21-08-2024

6001CJA10102124013 JA

PHYSICS

SECTION-I

1) A particle with charge q, moving with a momentum p, enters a uniform magnetic field normally.

The magnetic field has magnitude B and is confined to a region of width d, where , The

particle is deflected by an angle θ in crossing the field :-

(A)

(B)

(C)

(D)

2) Two long parallel wires are at a distance 2d apart. They carry steady equal currents flowing out of
the plane of the paper as shown. The variation of magnetic field B along the line XX' is given by :

(A)

(B)

(C)

(D)

3) A magnet of magnetic moment A-m2 is placed along the x-axis in a magnetic field
 T. The torque acting on the magnet is :-

(A)
(B)
(C)
(D)

4) A diamagnetic material in a magnetic field moves:-

(A) From weaker to the stronger parts of the field

(B) Perpendicular to the field
(C) From stronger to the weaker parts of the field
(D) In none of the above directions

5) Curie temperature is the temperature above which

(A) A paramagnetic material becomes ferromagnetic

(B) A ferromagnetic material becomes paramagnetic
(C) A paramagnetic material becomes diamagnetic
(D) A ferromagnetic material becomes diamagnetic

6) Calculate magnetic moment of shown system.

(A)

(B)

(C)

(D)
7)
The figure gives experimentally measured B vs. H variation in a ferromagnetic material. The
retentivity, co-ercivity and saturation, respectively, of the material are:

(A) 150 A/m, 1.0T and 1.5T

(B) 1.0T, 50 A/m and 1.5T
(C) 1.5T, 50 A/m, and 1.0T
(D) 1.5T, 1.0T and 50 A/m

8) A particle of mass 1.6 × 10–27 kg and charge 1.6 × 10–19 coulomb enters in a uniform magnetic
field of 1 Tesla as shown in the fig. The speed of the particle is 107 m/s. The distance PQ will be- (
)

(A) 0.14 m
(B) 0.28 m
(C) 0.4 m
(D) 0.5 m

9) A magnetic dipole in a uniform magnetic field has :

(A) Maximum potential energy when torque is maximum

(B) Zero potential energy when torque is minimum
(C) Zero potential energy when torque is maximum
(D) Minimum potential energy when the torque is maximum

10) A long hollow cylindrical wire carries a current Ι, having inner and outer radii 'R' and 2R
respectively. Magnetic field at a point which 3R/2 distance away from its axis is :-
(A)

(B)

(C)

(D)

11) A particle of charge q and mass m is moving along the x-axis with a velocity v and enters a
region of electric field E and magnetic field B as shown in figure below. For which figure the net
force on the charge may be zero :

(A)

(B)

(C)

(D)

12) A wire of length L metres carrying a current I amperes is bent in the form of a circle. The
magnitude of the magnetic moment is

(A)

(B)

(C)

(D)

13) When a material is subjected to a small magnetic field H, the intensity of magnetisation is
proportional to

(A) H1/2
(B) H
(C) H2
(D) H–1/2

14) If the number of turns and current become double for any solenoid, then the value of magnetic
field becomes :

(A) Same
(B) 2 times
(C) 3 times
(D) 4 times

15) A proton, a deuteron and an α-particle with same kinetic energy enter into a uniform magnetic
field at right angle to magnetic field. The ratio of the radii of their respective circular paths is :

(A)
(B)
(C)
(D)

16) A rectangular loop of sides 10cm and 5cm carrying a current I of 12A is placed in different
orientations as shown in the figures below:

If there is a uniform magnetic field of 0.3T in the positive z direction, in which orientations the loop
would be in (i) stable equilibrium and (ii) unstable equilibrium?

