ECE 101 Lecture3
ECE 101 Lecture3
SEMICONDUCTORS
Semiconductors
2
Possible Semiconductor Materials
1. Very Expensive
Carbon C 6 2. Band Gap Large: 6eV
3. Difficult to produce without high contamination
1. Cheap
Silicon Si 14 2. Ultra High Purity
3. Oxide is amazingly perfect for IC applications
1. High Mobility
Germanium Ge 32 2. High Purity Material
3. Oxide is porous to water/hydrogen (problematic)
3
The Silicon Atomic Structure
-
-
- -
- Si -
-
14 -
- -
-
• -
• Silicon: It’s a Group 4 element which means it has 4 electrons in
outer shell
• However, like all other elements it would prefer to have 8 electrons
in its outer shell
4
Bonding of Si atoms
5
Electrons and Holes
6
Electrons and Holes
For T > 0
• Some electrons in the valence band
receive enough thermal energy to be
excited across the band gap to the
conduction band.
• The result is a material with some
electrons in an otherwise empty
conduction band and some unoccupied
states in an otherwise filled valence
band.
• An empty state in the valence band is
Electron-hole pairs in a referred to as a hole.
semiconductor. The bottom of the • If the conduction band electron and the
conduction band denotes as Ec and hole are created by the excitation of a
the top of the valence band denotes
valence band electron to the
as Ev.
conduction band, they are called an
electron-hole pair (EHP).
7
Silicon Lattice Structure
Free electron
- - - - Vacancy
- -- -- - - -
At 0 K, all left by
Si Si Si Si
electrons are - - - - electron.
tightly shared - - - - - charge
Overall
on
-+- Si --
with neighbours
→ no current - Si -- Si -- Si - is
Si silicon
- - - - - - → this
zero
- - - - -
flow
“hole” must
- Si -- Si - - Si - - Si - - Si - be positive
- - - - -
- -
- Si -- Si -- Si -+- Si -
- - - -
-
- Si -
- Shares electrons with 4
Adding heat (even to room temperature) neighbouring atoms →
allows some bonds to break, and electrons 8 electrons in outer shell
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Intrinsic Material
• A perfect semiconductor crystal with no impurities or lattice defects is called an
intrinsic semiconductor.
At T=0 K – At T > 0
• No charge carriers • Electron-hole pairs are generated
• Valence band is filled with electrons • EHPs are the only charge
• Conduction band is empty carriers in intrinsic material
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Increasing conductivity by temperature
• As temperature increases, the number of free electrons and holes created increases
exponentially.
Carrier Con centrat ion vs Temp (in Si)
17
1 10
16
1 10
15
1 10
14
1 10
13
1 10
Intrinsic Concentration (cm^-3)
12
1 10
11
1 10
niT 1 10 10
9
1 10
1 108
1 107
1 106
1 105
4
1 10
3
1 10
100
150 200 250 300 350 400 450 500
T
T emperature (K)
Intrinsic Semiconductors
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Increasing conductivity
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Extrinsic Material
• By doping, a crystal can be altered so that it has a predominance of either electrons or holes.
• Thus there are two types of doped semiconductors, n-type (mostly electrons) and p-type
(mostly holes).
• When a crystal is doped such that the equilibrium carrier concentrations n0 and po are different
from the intrinsic carrier concentration ni, the material is said to be extrinsic.
13
Increasing conductivity by doping
- Si -- Si -+- Si - - Si -
- - - -
- -- - - -
- Si -- Ssi - -
A Si -+- Si -- Si -
- - - - - -
-- - - -- - - -
- ASsi -- Si - - Ssi - -
A Si - - Si - -
- - - - - -
- - - -
- Si - - Si - - Si -+- Si -
- - - -
-
• Inject Arsenic into the crystal with an implant step.
- Si -
• Arsenic is Group5 element with- 5 electrons in its outer shell, (one more than silicon).
• This introduces extra electrons into the lattice which can be released through the application of
heat and so produces an electron current
• The result here is an n-type semiconductor (n for negative current carrier)
14
Increasing conductivity by doping
- - - -
- Si -- Si -+- Si - - Si -
- - - -
- - - + - -
- Si -- Si- - Si -+- Si -- Si -
- - + - - - -
- - +- - -+
- Si - - Si - - SBi - - Si - - SBi -
- - - -- - -
- -+ + -
- Si - - SBi -- Si -+- Si -
- - - -
-
- Si -
- an implant step.
• Inject Boron into the crystal with
• Boron is Group3 element is has 3 electrons in its outer shell (one less than silicon)
• This introduces holes into the lattice which can be made mobile by applying heat. This gives
us a hole current
• The result is a p-type semiconductor (p for positive current carrier)
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The Fermi – Dirac distribution function
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The Fermi – Dirac distribution function
F (E F ) = 1+e (E F −E F ) / kT
−1
=
1 =1
1+1 2
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Extrinsic Semiconductor
• An extrinsic semiconductor is one that has been doped, that is, into
which a doping agent has been introduced, giving it different
electrical properties than the intrinsic (pure) semiconductor.
