®

®
Path to success KOTA (RAJASTHAN) WORKSHEET
Path to success KOTA (RAJASTHAN) CHEMISTRY-36
TOPIC : Aldehydes and ketones

1. Common name of H3C – CH – CH2 – CHO is O

Br (2) C4H9 – C – C4H9
(1) 3–Bromobutyl aldehyde
CH3 O CH3
(2) –Bromobutyl aldehyde
(3) CH3 – CH2 – CH – C – CH – CH2 – CH3
(3) –Bromobutyl aldehyde
(4) –Bromobutanol OH O
(4) CH3 – CH – CH2 – C – H
O
2. Names of –C – CH3 are 7. Hydration of which of the following alkyne gives
aldehyde
(1) Acetophenone (2) 1–phenyl ethanone (1) propyne (2) ethyne
(3) 2–phenyl ethanone (4) both 1 & 2 (3) bitume (4) pentyne
8. "DIBAL–H" can be used to prepare aldehyde from
3. NO2– –CHO is
(1) Cyanide only
(2) Ester & isocyanides
(1) 4 – Nitrobenzaldehyde
(3) Cyanide & isocyanides
(2) 4 – Formyl nitrobenzene
(4) Cyanide & ester
(3) 4 – Nitrobenzene carboaldehyde
(4) Both 1 & 2 9. Benzaldehyde can be prepared from which of the
following
4. The bond angles around carbonyl group is/are
(1) exactly 120° (1) By Rooenmund R4

(2) approximately 120° (2) By etard Rn

(3) always more than 120° (3) By the use of CrO3 on Toluence
(4) None of the above (4) All of the above
5. Carbonyl compounds have higher dipole moment
CH3
than ether due to
(i) Cl2/hv (twice)
10. ?
(1) Absence of resonance (ii) H20/373K

(2) Presence of resonance between C=O

bonds CCl3 C(OH)3
(3) Due to single bond present in ether (1) (2)
(4) None of the above
6. Which of the following is Di–sec. butyl ketone COOH
CHO
O
(3) (4)
(1) CH3 – C – CH2 – CH2 – CHO

Your Target is to secure Good Rank in Pre-Medical 2023 [1]

 ®

Path to success KOTA (RAJASTHAN)

11. Which of the following is "Gatterman–Koch O

Reaction" C2H5–C–Cl HCN
14. A B
AlCl3/CS2
CH3

CrO2Cl2 (1) A is phenyl propanone

(1) +
H3O (2) B is unsymetrical compound (Racemic mixture)
(3) B on acidic hydration can give carboxylic acid
COCl (4) All of the above
(2) H2
Pd–BaSO4 15.  C6 H 5CH 2  Cd 
CH Cl
3
 A 
Cl2
NaOH
B  C

A, B & C are
CH3
CrO3/ (1) C6H5CH2COCH3, CH3COCH3, CHCl3
(3)
(CH3CO)2O (2) C6H5CH2COCH3, C6H5CH2COOH, CHCl 3
(3) C6H5CH2COCH3, C6H5COOH, CHCl 3
COCl (4) None of the above
CO + HCl
(4) Anhy AlCl3/CuCl 16. Correct order of B.P. is
(1) C 3 H 7 CHO > C 4 H 9 OH > C 2 H 5 –O–C 2 H 5 >
12. Which of the following is/are correct ? C 4 H 10
(2) C 4 H 9 OH > C 2 H 5 –O–C 2 H 5 > C 3 H 7 CHO>
O
(1) CH3CH2CN PhMgBr C2H5 – C – Ph C 4 H 10
H2O (3) C 4H 9OH > C 3H 7CHO > C 2 H 5–O–C 2 H 5 >
C 4 H 10
O
MeMgBr (4) C4H10 > C4H9OH > C3H7CHO > C2H5–O–
(2) CH3 – CH2 – CN CH3 – CH – C – CH3
H2O
CH3 CH3 C 2H 5
17. Benzaldehyde is less reactive than propanal as
O
(1) the polarity of carbonyl group of
C – Ar/R
MeMgBr benzaldehydeis reduced due to resonance
(3) + Ar/RCOCl
H2O
(2) the polarity of carbonyl group of benzaldehyde
(4) All are correct is increased due resonance

13. In which of the following reagent is not correctly (3) both (1) & (2)
matched (4) None of the above
18. Reaction of HCN with carbonyl compound is
(1) Hexan  1  ol 
PCC
 Hexan  1  ol
catalysed by base
(2) P  fluorotoluene 
CrO
 P  Fluorobenzaldehyde
 
3
(CH CO) O
(1) To generate stronger nucleophile CN
3 2

DIBAL  H
(3) Ethane nitrile 
 Ethanal (2) HCN is strong acid no reaction take place
slowly
NHCrO3Cl– (3) Both (1) & (2)
(4) But-2-enl Ethanal
(4) None of the above

Your Target is to secure Good Rank in Pre-Medical 2023 [2]