(A) (1) and (2), respectively

(B) (1) and (3), respectively
(C) (2) and (4), respectively
(D) (2) and (3), respectively

17) A conducting ring of mass 2 kg and radius 0.5m is placed on a smooth horizontal plane. The ring
carries a current i = 4A. A horizontal magnetic field B = 10 T is switched on at time t = 0 as shown

in figure. The initial angular acceleration of the ring will be

(A) 40 π rad/s2
(B) 20 π rad/s2
(C) 5 π rad/s2
(D) 15 π rad/s2

18) Relative permeability of iron is 5500, then its magnetic susceptibility will be :

(A) 5500 × 107

(B) 5500 × 10–7
(C) 5501
(D) 5499

19) Two short magnets 1 and 2 of magnetic moment 9 Am2 and 16 Am2 respectively are placed along
two lines drawn at right angle to each other on the sheet of paper as shown in the figure. What is the

magnetic field at the point of intersection of their axis:

(A) 8.33 × 10-5 T

(B) 4.17 × 10-5 T
(C) 5.83 × 10-5 T
(D) 11.67 × 10-5 T

20) A coaxial cable is made up of two conductors. The inner conductor is solid and is of radius R1 &
the outer conductor is hollow of inner radius R2 and outer radius R3. The space between the
conductors is filled with air. The inner and outer conductors are carrying currents of equal
magnitudes and in opposite directions. Then the variation of magnetic field with distance from the

axis is best plotted as:

(A)
(B)

(C)

(D)

SECTION-II

1) A solenoid is to be constructed with a magnetic field of 0.168 T at its center. The radius of
solenoid is to be 0.01 m and the wire carries a curent of 2A. If the solenoid is 1.4 m long, what is the
length of wire needed (in m) [Give the answer to nearest integer]

2) A loop ABCDEFA of straight edges has six corner points A(0,0,0), B(5,0,0), C(5,5,0), D(0,5,0),

E(0,5,5) and F(0,0,5). The magnetic field in this region is . The quantity of flux
through the loop ABCDEFA (in Wb) is _____.

3) The mid points of two small magnetic dipoles of length d in end-on positions, are separated by a
distance x, (x >> d). The force between them is proportional to x–n where n is :-

4)

Two similar poles of strength 3 mWb and 27 mWb are separated by a distance of 24 cm. The neutral
point from the smaller pole will be at a distance of (in cm)

5) The value of aluminium susceptibility is 2.2 × 10–5. The percentage increase in the magnetic field

if space within a current carrying toroid is filled with aluminium is . Then the value of x is ____.

6)

The period of oscillations of a magnet is 2 sec. When it is remagnetised so that the pole strength is 4
times, its new time period will be ____ seconds.

7) A paramagnetic substance shows a net magnetisation of 8 A/m when placed in an external

magnetic intensity 0.6 A/m at temperature of 4K. When substance is placed in an external magnetic
field of 0.2 A/m at a temperature of 16K, the magnetisation (in A/m) will be x. Find value of 6x.
8) A square loop ABCD, carrying current i is placed near and coplanar a long straight conductor XY

carrying current I. If the net force on the loop will be then α is:

9) Magnetic field given by T in the region defined by x2 + y2 = 16 and y > 0. A charge

particle of mass m = 10–19 kg, q = 1.6 × 10–19 C, enters at origin with a velocity m/s. What is
the angle of deviation (in degree) suffered by charge particle in the magnetic field.

10) An electron moving with a velocity

5 × 106 ms–1 in the uniform electric field of 5 × 107 Vm–1. The minimum uniform magnetic field in
Tesla that will cause the electron to move undeviated along its original path is B. Find B.

CHEMISTRY

SECTION-I

1) Select correct order of C–O bond length:

(A)
(B)
(C)
(D)

2) The major product of following reaction is:

(A) RCHO
(B) RCOOH
(C) RCH2NH2
(D) RCONH2

3) , A is

(A)

(B)

(C)

(D)

4) The magnetic moment of is 5.9 BM. The geometry of the complex ion is:
(X = monodentate halide ion)

(A) Square planar

(B) Tetrahedral
(C) Both are possible
(D) None of these

5) In the given reaction sequence B is:

(A)

(B)
(C)

(D)

6) Which of the following pairs of complexes are isomeric with each other but their aqueous
solutions exhibit different molar conductivities?

(A) [PtCl2(NH3)4] Br2 and [PtBr2(NH3)4]Cl2

[CoCl2(NH3)4]NO2 and
(B)
[CoCl(NO2) (NH3)4]Cl
(C) [Co(NO2)(NH3)5] Cl2 and [Co(ONO) (NH3)5]Cl2
(D) [CoBr(NH3)5] SO4 and [Co(SO4)(NH3)5]Br

7) The number of aldol reaction(s) that occurs in the given transformation is

(A) 1
(B) 2
(C) 3
(D) 4

8) Which type of isomerism is not exhibited by complex ?

