Wood Ignition
Wood Ignition
•
FI RE RESEARCH NOTE
NO. 586
by.
April. 1965.
Fira Research Station.
. Boreham Wood.
Herts.
('phone ELStrlZe 1341)
© BRE Trust (UK) Permission is granted for personal noncommercial research use. Citation of the work is allowed and encouraged.
o
...
.,
F. R. Note No. 586
MINISTRY OF TECHNOLOGY
AND
FIRE OFFICES' COMMITTEE
JOINT FIRE RESEARCH ORGANIZATION
by
SUMIlARY
The effect of varying the moisture content an bath the pilot and
spontaneous ignition times of different woods of areas 7.6 cm square and 15 cm
square has been measured over a wide range of intensities of radiation. Moisture
increases the energy required for ignition; it also increases the minimum
intensity for ignition though with pilot ignition its effect is only marked for
moisture contents above. 40 per cent. .
Results have been correlated on the assumption that the material is inert
and ignites at a fixed temperature. Simple heat transfer theory has been used
to calculate this temperature with values for the thermal properties appropriate
to the given moisture content and with allowance made within the term for thermal
capaci ty for removing the water; the effect'} '(f moisture migration have been
neglected, fbllowing the results of Williams'7).
oC,
:Fer pilot ignition the correlating temperature is found to be 380
corresponding to a critical intensity of 0.31 cal cm-2s-1, except for fibre
insulating board which appears to ignite at a somewhat lower temperature of
330°C. Earlier experiments, with smaller specimens, gave a similar result, of
360 oC, with the results for fibre insulating board included. The present
correlation extends to much longer times (up to 59 min). The results show that
the chOice of 0.3 cal cm-2s-1 as the maximum accreptable level of radiation for
building regulation purposes, gives a larger margin of safety than was originally
~.. thought.
•
TIlE IGNITION OF WET A1ID DRY WOOD BY RADIATION
by
1• Introduction
•. It is important to lmow how moisture content can affect the behaviour
of wood in a fire and experiments have been carried out to investigate the
ignition of woods with varying moisture contents exposed to a wide range of
intensities of radiation o For oven dry wood both pilot and spont~eo~s
igilition occur when the heated surface reaches a fixed temperature\.1 ;2) and
-,
the ignition time can be calculated using the values of the thermal properties
of the dry wood, which is assumed to be inert. This note discusses the effect
of moisture on the thermal properties and shows how an allowance for this effect
enables the model assumed for dry wood to be applied to wet wood without further
modification o It then estimates how moisture can be expected to affect the
igilition of wood in practical conditions.
2. Experimental method and results
The specimens used in the pilot igilition experiments were also 7.6. cm square,
and these, as for spontaneous ignition, should give results close to those for an
infinite area.
The specimens of wood were oven dried and then conditioned to moisture
contents of approximately 20, 40 and 60 per cent of oven-dry weight by
repeatedly dipping t)J.em in water and allowing the water to sink: in. This
undoubtedly leaches out some vol~t:l-le material but the effect on the igilition
time is unlikely to be importantl4). The densities of the woods were obtained
from their volumes and weights when oven dried at 95°C Variations in density
0
between individual specimens of the same type of wood were found to be small.
-- The details of the specimens 'are given in Table 1 for the spontaneous
igilition and Table 2 for the pilot ignition experiments.
The experimental procedure was similar to that described earlier(5) except
that a modified water cooled Moll thermopile was used to measure radiation
instead of the Thwing type radiation pyrometer. The pilot flame was put.as
near as possible to the top front edge of the irradi~t~d surface, (Fig. 1.),
since this position gives the short.est igilition time \ 2) • Specimens were
exposed to radiation from the panel until they Lgrri.ted , If ignition occurr-ed,
the next specimen was exposed to a lower intensity of radiation until eventually
it was reasonable to assume that igilition would not occur, i.e •.until the rate
of production of volatiles became very low. With both pilot and spontaneous
igilition, flame could often be seen to appear in the volatile stream and then
flash down to the wood where it persisted on the surface With a few specimens
0
during pilot igilition, there was intermittent flashing between the pilot flame
and the surface for several seconds before flaming finally persisted, and with
a few others, the flame reached the wood but was intermittent before becoming
established o For these the ignition time was recorded as the first appearance
of flame. Specimens of European whitewood, other than those that were oven-
dry, 'behaved differently from the other woods; the moisture emerged from
the surface in small jets of steam. Sealing the edges of the larger specimens
appeared to have little effect on the ignition time. The results for pilot
ignition are shown in Fig. 2. The results for spontaneous ignition are given
in Table 1. The minimum intensities at w~ch ignition took place are shown in
Figs (3) and (4).
