I PUC- Chemistry

12. Alkaline earth metals are present in 19. Which element having following electronic
CLASSIFICATION OFELEMENTS AND (a) Group 1 (b) Group 2 configurations has minimum jonization
3 PERIODICITY IN PROPERTIES (c) Group 13 (d) Group 14 potential?
(a). 1s! (b) ls'2s2ps
Ans. (b) Group 2
rows in the modern periods.
13. Which one of the following species, has' the (c) ls2s2p3s! () 1s'2s*2p
6. The horizontal Ans. (c) 1s'2s'2p3s
Select thecorrect option from the givèn choices. table are called largest atomic radius?
(b) Groups (a) Na. (b) Mg 20. The most electronegative element. in the
1. Mendeleev's periodic law is based on (a) Blocks.
(d) None of the above (d) Si periodic table is.
(a) Atomic weight (c) Periods (c) Al
(a) Helium (b) Fluorine
(b) Atomic number Ans. (c) Periods Ans. (a) Na
14. Of the ions Nat, Mg?+, 0 and N,the one
(c) Chlorine (d) Oxygen
(c) Number of neutrons 7. Cs belongs to Ans. (b) Fluorine
(b) p-block with the smallest radius is....
(d) None of thé above (a) s-block
21. Among the following, the element with
(d) f-block (a) Na (b) Mg?*
Ans. (a) Atomic weight (c) d-block highest electro positivity is.......
2. Modern Periodic Law is based on (c) 02. (d) N
Ans. (a). s-block (a) Copper (b) Caesium
the same Ans. (b) Mg
(a) Atomic weight 8. All the elements in a group have (c) Barium (d) Chromium
15. Which one of the following is iso-electronic
(b) Atomic number (a) Number of valence electrons with a fluoride ion?
Ans. (b) Caesium
(c) Number of neutrons (b) Atomic number 22. If the differentiating electron enters (n-1)U
(a) Oxygen (b) Fluorine
Chemistry -PUC (d) None of the above
Ans. (b) Atomic number
3. In the modern periodic table, the period
indicates the value of.

(c) Atomic weight

(d) None of the above
Ans. (a) Number of valence electrons
9. An atom has the electronic configuration

Ans.
(c) Sodium
(d) Neon
(d) Neon
16. Which of the following statements is correct?
(a) X-ion is larger in size than X atom

d-sublevel. The element is........

