The Early Medieval Stained Glass Windows
The Early Medieval Stained Glass Windows
du 20e CONGRÈS
de l’ASSOCIATION
INTERNATIONALE
pour l’HISTOIRE du VERRE
Editing Committee
Erwin Baumgartner, Sylvia Fünfschilling,
Marion Gartenmeister, Anne de Pury-Gysel,
Stefan Trümpler, Sophie Wolf
Scientiic Committee
Anastassios Antonaras, Françoise Barbe, Erwin Baumgartner,
Uta Bergmann, Isabelle Biron, Brigitte Borell, Sally Cottam,
Patrick Degryse, Maria Grazia Diani, Anna-Barbara
Follmann-Schulz, Danièle Foy, Ian Freestone,
Sylvia Fünfschilling, Bernard Gratuze, Susanne Greif,
Yael Gorin-Rosen, Despina Ignatiadou, Caroline Jackson,
Yves Jolidon, Dedo von Kerssenbrock-Krosigk,
[Link] Stephen Koob, Ingeborg Krueger, James Lankton,
Irena Lazar, Isabelle Lecocq, Reino Liefkes, Dave Lüthi,
Teresa Medici, Marie-Dominique Nenna, Sarah Paynter,
Jennifer Price, Anne de Pury-Gysel, hilo Rehren,
Helmut Ricke, Beat Rütti, Lucia Saguì, Flora Silvano,
E. Marianne Stern, Stefan Trümpler, Marco Verità,
Sophie Wolf
Layout
Andrea Engl and ischbacher & vock
AIHV
Association Internationale pour l’Histoire du Verre
International Association for the History of Glass
Internationale Vereinigung für die Geschichte des Glases
[Link]
Romont 2017
Gesamtherstellung
CONTENTS
XI PRÉFACE
XIII PREFACE
XV VORWORT
Sylvia Fünfschilling
ROMAN GLASS
82 Gold-band glass fragments in the Römisch-Germanisches Museum of Cologne:
considerations about the techniques
Giulia Cesarin
87 La vaisselle en verre de deux sépultures aristocratiques augusto-tibériennes à Ath/Ghislenghien
(Province de Hainaut, Belgique)
Frédéric Hanut, Véronique Danese
92 Le verre romain de Montignac-sur-Vézère (Dordogne)
Laure Simon
98 he Roman necropolis of Budva (Montenegro) and its mould-blown glass assemblage
Irena Lazar
103 Mold-blown glass from the Roman province of Dalmatia
Berislav Štefanac
109 Römische Tintenfässer Isings 77
Michael Johannes Klein
116 A comparative investigation of the glass vessels and objects from eastern hrace and Lydian tumuli
in the light of the Düğüncülü and Güre inds
Ömür Dünya Çakmaklı, Emre Taştemür
V
Contents
124 Le sanctuaire d’Yvonand-Mordagne (Vaud, Suisse) : premier aperçu de la vaisselle cultuelle en verre
Chantal Martin Pruvot, Ellinor Stucki
132 Blown mosaic glass of the Roman period: technical observations and experiments
E. Marianne Stern
140 Two polychrome mosaic bowls and associated glass vessels from a rich 2nd century burial
at Kelshall, Hertfordshire, England
Sally Cottam, Jennifer Price
145 Früh- und mittelkaiserzeitliche Glasgefäße im nördlichen Obergermanien
Martin Grünewald
152 L’exceptionnelle verrerie d’un bûcher funéraire du IIIe siècle après J.-C. de Jaunay-Clan (Vienne, France)
Laudine Robin
160 Le verre archéologique du Canton du Tessin (Suisse) : une révision
Simonetta Biaggio-Simona
163 More glass from Aquileia (Italy)
Luciana Mandruzzato
VI
Contents
VII
Contents
379 13th–14th century glass in northwest Bohemia: typology, archaeometry and provenance
Eva Černá
385 Glass production in medieval Spain: a long-term perspective on knowledge transfer
Chloë N. Duckworth
391 Die Glaserzeugnisse Bolgars und ihr Verhältnis zu anderen mittelalterlichen Glasproduktionen
Svetlana Valiulina
399 Glass from Enez (ancient Ainos)
Üzlifat Canav-Özgümüş, Serra Kanyak
403 Indices de travail du verre rouge dans l’atelier médiéval d’Anlier, seconde moitié du XIVe siècle
(Luxembourg belge)
Chantal Fontaine-Hodiamont, Denis Henrotay
VIII
Contents
532 Mirrors, spectacles and looking glasses in Antwerp and the Duchy of Brabant:
aspects of production and use of optical glass based on serial documentary and archaeological evidence
Danielle Caluwé
537 Façon de Venise, une étiquette problématique. Propositions pour une méthodologie raisonnée de l’étude
de la verrerie à l’italienne en Europe, XVe–XVIIIe siècle, à partir de l’exemple du marché parisien (1550–1665)