(A) Ionization isomerism

(B) Hydrate isomerism
(C) Geometrical isomerism
(D) Optical isomerism

9) 2, 4–DNP test can be used to identify:

(A) Amine
(B) Aldehyde
(C) Ether
(D) Halogens

10)
'X' can be:
(A)
(B) Red P / HI

(C)
dry HCl/Raney Ni/H2
(D) All of these

11) Which of the following species can act as reducing agent ?

(A)
(B)
(C)
(D)

12)

(A)

(B)

(C)

(D) Both (A) and (B)

13) A complex typically absorbs at around 600 nm. It is allowed to react with ammonia
to form a new complex that should have absorption at:

(A) 800 nm
(B) 620 nm
(C) 580 nm
(D) 320 nm

14) Which of the following ketone will NOT give enamine on treatment with secondary amines?
[where t-Bu is ]

(A)

(B)

(C)

(D)

15) Out of total chlorine the fraction of chlorine precipitated by AgNO3 solution from
is

(A) 1/2
(B) 2/3
(C) 1/3
(D) 1/4

16) The coordination number and oxidation number of the central metal ion in the complex
is:

(A)
(B)
(C)
(D)

17)
In the above reaction, product (B) is :

(A)
(B)

(C)

(D)

18) (ppt.)
Product A and C are

(A)

(B)

(C)

(D)

19)
product (B) is:

(A)

(B)

(C)

(D)
20) The increasing order of the reactivity of the following compound in nucleophilic addition
reaction is:
Propanal, Benzaldehyde, Propanone, Butanone

(A) Butanone < Propanone < Benzaldehyde < Propanal

(B) Benzaldehyde < Butanone < Propanone < Propanal
(C) Propanal < Propanone < Butanone < Benzaldehyde
(D) Benzaldehyde < Propanal < Propanone < Butanone

SECTION-II

1) Find out value of expression (x-y) for complex compound

where,
x = Total number of O–Zn–O bond angle(s) in the compound
y = Total number of sp3 Hybridized atom(s) in the compound

2) In the reaction given below, the total number of atoms having sp2 hybridization in the major
product P is

3) 100 mL 0.15 M solution of CoCl3.xNH3 was treated with excess of AgNO3 solution and 0.03 moles
of AgCl was obtained, then find out value of x.

4) Find out total number of paramagnetic inner orbital complex: K2[NiCl4],K3[Fe(CN)6], K3 [Cr(CN)6],
K2 [PtCl4], Na2 [Fe(CN)5NO], [Fe(H2O)NO]SO4,
K3[Co(C2O4)3], K4 [Co(CN)6]

5) How many compounds gives iodoform test :

6) How many compounds can give cannizaro reaction ?

HCHO, PhCHO,

7)
Give total number of products including stereomers.

8) Find out number of electrons(s) in axial d orbitals of inner shell of central metal cation in
complex .

9) Consider the following transformation:

In both reactant and product follow EAN rule, then calculate value of (where x, y and z are
natural numbers).

10) Total number of space (stereo) isomers of complex ion are ________ .

MATHEMATICS

SECTION-I

1) Let , m are the number of critical and stationary points of the function

. Then _______.

(A) 2
(B) 3
(C) 4
(D) 5

2) Find the co-ordinates of the point on the curve which is at least distance from the line
.

(A) (1, 2)
(B) (2, 1)
(C) (1, 1)
(D) (– 1, 1)

3) The point of inflection for the curve is

(A) (1, 1)
(B) (0, 0)
(C) (1, 0)
(D) (0, 1)

4) If has local maximum and minimum at x = a and x = b respectively,

then ordered pair (a, b) is

(A)
(B)
(C)
(D)

5) If f(x) is continuous and differentiable over [– 2, 5] and for all x in (–2, 5), then the
greatest possible value of is

(A) 7
(B) 9
(C) 15
(D) 21

6) Let f(x) and g(x) are two function which are defined and differentiable for all . If
and for all x > x0 then

(A) for some

(B) for some
(C) only for some
(D) for all

7) The length of the tangent to the curve is

(A) ax
(B) ay
(C) a
(D) xy

8) The length of the normal to the curve at is

(A) 2a

(B)

(C)

(D)

9) If curve and intersect orthogonally then the value of a is

(A)

(B)

(C) 2
(D) 3

10) The least value of for which , for all x > 0, is

(A)

(B)

(C)

(D)

11) Let and . If , then the local minimum

value of h(x) is _____.

