Safety Data Sheet

According to Regulation (EC) No 1907/2006

Mr Muscle All Purpose Cleaner

Revision: 2014-02-06 Version: 05

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name: Mr Muscle All Purpose Cleaner
Mr Muscle ® Used under authority from S.C. Johnson & Son Inc., Racine, Wisconsin, U.S.A.

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses:
For professional use only.
AISE-P301 - General purpose cleaner. Manual process
AISE-P302 - General purpose cleaner. Spray and wipe manual process
Uses advised against: Uses other than those identified are not recommended

1.3 Details of the supplier of the safety data sheet

Diversey Ltd

Contact details
Weston Favell Centre, Northampton NN3 8PD, United Kingdom
Tel: 01604 405311, Fax: 01604 406809
Regulatory Email: MSDSinfoUK@[Link]

1.4 Emergency telephone number

For medical or environmental emergency only:
call 0800 052 0185

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
The product does not meet the criteria for classification in accordance with Directive 1999/45/EC and corresponding national legislation.

2.2 Label elements

Further indications on the label:

Rinse and dry hands after use. For prolonged contact, protection for the skin may be necessary.
Safety data sheet available for professional user on request.

2.3 Other hazards

No other hazards known. The product does not meet the criteria for PBT or vPvB in accordance with Regulation (EC) No 1907/2006, Annex
XIII.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Ingredient(s) EC number CAS number REACH number Classification Classification Notes Weight
(EC) 1272/2008 percent
alkyl alcohol ethoxylate Polymer* 68131-40-8 [4] Xn;R22 Eye Dam. 1 (H318) 1-3
Xi;R41 Acute Tox. 4 (H302)

* Polymer.
For the full text of the R, H and EUH phrases mentioned in this Section, see Section 16.
Workplace exposure limit(s), if available, are listed in subsection 8.1.
[1] Exempted: ionic mixture. See Regulation (EC) No 1907/2006, Annex V, paragraph 3 and 4. This salt is potentially present, based on calculation, and included
for classification and labelling purposes only. Each starting material of the ionic mixture is registered, as required.
[2] Exempted: included in Annex IV of Regulation (EC) No 1907/2006.
[3] Exempted: Annex V of Regulation (EC) No 1907/2006.
[4] Exempted: polymer. See Article 2(9) of Regulation (EC) No 1907/2006.

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SECTION 4: First aid measures

4.1 Description of first aid measures
Inhalation Remove from source of exposure. If discomfort persists, obtain medical attention.
Skin contact: Not required under normal use. Rinse with plenty of water. If irritation develops get medical
attention.
Eye contact: Wash off immediately with plenty of water. Get medical attention.
Ingestion: Remove material from mouth. Immediately drink 1-2 glasses of water or milk. If large amounts
swallowed or symptoms develop, get medical attention.
Self-protection of first aider: Consider personal protective equipment as indicated in subsection 8.2.

4.2 Most important symptoms and effects, both acute and delayed
Inhalation: Unlikely to be irritant or harmful in normal use.
Skin contact: Unlikely to be irritant in normal use.
Eye contact: Unlikely to be irritant in normal use.
Ingestion: Unlikely to be harmful unless excessive amount ingested.
Sensitisation: No known effects.

4.3 Indication of any immediate medical attention and special treatment needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found
in section 11.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol-resistant foam.

5.2 Special hazards arising from the substance or mixture

No special hazards known.

5.3 Advice for firefighters

As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
No special measures required.

6.2 Environmental precautions

Do not allow to enter drainage system, surface or ground water. Dilute with plenty of water.

6.3 Methods and material for containment and cleaning up

Absorb with liquid-binding material (sand, diatomite, universal binders, sawdust).

6.4 Reference to other sections

For personal protective equipment see subsection 8.2. For disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Advice on safe handling:
Handle in accordance with good industrial hygiene and safety practice. Do not mix with other products unless advised by Diversey. For advice
on general occupational hygiene see subsection 8.2. For environmental exposure controls see subsection 8.2. For incompatible materials see
subsection 10.5.

Prevention of fire and explosion:

No special precautions required.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage rooms / facilities:
In accordance with local and national regulations.