Benoît Painchart, Christiane Guyomar
542 Diagnostic diferences between early iligree glass and the Rosenborg Castle-type iligree glass
Kitty Laméris
547 he golden age of Amsterdam glass. A chemical and typological approach
to recognize Amsterdam 17th century glass production
Michel Hulst, Jerzy J. Kunicki-Goldinger
554 What’s the purpose: oil lamp, perfume sprinkler or trick-glass?
Reino Liefkes
561 Court, Pâturage de l’Envers : une verrerie forestière du début du XVIIIe siècle entre
tradition et modernité (Jura bernois, Suisse)
Christophe Gerber
567 Der Kühlprozess der Glashütte von Court, Pâturage de l’Envers (1699–1714) im Berner Jura (Schweiz)
Jonathan Frey
575 Quelques révélations sur l’outillage de la verrerie du Pâturage de l’Envers à Court (1699–1714)
Lara Tremblay
578 Eighteenth century lead glass in the Netherlands
Anna Laméris
585 Imported beads in Russia in the 17th and irst half of the 18th centuries
(Moscow, Mangazeya, Smolensk region)
Julia Likhter
591 „Pressglas“ aus Benedict Vivats Glasfabriken
Valentina Bevc Varl
597 Glass ishing loats from Greek sites
Anastassios Antonaras
602 Crizzling glass – corrosion products and chemical composition of Bohemian glass
Zuzana Zlámalová Cílová, Helena Brožková, Michaela Knězu° Knížová, Irena Kučerová
606 he development of the chemical composition of Czech mosaic glass from the Middle Ages to the present day
Michaela Knězu° Knížová, Zuzana Zlámalová Cílová, Irena Kučerová, Martin Zlámal
612 he glass collection of Felice Barnabei at the Museo Nazionale Romano – Palazzo Massimo in Rome
Giulia Giovanetti, Silvia Bruni
617 Zwei vernachlässigte Glasvarietäten des 19. Jahrhunderts: Aventurin-Hohlglas und Uran-Selenglas
Sibylle Jargstorf
621 he Glass Room of the National Palace of Necessidades in Lisbon
Alexandra Rodrigues, Bruno Martinho, Frederik Berger, Anísio Franco, Márcia Vilarigues
625 Albert Dammouse (1848–1926) et la pâte de verre (1897–1913)
Véronique Ayroles
631 Le verre artistique de Saint-Prex (1928-1964)
Stanislas Anthonioz, Ana Quintero Pérez
ASIAN GLASS
640 A unique glass object from a Buddhist context in Sri Lanka
Brigitte Borell
647 Glass exchange and people in ancient East Asia
Chizuko Kotera
IX
Contents
652 Glass from Mughal India. A study of four eighteenth century cobalt blue bottles
Tara Desjardins
GENERAL THEMES
740 Le verre à l’école, un projet pour les jeunes
Maria Grazia Diani, Luciana Mandruzzato
X
AIHV Annales du 20e Congrès 2015
Sophie Wolf, Cordula M. Kessler, Jürg Goll, Stefan Trümpler, Patrick Degryse
660
he early medieval stained glass windows from St. John, Müstair: materials, provenance and production technology
Two groups of window glass can be distinguished with where did it originate from? How was the window glass
respect to colour, form, thickness of the glass and ind loca- made? Was it produced locally? Where did the technologi-
tion: he irst group comprises over 700 fragments found in cal know-how come from? Taking a closer look at the results
an area along the eastern edge of the early monastic com- of recent elemental and isotopic analysis, as well as earlier
plex and from the excavation area west and north of the compositional data, we will try to answer some of these
Heiligkreuzkapelle. he pieces show a great variety of colour questions.
