17-08-2025

4001CJA101021250040 JA

PART-1 : PHYSICS

SECTION-I (i)

0
1) Magnetic field exist in the space and given as , where B and ℓ are positive constants.
A particle having positive charge ‘q’ and mass ‘m’ is projected with speed ‘v0’ along positive x-axis
from the origin. What is the maximum distance of the charged particle from the y-axis before it turns
back due to the magnetic field. (Ignore any interaction other than magnetic field)

(A)

(B)

(C)

(D)

2) A current carrying loop is placed in a plane perpendicular to a long current carrying wire as

shown :

(A) Force on the loop is attractive.

(B) Force on the loop is repulsive.
(C) Force on the loop is zero, only if loop is circular.
(D) Force on the loop is zero, for any shape of loop.

3) A light inextensible string carrying a spring [as shown in figure] is passed over two smooth fixed
pulleys. The rod is slightly displaced (about the hinge) from it’s equilibrium position (when the

spring is unstretched). The radius of smaller pulley is . The time period for small oscillation is:
(A)

(B)

(C)

(D)

4) Direct current power is supplied at 33 kV to a distant load by means of two parallel cables having
a capacitance between them of 1.00 × 10–11 F m–1. Such cables, when separated by a distance d and

loaded with a charge of σ per unit length, each experience a force per unit length of . At
what (non-zero) electrical load level is there no net force between the two supply cables?

(A) 33 MW
(B) 3.3 MW
(C) 11 MW
(D) 1.1 MW

SECTION-I (ii)

1) A hollow spherical conducting shell of radius ‘a’ has thin long wires connected at the top (r = a, θ
= 0) and bottom (r = a, θ = π). A direct current I flows down the upper wire, down the spherical
surface, and out the lower wire. The sphere is centered at the origin and the wires are along the x
axis.

(A) At the centre of the sphere, magnetic field is zero

(B) At point (0.5r, 0.8r, 0) the magnetic field is μ0I/1.6πr
(C) At point (0.3r, 0.4r, 0) the magnetic field is μ0I/1.2πr
(D) At point (0.5r, 0.8r, 0) the magnetic field is zero

2) A particle having charge 1C and mass 1 kg enters a region having uniform magnetic field of
strength '2T' with a speed of 12 m/s, as shown in figure, then the CORRECT statement(s) is/are:

(A)
The time for which the charge particle remains in magnetic field is s.
(B) The velocity of charged particle becomes parallel to x-axis 6 time during its motion
The distance between the point where the charge particle enters the uniform magnetic field and
(C)
the point where it emerges out is 6 m

(D)
The deviation of the charge particle when it emerges out of the magnetic field is rad.

3) Photons emitted by a gas consisting of excited hydrogen like atoms (A) during a transition from a
higher quantum state (quantum no. n) to a lower quantum state (quantum no : m) are incident on a
metallic surface (B) causing the emission of photoelectrons. The fastest photoelectrons pass
undeviated through a region consisting of electric field, E0 = 3.7 V/cm and magnetic field, B0 =
10–3 T, oriented in perpendicular directions and the photoelectrons enter the region perpendicular
to both electric and magnetic field. The threshold wavelength for the metal B equals 830 nm. The
spectrum of light emitted by the excited hydrogen –like atoms (A) consists of 15 different
wavelengths. (Take 1.89 /13.6 1/7)

(A) The quantum number of state n = 6

(B) The quantum number of state m = 4
(C) The atomic number of Z = 2 of the element of A
(D) The atomic number of Z = 4 of the element of A

4) An infinite horizontal square grid of side 'a' made of uniform material has current “i” fed into it at
node A and this current leaves at B. The semi infinite wires used for the entry and exit of current
into this grid are shown in the figure-2 which is an enlarged version (not drawn to scale) of the grid
in the locality of AB when observed along its plane. The feeding wires are parallel to AB and just
above the plane of the grid by a small distance δ(δ → 0). These feeding wires are thus not visible in
figure I. Consider an Amperean circular loop with AB as axis, midpoint of AB as its centre and R as
its radius as shown in figure 2. C is the midpoint of square formed by AB as its side shown in figure
1. Take Magnitude

of circulation around the shown Amperean loop if is taken due to grid and feeding wires
is x.