Combined storage in storage rooms / facilities:

In accordance with local and national regulations. For incompatible materials see subsection 10.5.

Basic storage conditions

Store in original container. For conditions to avoid see subsection 10.4.

7.3 Specific end use(s)

No specific advice for end use available.

SECTION 8: Exposure controls/personal protection

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8.1 Control parameters

Workplace exposure limits

Air limit values, if available:

Biological limit values, if available:

Recommended monitoring procedures, if available:

Additional exposure limits under the conditions of use, if available:

DNEL/DMEL and PNEC values

Human exposure
DNEL oral exposure - Consumer (mg/kg bw)
Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects effects effects
alkyl alcohol ethoxylate No data available No data available No data available No data available

DNEL dermal exposure - Worker

Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects (mg/kg bw) effects effects (mg/kg bw)
alkyl alcohol ethoxylate No data available No data available No data available No data available

DNEL dermal exposure - Consumer

Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects (mg/kg bw) effects effects (mg/kg bw)
alkyl alcohol ethoxylate No data available No data available No data available No data available

DNEL inhalatory exposure - Worker (mg/m3)

Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects effects effects
alkyl alcohol ethoxylate No data available No data available No data available No data available

DNEL inhalatory exposure - Consumer (mg/m3)

Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects effects effects
alkyl alcohol ethoxylate No data available No data available No data available No data available

Environmental exposure
Environmental exposure - PNEC
Ingredient(s) Surface water, fresh Surface water, marine Intermittent (mg/l) Sewage treatment
(mg/l) (mg/l) plant (mg/l)
alkyl alcohol ethoxylate No data available No data available No data available No data available

Environmental exposure - PNEC, continued

Ingredient(s) Sediment, freshwater Sediment, marine Soil (mg/kg) Air (mg/m3)
(mg/kg) (mg/kg)
alkyl alcohol ethoxylate No data available No data available No data available No data available

8.2 Exposure controls

General health and safety measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes.

The following information applies for the uses indicated in subsection 1.2.
If available, please refer to the product information sheet for application and handling instructions.
Normal use conditions are assumed for this section.

Recommended safety measures for handling the undiluted product:

Appropriate engineering controls: No special requirements under normal use conditions.

Appropriate organisational controls: No special requirements under normal use conditions.

Personal protective equipment

Eye / face protection: Safety glasses are not normally required. However, their use is recommended in those cases
where splashes may occur when handling the product.
Hand protection: Rinse and dry hands after use. For prolonged contact protection for the skin may be necessary.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.

Environmental exposure controls: No special requirements under normal use conditions.

Recommended safety measures for handling the diluted product:

Recommended maximum concentration (%): 1.25

Appropriate engineering controls: No special requirements under normal use conditions.

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Appropriate organisational controls: No special requirements under normal use conditions.

Personal protective equipment .

Eye / face protection: No special requirements under normal use conditions.
Hand protection: Rinse and dry hands after use. For prolonged contact protection for the skin may be necessary.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.

Environmental exposure controls: No special requirements under normal use conditions.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Information in this section refers to the product, unless it is specifically stated that substance data is listed

Method / remark
Physical State: Liquid
Colour: Pale, Green
Odour: Slightly perfumed
Odour threshold: Not applicable
pH: ≈ 12 ( neat)
Melting point/freezing point (°C): Not determined
Initial boiling point and boiling range (°C): Not determined

Substance data, boiling point

Ingredient(s) Value Method Atmospheric pressure
(°C) (hPa)
alkyl alcohol ethoxylate No data available

Method / remark
Flash point (°C): Not applicable.
Sustained combustion: Not determined
Evaporation rate: Not determined
Flammability (solid, gas): Not determined
Upper/lower flammability limit (%): Not determined

Substance data, flammability or explosive limits, if available:

Method / remark
Vapour pressure: Not determined

Substance data, vapour pressure

Ingredient(s) Value Method Temperature
(Pa) (°C)
alkyl alcohol ethoxylate No data available

Method / remark
Vapour density: Not determined
Relative density: 1.00 g/cm³ (20°C)
Solubility in / Miscibility with Water: Fully miscible

Substance data, solubility in water

Ingredient(s) Value Method Temperature
(g/l) (°C)
alkyl alcohol ethoxylate No data available

Substance data, partition coefficient n-octanol/water (log Kow): see subsection 12.3
Method / remark
Autoignition temperature: Not determined
Decomposition temperature: Not determined
Viscosity: Not determined
Explosive properties: Not explosive.
Oxidising properties: Not oxidising.