and form (igure 1a). he most common colours are pale
green, green and amber, followed by blue and dark green. Composition and origin of the glass
Examples of red and yellow glass are rarer. his group also A total of 45 samples of the early window glass and 14 sam-
includes relatively ine window glass pieces.4 heir thick- ples of the glass-working waste (glass droplets and glass ad-
nesses vary between one and two millimetres. A special hering to the crucibles) have been analysed chemically by
characteristic of this subgroup is that both glass surfaces X-ray luorescence (XRF).8 he data was complemented by
are even and shiny compared to the other fragments, which analysis of 27 fragments from the aforementioned sample
usually have one even and one rough surface. he second set plus four additional samples using inductively coupled
group includes approximately 130 fragments found in the plasma optical emission spectrometry (ICP-OES).9 In addi-
southern part of the Carolingian complex. he more limited tion to elemental analysis, isotopic compositions (87Sr/86Sr
colour spectrum ranges from pale green, via yellowish and 14³Nd/144Nd) of 31 glass samples were determined by
green to emerald green (igure 1b). he pieces are generally multi-collector inductively coupled plasma mass spectro-
larger in size than those of the irst group. heir average metry (MC-ICP-MS) at Leuven University.10
thickness varies between two and three millimetres; the he elemental and isotopic data provide information on
glass pieces all have surfaces that are even on one side and the raw materials used and the origin of the glass (table 1):
irregular or corrugated on the other. he strictly geometric Without exception, all the early window glass fragments
forms of the glass pieces remind us of motifs seen in opus have a soda-lime-silica composition, indicating that the
sectile. glass was originally made from sand and mineral soda (na-
Along with similar glass inds from Sion, Sous-le Scex 5, tron) as opposed to plant or wood ash. he composition of
those from Müstair are among the oldest remains of orna- the group is relatively homogeneous with the exception of
mental glass windows in Switzerland. Comparable inds in three glass samples that stand out because of slightly higher
terms of number of fragments and age have been discov- calcium and lower strontium concentrations (table 1, igure
ered at San Vincenzo al Volturno, Jarrow and Paderborn.6 2). Major element concentrations, which except for the high
More recent discoveries of early medieval window glass in
France and Belgium show the extent to which coloured 4 For example ind numbers M95/18184, M95/18381, M95/18396,
M95/18425.
glass was used for ornamental windows in ecclesiastical or 5 Kessler, Wolf and Trümpler 2005, 1–30; Wolf et al. 2005, 361–380.
monastic contexts.7 6 Dell’Acqua and James 2001; Cramp 1975; Gai 2001.
7 Balcon-Berry, Perrot and Sapin 2010.
he inds from Müstair raise many questions concern- 8 XRF analyses were carried out at the University of Basel (Prof. W. B. Stern)
ing the materials and the technology used in the production 2008; for analytical details see Wolf et al. 2005, 364–365.
9 ICP-OES analyses were done at Leuven University (Prof. P. Degryse) in
of the glass as well as the form and design of the glazing: 2015; method described in Ganio et al. 2012.
What type of glass was used to make the window glass and 10 Analytical procedures are described in Degryse et al. 2009, 58.
661
he early medieval stained glass windows from St. John, Müstair: materials, provenance and production technology
Fig. 3: Concentrations of colouring and decolourizing elements in Müstair window glass. (a) Copper versus iron content;
(b) Proportions of manganese-antimony versus alumina content. © authors.
iron levels in the yellow glass all relect the composition of at Müstair. Whether the tesserae were used exclusively to
an uncoloured base glass, are very similar to that of glass make the window glass – as seems to be the case for the blue
produced in the Eastern Mediterranean region, where the glass from San Vincenzo16 – or mixed with colourless glass
production of ‘natron’ glass has been attested to up until the from the Levant – as has been suggested for the window
9th century AD.11 he strontium and neodymium isotope glass from Jarrow Abbey 17 – is diicult to determine, be-
signatures of all except the three samples aforementioned, cause chemical analysis of the tesserae was not possible.
which have strontium isotope and calcium values similar to he results of analysis of the glass-working waste show
8th/9th century glass from Egypt, are identical to those of that the composition of the majority of the fragments is
glass produced on the Levantine coast between the 4th and nearly identical to that of the window glass (see igure 2).
8th centuries AD.12 heir εNd values, which range between hese results conirm the hypothesis of local production.
-6.2 and -5.1, point to a Nile sediment-dominated sand
source. 13 Production techniques and design of the windows
he majority of the window glass from Müstair, howev- he two groups of window glass can – as mentioned above – be
er, does not exactly match any of the previously identiied readily distinguished by their material characteristics. he
glass compositional groups from this region (see igure 2). irst group – which comprises very ine, thin glass fragments
his might be due to the use of raw glass from a yet unknown with shiny surfaces on both sides – is clearly cylinder-blown,
source or – more likely – a result of remelting cullet that in- whereas some of the characteristics of the second group ini-
cluded glass from several glass production centres along the tially made us think it could be cast window glass. Indirect
coast. he linear correlation of sand-related elements such evidence for this hypothesis was an unusually shaped
as alumina and lime (igure 2) is proof that glass was mixed glass-melting crucible (igure 4) – made from soapstone and
from at least two diferent sources. he fact that most of the assumed to be used for pouring glass – that was found in the
window glass contains both manganese and antimony fur- same area as the second group of glass fragments.18
ther corroborates the hypothesis of glass recycling, because In order to solve questions regarding the techniques of
Roman raw glass seems to be either manganese- or antimo- production of early window glass, an international work-
ny-decolorized.14 he manganese concentrations of the red, shop19 was organized and two archaeological experiments20
green and yellow and the dark cobalt blue glass are relative- were carried out. he form and use of the crucible were also
ly constant. he cobalt-coloured blue glass has much higher
antimony concentrations but a similar base glass composi- 11 For example Freestone 2006, 203.
tion to the rest of the glass (igure 3), which signiies that an- 12 Freestone, Wolf and Thirlwall 2009, 31–52; Degryse et al. 2009,
53–72.
timony is speciic to the making of the dark blue glass. he
13 Degryse and Schneider 2008, 1993–2000.
high content of iron in the yellow glass, of cobalt in the blue 14 Jackson 2005, 772 and Freestone 2015, 3–5.
and of copper in the green are related to the colouration of 15 Brepohl1999, 152.
