Solutions Contact Number: 9667591930 / 8527521718

1 Given below are two statements: one is labeled as 6 KH value for some gases at the same temperature 'T'
Assertion (A) and the other is labeled as Reason (R): are given:
Helium is used to dilute oxygen in the gas KH/k bar
Assertion (A):
diving apparatus. Ar 40.3
Reason (R): Helium has a high solubility in O2. CO2 1.67
In light of the above statements, choose the correct
answer from the options given below: HCHO 1.83 × 10–5
1. (A) is False but (R) is True. CH4 0.413
Both (A) and (R) are True and (R) is the correct KH is Henry's Law constant in water. The order of their
2.
explanation of (A). solubility in water is :
Both (A) and (R) are True and (R) is not the correct 1. Ar < CO2 < CH4 < HCHO
3.
explanation of (A).
2. Ar < CH4 < CO2 < HCHO
4. (A) is True but (R) is False.
3. HCHO < CO2 < CH4 < Ar
2 For an ideal solution, the non-zero value will be for: 4. HCHO < CH4 < CO2 < Ar
1. ΔHmix
2. ΔSmix 7 Freezing point of an aqueous solution is -0.166°C.
3. ΔVmix Elevation of boiling point of same solution would be-
4. ΔP = Pobserved − PRaoult (Kb = 0.512 K m-1 and Kf = 1.66 K m-1)
1. 0.18°C 2. 0.05°C
3 Colligative properties are dependent on which of 3. 0.09°C 4. 0.23°C
the following factors?
The nature of the solute particles dissolved in the 8 The correct option for the value of vapour pressure
1.
solution. of a solution at 45 °C with benzene to octane in a molar
2. The number of solute particles in the solution. ratio 3:2 is:
The physical properties of the solute particles [At 45 °C vapour pressure of benzene is 280 mm Hg
3.
dissolved in the solution. and that of octane is 420 mm Hg. Assume Ideal gas]
4. The nature of solvent particles. 1. 336 mm of Hg
2. 350 mm of Hg
4 The boiling point of 0.2 mol kg solution of X in 3. 160 mm of Hg
–1
4. 168 mm of Hg
water is greater than the equimolal solution of Y in
water. The correct statement in this case is:
9 The electrolyte having the same value of Van't Hoff
1. X is undergoing dissociation in water.
factor (i) as that of Al2(SO4)3 (if all are 100% ionized)
Molecular mass of X is greater than the molecular
2. is:
mass of Y.
1. K2SO4
Molecular mass of X is less than the molecular mass
3. 2. K3[Fe(CN)6]
of Y.
Y is undergoing dissociation in water while X 3. Al(NO3)3
4.
undergoes no change. 4. K4[Fe(CN)6]

5 A solution containing 10 g/dm3 of urea 10 Isotonic solutions have the same:

(molecular mass = 60 g mol-1) is isotonic with a 5 % 1. Vapour pressure
solution of a non-volatile solute. The molecular mass of 2. Freezing temperature
this non-volatile solute is: 3. Osmotic pressure
1. 25 g mol -1 2. 300 g mol -1 4. Boiling temperature
3. 350 g mol-1 4. 200 g mol-1

Page: 1
 Solutions Contact Number: 9667591930 / 8527521718

11 The freezing point of depression constant (Kf ) of 16 The equal weight of a solute is dissolved in an equal
benzene is 5.12 K kg mol–1. The freezing point weight of two solvents A and B to form a very dilute
depression for the solution of molality 0.078 m solution. The relative lowering of vapour pressure for
containing a non-electrolyte solute in benzene is: solution B has twice the relative lowering of vapour
(rounded off up to two decimal places) pressure for solution A.
1. 0.80 K If M and M are the molecular weights of solvents A
A B

2. 0.40 K and B respectively, then:

3. 0.60 K 1. M = M
A B

4. 0.20 K 2. M = 2M
B A

3. M = 4M
A B

12 The vapour pressure of a pure liquid solvent A is 4. M = 2M

A B

0.80 atm. When a non-volatile substance B is added to

the solvent, its vapour pressure drops to 0.60 atm. 17 Which of the following mixtures forms the
Mole fraction of the component B in the solution is: maximum boiling azeotrope?
1. 0.50 2. 0.75 1. Heptane + Octane 2. Water + Nitric acid
3. 0.40 4. 0.25 3. Ethanol + Water 4. Acetone + Carbon disulphide

13 The following solutions were prepared by 18 The relationship between osmotic pressure at 273
dissolving 10 g of glucose (C6H12O6) in 250 ml of water K, when 10 gm glucose (P1), 10 gm urea (P2), and 10
(P1), 10 g of urea (CH4N2O) in 250 ml of water (P2) and gm sucrose (P3) are dissolved in 250 ml of water, is-
10 g of sucrose (C12H22O11) in 250 ml of water (P3). 1. P1 > P2 > P3
The decreasing order of osmotic pressures of these 2. P3 > P1 > P2
solutions is: 3. P2 > P1 > P3
1. P2 > P3 > P1 2. P3 > P1 > P2 4. P2 > P3 > P1
3. P2 > P 1 > P 3 4. P1 > P 2 > P 3
19 For an ideal solution, the correct option is:
14 Consider the following statements about the 1. Δ mix G = 0 at constant T and P
composition of the vapour over an ideal 1:1 molar 2. Δ mix S = 0at constant T and P
mixture of benzene and toluene. The correct statement 3. Δ mix V ≠ 0 at constant T and P

is: 4. Δ mix H = 0 at constant T and P

Assume that the temperature is constant at 25 oC.

(Given, vapour pressure data at 25 °C, benzene = 12.8
20 The correct statement regarding a solution of two
kPa, toluene = 3.85 kPa) components A and B exhibiting positive deviation from
The vapour will contain a higher percentage of ideal behaviour is :
1. Intermolecular attractive force between A-A and B-B
toluene. 1.
are stronger than those between A-B
The vapour will contain equal amounts of benzene
2. 2. ∆mixH = 0 at constant T and P
and toluene.
Not enough information is given to make a 3. ∆mixV = 0 at constant T and P
3.
prediction. Intermolecular attractive forces between A-A and B-
The vapour will contain a higher percentage of 4. B are equal to those between A-B
4.
benzene.
21 One mole of sugar is dissolved in three moles of
15 The largest freezing point depression among the water at 298 K. The relative lowering of vapour pressure
following 0.10 m solutions is shown by: is:
1. KCl 2. C H O
6 12 6 1. 0.25 2. 0.15
3. Al2(SO 4) 3 4. K SO2 4 3. 0.50 4. 0.33