9.2 Other information

Surface tension (N/m): Not determined
Corrosion to metals
(according to IMDG/ADR regulation): Not determined

Substance data, dissociation constant, if available:

SECTION 10: Stability and reactivity

10.1 Reactivity

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No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability

Stable under normal storage and use conditions.

10.3 Possibility of hazardous reactions

No hazardous reactions known under normal storage and use conditions.

10.4 Conditions to avoid

None known under normal storage and use conditions.

10.5 Incompatible materials

Reacts with acids.

10.6 Hazardous decomposition products

None known under normal storage and use conditions.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Mixtures
No test data is available on the mixture

Substance data, where relevant and available, are listed below.

Acute toxicity
Acute oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure
(mg/kg) time (h)
alkyl alcohol ethoxylate No data
available

Acute dermal toxicity

Ingredient(s) Endpoint Value Species Method Exposure
(mg/kg) time (h)
alkyl alcohol ethoxylate No data
available

Acute inhalative toxicity

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate No data
available

Irritation and corrosivity

Skin irritation and corrosivity
Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate No data available

Eye irritation and corrosivity

Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate No data available

Respiratory tract irritation and corrosivity

Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate No data available

Sensitisation
Sensitisation by skin contact
Ingredient(s) Result Species Method Exposure time (h)
alkyl alcohol ethoxylate No data available

Sensitisation by inhalation
Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate No data available

Repeated dose toxicity

Sub-acute or sub-chronic oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
alkyl alcohol ethoxylate No data
available

Sub-chronic dermal toxicity

Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected

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alkyl alcohol ethoxylate No data

available

Sub-chronic inhalation toxicity

Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
alkyl alcohol ethoxylate No data
available

Chronic toxicity
Ingredient(s) Exposure Endpoint Value Species Method Exposure Specific effects and Remark
route (mg/kg bw/d) time organs affected
alkyl alcohol ethoxylate No data
available

CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)

Mixture data:
Based on available data, the classification criteria are not met.

Substance data, where relevant and available:

Carcinogenicity
Ingredient(s) Effect
alkyl alcohol ethoxylate No data available

Mutagenicity
Ingredient(s) Result (in-vitro) Method Result (in-vivo) Method
(in-vitro) (in-vivo)
alkyl alcohol ethoxylate No data available No data available

Toxicity for reproduction

Ingredient(s) Endpoint Specific effect Value Species Method Exposure Remarks and other effects
(mg/kg bw/d) time reported
alkyl alcohol ethoxylate No data
available

Potential adverse health effects and symptoms

Effects and symptoms related to the product, if any, are listed in subsection 4.2.

SECTION 12: Ecological information

12.1 Toxicity
Mixtures
No test data is available on the mixture.

Substance data, where relevant and available, are listed below

Aquatic short-term toxicity

Aquatic short-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate No data
available

Aquatic short-term toxicity - crustacea

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate No data
available

Aquatic short-term toxicity - algae

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate No data
available

Aquatic short-term toxicity - marine species

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (days)
alkyl alcohol ethoxylate No data
available

Impact on sewage plants - toxicity to bacteria

Ingredient(s) Endpoint Value Inoculum Method Exposure
(mg/l) time
alkyl alcohol ethoxylate No data
available

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Aquatic long-term toxicity

Aquatic long-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
alkyl alcohol ethoxylate No data
available

Aquatic long-term toxicity - crustacea

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
alkyl alcohol ethoxylate No data
available

Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available:
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
sediment)
alkyl alcohol ethoxylate No data
available

Terrestrial toxicity
Terrestrial toxicity - soil invertebrates, including earthworms, if available:

Terrestrial toxicity - plants, if available:

Terrestrial toxicity - birds, if available:

Terrestrial toxicity - beneficial insects, if available:

Terrestrial toxicity - soil bacteria, if available:

12.2 Persistence and degradability

Abiotic degradation
Abiotic degradation - photodegradation in air, if available:

Abiotic degradation - hydrolysis, if available:

Abiotic degradation - other processes, if available:

Biodegradation
Ready biodegradability - aerobic conditions
Ingredient(s) Inoculum Analytical DT 50 Method Evaluation
method
alkyl alcohol ethoxylate No data available

Ready biodegradability - anaerobic and marine conditions, if available:

Degradation in relevant environmental compartments, if available:

The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.
648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be
made available to them, at their direct request or at the request of a detergent manufacturer.

12.3 Bioaccumulative potential

Partition coefficient n-octanol/water (log Kow)
Ingredient(s) Value Method Evaluation Remark
alkyl alcohol ethoxylate No data available

Bioconcentration factor (BCF)

Ingredient(s) Value Species Method Evaluation Remark
alkyl alcohol ethoxylate No data available

12.4 Mobility in soil

Adsorption/Desorption to soil or sediment
Ingredient(s) Adsorption Desorption Method Soil/sediment Evaluation
coefficient coefficient type
Log Koc Log Koc(des)
alkyl alcohol ethoxylate No data available

12.5 Results of PBT and vPvB assessment

Substances that fulfill the criteria for PBT/vPvB, if any, are listed in section 3.

12.6 Other adverse effects

No other adverse effects known.

SECTION 13: Disposal considerations

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13.1 Waste treatment methods

Waste from residues / unused The concentrated contents or contaminated packaging should be disposed of by a certified handler
products: or according to the site permit. Release of waste to sewers is discouraged. The cleaned packaging
material is suitable for energy recovery or recycling in line with local legislation.
European Waste Catalogue: 20 01 30 - detergents other than those mentioned in 20 01 29.

Empty packaging
Recommendation: Dispose of observing national or local regulations.
Suitable cleaning agents: Water, if necessary with cleaning agent.

SECTION 14: Transport information

ADR, RID, ADN, IMO/IMDG, ICAO/IATA

14.1 UN number: Non-dangerous goods
14.2 UN proper shipping name: Non-dangerous goods
14.3 Transport hazard class(es): Non-dangerous goods
Class: -
14.4 Packing group: Non-dangerous goods
14.5 Environmental hazards: Non-dangerous goods
14.6 Special precautions for user: Non-dangerous goods
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: The product is not transported in bulk tankers.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Authorisations or restrictions (Regulation (EC) No 1907/2006, Title VII respectively Title VIII): Not applicable.

Ingredients according to EC Detergents Regulation 648/2004

non-ionic surfactants < 5%
perfumes, Hexyl Cinnamal, Citral, Limonene

15.2 Chemical safety assessment

A chemical safety assessment has not been carried out on the mixture

SECTION 16: Other information

The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product
features and does not establish a legally binding contract

MSDS code: MSDS4491 Version: 05 Revision: 2014-02-06

Reason for revision:

Overall design adjusted in accordance with Regulation (EC) No 1907/2006, Annex II

Full text of the R, H and EUH phrases mentioned in section 3:

•R41-Riskofser
iousdamaget oey
es.
•R22-Harmfuli
fswallowed.
•H302-Harmfuli
fswal l
owed.
•H318-Causesseriouseyedamage.

Abbreviations and acronyms:

•AISE-TheinternationalAs soci
ationforSoaps,Deter
gentsandMaint
enancePr
oduct
s
•DNEL-DerivedNoEf f
ec tLimit
•EUH-CLPSpec i
fi
chaz ar ds t
atement
•PBT-Persi
stent,Bioac cumul at
iveandTox ic
•PNEC-Predic t
edNoEf fec tConc ent
rati
on
•REACHnumber-REACHr egistr
ati
onnumber ,wi
thoutsuppl
i
erspeci
fi
cpar
t
•vPvB-ver
yPer s i
stentandver yBioaccumulat
ive

End of Safety Data Sheet

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