16 Schibille and Freestone 2013, 9.
the glass (igure 3). In his 12th-century Schedula diversarum 17 Freestone and Hughes 2006, 147–155.
artium, heophilus Presbyter mentions that the Francs col- 18 Kessler, Wolf and Trümpler 2013, 226.
19 he workshop was held in Müstair in 2011. It was inancially supported by
lected tesserae from the houses of pagans for glassmak- the Swiss National Science Foundation (No. 137382/1).
ing.15 he blue, green and red glass tesserae that were dis- 20 A irst experiment was carried out at Glashütte Lamberts in Waldsassen
in autumn 2013. he second experiment was done at Studio homas
covered along with glass-melting crucible fragments and Blank in Bern in spring 2014. he results will be published in more
glass-working waste suggest that this was also the practice comprehensive form (publication in preparation).
662
he early medieval stained glass windows from St. John, Müstair: materials, provenance and production technology
663
Window glass
664
he early medieval stained glass windows from St. John, Müstair: materials, provenance and production technology
Inv. No. Sample No. Colour SiO2 Al2O3 Fe2O3 MnO MgO CaO Na20 K2O TiO2 P2O5 SO3 Cl V Cr Co Ni Cu Zn Rb Sr Zr Sn Sb Ba Pb Sum
M94/17407-37 Mü-007 blue 67,0 2,5 1,2 0,7 0,9 6,9 17,5 0,7 0,2 < 0,1 0,3 0,6 na na 360 64 4132 104 48 471 140 849 4242 372 2488 99,7
M94/17407-37 Mü-007L blue 65,0 2,0 1,1 0,6 0,8 6,7 17,3 0,7 0,2 0,1 na na 19 23 na 49 2973 90 na 461 81 na na 260 3096 95,3
M94/17407-35 Mü-008 blue 67,9 2,5 1,2 0,6 0,8 7,8 16,9 0,9 0,1 0,1 0,2 0,5 na na 498 53 682 126 43 505 bd 147 1632 489 905 100,0
M94/17407-36 Mü-009 blue 67,1 2,3 1,2 0,6 0,8 7,1 17,2 0,7 0,2 < 0,1 0,3 0,6 na na 459 60 4585 105 47 453 118 490 6177 331 2870 99,7
M95/18381-24 Mü-044 blue 67,3 2,5 1,2 0,7 0,8 6,7 17,9 0,6 0,2 < 0,1 0,3 0,1 na na 420 71 4377 82 208 424 bd 637 4986 397 bd 99,4
M95/18191-4 Mü-046 blue 67,6 2,3 1,1 0,5 0,7 6,8 16,7 0,8 0,1 < 0,1 0,4 0,2 na na 685 71 2987 40 240 387 bd 114 12416 318 bd 98,8
M94/16900-1 Mü-057 blue 67,3 2,5 1,1 0,6 0,9 7,0 16,8 0,7 0,1 < 0,1 0,4 0,4 na na 392 39 5679 145 bd 442 bd 657 7421 293 3025 99,5
M96/19982-6 Mü-059 blue 68,3 2,4 1,0 0,6 0,7 7,5 16,7 0,7 0,1 < 0,1 0,3 0,5 na na 522 45 2074 96 48 460 bd 259 5157 316 1148 99,7
M93/15403-1 Mü-004 green (blueish) 69,3 2,4 0,6 0,5 0,7 7,5 16,3 1,0 0,1 < 0,1 0,2 0,6 na na 77 48 1150 259 26 454 127 1007 447 362 4826 100,1
M93/15403-1 Mü-004L green (blueish) 67,9 2,1 0,6 0,5 0,6 7,3 16,3 1,0 0,1 0,2 na na 30 16 na 17 1462 252 na 444 50 na na 264 4344 97,4
M94/17407-47 Mü-016 green (blueish) 69,0 2,3 0,7 0,6 0,8 7,4 17,0 0,8 0,1 < 0,1 0,2 0,6 na na bd < 15 3219 68 46 464 141 0 707 388 bd 100,0
M94/17407-47 Mü-016L green (blueish) 65,1 1,8 0,5 0,6 0,7 7,0 15,2 0,7 < 0,1 < 0,1 na na 40 21 na < 15 589 < 15 na 437 61 na na 274 696 92,1
M94/17407-46 Mü-017 green (blueish) 70,0 2,3 1,0 0,1 0,9 10,0 14,0 0,5 0,3 < 0,1 0,1 0,5 na na bd < 15 1747 34 41 203 182 0 65 249 bd 100,0