Experiments had also been carried out on the pilot ignition of dry specimens,
5 cm x 5 cm in area and these results(1) are also discussed later.
/
!
2 •.
. i
Table 1
Details of woods used' and experimental
results for spontaneous ignition
-.
Area Density Moisture Intensity of Ignition
Thickness
Wood oven dry content radiation time
cm 2 cm -dcm3 -% -cal cm-2 s -1 - s
"
-. Fibre insulating
board 7.6 x 7.6 1.3 0.~5 . oven-dry 1.00. 25
..
0.97 32
0.95 -
,
20 1.50 15
1.30 21
1 .25 33
1022 28
1021 33
1.20 ~
40 1.50 27
1 .40 30
1.30 37
1 .27 -
60 1.45 45
, 1.45 -
Columbian Pine T.6 x 7.6 1 .9 0.4 oven-dry 1020 53
(Pseudosuga 1.12 70
Taxifolia) 1 .10 70
1 .10 -
20 1.50 37
1.20 88
1.20 64
, 1.17 -.
40 1.50 47
1.45 68
1.43 55
1 .41 45
~-.
1.40 -
60 1.60 45
.... 1.58 50
1.55 -
Oak 7.6 x 7.6 1.9 0.7 oven-dry 1 .80 75
(Quercus sp. ) , 1 _20 93
1.16 -
20 1.50 62
1.40 72
/ - 1 .30 105
/
1 .28 -
, -
40 1.60 74
, 84
- 1.55
,, 1.52 80
1.50 -
60 1.60 96
1.58 94
1.57 119
1.55 •.
- 3 -
Table 1 continued
"
,
~
Baltic redwood 15 x 15 2.5 0.7 oven..,dry 0.7
(Pinus sylvestriS:) "
0.9
1 .1 r¢
. ".
I Edges and back surface' painted with flame retardant paint.
- 4 ..,
Table 2
Details of woods used in pilot ignition experiments
and range of experimental results
Area = 7.6 x 7.6 em 2
. ~.
- 5 -
3. Discussion of results
The effect of moisture is to increase the ignition time and energy and the
minimum intensity for both spontaneous and pilot ignition. For example, the
intensity of radiation required for the pilot ignition of dry wood is about half
that for wood with a moisture content of 60 fer cent. Similarly, at the same
intensity of radiation, (say 0.5 cal cm-2s-1) the pilot ignition time may be
increased from 2~ min for oven~dry oak, to 24 min for oak at a moisture content of
40 per cent. The minimum intensity required for pilot ignition in these experi-
ments with 7.6 em square specimens appears to be independent of the density of the
wood except for fibre insulating board which as before(1) is much easier to ignite
(Fig. 3). There appears to be a sharp increase in the minimum intensity between .'
40 and 60 per cent moisture content.
The increased size of the specimens used for the experiments on spontaneous
ignition has resulted in the minimum intensity for ignition being lowered with a
consequent increase in the times taken to ignite. For example dry wood 2.5 em
square ignites in about 30 s at a minimum intensity of about 1.2 cal cm- 2s-1,
7.6 em square in: about 70 s at 1.1 cal cm-2s-1 and 15 em square in about 800 s
at 1.0 cal cm-2s-1•
Heat transfer within the wood affects its temperatureorise and hence its
ignition time and the presence of moisture increa.ses the ignition time by
changing the heat transfer in at least three ways:
(1) moisture increases the values of the thermal properties Le. the therma.l
conductivity and the VOlumetric specific heat;
(3) evaporation cools the hotter regions and condensation heats the
cooler regions.
