Ot Ih: CC) Sio Pbo
Ot Ih: CC) Sio Pbo
~~ ,
-
49. Whi~h of t~e following c·o mpounds has (D) blfick phosphorus . .
pe.~ o~de linkage ? · .
62. An oxy acid of phosphorus is a White
(A) Pb 2 0 3 (B) C<;)
2 deliquescent crystalline solid. It can be
,·cc) Sio2 · (D) Pbo2 . prepared by the hydrolysis of P20 3 or PCI and
3
50. A gas' which burns with bfu~ 'flame is : its formula is :
(A) 0 2 (B) CO , (B) H3P03
2
(Cl N 2 1
(D) en . (D) H4P207,
51. Which of the following is •expected to have most 63. Which of the following elements does not form
ionic character ? oxy acids?
(A) PbC1 2 ' (B) SiC14 (A) p (B) N
(C) CC14 (D) PbC14.
(C) Cl (D) F.
5~./ Leas~ stable hydride is :
64. The oxy acid of phosphorus that forms
J (A) Rlumbane (B) Silane
' polymers is:
(C) Stannane (D) Methane.
(A) H3P03 (B) H4P207
53. Water gas is a mixture of :
(A) CO and N 2 (B) CO and H2 · .(Gl
HP03 (D) H3P02.
(C) CO 2 and H 2 . U?l CO 2 and :t;-J2. 65. Which of the following elements of group 15
54. The. strongest oxidant among the following is: does not show allotropy ? ·
1 (A) Phosphorus (B) Arsenic
. (A) "_Si0 . (B) GeO2 ,
2
(C) Pb0 2 (D) Sn0 2 (C) Nitrogen (D) Antimony.
55. The formula of freon-12 ·1s :
.-I t • • I
66. The · structure of pyrophosphoric acid is :
(A) CFC1 3 (B) CF3Cl
0
(C) CF2Cl2 (D) CF4.
II
Nitrogen Family (Group 15 Elements) (A) p~
(D) N02 .
HO
"'/ '
(B) HO--P--0--P--O H
0
/.
OH
0
~ ···· --· ~
0 77. The chemical used for cooling in electrical
II refrigeration is :
(Cl ~.....___ (A) liquid CO 2 (B) liquid NH3
HO
/~H
OH
(C) NH4 OH (D) solid CO 2 .
78. Yellow colour of usual nitric acid is due to the
presence of :
°\ /OH (A) NO 2
(C) NzO
(B) NO
(D) NzO5.
(D) H-P-0-P-H 79. Laugh~g _gas is prepared by heating :
I
HO
'\ OH
(A) NH 4 NO 3 • (B) (NHJ 2 SO 4
(C) NaNO 2 + NH 4 Cl (D) HNO 3 .
67, Anhydride of H 3 PO 4 is: 80. White phosphorus contains :
(Al P2O 5 (BJ P 2 O 3 (A) P 2 molecules (B) P4 molecules
(Cl Pol- (Dl Poi-. (C) P6 molecules (D) one P-P bond.
68. Which of t he following has smallest bond 81. Which of the following oxides of nitrogen is
angle ? colourless solid or gas ?
(A) PF 3 (B) PBr3 (A) NO (B) N 2 O
(CJ PC13 (D) PI 3 . (C) N 2 0 4 (D) N 2 0 5 .
69. Dinitrogen p entoxide dissolves in water to give : 82. The reddish brown gas formed when nitric acid
(A) HNO 2 (B) H 2 N 2 O 2 is oxidised by air is :
(A) N 2 0 5 (B) N 2 0 4
(CJ NO 2 (D) HNO 3 ..
(C) NO 2 (D) N2 O 3 .
70. The m ost electronegative element in group 15
is: 83. Which of the following trihalide of nitrogen is
the least basic ?
(A) As (BJ Bi
(A) NF3 (B) NC1 3
(CJ p (D) N.
(C) NBr3 (D) Nl3,
71. Which of the following hydrides of group 15
84. A hydride of nitrogen which is acidic is :
has the lowest boiling point ?
(A) NH3 (B) N2 H 4
(A) NH 3 (B) SbH 3
(C) N2 H 2 (D) N3 H.
(C) PH3 (D) AsH3 .
85. The gas evolved on heating (NH 4 ) 2 Cr2 O 7 is :
72. Which is m ost explosive ?
(A) NH 3 (B) N 2
(A) PC1 3 (B) AsC13
(C) N 2 0 (D) 0 2 .
(C) BC1 3 (D) NC1 3 .