M94/17407-44 Mü-018 green (blueish) 69,3 2,3 0,8 0,5 0,7 7,4 16,5 1,0 0,1 < 0,1 0,2 0,6 na na 73 46 2511 499 46 444 112 829 638 398 1960 100,1
M94/17407-44 Mü-018L green (blueish) 67,6 2,1 0,7 0,5 0,7 7,3 16,3 1,0 0,1 0,2 na na 20 22 na 21 2158 484 na 452 52 na na 269 2335 97,2
M94/17407-45 Mü-019 green (blueish) 69,7 2,4 0,6 0,5 0,6 7,5 16,5 0,8 0,1 < 0,1 0,2 0,6 na na 57 < 15 2386 162 39 450 142 646 837 399 253 100,0
M95/18409-13 Mü-038 green (blueish) 69,8 2,5 0,6 0,5 0,6 7,4 16,7 0,7 0,1 < 0,1 0,2 0,5 na na bd < 15 1809 181 54 443 bd 158 874 345 bd 100,1
M92/12406-33 Mü-041 green (blueish) 68,4 2,4 0,9 0,8 0,8 7,3 16,6 0,8 0,1 < 0,1 0,3 0,4 na na bd 16 7943 94 24 460 bd 799 1205 414 976 99,9
M92/12406-33 Mü-041L green (blueish) 67,7 2,1 0,5 0,5 0,6 7,4 16,5 0,8 0,1 0,2 na na 35 15 na < 15 1571 179 na 444 49 na na 260 816 96,9
M95/18315-8 Mü-042 green (blueish) 68,5 2,5 0,9 0,9 0,8 7,1 17,1 0,7 0,1 < 0,1 0,2 0,2 na na bd < 15 2746 805 223 438 bd 523 1017 489 bd 99,7
M95/18315-8 Mü-042L green (blueish) 62,5 1,6 0,5 0,8 0,7 6,5 15,6 0,8 0,1 < 0,1 na na 104 48 na 107 2133 736 na 429 104 na na 319 1639 89,9
M94/17511-8 Mü-055 green (blueish) 69,4 2,4 0,7 0,6 0,8 7,3 17,0 0,7 0,1 < 0,1 0,3 0,5 na na bd 41 1732 29 42 453 bd 0 1147 383 bd 100,0
M94/17511-8 Mü-055L green (blueish) 68,1 2,0 0,6 0,6 0,8 7,3 16,9 0,8 0,1 0,2 na na 21 20 na 18 604 46 na 448 56 na na 273 546 97,7
M95/18633 Mü-062L green (blueish) 67,2 2,1 0,8 0,6 0,9 7,7 16,5 0,9 < 0,1 < 0,1 na na 28 30 na 16 1797 70 na 483 63 na na 284 1141 97,5
M95/18409 Mü-064L green (blueish) 66,1 2,0 0,8 0,6 0,9 7,2 16,9 1,0 < 0,1 < 0,1 na na 52 28 na 35 1233 99 na 440 62 na na 271 1820 96,5
M95/18409 Mü-065L green (blueish) 68,1 2,1 0,5 0,5 0,6 7,3 17,1 0,9 < 0,1 < 0,1 na na 23 16 na 15 1362 123 na 432 45 na na 253 615 98,0
M94/16789-1 Mü-006 green 68,1 2,6 0,9 0,6 1,0 7,3 15,8 1,3 0,1 < 0,1 0,2 0,3 na na 91 44 6900 3681 96 499 117 1553 786 379 1831 99,7
M94/17407-40 Mü-010 green 65,7 2,4 0,9 0,6 0,8 7,2 15,8 0,8 0,1 < 0,1 0,3 0,3 na na bd 29 37770 81 64 418 96 363 1433 525 514 99,1
M94/17407-40 Mü-010L green 63,5 1,9 0,9 0,6 0,8 7,0 15,7 0,8 0,1 0,2 na na 23 22 na 37 35991 122 na 442 56 na na 277 912 95,4
M94/17407-38 Mü-011 green 67,9 2,5 0,7 0,5 0,7 7,4 15,7 0,9 0,1 < 0,1 0,2 0,3 na na bd 62 23095 174 45 441 106 354 1349 410 bd 99,4
M94/17407-38 Mü-011L green 64,8 2,0 0,6 0,4 0,6 7,1 15,2 0,9 0,1 0,2 na na 13 12 na 16 23618 187 na 422 44 na na 242 825 94,6
M94/17407-39 Mü-012 green 66,3 2,2 1,2 0,7 0,9 7,6 15,5 1,0 0,1 < 0,1 0,3 0,2 na na bd 39 27531 209 58 401 102 575 1076 486 2113 99,3
M94/17407-39 Mü-012L green 61,9 1,9 1,0 0,6 0,8 7,1 15,7 0,9 0,1 0,2 na na 32 25 na 27 23665 223 na 409 73 na na 269 1877 93,0
M95/18623-6 Mü-043 green 66,8 2,4 0,7 0,6 0,8 7,1 16,2 0,7 0,1 < 0,1 0,3 0,1 na na bd 45 29038 60 191 416 bd 313 1581 489 bd 99,0