(A) 3
(B) – 3
(C)
(D)

12) The maximum value of the function on the set

is

(A) 122
(B) – 122
(C) 222
(D) – 222

13) If is a twice differentiable function such that f"(x) > 0 for all and
 then

(A)

(B)
(C)

(D)

14) Let be a twice differentiable function such that , for all If

, then is

(A) Decreasing on (0, 2)

(B) Increasing on (0, 2)
(C) Decreasing on (0, 1) and increasing on (1, 2)
(D) Increasing on (0, 1) and decreasing on (1, 2)

15) The height of a right circular cylinder of maximum volume inscribed in a sphere of radius 3 is

(A)

(B)
(C)
(D)

16) A spherical iron ball of 10 cm radius is coated with a layer of ice of uniform thickness that melts
at a rate of 50 cm3/min. When the thickness of ice is 5 cm, then the rate (in cm/min.) at which the
thickness of ice decreases, is

(A)

(B)

(C)

(D)

17) The minimum value of is

(A)
(B)
(C)

(D)
18) If the tangent to the curve at a point (a, b) is parallel to the line joining and

then

(A) b = a

(B)

(C)
(D)

19) Let . Then which of the following statements are true?

P : x = 0 is a point of local minima of f
is a point of inflection of f
is increasing for

(A) Only P and Q

(B) Only P and R
(C) Only Q and R
(D) All P, Q and R

20) Let
Then the set of all values of b, for which f(x) has maximum value at x = 1, is

(A) (– 6, – 2)
(B) (2, 6)
(C)

(D)

SECTION-II

1) Let be a twice differentiable function in (0,1) such that f(0) = 3 and f(1) = 5. If the
line y = 2x + 3 intersects the graph of f(x) at only two distinct points in (0, 1) then the least number
of points at which f''(x) = 0, is _____.

2) If the minimum value of , is 14, then the value of is equal to

3) The number of real solutions of is equal to _____.

4) Let be the largest value of for which the function is

increasing for all . Then is equal to

5) Let . If m and M are respectively the number of points

of local minimum and local maximum of f in the interval (0, 4), then m + M is equal to

6) Let x, y > 0. If , then the least value of is _____.

7) If the curves and xy = k cut at right angles, then is equal to _____.

8) Let f(x) be a polynomial of degree 3 such that f(–1) = 10, f(1) = – 6, f(x) has a critical point at x = –
1, and has a critical point x = 1. Then f(x) has a local minima at x = _____.

9) If the tangent to the curve, at a point and the normal to the parabola, at the
point (1, 2) intersect at the same point on the x-axis, then the value of c is _____.

10) If the lines x + y = a and x – y = b touch the curve at the points where the curve
intersects the x-axis, then a + b is equal to _____.
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A B C B C B A C C B D B D D C A D A C

SECTION-II

Q. 21 22 23 24 25 26 27 28 29 30
A. 5880.00 175 4.00 6.00 22 1.00 4.00 1.50 60.00 10.00

CHEMISTRY

SECTION-I

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. A A A B B D C B B D B A C C B D B C B A

SECTION-II

Q. 51 52 53 54 55 56 57 58 59 60
A. 1.00 12.00 5.00 3.00 6.00 5.00 6.00 2.00 5.00 2.00

MATHEMATICS

SECTION-I

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. B B B C D D C C B C D A C C B B C D D C

SECTION-II

Q. 81 82 83 84 85 86 87 88 89 90
A. 2.00 128.00 1.00 72.00 3.00 40.00 4.00 3.00 4.00 3.00
 SOLUTIONS

PHYSICS

1)

From figure it is clear that

also r =

2)

Towards left of both wires direction of B is downward and at mid point between two wires, magnetic
field is zero.

3)

8) = r cos 45°
PQ = 2r cos 45°

r=
 9) τ = MB sinθ

U = –MB cosθ

=μi
0
10)

B.2π

B.3πR = ; B=

15)

28) The net force on the loop will be 1.50.

CHEMISTRY

31)

C–O bond length:

Bond order of CO in Cr(CO)6 is less than three.