(a) A representative element
(b) Anoble gas
(c) An alkali metal
(a) Atomic number 1s2s2p'3s3p which.. of the following (d) A transition element
(b) Mass nümber statementswith respect to this atom iscorrect? (b) X*ion is larger in size than X atom
Ans. (d) A'transition element
(c) Principal quantum number (a) Its atòmic nümber is 18 (c) X* ion is larger in size than X ion
(d) X*and X- ions are equalin size
23. Elements which generally exhibit variable
(d) Azimuthal quantumnumber (b) it belongs to group 18 of periodic table oxidation states and. form coloured ions
Ans. (c) Principal quantum number Ans. (a) X- ion is larger in size than X atom
(c) it has no tendency to form compounds are..eo.4e..
4. The atomic number of element Ung is 17. The ionization potential of boron is less than (a) Metalloids
(d) All of a,b,c
(a) 102 (b) 103 that of beryllium, Because (b) Transition elements
Ans. (d) All of a,b,c
(c)104 (a) 105 (a) Boron is a nonmetal while beryllium is (c) Non-metals
10. Elements of group 16 are called metal
Ans. (c) 104 (d) Gases
(a) Chalcogens (b) Halogens (b) Boron has lesser electron affinity
5. Fluorine, chlorine, bromine and iodine are (c) Pnictogens Ans. (b) Transition elements
(d) Rare gases (c) Beryllium has a completely filled s orbital
placed in the same group (17) of the periodic 24. Metalloids are present only in
table, because: Ans. (a) Chalcogens (d) None of these
11. In periodic table, elements with similar (a) s- block (b) p- block
(a)- They are electronegativ Ans. (c) Beryllium has a completely filled s orbital
valence shell configuration are placed in (c) d- block (d) f- block
(b) They have 7 electrons in the outermost 18. In' view of their low ionization energies the
shell of their atom (a) Separately below. alkali metals are... Ans. (b) p- block
(b) Same group (a) Weak oxidizing agents 25. Diagonal relationship is shown by
(c) their atoms are generally univalent
(d) they are non-metals
(c) Same period (b) Strong reducing agents (a) B -S (b) Li- Mg
(d) Same block (c) Mg - Ca (d) S- se
Ans.. (b) They have 7 electrons in the outermost (c) Strong oxidizing agents
shellof their atom Ans. . (b) Same group Ans. (b) Li - Mg
(d) Weak reducing agents
Ans. (b) Strong reducing agents
 HAND BOOR
281 I PUC- Chemistry 29
(d) Screening effect
26. Which of the following. element has a zero (d) Screening effect (c) Atomic size
ONE MARK QUESTIONS
valency? Ans.
electronic
configuration (d). Electron gain enthalpy
(a) Chlorine (b) Helium 33, Element with Ans. (c) Atomic size 51. State Mendeleev's periodic law. (M14)
3s' is
(c) Caesium (d) Magnesium Is' 2s'2p Ans: "The properties of the elements are a periodic
metal
40. Atonm of which of the following elements has function of their atomic weights".
Ans. (b) Helium (a) An alkali the greatest ability to attract electrons?
metals
27. While moving down in agroup, the metallic (b) An
alkaline earth
(a) Calcium (b) Magnesium
52. Which impottant property did, Mendeleev
character
use to classify theelements in his periodic
(c) A halogens
(c) Sodium (d) Chlorine table?
(a) Increases (d) Annert gases Ans. (d) Chlorine Ans: Atomic mass
(b) Decreases metal
Ans. (a) An alkali Fill in the blanks 53. On what parameter do the elements are
(c) Remains constant of the element classified in the modern periodic table?
34. The Atomic Number 41. Mendeleev left the gap under aluminium
(d) First increases than decreases. Electronic Configuration 1s' 2s² 2p 3s?3n! called it Eka-Alunminium. Later the element
(PUB)
Ans: Atomic number.
Ans: (a) Increases .(a) 15 (b) 16 fitted in that gap
28. The outermost electronic configuration of (d) 18 Ans. Gallium 54. State Modern Periodic law.
(c) 17
most electronegative elements is 42. Mendeleev left the gap under silicon called it (May 14,Feb. 19)
Ans. (a) 15
(a) ns? (b) ns' np
Eka-Silicon. Later the element-fitted in Ans: The physical and chemical properties of the
35. Element having atomic number 14 belonos that gap elements are the periodic functions of their
(c) ns² np (d) ns' np atomic.numbers.
(a) s-block (b) p- block Ans.. Germanium
Chemistry PUC Ans. (d) ns² np
29. Ability of an atom to attract shared pair of
electrons towards itself is called
(a) Electron affinity (b) Electronegativity

(c) d-block
An_. (b) p-block
(d) 'f- block
36, Which all elements do have ns²np outer
electrónic configuration?

43. According tó Modern Periodic Law elements

are arranged in the increasing order of-
Ans. Atomic nåmber
44. The IUPAC name of an element with atomic
number 112 is