Magnitude of circulation around the shown Amperean loop if is taken of due to entire
grid excluding the feeding wires is y.
Magnitude of at point C is z. Then

(A)

(B)

(C)

(D)

SECTION-II (i)

Common Content for Question No. 1 to 2

A charged particle enters a region in which there is a frictional force proportional to the particle’s
velocity , and the particle stops 10 cm from its entry point. If the particle repeats its motion
when a homogeneous magnetic field of magnitude B, perpendicular to the plane of its trajectory, is
also present, then the particle comes to rest at a displacement of 6 cm from its entry point (see
figure).
(velocity with which particle enters the region is to be taken same in all cases)
1) If the magnetic field were twice as large the particle would stop at a displacement of cm from
entry point, where N is:

2) The magnitude of the magnetic field for which the particle would stop at a displacement

of cm from entry point is , where n is:

Common Content for Question No. 3 to 4

A current-carrying ring of mass 'M' can be floated above a horizontal superconducting plane without
any mechanical support. In the figure, P is such a ring, floating above the superconducting plane z =
0.

Following a method similar to that of image charges in electrostatics , it can be shown that the
magnetic flux density in the region z ≥ 0, above and on the plane(but not below it), is the same as it
would be if the plane were removed and an identical ‘image ring’ Q, carrying the same current, were
placed the same distance below the plane as the real ring is above it.
If the ring radius ‘r’ is much greater than the ring-plane separation h, the two ring can be treated as
if they were long parallel straight wires. Bearing in mind the state of the real ring P,

0
3) The equilibrium height h is , where n is :

4) The frequency of the ensuing oscillation if the ring is displaced slightly in the vertical direction

and then released is , where n is:

SECTION-II (ii)

1) Two current carrying wire of infinite length are placed perpendicular to x-y plane at x = 0 and
as shown in figure. Current in both the wires is same and inwards to the x-y plane. Find
ratio of in segment CDA to segment ABC will be :

2) A hollow conducting cone (mass m, radius R, height h) has a current I flowing uniformly along its
curved surface area. This cone is kept on a very rough horizontal surface and a uniform magnetic

field exists in space. The maximum value of I so that the cone does not topple about point P

is given by , then n is:

3) An electron is projected normally from the surface of a sphere with speed v0 in a uniform
magnetic field perpendicular to the plane of the paper such that its strikes symmetrically opposite

on the sphere with respect to the x-axis. Radius of the sphere is and the distance of its centre
from the wall is 'b'. The required magnetic field so that the charge particle just escapes the wall will

be .. Find the value of k.

4) A conducting square loop of side ‘a’ is kept on a sufficiently rough horizontal surface and
connected to a charged capacitor as shown in the figure. The arms AB, BE, FC, CD and DA are rigid
but connecting wires EG, FH can behave as strings, so that the whole loop can rotate about BC.
The mass of each arm is m and the gap between points E and F can be neglected. A uniform

magnetic field B is present in the x direction. On closing the switch, is the amount of charge
flown in circuit so as to rotate the loop by 90° about BC, then find the value of k. (neglect the

resistance of wires)

5) An infinitely long wire is bent into the form of a parabola of focal length a. The wire carries a

steady current I. The magnetic field of induction at the focus F as shown in the figure is , where

N is

6) A uniform infinite thread of charge with linear charge density λ and another infinitely long
parallel conducting wire lie in same plane with distance d between them. Current i0 flows in
conducting wire as shown in the figure. A photoelectric plate PQ with work function ϕ is placed
perpendicular to the wires with C as midpoint on the plate between the wires.

The frequency of light to be radiated on the surface, for which fastest

photoelectron (mass m) ejected from C, normal to plate goes undeviated is

. Then N + M is

PART-2 : CHEMISTRY

SECTION-I (i)
1)
What is the correct match for molecular geometry about central atom?

(A) A ⇒ Tetrahedral
(B) Cationic part of B ⇒ Octahedral
(C) Anionic part of B ⇒ Octahedral
(D) C ⇒ Capped octahedral

2) What is the reactivity of the following compounds with hypobromite ion ?

