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Reaction Kinetics

The document presents data related to the kinetics of low-pressure methanol synthesis, including equilibrium constants (Keq), rate constants (kps), and various thermodynamic properties at specified temperatures and pressures. It includes detailed flow information for different streams, such as mass flow, molar flow, and specific enthalpy and entropy. The document also references a study published in Chemical Engineering Science, indicating its relevance to chemical engineering applications.

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13 views28 pages

Reaction Kinetics

The document presents data related to the kinetics of low-pressure methanol synthesis, including equilibrium constants (Keq), rate constants (kps), and various thermodynamic properties at specified temperatures and pressures. It includes detailed flow information for different streams, such as mass flow, molar flow, and specific enthalpy and entropy. The document also references a study published in Chemical Engineering Science, indicating its relevance to chemical engineering applications.

Uploaded by

tutundle
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd

TReact 480 K R

Keq,1 0.012771738

Keq,2 5.131567E-05

Keq,3 6.553903E-07

kps1 0.0004680994

kps2 2.721304E-05

kps3 3.499653E-05

kCO 1.6801305017

kCO2 2.2053580588

KK 97336828210
8.314 J/Kmol

6.553903E-07

7.126389

6.001449E-05

0.000786
6E-05

7.718E-05
G.H. Graaf, P.J.J.M. Sijtsema, E.J. Stamhuis, G.E.H. Joosten, Chemical Eng

KINETICS OF LOW-PRESSURE METHANOL SYNTHESIS G. H. GRAAF, E. J. S

Simulation and optimization of a methanol synthesis process from differ


, G.E.H. Joosten, Chemical Engineering Science 41 (1986) 2883–2890.

SYNTHESIS G. H. GRAAF, E. J. STAMHUIS, A. A. C. M. BEENACKERSZ Department of Chemical Engineering, State University of Groningen, Ni

l synthesis process from different biogas sources, Rafael Oliveira dosSantosLizandro de SousaSantosDiego MartinezPrata, https://doi.org/1
te University of Groningen, Nijenborgh l&9747 AC Groningen, Netherlands

MartinezPrata, https://doi.org/10.1016/j.jclepro.2018.03.108
T(K) 773 tcat

k1 8.141E+14

k2 3757

k3 4.129E+14

K1 0.2585277393

K2 42.570491809

K3 11.00565301

Kco 0.0000004765
Kh2 5.678E-11
Kch4 0.0000325
Kwater 2367
T(°C) 500 980

Convert Nm3/hr to m3/hr

P1 101.325 kPa P2 101.325 kPa


T1 273.15 K T2 773 K
V1 5000 Nm3/hr V2 14149.73 Nm3/hr

21554.24
Stream 1 2 5
Temperature °C 31.00 25.00 105.91
Pressure kPa 101.33 101.33 101.33
Mass Flow kg/h 15483.80 45000.00 60483.80
Molar Flow kmol/s 0.16 0.69 0.85
Volumetric Flow m3/h 14150.00 45.17 94763.40
Density (Mixture) kg/m 3 1.09 996.33 0.64
Specific Enthalpy (Mixture) kJ/kg 7.11 -2537.04 139.19
Specific Entropy (Mixture) kJ/(kg·K) 0.25 -6.83 0.66
Molar Fraction (Mixture) / Methane 0.60 0.00 0.11
Mass Fraction (Mixture) / Methane 0.35 0.00 0.09
Molar Fraction (Mixture) / Carbon dioxide 0.40 0.00 0.07
Mass Fraction (Mixture) / Carbon dioxide 0.65 0.00 0.17
Molar Fraction (Mixture) / Carbon monoxide 0.00 0.00 0.00
Mass Fraction (Mixture) / Carbon monoxide 0.00 0.00 0.00
Molar Fraction (Mixture) / Water 0.00 1.00 0.81
Mass Fraction (Mixture) / Water 0.00 1.00 0.74
Molar Fraction (Mixture) / Hydrogen 0.00 0.00 0.00
Mass Fraction (Mixture) / Hydrogen 0.00 0.00 0.00
Molar Fraction (Mixture) / Methanol 0.00 0.00 0.00
Mass Fraction (Mixture) / Methanol 0.00 0.00 0.00
Phases V L V