86. The anhydride of nitric acid is :
73. Which of the following hydrides of group 15 is
(A) NO (B) N 2 O 4
most exten sively hydrogen bonded ?
(C) NzO5 (D) NzO3,
(A) PH3 (B) NH3
87. Which of the· followiJ;lg properties is not correct
(C) AsH 3 (D) SbH 3 . regarding red phosphorus ?
74. Which of the following halides does not exist? (A) Non-poisonous nature
(A) SbF 5 (B) PF5 (B) Soluble in CS2
(C) NF 5 (D) AsF5 . (C) Does not undergo oxidation at room
75. P4O6 is hydrolysed to : temperature.
(A) (HPO 3 )n (B) H 3 PO 4 (D) Less reactive than white phosphorus.
(C) H 3 PO 3 (D) H 4 P 2 O 7 . 88. Nitrogen dioxide cannot be obtained by
7 6 . Phosphorus forms five bonds due to sp 3 d heating:
hydridisation put nitrogen does not form (A) KN0 3 (B) N 2 0 4
pentahalides due to : (C) Pb(NO 3 ) 2 (D) N 2 0 5 .
(A) small size of N atom 89. ·which of the following does not show
(B) high ionisa tion energy of N allotropy?
(C) absence of d-orbitals in valence shell (A) N (B) p
(D) its tenden cy to form multiple bonds. (C) Bi (D) As.
- "'<lt:J.11~
122130 ch of the following statements is 1'ily
104. Whi 1 . ? nott
90. Phosphorns is kept in : about hydroxy amme · t\ie
(A) cold water (B) alcohol (A) It can be prepared by Raschtg Illeth
0
(C) kerosene (D) ammonia. (B) It acts as an oxidising agent d
91. Which of the following is blue solid ? (C) It reacts with_ nitro~stracid to give Ilitrog
(A) NO (B) N 2 0 3 (D} It exists as c1s- an ans isomer. en
(C) N 2 0 4 (D) N 2 0 5 . 105 _ Which of the
following is a tribasic acid ?
92. Which of the following show prr.-prr. bonding ? (A) orthophosphortc acid ·
(A) P 4 (B) As 4 (B} Phosphorus acid
(C) Meta phosphortc acid
(C) Sb 4 (D) N 2 .
(D) Pyrophosphortc _acid.
93. A nitrate which on strong heating gives only
oxygen without any oxide of nitrogen is : oxygen FamilY (Group 16 Elements)
(A) Ammonium nitrate
(B) Silver nitrate 106 . The tendency of grou~ 16 elements to fonn
catenated compounds 1s greatest in case of .
(C) Lead nitrate
(A) oxygen (B) sulphur ·
(D) Potassium nitrate.
(C) selenium (D) tellurium.
94. Which is most basic ?
107. The minimum bond angle in the hydrides of
(A) NH 3 (B) PH 3
group 16 elements is in :
(C) SbH 3 (D) AsH 3 . (A) H 2 0 (B) H 2Te
95. Which one is Lewis acid ? (C) H 2 Se (D) H 2 S .
(A) PC1 3 (B) AIC1 3 108. The structure of pyrosulphurtc acid is :
(C) NC1 3 (D) AsC1 3 .
0 0
96. The number of P-H bonds in I I
hypophosphorous acid is : (A) HO-S-S-OH
(A) 1 (B) 2 I
0
(C) 3 (D) 4.
97. Which of the following is a cyclic oxo acid ? 0 0
(A) H 4 P 2 0 7 (B) H 4 P 2 0 6
II I
HO-S-0-S-OH
(B)
(C) H 3 P 3 0 9 (D) H 5P 5 0 15 . II I
0 0
98. White phosphorus c9ntains :
(A) P 2 molecules (B) P 6 molecules 0
(C) P 4 molecules (D) P8 molecules.
(C) H0-0-i-OH
99. Concentrated nitric acid reacts with iodine to II
give: 0
(A) 1-Il (B) 1-IlO
0 O
(C) ID03
(D)
II
HO-S-0-0-S-OH
I
100. Cone. HNO3 is stored in containers of :
(A) Copper (B) Zinc II 11
0 O
(C) Tin (D) Aluminium. 16
l09 . The boiling points of hydrtdes of group
101. Cone. HNO 3 oxidises cane sugar to : elements are in the order :
(A) CO 2 and H 2 O (A) H20 > H 2S > H 2Te > H 2Se
(B) CO and H 2 O (B) H2Te > H 2Se > H 2 S > H 20
(C) CO, CO 2 and H 2 O (C) H20 > H 2Te > H 2 Se > H 2 S
(D) Oxalic acid and water. (D) H2Te > H 20 > H S > H Se.
