IITIANS SPECTRUM EDUTECH

ATOMIC STRUCTURE
1. The triad of nuclei that is isotonic :-
10. Hydrogen atoms is excited to n = 4 state, in the
(1) 14
C, 15
N, 17
F (2) 14
C, 14
N, 17
F spectrum of emitted radiation, number of lines
6 7 9 6 7 9
in the ultravoilet and visible regions are
13 14 19 14 14 19
(3) 6 C, 7 N, 9 F (4) 6 C, 7 N, 9 F respectively:-
2. For an Al+3 ion, if atomic number (Z) = 13 and (1) 3 : 1 (2) 1 : 3 (3) 2 : 3 (4) 3 : 2
number of neutrons is 14. Then the number of 11. Total spin in Ni ion :-
+2

electrons in it will be :-
5 3 1
(1) 13 (2) 12 (3) 10 (4) 11 (1) ± (2) ± (3) ± (4) ± 1
+ 2+ –
2 2 2
3. X , Y and Z are isoelectronic with CO2 . In-
creasing order of protons in X+, Y2+ and Z– is : 12. In which of the following pairs is the probability
(1) X+ = Y2+ = Z– (2) X+ < Y2+ < Z– of finding the electron in only xy - plane is zero
(3) Z– < X+ < Y2+ (4) Y2+ < X+ < Z– for both orbitals ?
4. The frequency of light for 1.0 Å wavelength (1) 3dyz, 4d x 2 - y 2 (2) 2Pz, 3 d z 2
is:-
(3) 4dzx, 3P z (4) None of these
(1) 3 × 1018 Hz
13. If the total energy of an electron in a hydrogen
(2) 3 × 1018 sec–1
atom in an exicted state is –3.4 eV, then the de-
(3) 3 × 1018 Cycles per sec
broglie wavelength of the electron is :-
(4) All of the above
(1) 6.6 × 10–10 m (2) 3 × 10–10 m
5. The number of photons emitted in 10 hours by
(3) 5 × 10–9 m (4) 9.3 × 10–12 m
a 60 W sodium lamp (l of photon = 6000 Å)
14. The wavelength associated with a gold ball
(1) 6.50 × 1024 (2) 6.40 × 1023
weighing 200 g and moving at a speed of 5 m/
(3) 8.40 × 1023 (4) 3.40 × 1023
h is of the order of :-
6. The radius of which of the following orbit is
(1) 10–1 m (2) 10–20 m
same as that of the first Bohr’s orbit of
(3) 10–30 m (4) 10–40 m
hydrogen atom. +3
15. Magnetic moment of X ion of 3d series is
(1) He+ (n = 2) (2) Li2+ (n = 2) +3
(3) Li2+ (n = 3) (4) Be3+ (n = 2) 35 B.M. What is the atomic number of X ?
7. The energy needed to excite an e of hydro- (1) 24 (2) 25 (3) 26 (4) 27
gen atom from its ground state to its third ex- 16. Which orbit would be the first to have 'h'
cited state is :- subshell:-
(1) 12.1 eV (2) 10.2 eV (1) 3 rd (2) 4th (3) 5th (4) 6th
(3) 0.85 eV (4) 12.75 eV 17. What are the values of the orbital angular
8. In which of the following transitions will the momentum of an electron in the orbitals 1s, 3s,
wavelength be minimum ? 3d, and 2p :-
(1) n = 6 to n = 4 (2) n = 4 to n = 2 (1) 0, 0, 6h , 2h (2) 1, 1, 6h , 2h
(3) n = 3 to n = 1 (4) n = 2 to n = 1
9. The first emission line of Balmer series in (3) 0, 1, 6h , 3h (4) 0, 0, 20h , 6h
He +-spectrum has the wave no. in (cm –1 ) 18. There is no difference between a 2P and 3P
(R-Rydberg constant) orbital regarding ?
(1) Shape (2) Size
3R 20R 5R R
(1) (2) (3) (4) (3) Energy (4) Value of n
4 36 36 6