Water vapour in the atmosphere is an inerting gas, but the effect of this is
negligibly small compared with its effect on the moisture content of materials.
Gardon(8) also found little effect due to moisture migration and correlated
his results using a similar technique to Williams. Gardon pointed out that this
kind of correlation is based on calculating the extra enthalpy required to raise
the temperature of the wet wood by the same amount as the dry wood, Le. on
differences, and so that the method is not a sensitive one.
Williams(7) also calculated the rate at which the zone of vaporization moved
into the solid, by's method based on the work of Von Neumann•.; this divided the
solid into
. two regiorts, separated by an isothermal plane, the 100 0C plateau, the
plane of vaporisation. The rate at which this plane moves at any depthJC was
assumed to depenn only upon the net rate of heat transfer by conduction to that
depth. This led to the following trial equation for the depth X. 'of the plane
at time t
.See for example, Crank J., The ma.thematd.cs of diffusion, Oxford, 1954.
- 6 -
i
(£1)2 ierfc x = constant (1)
K 2 (kt)i
Fons (9) has suggested a simple means of allowing for the effects of
moisture on ignition on this basis. This enables three effects, the change
in the value of the thermal constants, the heat of wetting and the latent
heat to be, considered within the term for specific heat, viz.
The variations in: bo'th K and rdue to moisture are smaller than the variation
in 0, so that for simplicity the values for the wet wood can be assumed to
apply throughout the heating period up to' the time of ignition, although
striotly, once the water has been driven off the values for dry wood apply
and a we:i:g~ted average for the heating period should be taken.
- 7-
. \'
The ignition time, t, of oven-dry Viood in the form of a semi-infinite
solid, aasumed to be inert., opaque and totally abaor-b.Lng. irradiated on one face
by intenSity,(I~ and losing heat from that face by Newtonian cooling m~ ~e
obtained from. 2)
It
1
= (3/ (1 - erpr 2 erfcf) • •• • • • . . .. (5)
fO (kt)"2 Q.p
H (kt)!
where (3:= K
Ht
= 1
the cooling modulus
fC (kt)2,.
,
By substituting values of Km,f'm and cm given by equations (2), (3) and (4)
and inserting the experimental values of I and t in equation (5) we shall
attempt to find a value of OF. to give a correlation.
5. Correlation of results
Previous results for du wood, with the pilot flame in a nearly identical
position, were oorrelated(1) using the following values, 9F - 340 degC, H = 8 x 10-4
cal cm-2a-1 deg c-1 , Co := 0.34 cal g-1 deg C-1 o The correlation was satisfaotory
except for 1fibre insulating board at low values of I, i.e. at high values of
Ht~c (kt)2 where the points l~ below the line. The results for the new series
of~oven-dried materials are shown in Fig. 5; the~e.is a reasonably close fit
between the experimental points and aqua tion (5) using the same constants but
a better correlatiqn is· obtained by ignoring the fibre insulating board results
for high t/pc (kt)'2 and using GF = 360 deg C, H = 8.6 x 10-4 cal cm-2s-1 deg C-1•
The experimental results for the specimens of different moisture contents and
densities are plotte~in Fig. 6 using equation (5) and ~ =360 deg Co There is
reasonable agreement between the experimental points and equatio"n (5) except for
fibre insulating board, for which a better correlation is obtained by using
~ := 310 deg C, H = 7.4 x 10-4 cal cm-2s-1 deg C-1 • This leads to a value for
the oritical intensity of wood (1 0 = H~) of 0 ..31 cal cm-2s-1 and for fibre
insul8.ting board of 0.23 cal cm-2s-1•
The correlation shown in Fig. 6 appears to account for both the effects of
different moisture contents and of different densities on the pilot ignition
time of the woods. The results for fibre insulating board are a little below
those for wood, as was found earlier(1), but th~ residual effect associated with
density for the remaining woods found earlier( 1 ) with smaller specimens is absent
here. Addi tionally, although the ignition times are much longer tha.n thOse
studied previously ~ nearly an hour in one experiment and several specimens took
about 40 minutes to ignite - there is ncr sign of a trend away from the correlation
even at the highest value~ of Ht/pC(~t}2. This suggests that any effect due to:
self-heating (an earlier e'ip*anationl 1)) is small even for fibre insulating board.