M95/18381-25 Mü-045 green 68,1 2,4 0,6 0,5 0,6 7,3 15,9 0,8 0,1 < 0,1 0,3 0,4 na na bd < 15 22172 163 77 421 bd 287 755 452 bd 99,4
M92/12896-3 Mü-049 green 67,2 2,5 1,3 0,7 1,0 7,4 16,0 0,9 0,1 0,1 0,3 0,4 na na 63 31 5316 585 110 438 bd 2497 971 492 10582 99,8
M92/12896-3 Mü-049L green 65,9 2,1 1,2 0,7 1,0 7,5 16,2 1,0 0,1 0,2 na na 25 29 na 23 5225 584 na 453 68 na na 293 12297 97,9
M96/19982-8 Mü-061 green 66,1 2,3 0,6 0,6 0,7 6,9 16,4 0,6 0,1 < 0,1 0,3 0,4 na na 77 29 38446 28 bd 407 bd 156 1168 572 512 99,1
M96/19982-8 Mü-061L green 64,6 1,9 0,6 0,6 0,6 6,9 16,2 0,6 0,1 0,2 na na 21 17 na 29 35759 65 na 441 49 na na 275 494 96,2
M95/18633 Mü-063L green 67,4 2,2 0,9 0,6 0,9 7,5 16,1 0,9 < 0,1 < 0,1 na na 29 28 na 30 10341 105 na 431 68 na na 285 1610 98,3
M94/17407-48 Mü-020 green (yellowish) 69,1 2,4 0,8 0,7 0,9 7,6 16,5 0,9 0,1 < 0,1 0,2 0,5 na na bd 20 1999 86 83 457 106 484 1068 461 bd 100,0
M94/17407-48 Mü-020L green (yellowish) 67,8 2,0 0,7 0,6 0,9 7,5 16,6 0,9 0,1 0,2 na na 28 26 na 26 1104 81 na 466 64 na na 283 1087 97,9
M94/17407-49 Mü-023 green (yellowish) 68,1 2,3 1,1 0,7 1,0 7,8 16,1 0,9 0,2 < 0,1 0,2 0,4 na na bd 54 5130 260 51 397 86 499 1259 388 3011 99,9
M94/17407-49 Mü-023L green (yellowish) 65,8 2,0 1,0 0,7 0,9 7,5 16,0 0,9 0,1 0,2 na na 28 25 na 20 5696 257 na 417 78 na na 286 3527 96,3
M94/17407-50 Mü-024 green (yellowish) 66,5 2,4 1,2 0,8 1,1 7,1 16,5 0,8 0,2 < 0,1 0,3 0,4 na na 86 25 5332 514 29 434 154 3173 1667 428 14432 99,8
M94/17407-50 Mü-024L green (yellowish) 65,2 2,0 1,1 0,7 1,1 7,0 16,8 0,8 0,2 0,2 na na 30 33 na 44 5099 481 na 449 80 na na 299 13380 97,2
M94/17407-51 Mü-025 green (yellowish) 67,9 2,7 1,0 0,8 0,8 7,3 16,2 1,1 0,1 < 0,1 0,2 0,3 na na bd 28 5381 569 83 456 127 1685 1642 366 2606 99,8
M94/17407-51 Mü-025L green (yellowish) 67,7 2,3 1,0 0,7 0,8 7,3 16,6 1,1 0,1 0,2 na na 31 27 na 26 5452 572 na 472 68 na na 332 4554 99,2
M95/18604-1 Mü-027 green (yellowish) 68,1 2,5 0,9 0,9 0,9 7,3 17,0 0,8 0,2 < 0,1 0,2 0,5 na na bd 28 2768 83 29 461 150 283 1554 397 1752 100,0
M95/18604-1 Mü-027L green (yellowish) 66,9 2,1 0,8 0,9 0,9 7,2 16,9 0,8 0,1 0,1 na na 27 26 na < 15 1413 88 na 474 67 na na 342 2292 97,4
M95/18633-1 Mü-028 green (yellowish) 68,1 2,4 0,9 0,7 0,9 7,4 16,4 1,1 0,1 < 0,1 0,2 0,3 na na 68 41 3792 314 59 474 107 870 1642 366 3204 99,8
Inv. No. Sample No. Colour SiO2 Al2O3 Fe2O3 MnO MgO CaO Na20 K2O TiO2 P2O5 SO3 Cl V Cr Co Ni Cu Zn Rb Sr Zr Sn Sb Ba Pb Sum
M95/18633-2 Mü-029 green (yellowish) 68,1 2,3 0,9 0,7 0,9 7,7 16,3 0,9 0,1 < 0,1 0,3 0,2 na na bd 21 9667 140 na 438 117 1685 1488 393 1404 99,8
M95/18409-12 Mü-039 green (yellowish) 69,1 2,5 0,7 0,7 0,9 7,3 17,1 0,7 0,1 < 0,1 0,3 0,5 na na bd 10 1047 32 35 464 bd 343 1074 423 62 100,1
M95/18409-12 Mü-039L green (yellowish) 66,2 2,0 0,6 0,7 0,8 7,2 16,9 0,8 0,1 0,1 na na 22 24 na 25 672 40 na 456 62 na na 276 843 95,8