 ®

Path to success KOTA (RAJASTHAN)

19. "Proton transfer" take place in bisulphite test 27. Haloform test is given by compounds having

(1) As SO3 ion is more stable than SO2H O

(1) CH3 – C – gp
(2) SO3H is more stable than SO3

(3) As proton starts the reaction O

(2) CX3 – C – gp
(4) None of the above
20. Bisulphite test is given by OH
(1) All aldehyde (3) CH3 – C – gp
(2) Aliphatic methyl ketone
(4) All of the above
(3) Glucose
(4) both (1) & (2) O

21. Acetal & ketalo are C – CH3

28.
H2CrO4
(1) gem–dialkoxy compounds A
(2) vic–dialkoxy compounds I2/NaOH
B+C
(3) gem-dihydroxy compounds
A, B & C are
(4) vic–dihydroxy compounds
22. 2, 4–DNP test is not given by COOH COOH
(1) & CHI3
(1) Aldehyde (2) Ketone ,
(3) Glucose (4) Benzaldehyde
O O
23. Which of the following can reduce carbonyl
C – OH C–H
compounds (2)
, & CHI3
(1) LiAlH4 & NaBH4
(2) Zn–Hg/HCl & NH2NH2/KOH
O
(3) Red P/HI
COOH C – CH3
(4) All of the above (3)
, & CHI3
24. Sod. pot. Tartrate is
(1) Tollen's reagent (2) Fehling solution (4) None of the above
(3) Roschelle's salt (4) both (2) & (3)
2+ +
2Cu [Ag(NH3)2]
25. Fehling solution reacts with RCOO
–
– RCHO – RCOO
–

& OH OH &
29.
(1) Aromatic aldehyde Red ppt A B Silver ppt
(2) Aliphatic aldehyde
(3) Ketone Reaction A & B indicates

(4) both (1) & (2) (1) Haloform & Tollen's reagent

26. Fehling solution with aldehyde gives (2) Fehling's & Canizarro's

(1) Black ppt (2) Reddish brown ppt (3) Aldol & Fehling's

(3) purple ppt (4) white ppt (4) Fehling's & Tollen's reagent

Your Target is to secure Good Rank in Pre-Medical 2023 [3]

 ®

Path to success KOTA (RAJASTHAN)

NH2NH2 CH3  CH 2  CHO 

HCHO(excess)
A  B
– A 33. conc. base
OH
30. C=O CH2OH
NH2NH2 (1) CH3 – C – CHO & HCHO
B
CH2OH
A & B are CH2OH
(2) CH3 – C – CH2OH + HCOO–
(1) alkane & amine
CH2OH
(2) Alkane & Aldoxime
OH
(3) Alkene & hydrazone (3) CH3 – CH2 – CH – CHO

(4) Alkane & Hydrazone CH2OH

(4) CH3 – C – CHO + CH3OH
OH
Dil. 
31. CH3CHO
NaOH
CH3 – CH – CH2 – CHO CH3 – CH = CH – CHO CH 2OH
Step-I Step-II
34. Match the following
Column - I
Step I & II are
O
(1) H+
(1) Aldol condensation + HO – NH2

(2) Perkin's reaction NO2

O
(3) Aldol reaction & Aldol condensation (2) + HO – NH NO2

(4) Aldol reaction & Cannizzaro's reaction O

C H+
O (3) CH3 + CH3CH2CH2
CHO
32. C – CH3 Product
KOH/293k O
H+
(4) R – CH = CH – CHO + NH2–C –NH–NH2
Product will be Column - II
N–OH
O (a)
(1) C CH3
–C = N – C2H5
(b) CH3
O
(2) CH = CH – C CH3 –N2 – NH
NO2
(c)
OH O
NO2
(3) CH – CH2 – C
R – CH = CH – CH
(d) O
NH2 – C – NH – N
(4) CH = CH CHO
(1) 1-a, 2-b, 3-c, 4-d (2) 1-a, 2-c, 3-b, 4-d
(3) 1-d, 2-b, 3-c, 4-a (4) 1-b, 2-a, 3-d, 4-d

Your Target is to secure Good Rank in Pre-Medical 2023 [4]

 ®

Path to success KOTA (RAJASTHAN)