8 -
The temperature found to correlate this and the earlier results is similar
and this confirms that any effect of area on pilot ignition time is small,
but since the residual effect associated with density has been removed, it
also suggests that the effect cf area on pilot ignition time as well as on
the minimum intensity for pilot ignition may be associated with the density
of the wood. The rise in the value of the correlating temperature from
340 deg C to 360 deg C is due to the exclusion of the results for fibre
insulating board.
Previous results(2) for dry wood were correlated using the following
values, ~ = 525 deg C, H = 1.4 x 10-3 cal cm-2s-1 deg c-1 , Co = 0.34
cal g-1 deg C-1. The results for the new series of oven dried woods
7.6,cm square and 15 cm square are shown in Fig. 7. There is a reasonably
close fit between the experimental points and e quation (5) using the same
constants, except for the results for Baltic Redwood which ignited for' very
low intensities. Since there appeared to be no difference between the
results for the other species, these have not been plotted separately.
The results for the 7.6 cm S~lare specimens of different moisture contents
and densities are also plotted in Fig. 7 and there is again a reasonably
close fit between the experimental results and equation (5), although the
results tend to lie above the curve at long times and below it at short
times. '
6. APPLICATION 01 RESULTS
- 9 -
\.
decrease in moisture content of about 5 or 10 per cent in a wood, resulting in a
similar decrease in the total amount of heat required for pilot ignition; could
increase the probability of fire occurring. Further, the moisture content of
fabrics exposed to the direct radiatipn from the sun .may be lower( 16) than that
expected from the temperature and humidity of the surrounding air because they
are likely to be hotter. The effect would probably be less marked with thicker
materials because the moisture diffusion time 'constant is longer, but this is a
possible physical explanation for the variation of the number of fires with the
hour-s of sunshine (15}.
7. Conclusions ,/
Increasing the moisture content increases the time for both pilot ignition
and spontaneous ignition for any given intensity of radiation. The increase has
been accounted for satisfactorily by using the values of the thermal properties
appropriate to the different moisture contents, and allowing for the effect of
heat of wetting and latent heat of evaporation within the term for specific heat,
as in equation (2). This confirms Williams' calculations which showed that it
was possible to neglect the effeot of moisture migration on the temperature rise.
The pilot ignition time for the positi,on of the pilot flame shown in fig 1
may be oalculated using equation (56 assuming a fixed surface temperature
criterion of 380 0C for wood and 330 C for fibre insulating board, This
oorrelating temperature for pilot ignition is the same for speoimens 5 om and
7.6 om square and 1his suggests that the effect of area on pilot ignition time
is small. The new correlation also appears to be more satisfactory than that
found earlier(1) since there is no residual effect linked with density, and
although fibre insulating board, the lightest material, again appears to ignite
at a slightly l,ower temperature, there is little sign of any systematic departure
from the curve at high values of Ht which wo.uld denote self-heating,
',' i
pd(kt)2
Moisture contents of up to about 40 per cent by weight appear to ha~e little
effect on the minimum intensity at Which ignition occurs, although there mSii' be
an increase above this level, but the energy required for ignition inoreases
markedly for all moisture oontents, The rate of heating from, and the energy
contained in most small souroes, is about the minimum required for ignition so
that even small fluctuations in moisture content may affect the number of fires
started. The experimental results also i suggest that there is an amply safe
margin in the"choioe of 0.3 cal om-2s-:1 as the maximum acceptable level of
radiation used in the Building Regulations to determine' separation of buildings.
The spontaneous ignition time can a Lso be calculated from equation (5)
assuming a fixed surfaoe temperature critenon of 5450C. This correlating
.temperature for the larger specimens (7 cm and 15 om square) is about the same
as that given ,earlier for smaller specimens and the range of ignition times for
whioh it is applicable has been extendec. to at least 130s. However, for the
results of the smaller specimens, '5 om square, analysed :In this paper, there is
a residual effeot due to density similar to that found for pilot ignition for
the same size of speoimen which suggests that the area correction factor is
assooiated with the density both for ignition time and for minimum intensity
of ignition.
