THE COPPERBELT UNIVERSITY
DEPARTMENT OF CHEMICAL ENGINEERING
CE 480 ASSIGNMENT 4 SOLUTIONS
Calculation Question
1. Granular activated carbon particles where used in adsorption batch tests using solutions
of phenol in water. The table below shows the equilibrium data, that is, the phenol
surface concentration dependence on the equilibrium concentration in solution.
CA (kg/m3) 0.322 0.117 0.039 0.0061 0.0011
CA,S (Kg/kg) 0.15 0.122 0.094 0.059 0.045
Determine the isotherm that fits the data and give the constants of the equation using the
given units. [40 marks]
The Freundlich isotherm shows a better fit (R2=0.9941) than the Langmuir isotherm
(R2=0.9922).