Intrinsic
Donor atoms Acceptor atoms
semiconductor
Aluminum phosphide,
Aluminum arsenide, Beryllium, Zinc, Ca
Group III-V Selenium, Tellurium,
Gallium arsenide, dmium, Silicon, Ge
semiconductors Silicon, Germanium
Gallium nitride rmanium
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n-type extrinsic semiconductors
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n-type semiconductors
Before doping
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n-type semiconductors
After doping
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p-type semiconductors
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carrier concentrations (p-type)
Before doping
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carrier concentrations (p-type)
After doping
Ev
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Band diagram, density of states, Fermi-Dirac distribution,
and the carrier concentrations at thermal equilibrium
Intrinsic semiconductor
n-type semiconductor
p-type semiconductor
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Charge neutrality
n + N A = p + ND
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Majority and minority carriers
electrons holes
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n-type majority and minority carriers
• In n-type semiconductors,
electrons are the majority carriers
and holes are the minority
carriers.
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p-type majority and minority carriers
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Doped Semiconductors
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Doped Semiconductors
n-type doped semiconductor
➢ If ND is much greater than ni …
❑concentration of donor atoms is ND
➢ Then the concentration of electrons in the n-type is defined as
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Doped Semiconductors
p-type semiconductor
➢ Q: How can one find the concentration?
❑A: Use the formula to right, adapted for the p-type
semiconductor.
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Doped Semiconductors
n-type semiconductor
➢ Q: How can one find the concentration?
❑A: Use the formula to right, adapted for the n-type
semiconductor.
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Doped Semiconductors
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Doped Semiconductors
• Let
no : thermal-equilibrium concentration of electrons
po : thermal-equilibrium concentration of holes
Nd : concentration of donor atoms
Na : concentration of acceptor atoms
Nd+ : concentration of positively charged donors (ionized donors)
Na- : concentration of negatively charged acceptors (ionized acceptors)
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Doped Semiconductors
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INDIAN INSTITUTE OF TECHNOLOGY ROORKEE
v p − drift = p E vn − drift = − n E
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Drift Current
.E (volts / cm)
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• An electric field E established in a bar of silicon causes the holes to
drift in the direction of E and the free electrons to drift in the
opposite direction. Both the hole and electron drift currents are in
the direction of E.
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Drift Current
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Note…
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Diffusion Current
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Diffusion Current
• Take the following example…
inject diffusion occurs
➢ inject holes – By some unspecified holes
process, one injects holes in to the left
side of a silicon bar.
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Diffusion Current
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The pn Junction with Open-Circuit Terminals
Physical Structure
pn junction structure
➢ p-type semiconductor
➢ n-type semiconductor
➢ metal contact for connection
46
Operation with Open-Circuit Terminals
• A:
➢ p-type material contains majority of holes
❑these holes are neutralized by equal amount of bound negative charge
➢ n-type material contains majority of free electrons
❑these electrons are neutralized by equal amount of bound positive charge
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Operation with Open-Circuit Terminals
bound charge
➢ charge of opposite polarity to free electrons / holes of a given material
➢ neutralizes the electrical charge of these majority carriers
➢ does not affect concentration gradients
p-type n-type
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Operation with Open-Circuit Terminals
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• Step #1: The p-type and n-type semiconductors are joined at the
junction.
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• Step #2: Diffusion begins. Those free electrons and holes which
are closest to the junction will recombine and, essentially, eliminate
one another.
p-type n-type
Figure: The pn junction with no applied voltage (open-circuited terminals).
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• Step #3: The depletion region begins to form – as diffusion occurs
and free electrons recombine with holes.
p-type n-type
Figure: The pn junction with no applied voltage (open-circuited terminals).
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• Step #4: The “uncovered” bound charges affect a voltage
differential across the depletion region. The magnitude of this
barrier voltage (V0) differential grows, as diffusion continues.
No voltage differential exists across regions of the pn-junction outside
of the depletion region because of the neutralizing effect of positive
and negative bound charges.
voltage potential
barrier voltage
(Vo)
p-type n-type
location (x)
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• Step #5: The barrier voltage (V0) is an electric field whose polarity
opposes the direction of diffusion current (ID). As the magnitude
of V0 increases, the magnitude of ID decreases.
diffusion drift
current (ID) current (IS)
p-type n-type
Figure: The pn junction with no applied voltage (open-circuited terminals).
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• Step #6: Equilibrium is reached, and diffusion ceases, once the
magnitudes of diffusion and drift currents equal one another –
resulting in no net flow.
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The Drift Current IS and Equilibrium
• Specifically, some of the thermally generated holes in the p-type and n-type
materials move toward and reach the edge of the depletion region.
• Therefore, they experience the electric field (V0) in the depletion region and are
swept across it.
➢ Unlike diffusion current, the polarity of V0 reinforces this drift current.
