Quick Revision – Structure of Atom
Discovery of Subatomic Particles:
- Electron: J.J. Thomson (cathode rays)
- Charge of electron: Millikan's Oil Drop Experiment
- Proton: Goldstein (anode/canal rays)
- Neutron: James Chadwick
Atomic Models:
- Thomson's Model: 'Plum pudding'
- Rutherford's Model:
• Dense, positively charged nucleus
• Electrons orbit the nucleus
• Couldn't explain stability or spectra
Bohr's Model:
- Electrons in fixed quantized orbits
- Energy levels: E_n = -R_H Z^2 / n^2
- Transitions: ∆E = hν (emission/absorption)
Electromagnetic Radiation & Spectra:
- Relationship: c = λν, E = hν
- Hydrogen series: Lyman, Balmer, Paschen, Brackett, Pfund
Photoelectric Effect (Einstein):
- KE = hν - hν■
de Broglie & Heisenberg:
- λ = h/mv (wave nature of matter)
- ∆x·∆p ≥ h/4π (uncertainty principle)
Quantum Mechanical Model:
- Orbitals with quantum numbers n, l, m, s
Electronic Configuration Rules:
- Aufbau principle
- Pauli exclusion principle
- Hund's rule