(I) (II) (III) (IV)

(A) I > II > III > IV

(B) I > III > II > IV
(C) IV > III > II > I
(D) IV > II > III > I

3) The laevorotatory product upon the hydrolysis of invert sugar is:

(A)
(B)

(C)

(D)

4) Which of the following graphs correctly represents changes in the energy levels of the MOs and
the ground state electronic configurations of homonuclear diatomic molecules involving O2 & N2
respectively ?

(A)

(B)
(C)

(D)

SECTION-I (ii)

1) Which of the following sequence orders is/are correct?

(A) Acidic strength : HOCl < HOBr < HOI

(B) Acidic strength : HOCl < HOClO > HOClO2 < HOClO3
(C) Oxidizing power : HOCl < HOClO < HOClO2 < HOClO3
(D) Thermal stability : HOCl < HOClO < HOClO2 < HOClO3

2) Which of the following steps is/are industrially used for extracting metal from corresponding ore ?

(A) Sphalerite : roasting → reduction by coke → fractional distillation

(B) Calamine : calcination → carbon reduction → fractional distillation
(C) Malachite : Sulphuric acid leaching → smelting
(D) Bauxite : leaching → calcination → electrolysis

3)
Which of the following statements is/are correct ?

(A) The compound A has 3 total stereoisomerism.

(B) B is optically inactive due to external compensation.
(C) C is a γ–Lactam.
(D) C is a γ–Lactone.
4) Which of the following statements is/are incorrect regarding glucose ?

(A) Glucose forms pentaacetate that doesn't react with hydroxyl amine.
(B) Glucose is oxidized to glucaric acid by bromine water.
(C) C-5 epimer of D–glucose is D–idose.
(D) Amylose, amylopectin and glycogen are branched polymers to glucose.

SECTION-II (i)

Common Content for Question No. 1 to 2

1) How many moles of KOH are used per mole of 'G' ?

2) How many grams of product (major compound) is formed when 1 mole of B reacts with 1 mole of
aniline in presence of pyridine (assuming 100% efficiency) ?

Common Content for Question No. 3 to 4

25 mL of household bleach solution was mixed with 30 mL of 0.50 M KI and 10 mL of 4 N acetic
acid. In the titration of the liberated iodine, 48 mL of 0.25 N Na2S2O3 was used to reach the end
point.

3) The molarity of the household bleach solution is:

4) What volume (in ml) of the same solution will be required to oxidize 12 g of Cyclohexanol ?
 SECTION-II (ii)

1) For the following molecules:

White phosphorus, CH2SF4, XeO3F2, C3H4(allene)
ai = Maximum number of atoms in one plane.
bi = Number of such planes.

Find .

2) An interhalogen compound "A" upon hydrolysis yields "B" and "C". A is prepared from an
equimolar mixture of its constituent elements in standard state. B is a key raw material in deacon's
process and C has a molecular weight of 144. What are total number of valence electrons in a
molecule of "A" ?

3) Aniline yellow can be prepared in a good yield by rearrangement reaction of diazoaminobenzene

with a small quantity of aniline hydrochloride in the presence of aniline as solvent.
If 37 g of diazoaminobenzene reacts with 73% yield, the weight of aniline yellow prepared
is...........gram. (Nearest integer)

4) If "a" in the n–Factor of XeF4 in its complete hydrolysis reaction. Find 12a.

5) Zirconium can be refined using van Arkel method. What is the oxidation state of Zirconium in the
intermediate volatile specie ?

6) An organic compound 'A' on treatment with ethyl alcohol gives a carboxylic acid 'B' and
compound 'C'. Hydrolysis of 'C' under acidic conditions gives 'B' and 'D'. Oxidation of 'D' with
KMnO4, also gives 'B'. 'B' on heating with Ca(OH)2 gives 'E' (molecular formula, C3H6O), 'E' does not
give Tollen's test and does not reduce Fehling's solution but forms a 2,4–dinitrophenylhydrazone.
Find the sum of molecular weights of A, B, C, D and E.