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Operation with Open-Circuit Terminals
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Note that the magnitude of drift current (IS) is
unaffected by level of diffusion and / or V0. It will be,
however, affected by temperature.
diffusion drift
current (ID) current (IS)
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Operation with Open-Circuit Terminals
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Operation with Open-Circuit Terminals
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Operation with Open-Circuit
Terminals
• Q: What has been learned about the pn-junction?
➢A: depletion region
❑As these carriers disappear, they release bound
charges and effect a voltage differential V0.
➢A: depletion-layer voltage
❑As diffusion continues, the depletion layer voltage
(V0) grows, making diffusion more difficult and
eventually bringing it to halt.
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Operation with Open-Circuit
Terminals
• Q: What has been learned about the pn-junction?
➢A: minority carriers
❑Are generated thermally.
❑Free electrons are present on p-side, holes are
present on n-side.
➢A: drift current IS
❑The depletion-layer voltage (V0) facilitates the flow
of minority carriers to opposite side.
➢A: open circuit equilibrium ID = IS
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The pn Junction with an Applied Voltage
Figure 11: The pn junction in: (a) equilibrium; (b) reverse bias; (c) forward bias.
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1) no voltage 1) negative voltage 1) positive voltage
applied applied applied
2) voltage differential 2) voltage differential 2) voltage differential
across depletion zone across depletion zone across depletion zone
is V0 is V0 + VR is V0 - VF
3) ID = IS 3) ID < IS 3) ID > IS
• Figure to right shows pn-
junction under three
conditions:
– (a) open-circuit –
where a barrier
voltage V0 exists.
– (b) reverse bias –
where a dc voltage
VR is applied. Figure 3.11: The pn junction in:
– (c) forward bias – (a) equilibrium; (b) reverse bias;
where a dc voltage (c) forward bias.
VF is applied.
Description of Junction Operation
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Description of Junction Operation
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Forward-Bias Case
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Reverse-Bias Case
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Reverse Biased Diode’s Application:
Voltage-Dependent Capacitor
• The PN junction can be viewed as a capacitor. By varying VR, the
depletion width changes, changing its capacitance value; therefore,
the PN junction is actually a voltage-dependent capacitor.
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Current-Voltage Relationship of the
Junction
• Q: What happens, exactly, when a forward-bias voltage
(VF) is applied to the pn-junction?
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• step #1: Initially, a small forward-bias voltage (VF) is applied. It,
because of its polarity, pushes majority (holes in p-region and
electrons in n-region) toward the junction and reduces width of the
depletion zone. V F
Note that, in this figure, the smaller circles represent minority carriers
and not bound charges – which are not considered here.
P-type N-type
P-type N-type
P-type N-type
diffusion drift
current (ID) current (IS)
P-type N-type
np0 pn0
P-type location (x) N-type
Figure: The pn junction with no applied voltage (open-circuited
terminals).
Figure: The pn junction with applied voltage.
step #4: The concentration of minority charge carriers increases on
either side of the junction. A steady-state gradient is reached as rate
of majority carriers crossing the junction equals that of recombination.
VF
minority carrier
concentration
P-type N-type
Figure: The pn junction with applied voltage.
PN junction Characteristics
Conduction band
Valence band
N type P type
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Current-Voltage Relationship of the
Junction
• saturation current (IS) – is the
maximum reverse current
which will flow through pn-
(eq3.40) I = IS (eV / VT − 1)
junction.
➢ It is proportional to cross-
section of junction (A).
➢ Typical value is 10-18A.
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Reverse Breakdown
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Zener breakdown
• The electric field in the depletion layer increases to cause breaking covalent
bonds and generating electron-hole pairs.
• The electrons generated in this way will be swept by the electric field into the n
side and the holes into the p side. Thus these electrons and holes constitute a
reverse current across the junction.
• Once the zener effect starts (VR=5V), a large number of carriers can be
generated, with a negligible increase in the junction voltage. Thus the reverse
current in the breakdown region will be large and its value must be determined
by the external circuit.
• The reverse voltage appearing between the diode terminals will remain close to
the specified breakdown voltage VZ.
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Avalanche breakdown
• The minority carriers that cross the depletion region under the influence of the
electric field gain sufficient kinetic energy to be able to break covalent bonds in
atoms with which they collide.
• The carriers liberated by this process may have sufficiently high energy to be
able to cause other carriers to be liberated in another ionizing collision.
• This process keeps repeating in the fashion of an avalanche, with the result that
many carriers are created that are able to support any value of reverse current, as
determined by the external circuit, with a negligible change in the voltage drop
across the junction.
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Reverse Breakdown
• The maximum reverse-bias potential that can be applied before
entering the breakdown region is called the peak inverse voltage
(referred to simply as the PIV rating) or the peak reverse voltage
(denoted the PRV rating).
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Capacitive Effects in the pn Junction
2. Diffusion Capacitance
When a pn junction is forward biased
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Capacitive Effects in the pn Junction
• Junction capacitance:
✓ due to the dipole in the transition region (associated with the charge stored in the
depletion region).
✓ Also called transition region capacitance or depletion layer capacitance.
✓ Dominates under reverse bias conditions.
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