Page 1 of 4
IITIANS SPECTRUM EDUTECH

19. The energy corresponding to second line of 28. The ratio of the radii of first orbits of H, He+
Balmer series for hydrogen atom will be :- and Li2+ is :-
(1) 12.1 eV (2) 1.89 eV (1) 1 : 2 : 3 (2) 6 : 3 : 2
(3) 2.55 eV (4) 13.6 eV (3) 1 : 4 : 9 (4) 9 : 4 : 1
20. If the velocity of an electron in Ist orbit of H is 29. The line with smallest wavelength in the Balmer
V, then what will be the velocity in 4 orbit of
th series in the hydrogen spectrum will have the
Be+3 :- frequency :-
(1) 4.57 × 1014 s –1 (2) 3.29 × 1015 s–1
V (3) 8.22 × 1015 s–1 (4) 8.05 × 1013 s–1
(1) V (2) (3) 16 V (4) 4 V
4 30. The ionization energy of hydrgen atom is 13.6 eV.
The ionization energy of Li2+ would be :-
21. Magnetic moments of V (Z = 23), Cr (Z = 24),
(1) 13.6 eV (2) 27.2 eV
Mn (Z = 25) are x, y, z. Hence :-
(3) 40.8 eV (4) 122.4 eV
(1) x = y = z (2) x < y < z
31. The two particles A and B have de Broglie
(3) x < z < y (4) z < y < x
wavelengths 1 nm and 5 nm respectively. if
22. The wavelength of the radiation emitted when
mass of A is four times the mass of B, the ratio
an electron falls from Bohr's orbit 4 to 2 in H
of kinetic energies of A and B would be :-
atom is
(1) 5 : 1 (2) 25 : 4
(1) 972 nm (2) 486 nm
(3) 20 : 1 (4) 5 : 4
(3) 243 nm (4) 182 nm
32. For an element, if atomic number (Z) and mass
23. According to Bohr's atomic model
number (A) are 29 and 63 respectively. Then
(1) Electron in an atom of hydrogen can have the number of protons, neutrons and electrons
only certain values of angular momentum respectively are :-
(2) Electrons have particle as well as wave (1) 29, 63, 29 (2) 29, 29, 63
character (3) 29, 34, 29 (4) 29, 29, 29
(3) Atomic spectrum of an element should 33. Among the following groups which represents
contain only five lines the collection of isoelectronic species ?
(4) All the above statements are incorrect (1) NO+, C22–, O2– , CO (2) N2, C22–, CO, NO
24. A subshell with n = 6, l = 2 can accommodate (3) CO, NO+, CN–, C22– (4) NO, CN–, N2, O2 –
a maximum of 34. The specific charge of a proton is 9.6 × 107C kg–1,
(1) 12 electrons (2) 36 electrons then for an a-particle it will be -
(3) 10 electrons (4) 72 electrons (1) 2.4 × 107C kg–1
25. According to Aufbau principle, the 19 th (2) 4.8 × 107C kg–1
electron in an atom goes into the :- (3) 19.2 × 107C kg–1
(1) 4s-orbital (2) 3d-orbital (4) 38.4 × 107C kg–1
(3) 4p-orbital (4) 3p-orbital 35. It is known that an atom contains protons,
26. Which of the d-orbitals lie/s in the xy-plane ? neutrons and almost electrons. If the mass of
(1) dxy only (2) dxz only neutron is assumed to half of its original value
where as that of proton is assumed to be twice
(3) d x2 - y2 only (4) dxy and d z2
of its original value then the atomic mass of
27. Which of the following sub-shells is not 7
N14 will be :-
permitted ? (1) same (2) 25 % more
(1) 4f (2) 4d (3) 3s (4) 4g (3) 14.28 % more (4) 28.5 % less