Stream 1 2 5
Temperature C 31 25 105.907
Pressure KPa 101.325 101.325 101.325
Mass Flow Kg/h 15483.8 45000 60483.8
Molar Flow Kmol/s 0.157957 0.693856 0.851813
Specific Enthalpy (Mixture) KJ/Kg 7.11459 -2537.04 139.186
Molar Fraction (Mixture) / Methane 0.6 0 0.111262
Mass Fraction (Mixture) / Methane 0.353497 0 0.090495
Molar Fraction (Mixture) / Carbon dioxide 0.4 0 0.0741745
Mass Fraction (Mixture) / Carbon dioxide 0.646503 0 0.165504
Molar Fraction (Mixture) / Carbon monoxide 0 0 0
Mass Fraction (Mixture) / Carbon monoxide 0 0 0
Molar Fraction (Mixture) / Water 0 0.999999 0.814563
Mass Fraction (Mixture) / Water 0 1 0.744001
Molar Fraction (Mixture) / Hydrogen 0 1.00E-06 8.15E-07
Mass Fraction (Mixture) / Hydrogen 0 1.12E-07 8.33E-08
Molar Fraction (Mixture) / Methanol 0 0 0
Mass Fraction (Mixture) / Methanol 0 0 0
Phases V L V
6 8 9 10 12 14 15 17 18
125.00 154.86 650.00 650.00 22.00 22.00 22.00 945.08 200.00
101.32 150.33 150.33 150.32 150.07 150.07 150.07 20530.30 20530.30
45000.00 60483.80 60483.80 60501.40 60501.40 25654.70 34846.70 25654.70 25654.70
0.69 0.85 0.85 1.04 1.04 0.50 0.54 0.50 0.50
81016.80 72096.50 156504.00 190668.00 29449.90 29415.00 34.95 920.84 357.57
0.56 0.84 0.39 0.32 2.05 0.87 997.03 27.86 71.75
184.63 226.67 1236.17 1358.47 -1471.43 -7.25 -2549.38 2265.32 363.85
0.54 0.71 2.25 3.97 -3.53 1.02 -6.88 1.53 -0.87
0.00 0.11 0.11 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.09 0.09 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.07 0.07 0.12 0.12 0.24 0.00 0.24 0.24
0.00 0.17 0.17 0.31 0.31 0.74 0.00 0.74 0.74
0.00 0.00 0.00 0.03 0.03 0.07 0.00 0.07 0.07
0.00 0.00 0.00 0.06 0.06 0.14 0.00 0.14 0.14
1.00 0.81 0.81 0.52 0.52 0.02 1.00 0.02 0.02
1.00 0.74 0.74 0.58 0.58 0.02 1.00 0.02 0.02
0.00 0.00 0.00 0.32 0.32 0.67 0.00 0.67 0.67
0.00 0.00 0.00 0.04 0.04 0.09 0.00 0.09 0.09
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
V V V V V+L V L V V