$5. Write the IUPACname of the element with

atomic number () 104 (F-19) (i) 107(F- 16)
(ii) 108 (M-15) (iv) 11 (M-15)
Ans: (i) Unnilquadium (ii)) Unnilseptium
(ii) Unniloctium (iv) Unununium
(c)' Ionization energy (d) Shielding effect
(a) Chalcogens. Ans. Ununbjum 56. Among N,Cu,Ca and Uidentify the element
Ans. (b) Electronegativity which belongs to (i)p block () d- block
(b) Alkaline earth. 45. The elements in which 4f orbitals are filled
30. When an electron is added to the valence shell (i) Actinoid (iv) s-block
(c) Noble gasses. are called ---
(a) Energy is absorbed Ans. lanthanoids
(IMark each-EQ, PUB)
(d) Transition elements. Ans: (i) N (ii) Cu (ii) U (iv) Ca
(b) Energy is released 46. The elements in which 5f orbitals are filled
Ans. (c) Noble gasses. 57. Which group elements the periodic table
(c) Energy remains same are called --
37. Number of elements present 3th Period? are called (1) halogens i) noble gases?
(d) Force of attraction increases Ans. actinoids PUB)
(a).18 (b) 10
Ans. (b) Energy is released 47. Elements of Group 17 are called Ans: (i) Group- 17 (i) Group- 18
(c) 32 (d) 8 Ans. halogens
31. As we go from left to right across period, 58. What are representative elenments?
ionisation enthalpy Ans. (d) 8
48. Elements that.show characteristic properties Ans: s and p block elements together are calld
(a) Increases (b) Decreases 38. Electron gain enthalpy refers to of both metals and non-metals are called. representative elements.
Ans. Metallojds
(c) Remains same (d) None of above (a) Removál of electron
49. Atoms and ions which contain the same
59. What are chalcogens?
Ans. (a) Increases (b) Attraction towards bonded pair of electrons Ans: Chalcogens are the eleménts of group - 16.
number of electrons are called
32. Decrease in force of attraction between (c) Addition of electron (oxygen family)
valence electrons and nucleus by inner Ans. isoelectronic species
(d) None of the above 60. Writethepenera outer outer electronic
electrons is called .Ans. (C) Addition of 50. A qualitative measure of the ability of an atom
electron in a chemical compound to attract shared configuration of s, p-(Feb 19), d+ (Feb 20),
(a) Electrometric effect electrons to itself is called -blockelements, halogens,añd Inertgases
39. The property which
(b) Inert pair effect. regularly increases d0w Ans. electronegativity noble.gases. (IMarkeach EQ)
the group in the periodic
(c) Photoelectric effect table is: Ans: s-block - nsl-2
(a) lonization enthalpy
p- block - ns² npl4
(b) Electronegativity d-block - (n-1) d-1ong2
 HAND BOOR
I PUC- Chemistry
the
aspecies
following
in the
Arrange
radii. PUBE 13 Which of the following species will have the
f-block - (n-2) f1-14 (n-1) do-l ns?. 63. order of ionic
increasing
largest and the smallest size? Mg, Mg, Al,
88. What is electron gain enthalpy? How does it
Halogens ns'np³ F<02
vary in a periodic table? F-20)
Inert gases - ns²npó Mg?t < Na* < Ans : Electron gain enthalpy of an element is defined as
Ans. A*< Ans: Largest size- Mg Smallest size - Al3+
mo pecies will have tha the energy required or liberated when an electron
61. Give reason (1 mark each)
(i) A cation is smaller than its parent 64. Which
of the following
Mg, Al, AP" (M-14) vaWhtre iso-electronte species? Arrange is added to outermost orbit of an isolated neutral
smallest size? Mg, the following in th¹ increasing order of their gaseous atom.
atom.
(i) An anion is larger thanits parent atom Ans. Al3+ ioníc radius N, Mg?, Na andÞ, Across a period: Becomes more negative
(F-16)
and F jons, which one hag (M-14, F17, 18) Down the group : Becomes less negative
65. Among Ans. Atoms: / ions containing same number of
(iii) Nitrogen - has ahigher Ionisation Smaller in size? THREE MARK QUESTIONS
electrons are called isoelectronic species.
enthalpy than oxygen/. Oxygen has Ans. F jon.
lower ionisation enthalpy than nitrogen Mg*², Nat, 0², N3 81. Mention three defects of Mendeleev's
(M-15,17, F-17) 66. Select
ectronic species among Na,C Periodictable.
(F-20 75. Arrange the following ions in the order of
(iv) lonisation enthalpy of inert gases is Fand.L0 increasing lonic radii and also indicate the Ans: (i) Some elements are not arranged in the
very high. (EQ) Ans: Nat and F number of electrons present 'around each increasing order of their atomic masses.
(v) Noble gases have large positive electron electronegativityVary down the pr ion: K Ca S (EO) (i) Position of hydrogen is not clear because it
:(EQ) 67 How ORO Ans. Increasing order of ionic radii shows properties similar to metals as well
gain enthalpies.
(vi) Group. 17, elements (halogens) have in the periodic table ? Ca?t<K*< 18 electrons
as non metals.
Ans: Electronegativity decreases down ne group:G (iii) The position of isotopes of elements is not
very high negative : electron gain the periodic table. clear.
enthalpies. 76 Define ionisation enthalpy of an element.
Chemistry -PUC (vii) (EQ)
(viii) Electron gain enthalpy of chlorine is
higher than fluorine. EQ)
68, Which one has highest
enthalpy amongP,S,Cl and F
Ans: Chlorine

electron .oai How does itvery in a periodic table?