Bond order of CO = 3
Bond order of

32)

33)

34)
 35)

36)

[CoBr(NH3)5]SO4 Total charges = 4

+ –
[Co(SO)4(NH3)5]Br [Co(SO4)(NH3)5] +Br ; Total charges = 2
Hence, both have different molar conductivities.

38)

is not hybrate isomer of the complex .

41)

can act as reducing agent because the metal carbonyl is stable when EAN is equal to
nearest noble gas configuration.

42)

43)

As NH3 is stronger ligand than H2O, hence CFSE value of > CFSE
of therefore, absorption shifts to smaller wavelength. Also difference between splitting power of
NH3 and H2O is not very high.

44)
 No enamine

45)

2/3 chlorine is precipitated.

46)

C.N = 4
O.N = +2

47)

48)

49)

50)

Nucleophilic addition & electrophilicity

51)
[Zn (acac)2] is tetrahedral complex in which O–Zn–O bond angles are 6 and total no. of sp3 hybridised
atoms = 5.

52)

53)

Moles of complex
Moles of AgCl formed = 0.030, i.e., twice the moles of complex.
Hence, 2Cl– ions must present in ionization sphere.
For octahedral geometry, complex

54)

K2[NiCl4] sp³ paramagnetic

K3[Fe(CN)6] dsp³ paramagnetic
K3[Cr(CN)6] d²sp³ paramagnetic
K2[PtCl4] dsp² diamagnetic
Na2[Fe(CN)5NO] d²sp³ diamagnetic
[Fe(H2O)NO]SO4 sp³d² paramagnetic
K3[Co(C2O4)3] d²sp³ diamagnetic
K4[Co(CN)6] d²sp³ paramagnetic.

55)

56)

HCHO, PhCHO, ,

58)
 59)

x = 6, y = 3, z = 2

MATHEMATICS

61)

f'(x) does not exist at x = 2 and f'(x) = 0 at x = 1

are critical points and x = 1 is stationary point.

62)

Let P(x1, y1) be a point on the curve x2 = 4y

at which normal is also a perpendicular to the line y = x – 4.

Slope of the tangent at (x1, y1) is

Hence required point is (2, 1)

63)

Here
From the given points we find that (0, 0) is the point of the curve where

does not exist but sign of changes about this point.

is the required point.

64)
 and

Now

f"(– 2) = – 30
is a point of local maximum
f"(3) = 30
is a point of local minimum
Hence, (– 2, 3) is the required ordered pair.

65)

Apply LMVT

for some x in (–2, 5)

Now,

Greatest possible value of is 21.

66)

Let

67)

Length of the tangent

68)

Also at
required length of normal
 69)

Two curves intersect orthogonally if

...(i)
Now eliminating y from the given equations we have
... (ii)

Eliminating x2 from (i) and (ii) we get

70)

f(x) attains its minimum at

71)

if

if

72)

Now
So
For given interval, f(x) will have maximum value for x = 6

73)

Using LMVT on f(x) for

, where

, where
is an increasing function

74)

differentiating w.r.t. x

For to be increasing

( then f'(x) is an increasing function)

So is increasing in (1, 2) and decreasing in (0, 1).

75)

Let radius of base and height of cylinder be r and h respectively.

...(i)
Volume of cylinder

and
Volume is maximum when

76)
When

77)

78)

Curve and point is (a, b)

...(i)

from (i)
So,

79)
 is the local minima

is point of inflection
is increasing for

80)

If f(x) has maximum value at x = 1 then

(i)
(ii)
Intersection of above two sets

81)

If a graph cuts y = 2x + 5 in (0, 1) twice then its concavity changes twice

at atleast two points.

82)

83)
 84)

for all x

85)

at one point

So, 3 points

86)

x, y > 0 and x3y2 = 215

Now,
So, by inequality

Least value of 3x + 4y = 40

87)

and

Point of intersection of C1 and C2 is

 88)

and b + d = 2 a+c=–8
a = 1, c = – 9, b = – 3, d = 5
local minima at x = 3

89)

For

Tangent is
Put
For

Normal is
Put
From (i) and (ii); c – 1 = 3

90)

, this curve intersects the x-axis at A(1, 0) and B(2, 0)

Equation of tangent at A(1, 0);

and equation of tangent at B(2,0)

So a = 1 and b = 2
a+b=3