Page: 2
 Solutions Contact Number: 9667591930 / 8527521718

22 The incorrect statement among the following for an 27 The correct match for the below table is:
ideal solution is: Type of
1. ΔHMix = 0 Example
solution
2. ΔUMix = 0 a. Solid in gas i. Aerated water
3. ΔP = Pobs. − P(Calculated by Raoult's law) = 0 b. Gas in liquid ii. Smoke
4. ΔGMix = 0 iii. Solution of hydrogen in
c. Liquid in solid
palladium
23 Which of the following aqueous solutions of d. Gas in solid iv. Amalgams
electrolytes will exhibit the least elevation in boiling
point? a b c d
1. i iii iv ii
1. 0.05 M NaCl 2. 0.1 M KCl 2. ii i iv iii
3. 0.1 M MgSO4 4. 1 M NaCl 3. iii i iv ii
4. iv i ii iii
24 Match List-I with List-II
List-I
List-II 28 The solubility of a gas in a liquid decreases with an
(Name of the increase in temperature because:
(Reagent)
reaction) Dissolution of a gas in a liquid is an endothermic
A. Liquid ⇌ V apour I. Melting point 1.
process.
B. Solid ⇌ Liquid II. Boiling point Dissolution of a gas in a liquid is an exothermic
2.
C. Solid ⇌ V apour III. Sublimation point process.
D. Solute(solid) ⇌ Solute(solution) IV. Saturated solution 3. Gases are highly compressible.
V. Unsaturated solution4. All of the above.
Choose the correct answer from the options given
below: 29 The positive deviations from Raoult’s law mean the
1. A-II, B-I, C-III, D-IV vapour pressure is:
2. A-I, B-II, C-III, D-IV 1. Higher than expected.
3. A-III, B-II, C-I, D-IV 2. Lower than expected.
4. A-II, B-I, C-III, D-V 3. As expected.
4. None of the above
25 A solution that has the highest boiling point among
the following is: 30 To minimize the painful effects accompanying deep
1. 1.0 M NaOH sea diving, oxygen diluted with less soluble helium gas
2. 1.0 M Na2SO4 is used as breathing gas by the divers. This is an
3. 1.0 M NH4NO3 example of the application of:
4. 1.0 M KNO3 1. Raoult's law 2. Henry's law
3. Ideal gas Equation 4. All of the above
26 An aqueous solution of hydrochloric acid -
1. Obeys Raoult's law 31 The van’t Hoff factor (i) for a dilute aqueous
2. Shows negative deviations from Raoult's law solution of a strong electrolyte barium hydroxide is:
3. Shows positive deviations from Raoult's law 1. 0
4. Obeys Henry's law at all compositions 2. 1
3. 2
4. 3

Page: 3
 Solutions Contact Number: 9667591930 / 8527521718

32 One molal solution contains 0.5 moles of a solute 36 The type of inter-molecular interactions present in:
in: n-Hexane and n- Van der Waal’s forces of
(a) (i)
1. 1000 g of solvent 2. 500 mL of solvent octane attraction
3. 500 g of solvent 4. 100 mL of solvent (b) NaClO 4 and water (ii) Ion-dipole interaction
(iii) Dipole-dipole interaction
33 The plot of osmotic pressure (π) vs concentration
(molL
−1
) for a solution gives a straight line with slope (a) (b)
25.73 L bar mol-1. The temperature at which osmotic 1. (i) (ii)
pressure measurement is done is: 2. (ii) (ii)
Use R = 0.083 Lbarmol −1 −1
( K ) 3. (i) (iii)
1. 310°C 4. (iii) (iii)
2. 25.73°C
3. 12.05 °C 37 If 8 g of a non-electrolyte solute is dissolved in 114
4, 37°C g of n-octane to reduce its vapor pressure to 80 %, the
molar mass (in g mol–1) of the solute is:
34 Lowering in vapour pressure is the highest for:
[Molar mass of n-octane is 114 g mol–1]
1. 0.2 m urea
1. 40 2. 60
2. 0.1 m glucose
3. 0.1 m MgSO4 3. 80 4. 20
4. 0.1 m BaCl2
38 The azeotropic mixture of water and ethanol boils at
o
35 Which graph represents the positive deviation of 78.15 C. When this mixture is distilled, it is possible to
vapor pressure? obtain-
1. Pure H2O
2. Pure C2H5OH
3. Pure H2O as well as pure C2HOH
4. Neither H2O nor C2H5OH in their pure state
1. 2.
39 At 100 °C the vapour pressure of a solution of 6.5 g
of a solute in 100 g water is 732 mm. If Kb = 0.52, the
boiling point of this solution will be:
1. 100 oC
2. 102 oC
3. 103 oC
4. 101 oC

3. 4. None of the above 40 The osmotic pressure of 5 % (mass-volume)

solution of cane sugar at 150 °C (mol. mass of sugar =
342 g/mole) is:
1. 4 atm 2. 5.07 atm
3. 3.55 atm 4. 2.45 atm

Page: 4
 Solutions Contact Number: 9667591930 / 8527521718

Fill OMR Sheet*

*If above link doesn't work, please go to test link from
where you got the pdf and fill OMR from there. After
filling the OMR, you would get answers and explanations
for the questions in the test.

CLICK HERE to get

FREE ACCESS for 2
days of ANY
NEETprep course

Page: 5