Solve part b
For part (b), the expected form of the valence-band constant-energy surfaces for a cubic
material can be sketched as follows: Both A and B bands produce surfaces with distinct
curvatures due to their different effective masses. Near the B band maxima, the constant
energy surfaces will be spherical and larger due to the smaller effective mass, whereas near
the A band maxima, surfaces will be more compressed and smaller, reflecting a larger
effective mass. [1]
Explanation of Constant-Energy Surfaces
In a cubic crystal, the E–k relationship is isotropic and parabolic near the band extrema,
meaning that the constant-energy surfaces are described by the equation $ E = \alpha k^2
$ for each direction around a maximum or minimum. [1]
For a parabolic band around band maxima (as specified for the B band), the constant-
energy surfaces are spheres in k-space due to the symmetry and uniform effective mass in
all directions.
Sketch and Comparison
Band B (smaller effective mass):
Near the B band maximum, the curvature is higher ( is large), so the effective mass
is smaller ( ). Thus, for a fixed energy, the corresponding k-surface
(sphere) has a larger radius. [1]
Band A (larger effective mass):
For band A, the curvature is lower, resulting in a larger effective mass, so the corresponding
energy surface is a smaller sphere in k-space for the same energy difference from the
maximum. [1]
Inclusion of Both Bands
The final sketch should show:
Two sets of spheres centered at the maxima of bands A and B (in k-space, usually at
the Γ point for such problems), with the spheres for band B being noticeably larger.
These surfaces illustrate all k-points having the same energy for both bands, with size
inversely related to the effective mass. [1]
In summary:
Constant-energy surfaces for both bands are spheres due to cubic symmetry and parabolic
E–k dependence.
Surfaces for band B (smaller effective mass) are larger than those for band A (larger
effective mass), with both sets centered around their respective band maxima in k-space. [1]
⁂
Draw the diagram
Media generated: 'Constant-energy surfaces for A and B bands in cubic crystal k-space. B
surface is larger due to smaller effective mass.'
Draw the diagram
Media generated: 'Constant-energy surfaces in k-space for bands A (smaller sphere) and B
(larger sphere) for a cubic crystal.'
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