6 8 9 10 12 14 15 17 18
125 368.298 650 650 22 22 22 552.715 200
101.315 650.325 650.325 650.315 650.065 650.065 650.065 20530.3 20530.3
45000 60483.8 60483.8 60501.7 60501.7 23822.9 36678.8 23822.9 23822.9
0.693856 0.851813 0.851813 1.00774 1.00774 0.442884 0.564851 0.442884 0.442884
184.63 629.802 1233.19 1337.78 -1546.59 -9.53744 -2544.9 1218.72 351.447
0 0.111262 0.111262 0.0165386 0.0165386 0.0376316 8.23E-10 0.0376316 0.0376316
0 0.090495 0.090495 0.0159093 0.0159093 0.0404037 7.32E-10 0.0404037 0.0404037
0 0.0741745 0.0741745 0.112447 0.112447 0.254764 0.0008589 0.254764 0.254764
0 0.165504 0.165504 0.296739 0.296739 0.750383 0.0020956 0.750383 0.750383
0 0 0 0.0277555 0.0277555 0.0631544 3.85E-08 0.0631544 0.0631544
0 0 0 0.0466171 0.0466171 0.11839 5.98E-08 0.11839 0.11839
0.999999 0.814563 0.814563 0.561623 0.561623 0.0036205 0.99914 0.0036205 0.0036205
1 0.744001 0.744001 0.606691 0.606691 0.0043653 0.997904 0.0043653 0.0043653
1.00E-06 8.15E-07 8.15E-07 0.281636 0.281636 0.640829 1.10E-06 0.640829 0.640829
1.12E-07 8.33E-08 8.33E-08 0.0340436 0.0340436 0.0864579 1.23E-07 0.0864579 0.0864579
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
V V V V V+L V L V V
19 20 21 22 24 25 26 27 28
759.10 15.00 15.00 15.00 1.30 1.30 1.30 15.17 90.04
20530.10 20530.10 20530.10 20530.10 305.33 305.33 305.33 201.33 101.33
25654.70 25654.70 1298.39 24356.40 24356.40 3853.19 20503.10 14357.10 6146.00
0.26 0.26 0.02 0.24 0.24 0.03 0.22 0.13 0.09
400.96 35.28 7.69 27.59 684.98 661.82 23.16 17.67 6.52
63.98 727.25 168.84 882.91 35.56 5.82 885.24 812.67 942.05
1369.15 -1331.77 -97.01 -1397.59 -1428.13 -23.43 -1692.12 -1318.84 -2085.17
1.46 -3.80 -0.90 -3.95 -3.92 0.11 -4.68 -3.80 -5.51
0.01 0.01 0.09 0.00 0.00 0.01 0.00 0.00 0.00
0.00 0.00 0.08 0.00 0.00 0.00 0.00 0.00 0.00
0.12 0.12 0.23 0.12 0.12 0.95 0.02 0.03 0.00
0.20 0.20 0.54 0.18 0.18 0.98 0.03 0.05 0.00
0.02 0.02 0.22 0.00 0.00 0.01 0.00 0.00 0.00
0.02 0.02 0.33 0.00 0.00 0.01 0.00 0.00 0.00
0.36 0.36 0.00 0.39 0.39 0.00 0.44 0.09 0.93
0.24 0.24 0.00 0.25 0.25 0.00 0.30 0.05 0.88
0.04 0.04 0.46 0.00 0.00 0.02 0.00 0.00 0.00
0.00 0.00 0.05 0.00 0.00 0.00 0.00 0.00 0.00
0.45 0.45 0.00 0.49 0.49 0.01 0.55 0.88 0.07
0.54 0.54 0.00 0.56 0.56 0.01 0.67 0.90 0.12
V V+L V L V+L V L L L