PART-3 : MATHEMATICS

SECTION-I (i)

1) If f : R → R be a periodic and a twice differentiable function with fundamental period π. Also

then :

(A)
(B)
(C)
(D)

2) Two circles touches both the co-ordinate axis and are orthogonal to each other. If both of them
passes through (a, b) then is equal to :

(A) 1
(B) 2
(C) 3
(D) 4

3) If every root of a polynomial equation h(x) = 0 of degree ‘5’ with leading coefficient ‘1’ is real
and distinct, then the number of real roots of the equation is :

(A) 0
(B) 2
(C) 3
(D) 4

4) Find the value of m, where

(A) 21
(B) 41
(C) 3
(D) None of these

SECTION-I (ii)

1) Let f : R → Q and y = f(x) be a continuous differentiable function such that x = a is a point of

maxima then :

(A) for which f(x) is a decreasing function in (a, a + δ)

(B) for which f(x) is a increasing function in (a – δ, a)
(C) for which
(D)

2) f(x) is a twice differentiable function in [a, b] such that f(a)=f(b)=0 and

then

(A)
(B)

(C)

(D)

3) Let tangent at (a1, b1) on the curve touch the curve again at (a2, b2) then (a1 <
a2) :
(A) |a1| + |b1| + |a2| + |b2| = 4
(B) a1b1a2b2 = 0
(C) a1 + b1 + a2 + b2 = –2
(D) b1 – a1 + a2 – b2 = 4

4) Let y = f(x) be a differentiable function and also then

(A) where f(c) = c

(B) where f(c) = c
(C) where f(c) = c
(D) function must have a point on inflection

SECTION-II (i)

Common Content for Question No. 1 to 2

Let P be a point on and Q be a point on line 7x + y + 3 = 0; perpendicular bisector of
PQ is line x – y + 1 = 0

1) Let P(α, β) where α, β ∈ I from α + β is equal to

2) Let P(y, δ) where y, δ ∈ Q – I then |[y + δ]| is equal to where [ . ] denotes greatest integer
function :

Common Content for Question No. 3 to 4

Let f : R+ → R be a strictly increasing or (decreasing) function such that and

then

3) If f(x) is monotonically strictly increasing function then |[f(1)]| is equal to : (where [ . ] represents
greatest integer function)

4) If f(x) is monotonically strictly decreasing then [f(1)] is equal to : (where [ . ] represents greatest
integer function)

SECTION-II (ii)

1) A and B are two fixed points on circle ; two parallel chords AC and BD are drawn. If

AD and BC intersects at O then is (Given AB = 2)

2) The maximum and minimum value of are I1 and I2 where

 p, q ∈ R then find (I1I2)2

3) and α, β, γ are distinct prime

numbers then the minimum value of is

4) If where n ∈ N then T1T2T3 is equals

5) Let ‘M’ be the maximum value of then M2 is

equal to :

6) The maximum value of 3 × 3 determinant, whose elements belong to {0, 1, 2, 3} is

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. C D A B

SECTION-I (ii)

Q. 5 6 7 8
A. A,D A,B,D A,B,C A,C

SECTION-II (i)

Q. 9 10 11 12
A. 73 3 2 4

SECTION-II (ii)

Q. 13 14 15 16 17 18
A. 2 7 4 20 4 3

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22
A. C A C D

SECTION-I (ii)

Q. 23 24 25 26
A. B,C,D A,B,C,D C B,C,D

SECTION-II (i)

Q. 27 28 29 30
A. 3.00 135.00 0.24 500.00

SECTION-II (ii)

Q. 31 32 33 34 35 36
A. 40 14 27 24 4 354

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 37 38 39 40
A. B D A D

SECTION-I (ii)

Q. 41 42 43 44
A. C,D B,C A,B,C,D C

SECTION-II (i)

Q. 45 46 47 48
A. 3 3 1 1

SECTION-II (ii)

Q. 49 50 51 52 53 54
A. 2 384 36 216 10 54
 SOLUTIONS

PART-1 : PHYSICS

1)

2)

Force on the element is,

where is a unit vector along the current in the wire.
 [since ]

3)

Stretch of spring is ℓ/2q.

Net torque

For small θ cos θ = 1 sin θ = θ

rom which we get

or
When rod is displaced to right.

When rod is displaced by θ towards left, immediately after that string gets slack, and time
period for half or motion is given by

Thus total time period

4)

As the two cables act as a capacitor charged to V = 33 kV, the charges on them are of opposite
signs, and the force between them is attractive. The size of the force per unit length has been

given as , with s = C1V for a capacitance per unit length of C1.