- 10 -
References
(6) THOJ4AS, Po R., SIMMS, Do L o and LA'jV, Margaret. The effect of moisture
content on the spontaneous igqition of wood by radiation. Joint Fire
Research Organization.F.R. Note No. 280/19550
(15) HOGG, Jane M. The relationship between fire incidence and climato-·
logical variations 1951-1961 Joint Fire Research Organization;
F.R. Note No. 522.
(17) LAW, Margaret. Heat radiation from fires and building separation.
Fire Research Technical Paper No.5. London, HoMoS.O. 1963.
(18) LAW, Margaret. Spacing from timbf,lr Jrtacks to reduce fire spread.
IoF.E. Quarterly 196312 (49) 68-71.
- 11 -
: ..
~'.
\il 1·25cm
1·25cm
Specimen
FIG.1. POSITION
.~
OF PILOT FLAME
o
on
t::
1.:
:>
n
D
~
. ..
- -.
., .'
"
0·8
Densit y - 9 Icm J 0'66 0·79
Thickness - c m 1 '3 1 ·9
0·7 <.
• v ....
Moisturrz content
per- cent
dry 0
•
~ <, 20 /)"
•
,•
III)
0 40 0
';IE 0·6 o ....
u·
<, 60 V
u
o
\...
A
~. A
-,
I 0·5
z
o
~
o 0·4 ... --- - -
~
Q:
u,
~ • "
o
>- 0·3
l-
(/)
Z
W
t-
z 0.2
0·1
o 10 20 30 40
IGNITION TIME (t) -min
o· n
-
"
-- '
t:J:: ::!::
• -;
cr
LL
0 O· 3
>-
l-
V)
Z
W O· 2
I-
Z
O· 1
o 10 20 30
IGNITION TIME (t) - min
0-8
Dlll'lsity g/crrf
.>
0-46 0·71
Thlckness>- em 1·3 1·9
0- 7 Moisture content
~t - -
per- oent
dry 0
•
"iIII O. 6
20 fj,
•
~E
u
~ r-,
40
60
0
'V
••
o
u 0.5 ... ,....
I ~
z =-- A
o
I-
<! 0'4
o
- • -
• ,-
<!
a::
IJ.
o 0'3
>-
l-
V>'
Z 0·2
W
I-
Z
0·1
o
.
I
I . 3
Density - 9 l ctt; 0·25 0·25
Thickness -cm 1· 3 1 ·9
Till
0'5
.... Moisture content
,\ -.
.- per oant
';'E
u
0 .
dry
20
0
t::"
•
A
u 0-4 40 0
•
~~t----
~ I
z , 60 V y
0
~
0
,.
"
~ 0·3
"
\ 0
<i
0:
-
~~-
.' -P-- ~
...
-• -
IJ..
0 0·2
-
>-
I-
-
If)
Z 0·1
W
I-
Z
o 10 20 .30 40
IGNITION TIME ( t ) - min
z 0- A
o
(~
~
- ..>:
(l
cr
(
-, ~~
e o· 2
~
lJ)
z
w
~ 0
20 40 60
~ MOISTU RE CONTENT OF WOOD - per cent
~
z
z t:. Fibre Insulating board
2 v Columbian pine
o EuroplZan whitewood
n Oak
o ,-.
u ( .-JI ~
I 1.5
z I.-
o
t= ~
Z
(!) 1·0
a:
6:
"..
. -
?=' 0·5
l J)
... z:
-.. ~ -,
z·
o 20 40 60
MOl sru RE CONTENT OF WOOD - per cent
-
A Fibr<Z Insulating board
V Co.lumbian pine
o Europ<zan whitewood
(] Oak
3
sxto
(0)
/ (b)
u (e)
U'I
~
'0
.....
-
~
~ -
~
" 1cr
2 -I
em S degC cal-
e·
. f H
-2 -I -I
Curve deg C cal em S dflg C
-4
(a) 360 8· 6 x 10
-4
( b) 340 8 ·0 x 10
-4
(e ) 310 7·4 x 10 .
0 European Whitewood
li Columbian pine
0 Oak
V Fibre lnsutctlnq board
<D
~
-lO
,'"
."