(F-18,19,20 M-15)
An's. The ionisation enthalpy of an element is defined

82. Write a brief note on s, p and d block

elements.
Ans: s-block elements:- The elements of group-1
F-17) Ajstwe
(i) Because it has lesser number electrons. as the energy required to remove the outermost and group-2 of modern periodic table are called
Ans:
Electrons are strongly attracted by thé 69. Name the halogenwhich has highes electron from an isolated neutral gaseous atom. s-block elements. The group - 1elements .are
nucleus and pulled inwards. As a result, the electron gain enthalpy. Across a period: It increases
called alkali metals and group-2 elements are
size decreases Ans: Chlorine. called alkaline earth metals the general etectronic
Down the group:It decreases configuration is ns
(ii) Because the addition of one or more
electrons would result in increased 70 Which is the most electro negative element 77 What is screening effect? How does it p-block elements:- The elements of group-13
repulsion among the electrons and a Ans: Fluorine influence the ionisation enthalpy? to group-18 of modern periodic table are called
decrease in effective nuclear charge. p-block elements. Their valence electrons are in
TWO MARK QUESTIONS Ans: The nucleus reduces its force of attraction on the p-orbital. The general electronic configuration is
(i) Nitrogen has half-filled p- orbital which is "valence electrons due to the presence of electrons ns² np-s
more stable in the inner-shells.
(iv) Outermost shell is completely filled. aL What is the basic difference in approach d-block elements:- The eleinents of group-3
Increase in screening effect decreases ionisation to group-12 of modern periodic table are called
(v) Because the electron has to enter the next between the. Mendeleev's Periodic Law and enthalpy. d-block. elements. They are also called transition
higher principal quantum level leading to a the Modern Periodic Law? (PUB
78.Define electronegativity. Which is the most elements due to their gradual change. in
very unstable electronic configuration. Ans. Mendeleev's Periodic Law states that th properties. The general electronic configuration
(v) Because they can attain stable noble gas properties of the elements are periodic function electronegative element? -17, 19, M-15) is (n-1)d-10 ns2
electronic configurations by picking up an of their atomic weights. Ans: The, ability of an atom to attract shared pair of
electrons towards itself. 83. What are transition and inner transition
electron. Modern Periodic Law states that the propertid elements?Give anexample of each.
(vii) Due to increase in effective nuclear charge of the elements are periodic functions of thei The most electronegative element is fluorine.
(vii) Because added electron should go to atomic numbers. Ans. Transition elements are present in group 3 to 12
smaller orbit in Fluorine (n = 2) whichrhne atomic radius? How does it vary in 79. How electronegativity vary in a periodic in the modern periodi table. These elements
table? PUB) are characterised by the filling of electrons in
suffers electron - electron repulsion. periodic table? inner d orbitals. Therefore they are referred to as
(M-15) Ans : Across a period: It increases
62. Name a species (orion) that will be Ans.. Atomic radius is the distance between the cenly d-block elements. Transition elements have the
isoelectronic with Mg ion. of the nucleus and the outermost shell of Down the group :It decreases general outer electronic configuration
(M14)
Ans. Na or Al3* or F-. atom. (n-1)d-0 ng2, Ex: Scandium and copper.
Across a period: It decreases.
Down the group: It
increases
 HAND BOOr
The two rows of elements at the bottom of the nuelei
the (iii), It is half the distance.between
periodic table are called the inner transition tw¡ covalently bonded atoms of the _an
elements. The last electron added to each element in a molecule.
element is filled. in f-orbital. These elements
have the general outer electronic configuration VERY IMPORTANT QUESTIONS
.configuration. (n-2)f-4(n-1)d"ns 1. State Modern Periodic law.
Ex: Cerium and uranium. 'electronic configurat,
2. Write the general outerelements
of s, p, d, and f- block
84. (i) Define vander waal's radius. 3. What are iso-electronic species? Give o
(ii) There is abrupt increase in the atomic example
size of Neon. Give reason. (M-22) 4. Define atomic radius, ionisation enthaln
(ii) Define covalent radius. electron gain enthalpy and electronegativi
How do they very in a periodic table?
Ans. (i) Van der Waals' radius is half of the distance 5. Give reason
between centers of nuclei of two non (i) A cation is smaller than itsparent átom.
bonded atoms of a given element. (ii) An anion is larger than its parent atom
(ii) Since the valence shell of neon is (ii) Electron gain enthalpy of chlorine is highl
completely filled (2s? 2p), it experiences than fluorine.
greater electronic repulsion.

Chemistry -PUC
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