The magnetic-field induced force is, as shown in solution, attractive for parallel currents and
repulsive for anti-parallel ones; here, they are antiparallel. Further, the repulsive force per

unit length . Thus, there will be no net force when

R = 331 W.

With this (equivalent) load resistance, the required transmitted power is ,

and does not depend on how far apart the cables are.

5)
B × 2πr = µ0iemc = 0
Bin = 0

Inside points ⇒ Bin = 0

6)
7)

The quantum number of the initial state is given by n, where = 15, i.e. n = 6
The work function of the photo cathode (B) is given by

E= eV = 1.5 eV.
The maximum velocity of the emitted photoelectrons is given by

v= = 3.7 × 105 m/s

the kinetic energy of the fastest photoelectrons is

The energy of the emitted photons is 1.5 eV + 0.39 eV = 1.89 eV

If the atomic number of the atoms is Z, and the quantum number of the final state is m, then

Rewriting this equation in the form:

or, z =
We get by substituting possible values of m : 5, 4, 3 …… etc ; for the only possible integral
value of z.
The correct values are: n = 6, m = 4 and z = 2.

8)

Using super position principle iAB = i/2

..... (i)
Let's find circulation due to only feeding wires.

If is equal to circulation due to infinite long wire minus the circulation due to the missing
segment.

....(ii)
y = |Quantity (i) – Quantity (ii)|

Magnetic field on the entire Amperean loop is not the same (Symmetry is 2D but not 3D)
So,

9)

(a) when
(b) when

(c)

10)

(a) when
(b) when
(c)

11)

Since the ring P is being supported against gravity, the force it experiences must act upwards.
To achieve this, either from knowing that oppositely directed currents repel each other (unlike
oppositely charged particles), or from applying Fleming’s left hand rule to determine the
appropriate direction for B, we require the currents in P and Q to flow in opposite senses.

12)

Since the ring P is being supported against gravity, the force it experiences must act upwards.
To achieve this, either from knowing that oppositely directed currents repel each other (unlike
oppositely charged particles), or from applying Fleming’s left hand rule to determine the
appropriate direction for B, we require the currents in P and Q to flow in opposite senses.

13)

14)
15)

a2 + R2 = (b – R)2

R=

16)

The charge will flow instantly, so it will provide an angular impulse about BC

....(i)
I = IAB + IAD + IDC + IBC

Using conservation of mechanical energy

17)
r = 2a + r cos θ
 18)

PART-2 : CHEMISTRY

19) A ⇒ XeF4
B ⇒ [XeF3]+ [SbF6]–
C ⇒ O2
D ⇒ XeF6

20) When the migrating group is aryl, the rate of the Hofmann degradation is increased by the
presence of electron–releasing substituents in the aromatic ring.

21) β–D–(–)–Fructose.

22) Energy of orbitals decrease as Z

23) As oxidation state of central atom , thermal stability of oxy acid .

24) Sphalerite : ZnS

Calamine : ZnCO3
Malachite : CuCO3.Cu(OH)2
Bauxite : Al2O3.xH2O

25)

26) Glucose is oxidized to gluconic acid by bromine water.

C–5 epimer is L–idose.
Amylopectin and glycogen are branched polymers of glucose.

27)

28)
 29) Molarity of household bleach

=
= 0.24 M

30) Molarity of household bleach =

=
= 0.24 M

31)

ai bi

White phosphorus 3 4

CH2SF4 6 1

XeO3F2 4 3

C3H4(allene) 5 2

32)

33)
 34)

35) ZrI4

36)

PART-3 : MATHEMATICS

37)

Using (MVT . (B) is correct)

38)

a2 – 4ab + b2 = 0

39)

40) After differentiation max value = 1

41)

Fact based .

42)

43) Let tangent y = mx + c

⇒
⇒ a = 0, b = –1; m = –1, c = –1
x + y + 1 = 0 is tangent at (–1, 0) and (1, –2)

44) conceptual

45) Solving P(3, 0) or

46)

Fact based .

47)

48)

Fact based .

49)

Let centre of circle is at x

then

⇒
50)

I1 =
I2 =
⇒

51)
⇒

52)

53) where

54) Using determinant problems answer 54