102. Nitrolium is : l lO. The most acidic aming th; following is :
(A) CaC 2 (B) CaCN 2 + C (A) Te02 (B) SeO
2
(C) SQ .0
(C) CaC 2 N2 (D) CaC 2 + CaCN2 . 111 · 2 (D) Po02- dllci%
103. Nitrogen was discovered by: · Which of the following has lowest re
character?
(A} Cavendish (B) Lavoisier
(A) ~O
(C} Scheele (D) Daniel Rutherford. (C) H 2Te
y Ot- frP._V..," - - - · --- . -
c~E,~~1srA . . rrs1■nc
su lphuric acid reacts with formi c acid to give 125. Which of the following has maximum
2
11 · o,e m ain produ ct : catenation property ?
(A) co 2 and CO (B) C (A) S (B) Se
(C) HCHO (D) CO. (C) 0 (D) Po.
_Which of t he following mainly exhibits -2 126. Sulphur dioxide is used as :
113
oxidation state ? (A) Bleaching agent (B) Disinfectant
ws (~ 0 (C) Antichlor (D) All.
(C) Se (D) Te. 127. Oxygen can be absorbed by:
. Which of the following has highest bond (A) Sodium hydroxide
114
energy? (B) CuS0 4 (aq)
(A) 0-0 (B) S-S (C) Pyrogallol
(C) Se-Se (D) Te-Te. (D) C 2 H 5 OH.
5, o xygen exhibits positive oxidation state in 128. Which of the following is the constituent of
11
(A) CO (B) .F 2 O metal superoxides ?
(C) NO (D) N 2 O. (A) o 2- (B) 022-
(C) 0 2 - (D) o3-.
l 16. so 2 is not a
(A) bleaching agent (B) disinfectant 129. Wl)ich of the following has highest energy ?
(A) Se-Se (B) Te-Te
(C) reducing agent (D) basic oxide.
(C) S-S (D) 0-0.
117, Oxygen molecule is :
(B) diamagnetic
130. S 2 0 7 is an hydride of: .
(A) paramagnetic
(A) Peroxodisulphuric acid
(C) ferromagnetic (D) fenimagnetic.
(B) Sulphuric acid
118. Low volatility of H 2 SO 4 is due to :
(C) Sulphurous acid
(A) van der Waal's forces
(D) Disulphuric acid.
(B) ionic nature
131. Ozone molecule is :
(C) hydrogen bonds (B) linear
(A) angular
(D) acidic character. (D) cyclic.
(C) tetrahedral
119. Which of the following dissolves in H 2 S0 4 to 132. Ozone oxidises aqueous iodine to :
give oleum? (A) 13 - (B) HI03
(A) H 2 S (B) S 2 0
(C) 12 0 5 (D) ICI.
(C) SO 2 (D) S03 .
133. Which of the following statements is not correct
120. Sulphur dioxide is : regarding ozone .?
(A) Acidic (B) Basic (A) It is of light blue colour having pungent
(C) Amphoteric (D) Neutral. odour
121. Bleaching action of S0 2 is due to : (B) It acts as a mild bleaching agent
(A) reduction (B) oxidation (C) It is lighter than air
(C) acidic nature (D} hydrolysis. (D) It liquefies to a deep blue liquid at 1 73 K.
122. An oxide that gives hydrogen peroxide on 134. Which of the following species gets oxidised by
treatment with dilute H 2 S04 is : reaction with 0 3 but does not evolve 0 2 during
(A) SnO 2 (B) Mn02 the reaction ?
(A) S0 2 (g) (B) S0 2 (aq)
(C) Pb0 2 (D) Na2 02 ·
123. Which of the following oxy acid of sulpur has (C) HgO (D) PbS.
■-
M UUl.fH" -
2 11. The n oble gases are genera lly unreac tive (A) sp 3d3 (B) sp3 d 2
because : (C) sp3 d (D) sp 3
(A) they h ave high ionisat ion energy c 224. Partial hydrol ysis of XeF6 gives:
(B) they are monoa tomic
(A) XeOF4 (B) Xe0 3
· (C) they h ave high electro n affinity
(D) XeOF2
(D) they form diatom ic molecu les.
~ 225. Highly explosi ve xenon compo und is:
218. Which of the followi ng is called strang er gas ?
' (A) Xe (A) XeF6 (B) Xe0 3
(B) Ne
(C) Ar (D) Kr. (C} XeOF2 (D} XeF4