19 20 21 22 24 25 26 27 28
706.823 15 15 15 0.388884 0.388884 0.388884 25.032 92.5158
20530.1 20530.1 20530.1 20530.1 305.333 305.333 305.333 201.325 101.325
23822.9 23822.9 3258.58 20564.4 20564.4 3465.25 17099 14067.1 3031.97
0.242952 0.242952 0.0394046 0.203547 0.203547 0.0225379 0.181009 0.136011 0.044998
1242.46 -1211.09 -157.577 -1378.03 -1408.6 -24.2487 -1689.15 -1424.09 -2121.43
0.0685997 0.0685997 0.40999 0.0025067 0.0025067 0.0226252 1.63E-06 2.16E-06 1.52E-16
0.0404037 0.0404037 0.286328 0.001433 0.001433 0.0084985 9.94E-07 1.21E-06 1.31E-16
0.150291 0.150291 0.292202 0.122817 0.122817 0.952222 0.0195409 0.0260058 5.75E-10
0.242833 0.242833 0.559822 0.192601 0.192601 0.981217 0.0327735 0.0398375 1.35E-09
0.0177874 0.0177874 0.106195 0.0006716 0.0006716 0.0060629 3.32E-07 4.42E-07 2.96E-17
0.0182917 0.0182917 0.129491 0.0006704 0.0006704 0.0039762 3.55E-07 4.31E-07 4.43E-17
0.320726 0.320726 0.0003242 0.382756 0.382756 0.0010644 0.430284 0.258344 0.949991
0.212131 0.212131 0.0002542 0.245706 0.245706 0.000449 0.295412 0.162 0.914387
0.0311303 0.0311303 0.18569 0.0012076 0.0012076 0.0109022 4.10E-07 5.45E-07 5.68E-17
0.002304 0.002304 0.0162957 8.67E-05 8.67E-05 0.0005146 3.15E-08 3.83E-08 6.12E-18
0.411465 0.411465 0.0055975 0.490041 0.490041 0.0071235 0.550173 0.715647 0.0500093
0.484037 0.484037 0.0078078 0.559503 0.559503 0.0053443 0.671813 0.798161 0.0856127
V V+L V L V+L V L L L
31 34 PURGE 99% Water 94% Me-OH
41.25 77.32 82.57 32.99 -14.18
305.33 101.33 20530.10 117.57 101.33
20503.10 1000.00 5151.58 41992.70 13357.10
0.22 0.01 0.04 0.64 0.12
155.69 1.13 18.80 42.43 16.04
131.69 882.87 274.06 989.70 832.64
-1549.06 -1727.23 -41.97 -2461.86 -1369.70
-4.18 -4.57 0.16 -6.60 -4.11
0.00 0.00 0.04 0.00 0.00
0.00 0.00 0.02 0.00 0.00
0.02 0.00 0.64 0.00 0.04
0.03 0.00 0.87 0.00 0.05
0.00 0.00 0.10 0.00 0.00
0.00 0.00 0.09 0.00 0.00
0.44 0.68 0.00 0.98 0.03
0.30 0.55 0.00 0.97 0.02
0.00 0.00 0.21 0.00 0.00
0.00 0.00 0.01 0.00 0.00
0.55 0.32 0.01 0.02 0.94
0.67 0.45 0.01 0.03 0.94
V+L L V L L

31 34 PURGE 99% Water 80% Me-OH


45 98.3739 59.8326 29.1637 -4.06895
305.333 101.325 20530.1 284.238 101.325
17099 1000 6723.84 40710.7 13067.1
0.181009 0.0153125 0.0619425 0.625161 0.120699
-1514.89 -2184.47 -88.8639 -2504.51 -1446.79
1.63E-06 1.15E-21 0.269047 7.44E-10 2.44E-06
9.94E-07 1.02E-21 0.143144 6.60E-10 1.30E-06
0.0195409 7.46E-14 0.532352 0.00077605 0.0293054
0.0327735 1.81E-13 0.776996 0.00188808 0.0428864
3.32E-07 2.27E-22 0.069762 3.48E-08 4.98E-07
3.55E-07 3.51E-22 0.0648048 5.39E-08 4.64E-07
0.430284 0.991063 0.0005935 0.995404 0.165379
0.295412 0.984215 0.0003546 0.991348 0.0990715
4.10E-07 5.74E-22 0.122093 9.96E-07 6.15E-07
3.15E-08 6.37E-23 0.0081626 1.11E-07 4.12E-08
0.550173 0.0089366 0.0061527 0.00381847 0.805312
0.671813 0.0157847 0.0065382 0.00676382 0.85804
V+L L V L L
Stream E1 E3 E4 E5
Energy Flow KW 34020.9 8242.86 10137.6 15689.9

Stream 1 2 5 6
Specific Enthalpy (Mixture) kJ/kg 7.11 -2537.04 139.19 184.63
Phases V L V V

971.4
E6 E10 E8 E9 E11 E12 E14 E13 E16 E18
48474.7 8127.95 5739.14 0 16236.3 -174.594 827.691 7569.14 7798.07 7386.14

8 9 10 12 14 15 17 18 19 20
226.67 1236.17 1358.47 -1471.43 -7.25 -2549.38 2265.32 363.85 1369.15 -1331.77
V V V V+L V L V V V V+L
E17
7779.52

21 22 24 25 26 27 28 31 34 PURGE
-97.01 -1397.59 -1428.13 -23.43 -1692.12 -1318.84 -2085.17 -1549.06 -1727.23 -41.97
V L V+L V L L L V+L L V
99% Water94% Me-OH
-2461.86 -1369.70
L L

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