35. Formalin is mainly used CH3 CH3

(1) to prepare acetic acid (IV) CH3–CH–C–CH–CH3
(2) to prepare bakallite & to prepare biological O
specimen
(1) I < II < III < IV
(3) to prepare fertilizers
(2) III < IV < I < II
(4) to prepare PVC
(3) IV < III < II < I
36. Arrange the following in order of reactivity towards NAR
(4) II < I < IV < III
(1) Butanone > Propanone < Propanal < Ethanal
39. Cyanohydrin of the following compound on
(2) Acetophenone > p–Tolualdehyde > p–
hydrolysis gives compound that can show optical
Nitrobenzaldehyde isomerism :
(3) Ethanal > Propanal > Propanon > Butanone (1) HCHO (2) CH3CHO
(4) Acetophenon > p–nitrobenzaldehyde > p– (3) CH3COCH3 (4) All the above
Tolualdehyde
40. Compound A and C in the following reaction are
37. Fill in the blanks :
(i) CH3MgBr H SO
O CH3CHO (A) 2 4 (B)
(ii) H2O 
[Ag(NH3)2]
(1) ?
CHO B2H6/THF
–
(C)
H2O2/OH
? (1) Identical
(2) CH3COCH 2COOCH 3
(2) Chain isomer
? (3) Positional isomer
(4) Optical isomer
O /Zn
(3) –CH3 3 ?
H2O O
41. C can be obtained by :
CH2
?
(4)
O
(1) C–Cl + (Ph)2Cd
dil. NaOH
–CHO ?

(5) OH
+ O
CH3CH2CHO
(2) C–Cl +
38. Arrange the following in the increasing order of
reactivity of NAR.
(I) CH2O (3) + CO + ZnCl2 + HCN
(II) CH3CHO
(III) CH3–CO–CH3 (4) None of the above

Your Target is to secure Good Rank in Pre-Medical 2023 [5]

 ®

Path to success KOTA (RAJASTHAN)

O CHO
OH
PCC NH2–NH–C–NH2 45. Conc. NaOH
42. Ph–CH–CH3 (A) (B) Product

Product (B) is :
What is the product obtained in the above reaction?
CH3 O
(1)
Ph–C=N–C–NH–NH2 COONa CH2OH

O (1) only (2) only

Ph–C=N–NH–C–NH2
(2)
CH3
COONa CHOH
2

O
(3) +
Ph–CH=N–N–C–NH2
(3)
CH3
CH3 CH2OH
O
(4) (4)
Ph–CH=N–C–NH2 +

43. The appropriate reagent for the following

transformation is
46. Of the following, which is the product formed when
cyclohexanone undergoes aldol condensation
O
followed by heating ?
CH2CH3
CH3

HO HO
(1)
(1) Zn(Hg), HCl (2) NH2NH2, OH– O
(3) H2/Ni (4) NaBH4

44. How many compounds in given below can react

with NaHSO3 (2)
OH
O
C–CH,3
HCHO, CH–C
3 –CH3,
O (3)
O O
CH–
3 CHO,

(1) 4 (2) 3
(4)
(3) 1 (4) 2
OH
Your Target is to secure Good Rank in Pre-Medical 2023 [6]
 ®

Path to success KOTA (RAJASTHAN)

47. For the reaction: 49. In Cannizzaro reaction given below :-

OH : OH
Ph–CHO + Ph–C–CH 3 Major 2PhCHO PhCH2OH + PhCO2
293K
O
The major product is : the slowest step is :-
CH3 (1) The abstraction of proton from the carboxylic
group
(1) Ph–C–CH 2–C–Ph
OH O (2) The deprotonation of PhCH2OH
Ph–C–O + Ph–CH 2–OH
(2)
O (3) The attack of : OH at the carboxyl group
O (4) The transfer of hydride to the carbonyl group
(3) Ph–CH–C–Ph 50. Mixture of Ph–CHO and H-CHO is treated with
OH conc. NaOH, then cannizzaro reaction involves
O
(4) (1) Oxidation of HCHO
Ph –CH=CH –C–Ph
48. The Cannizzaro reaction is not given by (2) Readuction of HCHO
(1) trimethylacetaldehyde
(3) Reduction of PhCHO
(2) acetaldehyde
(3) benzaldehyde (4) Both (1) and (3)
(4) formaldehyde

ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 4 4 2 2 3 2 4 4 3 4 4 4 4 2
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 3 1 1 1 4 1 3 4 4 2 2 4 1 4 4
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 3 4 2 2 2 1 3 2 3 1 2 2 2 3
Que. 46 47 48 49 50
Ans. 1 4 2 4 4

37. Fill in the blanks :

O
[Ag(NH3)2]
(1) ?
CHO
O
O
[Ag(NH3)2]
Ans.
CHO
COOH

Your Target is to secure Good Rank in Pre-Medical 2023 [7]

 ®

Path to success KOTA (RAJASTHAN)

?
(2) CH3COCH 2COOCH 3

DIBAL–H
CH3COCH2CHO
Ans. CH3COCH2COOCH3
NaBH4
CH3CH – CH2 – COOCH3
OH

O3/Zn
(3) –CH3 ?
H2O

O2/Zn
Ans. –CH3 O+O –CH3
H2O

CH2
?
(4)

CH2
Cl–CH2–
Ans.
AlCl3

dil. NaOH
(5) –CHO + CH3CH3CHO ?


dil.
Ans. –CHO + CH3CH2CHO CH3–CH2–CH=CH–
NaOH

Your Target is to secure Good Rank in Pre-Medical 2023 [8]