. a. OAK
5·01-------+-----+------_+_---___;
+I " E
joo.oju
~E
ar 2- 0 I------+--Qr~:::...;:;;:;:--_+_-----_+_-__:_-___;
1- 0
0·5 1'0 ' 2-0 5·0 10'0
. Ht
PmCm( I<m t >!
5·0
-
-IN
.....,
.:i£E
+'
1-1
-
uE
Q..E
(1)"'"
2-0
1 . O'""--...-~...................----~--l----"-....a..........&.. .......................
0-5 1-0 5-0 10·0
r-,
1.0
FIG.6A .. CORRELATION OF PILOT IGNITION RESULTS
w
-
~
FOR SPECIMENS 7-6cm SQUARE
c. COLUMBIAN PIN
5'0
-IN
-
+'
E
~
...,
..... uE
~E
ar .2·0
2· 01------t-~___'lf__"""'_+------+_---__1
,"
2'0 5·0
:!
Ht 1
PmCm( k,ntl2
D
:0 Symbol Molsture content
0- p<lr eent
l::
1..: 0 dry
o /1 20
o
D 0 40
.... V 60
-4 -2 -I -I
Curve ~iwn by equctlon 5 with 8t = 360 deg C H =8"6 x10 eal em s dcq C ~
-4 -2 -I -I
- - - - - - - 9t=310 de9 C H=7'4 x 10 cal crn js dt2g C
,.
9·Qr-----------..,.-------,--------,---------r-------,
,
5-0
Moisture Arl20
content-
per cant 7·6x7·6 1S-0x1"5'O
-
-iN
o+J
e' 0
: dry ~ '.
crif
0
cm2
•
-
~
20, II
•
.•
otJ
E
...... u, 40 0
60 'l
.sr:
~ 2·0
0),
/
~Oltic
redwood
1 . Ot--------~--~-----:--=-+-+------+--------+--------1
Pme,rt. k m t )~
-3 -2 ·-1 :-1
The curve Is given by equotlon 5 with 9t=525~ deg C , H ..1·4 x10 col cm 5 d129 C
2·0
0
.....
t-1
t!
E
U
1·5
~ 1· 0
e
0.7 _--'_ _--lo_~_...L.._...I-..O~__I,_...J"",..L---~
0·15 0·2 0·4 0·6 1·0 1·5
Ht
-
(i)
r:
..
......
.~
~
'. .
SPECIMENS
3-0 ....--------r"----..----........---
2 -0 I--_f---------+----+-------,,---+-_~
1 - 5 t--_I-----"""O"'+------... .~-+--~
•
1.0 I--_f-----~=I__--l----~--....:.....--+----__I
••
0-7 ......._I-.-_----L_----L_~--I.. ........__""_--I......I...-_ ____I
Ht
PmCmj"k;f
2-0
~.
1 ·5
..... E
H u
Q..E
~ 1 -0
Ht
1 . 5 t--------!I--------+ ~~""'---_+_-____f
1 . 0 ......----.,1__------+---+----+-----1
•
o ·7 .......
- - . j l - - _ . . . . . . . . l . _ - - - . l . _ - ' - -.........---...L.--&.........r......a-._---...
Ht
PmCm\p
3·0r-~-------r--..,.------,...._-___,
2·0 ~--t-----+---+----=-jt------i
1 . 51-----+------f,o__~l::J---".II::.----1I__-___4
..., E
~ u
-
~E
,0>
1 ·0.---+-...... , . . . - - 4 - - - - + - - - - 1 - - - - - - 4
••
o .-15""'-0......-2_ _...a-..._"O""-----'---..._L......I----.&_
0·7 _- - ~
,·0'1·5
0'4 0'6
.•-'
Hi
o.
. ..' I'm CmJkm t
0,
io ..
.c ( f) Moisture content ~ 18 per cant
Fibre, insulat,lng board moisture content -28 per cent
:\I
o'
(5
.... For key see fig. SA·
-.
,
. -3 -2 -I -I
cur-ve Is given by equntlon 5 with St 525 da9 C H -1 '4x 10 cal em s deg C
, "
•
~.