M92/12896-4 Mü-050 green (yellowish) 69,4 2,4 0,6 0,6 0,7 7,2 17,0 0,6 0,1 < 0,1 0,3 0,6 na na bd 33 1579 20 110 422 bd 0 1457 411 bd 99,9
M92/12896-4 Mü-050L green (yellowish) 68,3 2,0 0,6 0,6 0,8 7,2 17,2 0,7 0,1 0,1 na na 26 21 na 21 763 32 na 447 56 na na 282 794 98,0
M94/17112-2 Mü-053 green (yellowish) 68,7 2,3 1,0 1,2 0,7 9,5 15,2 0,4 0,3 < 0,1 0,2 0,5 na na bd < 15 757 68 bd 189 bd 0 bd 343 bd 100,2
M94/17112-2 Mü-053L green (yellowish) 69,2 2,0 1,1 1,2 0,7 9,8 15,5 0,5 0,3 0,1 na na 24 165 na 69 <75 77 na 196 177 na na 268 51 100,4
M96719881-2 Mü-058 green (yellowish) 70,7 2,5 0,5 0,4 0,5 7,6 16,2 0,7 0,1 < 0,1 0,2 0,5 na na bd < 15 557 2 bd 446 bd 0 276 291 bd 100,1
M95/18409-14 Mü-040 red 67,6 2,6 0,8 0,6 0,7 6,9 16,1 1,0 0,1 < 0,1 0,2 0,4 na na bd 18 5165 2307 35 452 bd 4063 695 338 14555 99,9
he early medieval stained glass windows from St. John, Müstair: materials, provenance and production technology
M95/18339-5 Mü-047 red 68,4 2,6 0,9 0,5 0,7 7,1 15,9 1,0 0,1 < 0,1 0,2 0,4 na na 59 28 7669 3783 89 452 bd 1776 1292 397 2562 99,7
M96/19982-7 Mü-060 red 67,1 2,5 1,1 0,8 0,8 7,0 16,5 1,0 0,1 < 0,1 0,3 0,3 na na bd 32 6992 5663 39 451 bd 1199 1937 414 4389 99,7
M94/17511-9 Mü-056 red orange 70,5 2,5 0,6 0,4 0,5 7,6 16,5 0,7 0,1 < 0,1 0,1 0,3 na na bd 23 1015 35 151 418 bd 0 158 375 bd 99,9
M94/17407-41 Mü-013 yellow 66,0 2,4 3,5 0,6 0,8 7,1 15,9 0,8 0,1 < 0,1 0,2 0,1 na na 59 41 16021 93 92 418 123 408 821 494 bd 99,5
M94/17407-41 Mü-013L yellow 59,8 1,8 3,2 0,6 0,7 6,5 14,8 0,8 < 0,1 < 0,1 na na 24 18 na 21 15379 71 na 409 50 na na 257 950 90,3
M94/17407-42 Mü-014 yellow 65,3 2,2 3,5 0,6 0,8 7,1 15,8 0,8 0,1 < 0,1 0,2 0,3 na na bd 46 22377 127 90 449 102 391 1239 524 bd 99,4
M94/17407-42 Mü-014L yellow 61,8 1,9 3,4 0,6 0,7 6,7 15,3 0,8 < 0,1 < 0,1 na na 24 18 na 27 18601 70 na 424 54 na na 267 905 93,7
M94/17407-43 Mü-015 yellow 65,6 2,3 3,4 0,6 0,8 7,1 16,0 0,8 0,1 < 0,1 0,2 0,3 na na bd 46 20370 60 bd 407 119 484 1157 462 436 99,6
M77/1308-8 Mü-048 yellow (greenish) 65,6 2,4 2,9 0,6 1,1 7,1 15,9 1,0 0,1 < 0,1 0,3 0,3 na na bd 62 17076 244 81 419 bd 1207 1632 471 1878 99,5
M77/1308-8 Mü-048L yellow (greenish) 61,3 1,9 2,8 0,6 1,0 6,9 14,8 1,1 < 0,1 < 0,1 na na 23 29 na 38 13745 223 na 416 64 na na 270 2742 92,6
M92/15856-3 Mü-051 yellow (greenish) 65,4 2,4 2,1 0,7 1,0 7,0 15,8 0,9 0,1 < 0,1 0,3 0,3 na na bd 70 26497 444 75 429 bd 1927 1864 531 2650 99,3
M94/17511-7 Mü-054 yellow (greenish) 65,8 2,3 3,4 0,6 0,8 6,9 16,0 0,7 0,1 < 0,1 0,3 0,3 na na bd 21 19724 71 33 428 bd 132 1377 445 503 99,5
M94/17511-7 Mü-054L yellow (greenish) 61,7 1,8 3,3 0,6 0,7 6,7 15,7 0,8 < 0,1 < 0,1 na na 23 40 na 26 17214 65 na 429 53 na na 264 883 93,7
bd: below detection limit average 67,0 2,2 1,2 0,6 0,8 7,3 16,3 0,8 0,1 0,1 0,2 0,4 30 29 238 37 9119 391 76 431 90 752 1895 360 2759
na: not analysed minimum 59,8 1,6 0,5 0,1 0,5 6,5 14,0 0,4 0,1 0,1 0,1 0,1 13 12 57 10 557 2 24 189 44 0 65 242 51