Page 2 of 4
 IITIANS SPECTRUM EDUTECH

36. The energy of a 700-nm photon is :- 45. Choose the wrong one on the basis of Bohr's
(1) 1.77 eV (2) 2.47 eV theory:-
(3) 700 eV (4) 3.57 eV 1
(1) Velocity of electron µ
37. In hydrogen atom the energy difference r
between the states n = 2 and n = 3 is E eV . The 1
(2) Frequency of revolution µ
ionisation potential of H atom is - n3
(1) 3.2 E (2) 5.6 E (3) Velocity of electron µ r
(3) 7.2 E (4) 13.2 E (4) mvr µ n
38. Which of the following statement (regarding an 46. In which transition minimum energy is emitted
atom of H) is correct - (1) ¥ ® 1 (2) 2 ® 1
(1) Kinetic energy of the electron is maximum
(3) 3 ® 2 (4) n ® (n – 1) [n ³ 4]
in the first orbit
47. If the value of principal quantum number is 4,
(2) Potential energy of the electron is maximum
the possible values for magnetic quantum
in the first orbit
number will be :-
(3) Radius of the second orbit is two times the
(1) 4 (2) 16 (3) 32 (4) 9
radius of the first orbit
48. If the value of E = –78.4 kcal / mol, the serial
(4) Various energy levels are equally spaced
no. of the orbit in hydrogen atom is :-
39. The ionisation potential of hydrogen atom is
(1) 4 (2) 3 (3) 2 (4) 1
13.6 eV. The energy required to remove an
electron in the n = 2 state of hydrogen atom is. 49. The ratio of the energy of the electron in ground
(1) 27.2 eV (2) 13.6 eV state of hydrogen to the electron in first excited
state of Be3+ is :-
(3) 6.8 eV (4) 3.4 eV
40. When the electron of a hydrogen atom jumps (1) 1 : 4 (2) 1 : 8 (3) 1 : 16 (4) 16 : 1
from the n = 4 to the n = 1 state, the number of 50. The most intense line in the Brackett series of
all possible spectral lines emitted is :- the spectrum of atomic hydrogen is the
(1) 15 (2) 6 (3) 3 (4) 4 transition :-
41. An electron in an atom jumps in such a way (1) n2 = ¥ ® n1 = 1 (2) n2 = 8 ® n1 = 4
x (3) n2 = ¥ ® n1 = 4 (4) n2 = 4 ® n1 = 3
that its kinetic energy changes from x to . The 15
4 51. Five valence electrons of P are labelled as
change in potential energy will be :-

3 3 3 3
(1) + x (2) – x (3) + x (4) – x
2 8 4 4 1
If the spin quantum numbers of B and Z is + 2 ,
42. Which oribital notation does not have spherical
node :- the group of electron with three of the quantum
(1) n = 2, l = 0 (2) n = 3, l = 1 number (n, l , m) same are.
(3) n = 3, l = 0 (4) n = 1, l = 0 (1) AB, XYZ, BY (2) AB
43. In how many elements does the last electron (3) XYZ, AZ (4) AB, XYZ
have the quantum number of n = 4 and l = 1? 52. If kinetic energy of a proton is increased nine
(1) 4 (2) 6 (3) 8 (4) 10 times the wavelength of the de-Broglie wave
44. For principle quantum number n = 4, the total associated with it would become :-
number of orbitals having l = 3 is :- (1) 3 times (2) 9 times
(1) 3 (2) 7 (3) 5 (4) 9 1 1
(3) times (4) times
3 9

Page 3 of 4
IITIANS SPECTRUM EDUTECH

53. The I.P. of an atom is 16eV. What is the value 56. An electron is present in 4f sub-shell. The
of first excitation potential :– possible values of azimuthal quantum number
(1) 10·2 eV (2) 12 eV for this electron are :-
(3) 14 eV (4) 16 eV (1) 0, 1, 2, 3 (2) 1, 2, 3, 4
54. The angular momentum J of the electron in a (3) 3 (4) 4
hydrogen atom is proportional to n power of
th
57. How many electrons in calcium have l = 0 ?
r (radius of the orbit) where n is:- (1) 6 (2) 8 (3) 10 (4) 12
(1) 1 (2) –1 58. For n = 4
(1) The total possible values of l are 3
1
(3)
2
(4) None (2) The highest value of l is 4
(3) The total number of possible values of m
55. Which one of the following sets of quantum is 7
numbers represents an impossible (4) The highest value of m is +3
arrangement? 59. An atom has 35 nucleons and has atomic
n l m1 ms number equal to 17. The number of electrons
(1) 3 2 –2 + 1/2 with n = 2, m = 0 in it is :-
(2) 4 0 0 + 1/2 (1) 2 (2) 4 (3) 6 (4) 3
(3) 3 2 –3 + 1/2 60. The maximum number of electrons in p-orbital
(4) 5 3 0 – 1/2 with n = 6, m = 0 is :-
(1) 2 (2) 6 (3) 10 (4) 14

ANSWE R KE Y
Que. 1 2 3 4 5 6 7 8 9 10 11
Ans 1 3 3 4 1 4 4 3 2 4 4
Que. 12 13 14 15 16 17 18 19 20 21 22
Ans 4 1 3 3 4 1 1 3 1 3 2
Que. 23 24 25 26 27 28 29 30 31 32 33
Ans 1 3 1 1 4 2 1 4 2 3 3
Que. 34 35 36 37 38 39 40 41 42 43 44
Ans 2 2 1 3 1 4 2 1 4 2 2
Que. 45 46 47 48 49 50 51 52 53 54 55
Ans 3 4 2 3 1 3 2 3 2 3 3
Que. 56 57 58 59 60
Ans 3 2 4 2 1

Page 4 of 4