 4
F = 10 – 5x

a=
a=2–x
a = – (x – 2)
so w2 = 1
w=1
(c) vmax = Aw
A=2
w=1
vmax = 2
(d) velocity at mean position
at x = 2

6)
(After connection entire charge moves towards outer shell)
Amount of heat produced = loss in electric potential energy

7) For (A) : increasing accelerating voltage will increase the velocity of electron thus will
decrease the time to cross the plates thus deflection decreases.
For (B) : increasing deflecting voltage will increase the magnitude of electric field between the
plates thus increase the deflection.
For (C) : increasing the distance between the electron gun and the deflecting plates will have
no effect on the deflection.
For (D) increasing the distance between two deflecting plates will decrease the electric field if
potential difference between the plates is kept constant thus the deflection decreases.

8)

k = Potential gradient =

E2 = kℓ =

9)

E2 = ⇒ ℓ = 12.5 cm

10)
Switch connected to position 'P'

Potential drop across capacitor

∴ Charge on capacitor

Switch at Position 'Q'

Potential difference across capacitor
∴ Charge on capacitor

11) Switch connected to position 'P'

Potential drop across capacitor

∴ Charge on capacitor

Switch at Position 'Q'

Potential difference across capacitor

∴ Charge on capacitor

12) Using the parallel axis symmetry it can be reduced to the following circuit.
Solving this circuit will give us equivalent capacitance between A and O as

13) Let each plate moves a distance 'x' from its initial position. Let q charge flows in the loop.
using KVL

=0

∴q= ;I= = ;

Ans, I =

14)

15)

At t = 0,
50αβt2 – 100αβ(t2 – 5t) = 0
t – 2(t – 5) = 0
 t = 10 sec

16) Correction by Aditya Sir

17) Equivalent circuit is

PART-2 : CHEMISTRY

18)

For HN3, In final solution

19)
20) Student-1 :

Student-2 :

21)

22)
↓Δ

23)

(B) One of the step involve product’s formation is acid base reaction
(C) It involve intramolecular SN2 reaction with inversion of configuration.
(D) The product obtained in this reaction is unreactive towards KOH but it reacts with HI

24)

(A) All Arrhenius acids are also Bronsted acids.

(C) All Bronsted bases are also Lewis bases.

25)

AgNO3(aq) —→ Ag+(aq) +
0.05 m 0.05 m 0.05 m
BaCl2(aq) —→ Ba (aq) + 2Cl–(aq)
2+

0.05 m 0.05 m 0.1 m

+ –
Ag and Cl combine to form AgCl precipitate

Ag+(aq) + Cl–(aq) → AgCl(s)

t = 0 0.05 m 0.1 m
t=∞ 0 0.05 m
In final solution total concentration of all ions :
[Cl–]+ +[Ba2+] = 0.05 + 0.05 + 0.05
= 0.15 m
ΔTb = 0.5 × 0.15 = 0.075 °C
B.P. of solution ‘B’ = 100.075°C
B.P. of solution ‘A’ = 100.1°C
|y| = 100.1 – 100.075
 = 0.025 = 2.5 × 10–2

26)

ΔTb = 0.2 × 0.5 = 0.1°C = 0.1 K

Boiling point of solution = 100.1°C = X

27) Refer notes

28)

Statement are correct 3

29)

log k = 30

OH– = 10–6
pOH = 6, pH = 8

30)
 [Co(NH3)2(H2O)2Cl2]+ , [Cr(H2O)3IBrCl] ,
[Pt(en)2Cl2]2+, [Cr(bipy)2BrCl]+ ,
[Co(en)3]3+ these five complex exist in enantiomeric from

31) (Copper pyrites, Sphalerite)

32)

Refer notes.

33) Since the reactant has a chiral center, all the seven products formed are diastereomers.

34)

Value of is = 25

PART-3 : MATHEMATICS

35) ƒ(x) = = x([Link])'

g(x) = [Link]
g(1) = 0, g(π) = 0, g(2π) = 0
∴ by Rolle's theorem
g'(x) = 0 has at least two root in (1, 2π)

36) Let g(x) =

⇒ g(x) = x4 – 3x3 + 6x2 – 12x
g(1) = g(2) = –8
⇒ atleast one solution of g'(x) = 0 in (1, 2)
⇒ 4x3 – 9x2 + 12x = 0 atleast once in (1, 2)

37) (A) ƒ(x) = x(x + 1)2

use LMVT in [0, 1]

3c2 + 4c – 3 = 0

∵ c ∈ (0, 1)

So

(B)

Maxima occur at

(C)

(D)

roots of ƒ'(x) are

38) Shortest distance along with normal

39) If the circle x2 + y2 + 2gx + 2fy + c = 0 bisects the circumference of a given circle, then
the common chord will pass through the centre of given circle.
⇒ 2gx + 2fy + c + 6 = 0 passes through (0,0)
⇒ c = –6
Also 2gx + 2fy + c + 6x + 4y – 10 = 0 passes through (3,2)
⇒ 6g + 4f + 10 = 0 ...(i)
and 2gx + 2fy + c – 2x + 2y + 2 = 0 passes through (–1,1)
⇒ –2g + 2f = 0 ...(ii)
From (i) & (ii), g = f = –1

40) Since line passes through (1,1)

which lies inside the circle ⇒ m ∈ R

41) x = t2

⇒
α = 2007, β = 2008. Now check

42) graph of |g(|x|)|

6 solutions

43) by (i) degree of g(x) must be less than 4

by (iii) g(x) must have x – 1 and x – 2 in its factors
by (iv) No other factor of g(x) will be possible as it can not be a linear factor or a repeated
fector
∴ Let g(x) = a(x – 1)(x – 2)

h(x) =

⇒ a=2
∴ g(x) = 2(x – 1)(x – 2)
= 2x2 – 6x + 4
44)
in (0,2π) there are 1 local maximum.
in (0,8π) there are 4 local maximum.

45)

in (10π,22π) there will be

12 points of inflections

46)

47) Let f(x) = (x – 1)100 (x – 2)2(99) (x – 3)3(98) ……….. (x – 1)100

take log both side

{∵ log(ab) = log(a) + log(b)}

⇒
Diff. both side w.r.t. x
 .

48) = A cos 8x + k ;
Differentiate both sides w.r.t x, we get

= – 8A · sin 8x

⇒ = – 8A · sin 8x

⇒ sin8x = – 8A · sin 8x

⇒A=

49) dx

= dx

= dx

= dx

= ℓn +c
∴k=1

50)

(x – 2)2 – (m1 + m2) (x – 2) (y + 2) – m1m2(y + 2)

are pair of tangents to circle passing
(x – 1)2 + (y – 1)2 = 2
Let slopes be m1 and m2
y + 2 = m(x – 2)
mx – y – (2m + 2) = 0
perpendicular distance from centre = Radius

⇒ (m – 7) (m + 1) = 0
But in given pair of lines slopes are reciprocal of m

∴ and (m1 > m2)

Length of tangent = ℓ =

square of radius of circumcircle =

Area of quad. = ℓ.r =

51) f'(c) = c ∈ [1, 4]

f(4) ≥ 4