maximum 70,7 2,7 3,5 1,2 1,1 10,0 17,9 1,3 0,3 0,2 0,4 0,6 104 165 685 107 38446 5663 240 505 182 4063 12416 572 14555
bd: below detection limit average 67,6 2,5 1,0 0,7 1,2 7,4 16,2 1,1 0,1 0,1 0,3 0,4 30 25 179 48 3318 228 63 455 108 1401 1996 379 4008
na: not analysed minimum 65,7 2,0 0,7 0,5 0,8 6,1 14,8 0,8 0,1 0,1 0,2 0,2 23 22 62 21 831 74 28 390 59 387 692 280 1188
maximum 69,0 2,9 1,6 0,8 3,2 8,4 16,9 2,3 0,1 0,3 0,3 0,5 35 27 538 127 9123 591 181 518 166 2948 8411 522 15010
Table 1: Results of chemical analysis of window glass and glass-working waste from St. John Müstair. Major and minor elements are given in wt.%, trace elements in ppm. Samples with sample numbers
665
ending in ‘L’ were analysed by ICP-OES and MC- ICP-MS at Leuven; all other samples were analysed by XRF in Basel.
he early medieval stained glass windows from St. John, Müstair: materials, provenance and production technology
Regarding the question of know-how transfer, the com- Michael J., 2000. ‘Primary glass from Israel and the pro-
parison of inds from the Carolingian monasteries at Fulda duction of glass in late Antiquity and the early Islamic
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ly 25, France26 and Great Britain 27, reveals that the materials verre Ateliers primaires et secondaires du second
and technology used to make the window glass were quite millénaire av J-C au Moyen Âge. Lyon, 65–83.
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ties suggest that materials were traded – and know-how 2000. ‘Byzantine and early Islamic glassmaking in the
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ACKNOWLEDGEMENTS Freestone, Ian C., Wolf, Sophie and Thirlwall, Mathew,
We would like to thank the Swiss National Science Fund 2009. ‘Isotopic composition of glass from the Levant
(SNSF) for inancially supporting this investigation as part and the south-eastern Mediterranean Region’. In:
of a larger research project on early medieval window glass Degryse, Patrick, Henderson, Julian and Hodgins,
in Switzerland (No. 1214-068293/1). Greg (eds.), Isotopes in Vitreous Materials. Leuven, 31–52.
Freestone, Ian C. and Hughes, Michael J., 2006. ‘Origins of
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he early medieval stained glass windows from St. John, Müstair: materials, provenance and production technology
Sophie Wolf,
Vitrocentre Romont,
Swiss Research Centre for Stained Glass and Glass Art,
Romont, Switzerland,
[Link]@[Link]
Cordula Kessler,
Nationale Informationsstelle zum Kulturerbe,
Bern, Switzerland,
[Link]@[Link]
Jürg Goll,
Archäologischer Dienst Graubünden,
Chur, Switzerland,
goll@[Link]
Stefan Trümpler,
Vitrocentre Romont,
Swiss Research Centre for Stained Glass and Glass Art,
Romont, Switzerland,
[Link]@[Link]
Patrick Degryse,
Katholieke Universiteit Leuven, Geology,
Leuven, Belgium,
[Link]@[Link]
667